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At least 19 records

Mass and power estimates for Mars in-situ propellant production systems

An in-situ propellant production (ISPP) concept, a method for producing oxygen from carbon dioxide in the Martian atmosphere, is evaluated. The concept considered here employs zirconia membrane technology to separate O2 from CO2. Several options which can improve the reliability of the CO2/O2 ISPP system and also reduce the mass and power requirements are examined, and it is noted that the use of absorption pumps and advanced zirconia membranes significantly improves system reliability by eliminating the rotating turbomachinery of mechanical pumps. Mass and power requirements of ISPP systems designed to produce O2 only from CO2 (for an unmanned Mars mission) and to produce both CO and O2 from CO2 (for a manned Mars mission) are evaluated.

Frisbee, R. H.

Cooling of in-situ propellant rocket engines for Mars mission

One propulsion option of a Mars ascent/descent vehicle is multiple high-pressure, pump-fed rocket engines using in-situ propellants, which have been derived from substances available on the Martian surface. The chosen in-situ propellant combination for this analysis is carbon monoxide as the fuel and oxygen as the oxidizer. Both could be extracted from carbon dioxide, which makes up 96 percent of the Martian atmosphere. A pump-fed rocket engine allows for higher chamber pressure than a pressure-fed engine, which in turn results in higher thrust and in higher heat flux in the combustion chamber. The heat flowing through the wall cannot be sufficiently dissipated by radiation cooling and, therefore, a regenerative coolant may be necessary to avoid melting the rocket engine. The two possible fluids for this coolant scheme, carbon monoxide and oxygen, are compared analytically. To determine their heat transfer capability, they are evaluated based upon their heat transfer and fluid flow characteristics.

Armstrong, Elizabeth S.

In-situ propellant rocket engines for Mars mission ascent vehicle

When comtemplating the human exploration of Mars, many scenarios using various propulsion systems have been considered. One propulsion option among them is a vehicle stage with multiple, pump fed rocket engines capable of operating on propellants available on Mars. This reduces the Earth launch mass requirements, resulting in economic and payload benefits. No plentiful sources of hydrogen on Mars have been identified on the surface of Mars, so most commonly used high performance liquid fuels, such as hydrogen and hydrocarbons, can be eliminated as possible in-situ propellants. But 95 pct. of the Martian atmosphere consists of carbon dioxide, which can be converted into carbon monoxide and oxygen. The carbon monoxide oxygen propellant conbination is a candidate for a Martian in-situ propellant rocket engine. The feasibility is analyzed of a pump fed engine cycle using the propellant combination of carbon monoxide and oxygen.

Roncace, Elizabeth A.

In-situ propellant advantages for fast transfer to Mars

The advantages of in situ propellant for a fast transfer to Mars were studied as compared to all earth-based propellants and other options for reduction of total masss in low earth orbit. For a 10-year, 10-mission model and a baseline vehicle taken from the literature, the total reduction in number of earth launches was calculated. The scenario in which the return propellants are transferred to Mars on a slow cargo vehicle provides a 29-percent reduction in ALS launches over the baseline scenario in which all propellants are brought directly from earth. The scenarios in which in situ propellants are used for a successively greater portion of the total mission continue to reduce the number of launches required. With Mars propellant used for the Mars ascent vehicle and the return leg of the mission, a 59-percent reduction in launches is obtained. Finally, if the oxygen, or oxygen and fuel, for the outbound leg of the mission is also obtained by in situ production, from the moon for example, then the total reduction in number of earth launches is more than 80 percent.

Galecki, Diane L.

In-situ propellant rocket engines for Mars missions ascent vehicle

When contemplating the human exploration of Mars, many scenarios using various propulsion systems have been considered. One propulsion option among them is a vehicle stage with multiple, pump fed rocket engines capable of operating on propellants available on Mars. This reduces the earth launch mass requirements, resulting in economic and payload benefits. No plentiful sources of hydrogen on Mars have been identified on the surface of Mars, so most commonly used high performance liquid fuels, such as hydrogen and hydrocarbons, can be eliminated as possible in situ propellants. But 95 pct of the Martian atmosphere consists of carbon dioxide, which can be converted into carbon monoxide and oxygen. The carbon monoxide oxygen propellant combination is a candidate for a Martian in situ propellant rocket engine. The feasibility is analyzed of a pump fed engine cycle using the propellant combination of carbon monoxide and oxygen.

Roncace, Elizabeth A.

Mission and transportation systems uses of in-situ derived propellants

The uses of in-situ derived propellants are discussed for lunar and Mars transportation systems and the impact on mission architectures. Transportation systems include surface rovers, ascent/descent vehicles and space transfer vehicles at both the Moon and Mars. A brief survey of available propellant types is included. A brief description of typical transportation systems proposed for use on the Moon and Mars is presented. Comparisons are made of overall mission parameters such as mass, costs, schedules and performance assuming the use of in-situ derived propellants versus Earth supplied propellants using 4 different mission scenarios to cover the range of missions being studied today.

Repic, ED

The ballistic Mars hopper - An alternative Mars mobility concept

The ballistic Mars hopper is proposed as an alternative mobility concept for unmanned exploration of the Martian surface. In the concept, oxygen and carbon monoxide produced from the Martian atmosphere are used as propellants in a rocket propulsion system for an unmanned vehicle on suborbital trajectories between landing sites separated by distances of up to 1000 km. This mobility concept is seen as uniquely capable of allowing both intensive and extensive exploration of the planet using only a single landed vehicle of mass approximately 2000 kg. The technical challenges associated with in-situ propellant production on the surface of Mars are reviewed. A rocket propulsion subsystem capable of using oxygen and carbon monoxide as propellants is described. Finally, results of mission analysis and a hopper landing hazard simulation are reported. It is concluded that an attractive Mars hopper can be developed based on relatively near-term technology.

Sercel, Joel C.

External perturbation-driven Sabatier breakthrough

The Sabatier reaction (CO 2 + 4H 2 → CH 4 + 2H 2 O) is gaining renewed interest due to its potential to reduce energy carrier storage costs, serve as a feedstock for various organic chemicals, and supply in-situ propellant and life-support resources for long-duration Mars missions. This study demonstrates that combining a modest 2 mA electric field with H 2 feed modulation markedly elevates the CO 2 hydrogenation activity of 2 wt% Ru/CeO 2 catalyst. CO 2 conversion reaches 88 % and 93 % with a CH 4 yield of 83 % and 89 % at 350 °C and 450 °C, respectively. A simple lumped kinetic model reveals that the combined external perturbations not only shift the reaction mechanism but also redistribute key surface-adsorbed intermediates such as hydrogen adatoms and hydrogen-activated CO 2 among the Ru clusters, Ru/CeO 2 interface, and ceria surface. The electric field accelerates the conversion of adsorbed CO 2 to the hydrogenated CO 2 species on Ru and boosts CH 4 formation rate constant, while simultaneously suppresses the formation of undesired, non-reactive surface intermediates. Degree-of-rate-control analysis pinpoints proton migration across the metal-support interface as the decisive lever under these coupled perturbations. In conclusion, these findings establish that rational pairing of metal-support design with well-tuned electric fields and feed oscillations can unlock unprecedented Sabatier rates, guiding the development of next-generation reactors for efficient CO 2 to CH 4 conversion.

10 - SYNTHETIC FUELS

Mars sample return mission options (1996-2005)

Missions to the surface of Mars, carrying a Rover and having a sample return capability, constitute another logical step in the exploration of that planet in the late 1990's. Results of a recent study are described. A comparison of viable mission options, involving: retropropulsion vs. aerobraking/aeromaneuvering, direct return vs. Mars orbit rendezous, as well as the future potential of 'in-situ propellant production', is presented. An overview of a variety of scenarios of unmanned expeditions to Mars and their subsequent return to earth, within the addressed time period, is provided.

Sergeyevsky, A. B.

Space R/T base: Propulsion (high thrust chemical)

The topics presented are covered in viewgraph form. The programmatic objective is to provide a technology base and maintain an institutional capability for continued advances in the development of advanced space propulsion systems to support launch, upper stage, orbit transfer and ascent/descent engines. The technical objectives are to study: (1) validated design and analytical codes for cryogenic turbopump bearings and seals; (2) design methodologies and diagnostic capabilities for combustion stability; and (3) reduced operations cost, increase life, safety, higher energy density propellants, and in-situ engine concepts.

Gorland, S.

Prototype Demonstration of Solar-Carbothermal System to Extract Oxygen From Regolith

The Carbothermal Reduction Demonstration (CaRD) project was an effort to develop a prototype system to demonstrate the extraction of oxygen from simulated lunar regolith using concentrated solar energy and a carbothermal reaction. The prototype consisted of a deployable solar concentrator capable of tracking the sun, carbothermal reactor, fluid system, gas analysis, and a solar concentrator control system consisting of avionics and software. These subsystems were developed by multiple NASA centers and a private industry partner, Sierra Space. The various teams worked together to define requirements and interfaces to successfully assemble the complex system and demonstrate an integrated solar carbothermal process. The solar concentrator developed at Glenn Research Center (GRC) was designed to be stowed for a launch environment then deployed on the lunar surface. It utilized a crossed dragone configuration of composite mirrors to direct horizontal sunlight onto a target 90° from the incoming sunlight. The key performance parameters for the solar concentrator were efficiency and power density. The carbothermal reactor was developed by Sierra Space through a separate project called the Carbothermal Oxygen Production Reactor (COPR) where it successfully demonstrated a fully automated process in a thermal vacuum environment [1]. The fluid system needed for the carbothermal reaction was also developed by Sierra Space and successfully demonstrated in the same thermal vacuum test. The gas analysis system was developed at Kennedy Space Center (KSC) and was required to determine the amount of oxygen extracted during each test. The gas analysis system was based on the Mass Spectrometer Observing Lunar Operations (MSOLO) instrument. Avionics and software for the CaRD prototype were also developed at KSC and based on experience with MSOLO avionics and software. The control system was designed to stow, deploy, track the sun, and perform beam alignment of the concentrated light. The prototype subsystems were integrated and tested at Johnson Space Center’s (JSC) Energy Systems Test Area. A heliostat was used to direct sunlight toward the prototype in a way that is representative of the sunlight conditions at the south pole of the Moon. When concentrated sunlight was focused on simulated lunar regolith within the reactor, the gas analysis team confirmed the presence of carbon monoxide gas, which confirmed that a solar carbothermal reaction took place. The key performance parameter for the integrated prototype was grams of oxygen extracted per kilowatt hour of energy arriving at the concentrator primary mirror. The prototype design successfully demonstrated end-to-end capability and further steps to achieve a flight capable system have been defined. With lunar data, engineers would be able to design a scaled-up system capable of extracting oxygen from regolith at useful quantities for crew life support and rocket propellant. On the long term, this method of In-Situ Resource Utilization could be used to drastically reduce the cost and risk of a sustained human presence on the Moon by reducing the amount of oxygen that would have to be delivered.

Koorosh R Araghi

Prototype Demonstration of Solar Carbothermal System to Extract Oxygen from Regolith

The Carbothermal Reduction Demonstration (CaRD) project was an effort to develop a prototype system to demonstrate the extraction of oxygen from simulated lunar regolith using concentrated solar energy and a carbothermal reaction. The prototype consisted of a deployable solar concentrator capable of tracking the sun, carbothermal reactor, fluid system, gas analysis, and a solar concentrator control system consisting of avionics and software. These subsystems were developed by multiple NASA centers and a private industry partner, Sierra Space. The various teams worked together to define requirements and interfaces to successfully assemble the complex system and demonstrate an integrated solar carbothermal process. The solar concentrator developed at Glenn Research Center (GRC) was designed to be stowed for a launch environment then deployed on the lunar surface. It utilized a crossed dragone configuration of composite mirrors to direct horizontal sunlight onto a target 90° from the incoming sunlight. The key performance parameters for the solar concentrator were efficiency and power density. The carbothermal reactor was developed by Sierra Space through a separate project called the Carbothermal Oxygen Production Reactor (COPR) where it successfully demonstrated a fully automated process in a thermal vacuum environment. The fluid system needed for the carbothermal reaction was also developed by Sierra Space and successfully demonstrated in the same thermal vacuum test. The gas analysis system was developed at Kennedy Space Center (KSC) and was required to determine the amount of oxygen extracted during each test. The gas analysis system was based on the Mass Spectrometer Observing Lunar Operations (MSOLO) instrument. Avionics and software for the CaRD prototype were also developed at KSC and based on experience with MSOLO avionics and software. The control system was designed to stow, deploy, track the sun, and perform beam alignment of the concentrated light. The prototype subsystems were integrated and tested at Johnson Space Center’s (JSC) Energy Systems Test Area. A heliostat was used to direct sunlight toward the prototype in a way that is representative of the sunlight conditions at the south pole of the Moon. When concentrated sunlight was focused on simulated lunar regolith within the reactor, the gas analysis team confirmed the presence of carbon monoxide gas, which confirmed that a solar carbothermal reaction took place. The key performance parameter for the integrated prototype was grams of oxygen extracted per kilowatt hour of energy arriving at the concentrator primary mirror. The prototype design successfully demonstrated end-to-end capability and further steps to achieve a flight capable system have been defined. With lunar data, engineers would be able to design a scaled-up system capable of extracting oxygen from regolith at useful quantities for crew life support and rocket propellant. On the long term, this method of In-Situ Resource Utilization could be used to drastically reduce the cost and risk of a sustained human presence on the Moon by reducing the amount of oxygen that would have to be delivered.

Aaron Paz

Prototype Demonstration of an Integrated Solar Concentrator System and Carbothermal Reactor Using Solar Energy to Extract Oxygen from Regolith

The Carbothermal Reduction Demonstration (CaRD) project was an effort to develop a prototype system to demonstrate the extraction of oxygen from simulated lunar regolith using concentrated solar energy and a carbothermal reaction. The prototype consisted of a deployable solar concentrator capable of tracking the sun, carbothermal reactor, fluid system, gas analysis, and a solar concentrator control system consisting of avionics and software. These subsystems were developed by multiple NASA centers and a private industry partner, Sierra Space. The various teams worked together to define requirements and interfaces to successfully assemble the complex system and demonstrate an integrated solar carbothermal process. The solar concentrator developed at Glenn Research Center (GRC) was designed to be stowed for a launch environment then deployed on the lunar surface. It utilized a crossed dragone configuration of composite mirrors to direct horizontal sunlight onto a target 90° from the incoming sunlight. The key performance parameters for the solar concentrator were efficiency and power density. The carbothermal reactor was developed by Sierra Space through a separate project called the Carbothermal Oxygen Production Reactor (COPR) where it successfully demonstrated a fully automated process in a thermal vacuum environment. The fluid system needed for the carbothermal reaction was also developed by Sierra Space and successfully demonstrated in the same thermal vacuum test. The gas analysis system was developed at Kennedy Space Center (KSC) and was required to determine the amount of oxygen extracted during each test. The gas analysis system was based on the Mass Spectrometer Observing Lunar Operations (MSOLO) instrument. Avionics and software for the CaRD prototype were also developed at KSC and based on experience with MSOLO avionics and software. The control system was designed to stow, deploy, track the sun, and perform beam alignment of the concentrated light. The prototype subsystems were integrated and tested at Johnson Space Center’s (JSC) Energy Systems Test Area. A heliostat was used to direct sunlight toward the prototype in a way that is representative of the sunlight conditions at the south pole of the Moon. When concentrated sunlight was focused on simulated lunar regolith within the reactor, the gas analysis team confirmed the presence of carbon monoxide gas, which confirmed that a solar carbothermal reaction took place. The key performance parameter for the integrated prototype was grams of oxygen extracted per kilowatt hour of energy arriving at the concentrator primary mirror. The prototype design successfully demonstrated end-to-end capability and further steps to achieve a flight capable system have been defined. With lunar data, engineers would be able to design a scaled-up system capable of extracting oxygen from regolith at useful quantities for crew life support and rocket propellant. On the long term, this method of In-Situ Resource Utilization could be used to drastically reduce the cost and risk of a sustained human presence on the Moon by reducing the amount of oxygen that would have to be delivered.

Oxygen from Regolith

Oxygen plant breadboard design, and techniques for improving mission figure-of-merit

A breadboard oxygen plant to process anaerobic carbon dioxide is designed and constructed; the objective is not only to produce a key propellant component extraterrestrially, but also to develop the important technologies that are necessary for a successful operation of in-situ materials utilization hardware. The solid electrolytic cells are supplied to specifications by an established vendor. The cell thermal control, electrical control, and flow control are installed after detailed designs. Extensive data are obtained that characterize the operation of the plant as the input parameters are varied. The initial mass, energy, and volume-needs provide the input to a figure-of-merit software program to calculate the impact of various candidate technologies upon the overall mission. The desirability of studies on storage and high-density propellants is shown. This task dovetails into other tasks that are evaluating alternative cell materials, catalysis for compactness, and smart sensors for effective control.

Ramohalli, Kumar

Electrodeposition applications for the Space Shuttle Main Engine

Electrodeposition processes play a key role in the fabrication and in-service performance of the Space Shuttle Main Engine. Applications range from the electroforming of the main combustion chamber to the deposition of high-purity copper or gold for hydrogen embrittlement protection of susceptible materials of construction, or nickel for mechanical protection of foam insulated propellant ducts. Techniques for controlling electrolyte purity, verification of deposit integrity, and deposit profile and thickness are reported. The use of in-situ techniques (cell-plating) for localized plating and repair of damaged substrate materials are summarized.

Otousa, J. E.

A study to identify and compare airborne systems for in-situ measurements of launch vehicle effluents

An in-situ system for monitoring the concentration of HCl, CO, CO2, and Al2O3 in the cloud of reaction products that form as a result of a launch of solid propellant launch vehicle is studied. A wide array of instrumentation and platforms are reviewed to yield the recommended system. An airborne system suited to monitoring pollution concentrations over urban areas for the purpose of calibrating remote sensors is then selected using a similar methodology to yield the optimal configuration.

Thomas, T. J.

Hydrotrope-enabled high concentration aqueous electrolytes for reversible and sustainable iron metal anodes

Iron metal-based energy storage devices hold great potential in stationary grid-scale sustainable energy due to the high theoretical specific capacity, ultralow cost, and abundance of iron. However, their practical deployment is limited by the poor reversibility of iron plating and stripping, as well as competitive hydrogen evolution. Here we introduce the concept of hydrotropy into iron electrolytes by developing an environmentally friendly and cost-effective high-concentration ferrous sulfate electrolyte using urea as a hydrotropic agent. The designed electrolyte increases the Coulombic efficiency of iron metal electrodes to approximately 96.5%, compared with ~84.6% for the dilute electrolyte. Molecular dynamics simulations and Raman spectroscopy illustrate that urea regulates the competitive coordination of anions and urea in the iron solvation sheath, while reconstructing the hydrogen-bond network in free water molecules. This reduces the activity of both solvated and free water, thereby alleviating hydrogen evolution. Moreover, the coordinated anions and urea molecules facilitate the in-situ formation of an organic-inorganic hybrid protective layer on the metallic iron, establishing a physical barrier against water and promoting homogeneous interfacial reactions. This work demonstrates an appealing opportunity to design cost-effective and high-performance electrolytes and propels the practical application of iron metal-based energy storage devices.

Feng, Guangxia [Stanford Univ., CA (United States)

The Future of in-Situ Sequencing-Based Microbial Monitoring: Development of a Shelf-Stable Method for Artemis and Beyond

Microbial monitoring onboard the International Space Station (ISS) is essential for assessing the efficiency of the Environmental Control and Life Support Systems (ECLSS) and providing insight into potential risk to both crew and spacecraft. Historically, this monitoring required the need to culture organisms onboard, return these cultures to Earth, and then complete the identifications, a process that would take months. Over the past decade, and through numerous payloads, advances in molecular biology have enabled in-flight microbial identifications using nanopore sequencing. The swab-to-sequencer method resulting from these efforts was transitioned from research to operations for microbial monitoring under the Crew Health Care Systems (CHeCS) BioMole. Collectively, these accomplishments have propelled the swab-to-sequencer method to be selected as the Microbial Surface Monitor (MSM) for Gateway, as well as a payload on Artemis IV. However, the lack of cold stowage availability for Artemis requires modifications to the entire method due to the thermal instability of the reagents required for sample preparation. To achieve this, new development, optimization, and validations were undertaken. Key considerations included enzyme concentration, buffer compatibility, and equal or enhanced sensitivity and specificity. At each step, thorough side-by-side comparisons with the current ISS method were performed. The development of a robust shelf-stable method will ensure continued sequencing-based microbial monitoring for Artemis and beyond, providing data in near real-time, enhancing risk response time, and yielding clear insight into the microbiome of spacecraft.

Christian G Mena