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A New Approach to Measure Contact Angle and Evaporation Rate with Flow Visualization in a Sessile Drop

The contact angle and the spreading process of sessile droplet are very crucial in many technological processes, such as painting and coating, material processing, film-cooling applications, lubrication, and boiling. Additionally, as it is well known that the surface free energy of polymers cannot be directly, measured for their elastic and viscous restraints. The measurements of liquid contact angle on the polymer surfaces become extremely important to evaluate the surface free energy of polymers through indirect methods linked with the contact angle data. Due to the occurrence of liquid evaporation is inevitable, the effects of evaporation on the contact angle and the spreading become very important for more complete understanding of these processes. It is of interest to note that evaporation can induce Marangoni-Benard convection in sessile drops. However, the impacts of the inside convection on the wetting and spreading processes are not clear. The experimental methods used by previous investigators cannot simultaneously measure the spreading process and visualize the convection inside. Based on the laser shadowgraphic system used by the present author, a very simple optical procedure has been developed to measure the contact angle, the spreading speed, the evaporation rate, and to visualize inside convection of a sessile drop simultaneously. Two CCD cameras were used to synchronously record the real-time diameter of the sessile drop, which is essential for determination of both spreading speed and evaporation rate, and the shadowgraphic image magnified by the sessile drop acting as a thin plano-convex lens. From the shadowgraph, the inside convection of the drop can be observed if any and the image outer diameter, which linked to the drop profile, can be measured. Simple equations have been derived to calculate the drop profile, including the instantaneous contact angle, height, and volume of the sessile drop, as well as the evaporation rate. The influence of the inside convection on the wetting and spreading processes can be figured out through comparison of the drop profiles with and without inside convection when the sessile drop is placed at different evaporation conditions.

Zhang, Nengli↗

Modeling the Influences of Aerosols on Pre-Monsoon Circulation and Rainfall over Southeast Asia

We conduct several sets of simulations with a version of NASA's Goddard Earth Observing System, version 5, (GEOS-5) Atmospheric Global Climate Model (AGCM) equipped with a two-moment cloud microphysical scheme to understand the role of biomass burning aerosol (BBA) emissions in Southeast Asia (SEA) in the pre-monsoon period of February-May. Our experiments are designed so that both direct and indirect aerosol effects can be evaluated. For climatologically prescribed monthly sea surface temperatures, we conduct sets of model integrations with and without biomass burning emissions in the area of peak burning activity, and with direct aerosol radiative effects either active or inactive. Taking appropriate differences between AGCM experiment sets, we find that BBA affects liquid clouds in statistically significantly ways, increasing cloud droplet number concentrations, decreasing droplet effective radii (i.e., a classic aerosol indirect effect), and locally suppressing precipitation due to a deceleration of the autoconversion process, with the latter effect apparently also leading to cloud condensate increases. Geographical re-arrangements of precipitation patterns, with precipitation increases downwind of aerosol sources are also seen, most likely because of advection of weakly precipitating cloud fields. Somewhat unexpectedly, the change in cloud radiative effect (cloud forcing) at surface is in the direction of lesser cooling because of decreases in cloud fraction. Overall, however, because of direct radiative effect contributions, aerosols exert a net negative forcing at both the top of the atmosphere and, perhaps most importantly, the surface, where decreased evaporation triggers feedbacks that further reduce precipitation. Invoking the approximation that direct and indirect aerosol effects are additive, we estimate that the overall precipitation reduction is about 40% due to the direct effects of absorbing aerosols, which stabilize the atmosphere and reduce surface latent heat fluxes via cooler land surface temperatures. Further refinements of our two-moment cloud microphysics scheme are needed for a more complete examination of the role of aerosol-convection interactions in the seasonal development of the SEA monsoon.

SE Asia Monsoon↗

Fast infrared response of YBCO thin films

The response to short infrared pulses of some epitaxial YBCO films prepared by sputter deposition and by electron-beam evaporation is reported. The response is found to be essentially bolometric on the ns timescale, with some indirect hints of nonequilibrium electron transport on the ps scale. Fast switching could be obtained either by biasing the switch close to the critical current or by cooling the film below about 20 K. These results are encouraging for potential application to a high-current optically-triggered opening switch.

Ballentine, P. H.↗

Possible Influences of Air Pollution, Dust and Sandstorms on the Indian Monsoon

In Asian monsoon countries, such as China and India, human health and safety problems caused by air pollution are becoming increasingly serious, due to the increased loading of atmospheric pollutants from waste gas emissions and from rising energy demand associated with the rapid pace of industrialization and modernization. Meanwhile, uneven distribution of monsoon rain associated with flash floods or prolonged drought, has caused major loss of human life and damage to crops and.property with devastating societal impacts. Historically, air-pollution and monsoons research are treated as separate problems. However recent studies have suggested that the two problems may be intrinsically linked and need to be studied jointly. Fundamentally, aerosols can affect precipitation through radiative effects cif suspended particles in the atmosphere (direct effect) and/or by interfering and changing: the cloud and precipitation formation processes (indirect effect). Based on their optical properties, aerosols can be classified into two types.: those that absorb solar radiation, and those that do not. Both types of aerosols scatter sunlight and reduce the amount of solar radiation from reaching the Earth's surface, causing it to cool. The surface cooling increases atmospheric stability and reduces convection potential, Absorbing aerosols, however, in addition to cooling the surface, can heat the atmosphere. The heating of the atmosphere may reduce the amount of low clouds by increased evaporation in cloud drops. The heating, however, may induce rising motion, enhance low-level moisture, convergence and, hence, increases rainfall, The latent heating from enhanced rainfall may excite feedback processes in the large-scale circulation, further amplify.the initial response to aerosol heating and producing more rain. Additionally, aerosols can increase the concentration of cloud condensation nuclei (CCN), increase cloud amount and decrease coalescence and collision rates, leading to reduced precipitation. However, in the presence of increasing moist and warm air, the reduced coalescence/collision may lead to supercooled drops at higher altitudes where ice precipitation falls and melts. The latent heat release from freezing aloft and melting below implies greater upward heat transport in polluted clouds and invigorate deep convection. In this way, aerosols may lead to increased local convection. Hence, depending on the ambient large-scale conditions and dynamical feedback processes, aerosols' effect on precipitation can be positive, negative or mixed. In the Asian monsoon and adjacent regions, the aerosol forcing and responses of the water cycle are even more complex, Both direct and indirect effects may take place locally and simultaneously, interacting with each other. in addition to local effects, monsoon rainfall may be affected by aerosols transported from other regions and intensified through large-scale circulation and moisture feedback. Thus, dust transported by the large-scale circulation from the adjacent deserts to northern India may affect rainfall over the Bay of Bengal; sulphate and black carbon front industrial pollution in central, southern China and northern India may affect the rainfall regime over the Korean peninsula and Japan; organic and black carbon front biomass burning from Indo-China may modulate the pre-monsoon rainfall regime over southern China and coastal regions, contributing to variability in differential heating and cooling of the atmosphere and to the land-sea thermal contrast. During the pre-monsoon season and monsoon breaks, it has been suggested that radiative forcing by absorbing aerosols have nearly the same order of magnitude as the forcing due to latent heating from convection and surface fluxes. The magnitude of the total aerosol radiative cooling due to sulphates and soot is of the order of 20-40 W/m2 over the Asian monsoon land region in the pre-monsoon season, compared to about 1-2 W/m2 for global warng. However, the combined forcing at the surface and in the atmosphere, including all species. if aerosols, and details of aerosol mixing, and impacts on the energy and water cycles in the monsoon land regions, are not well known.

Lau, William K. M.↗

Radiative Importance of Aerosol-Cloud Interaction

Aerosol particles are input into the troposphere by biomass burning, among other sources. These aerosol palls cover large expanses of the earth's surface. Aerosols may directly scatter solar radiation back to space, thus increasing the earth's albedo and act to cool the earth's surface and atmosphere. Aerosols also contribute to the earth's energy balance indirectly. Hygroscopic aerosol act as cloud condensation nuclei (CCN) and thus affects cloud properties. In 1977, Twomey theorized that additional available CCN would create smaller but more numerous cloud droplets in a cloud with a given amount of liquid water. This in turn would increase the cloud albedo which would scatter additional radiation back to space and create a similar cooling pattern as the direct aerosol effect. Estimates of the magnitude of the aerosol indirect effect on a global scale range from 0.0 to -4.8 W/sq m. Thus the indirect effect can be of comparable magnitude and opposite in sign to the estimates of global greenhouse gas forcing Aerosol-cloud interaction is not a one-way process. Just as aerosols have an influence on clouds through the cloud microphysics, clouds have an influence on aerosols. Cloud droplets are solutions of liquid water and CCN, now dissolved. When the cloud droplet evaporates it leaves behind an aerosol particle. This new particle does not have to have the same properties as the original CCN. In fact, studies show that aerosol particles that result from cloud processing are larger in size than the original CCN. Optical properties of aerosol particles are dependent on the size of the particles. Larger particles have a smaller backscattering fraction, and thus less incoming solar radiation will be backscattered to space if the aerosol particles are larger. Therefore, we see that aerosols and clouds modify each other to influence the radiative balance of the earth. Understanding and quantifying the spatial and seasonal patterns of the aerosol indirect forcing may have even greater consequences. Presently we know that through the use of fossil fuel and land-use changes we have increased the concentration of greenhouse gases in the atmosphere. In parallel, we have seen a modest increase of global temperature in the last century. These two observations have been linked as cause and effect by climate models, but this connection is still experimentally not verified. The spatial and seasonal distribution of aerosol forcing is different from that of greenhouse gases, thus generating a different spatial fingerprint of climate change. This fingerprint was suggested as a method to identify the response of the climate system to anthropogenic forcing of greenhouse gases and aerosol. The aerosol fingerprint may be the only way to firmly establish the presence (or absence) of human impact on climate. Aerosol-cloud interaction through the indirect effect will be an important component of establishing this fingerprint.

Tsay, Si-Chee↗

The Role of Atmospheric Aerosol Concentration on Deep Convective Precipitation: Cloud-Resolving Model Simulations

Aerosols and especially their effect on clouds are one of the key components of the climate system and the hydrological cycle [Ramanathan et al., 2001]. Yet, the aerosol effect on clouds remains largely unknown and the processes involved not well understood. A recent report published by the National Academy of Science states "The greatest uncertainty about the aerosol climate forcing - indeed, the largest of all the uncertainties about global climate forcing - is probably the indirect effect of aerosols on clouds NRC [2001]." The aerosol effect on Clouds is often categorized into the traditional "first indirect (i.e., Twomey)" effect on the cloud droplet sizes for a constant liquid water path and the "semi-direct" effect on cloud coverage. The aerosol effect on precipitation processes, also known as the second type of aerosol indirect effect, is even more complex, especially for mixed-phase convective clouds. In this paper, a cloud-resolving model (CRM) with detailed spectral-bin microphysics was used to examine the effect of aerosols on three different deep convective cloud systems that developed in different geographic locations: South Florida, Oklahoma and the Central Pacific, In all three cases, rain reaches the ground earlier for the low CCN (clean) case. Rain suppression is also evident in all three cases with high CCN (dirty) case. However, this suppression only occurs during the first hour of the simulations. During the mature stages of the simulations, the effects of increasing aerosol concentration range from rain suppression in the Oklahoma case, to almost no effect in the Florida case, to rain enhancement in the Pacific case. These results show the complexity of aerosol interactions with convection. The model results suggest that evaporative cooling is a key process in determining whether high CCN reduces or enhances precipitation. Stronger evaporative cooling can produce a stronger cold pool and thus stronger low-level convergence through interactions with the low-level wind shear. Consequently, precipitation processes can be more vigorous. For example,, the evaporative cooling is more than two times stronger in the lower troposphere with high CCN for the Pacific case. Sensitivity tests also suggest that ice processes are crucial for suppressing precipitation in the Oklahoma case with high CCN.

Tao, Wei-Kuo↗