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At least 19 records

Apparent Optical Properties in Waters Influenced by the Mississippi River

In-water downwelling irradiance (E(sub d)) and upwelling radiance (L(sub u)) were measured in coastal waters influenced by the Mississippi River at wavelengths corresponding to SeaWiFS spectral bands in April of 2000. Results of derived apparent optical properties (AOP's) such as spectral diffise attenuation coefficient for downwelling irradiance (K(sub d)) suggest that they are mainly influenced by phytoplankton chlorophyll. Large variations in chlorophyll concentrations (0.2 to greater than 10 mg per cubic meters) correspond to variations in K(sub d) at 443 nm ranging from about 0.1 to greater than 1.5 per meter. Attenuation values at 443 nm generally peaked (or were minimal at 555 nm) at depths where chlorophyll concentrations were high. Above water remote sensing reflectance R(sub rs) (443) derived from E(sub d) and L(sub u) shows good agreement to surface chlorophyll. Ratios of remote sensing reflectance, R(sub rs)(443/R(sub rs)(555)versus chlorophyll suggests a potential for obtaining a suitable bio-optical algorithm for the region influenced by the Mississippi River.

D'Sa, E.↗

Mapping CDOM Concentration in Waters Influenced by the Mississippi River Plume

Colored dissolved organic matter (CDOM) is often an important component of the organic carbon pool in river-dominated coastal margins. CDOM directly influences remote sensing applications through its strong absorption in the UV and blue regions of the spectrum. This effect can complicate the use of chlorophyll a retrieval algorithms and phytoplankton production models that are based on remotely sensed ocean color. As freshwater input is the principle source of CDOM in coastal margins, CDOM distribution can often be described by conservative mixing with open ocean waters and may serve as an optical tracer of riverine water. Hence, there is considerable interest in the ability to accurately measure and map CDOM concentrations as well as understand the processes that govern the optical properties and distribution of CDOM in coastal environments. We are examining CDOM dynamics in the waters influenced by the Mississippi River plume. Our program incorporates discrete samples, flow-through measurements, and remote sensing. CDOM absorption spectra of discrete samples are measured at sea using a portable, multiple pathlength waveguide system. A SAFire multi-spectral fluorescence meter provides spectral characterization of CDOM (fluorescence and absorption) using a ship flow-through system for continuous surface mapping. In situ reflectance spectra are obtained by a hand held spectroradiometer. Remotely sensed images are obtained from the SeaWiFS and CRIS (Coastal Research Imaging Spectrometer) instruments. We describe here the instruments used, sampling protocols employed, and the relationships derived between in situ measurements and remotely sensed data for this optically complex environment.

Miller, Richard L.↗

Bio-Optical Properties and Ocean Color Algorithms for Coastal Waters Influenced by the Mississippi River During a Cold Front Passage

During the passage of a cold front in March 2002, bio-optical properties examined in coastal waters impacted by the Mississippi River indicated westward advective flows and increasing river discharge containing a larger nonalgal particle content contributed significantly to surface optical variability. A comparison of seasonal data from three cruises indicated spectral models of absorption and scattering to be generally consistent with other coastal environments, while their parameterization in terms of chlorophyll a concentration (Chl) showed seasonal variability. The exponential slope of the colored dissolved organic matter (CDOM) averaged 0.0161 plus or minus 0.00054 per nanometer, and for nonalgal absorption it averaged 0.011 per nanometer with deviations from general trends observed due to anomalous water properties. Although the phytoplankton specific absorption coefficients varied over a wide range (0.02 to 0.1 square meters (mg Chl) sup -1)) being higher in offshore surface waters, values of phytoplankton absorption spectra at the SeaWiFS wavebands were highly correlated to modeled values. The normalized scattering spectral shapes and the mean spectrum were in agreement to observations in other coastal waters, while the backscattering ratios were on average lower in phytoplankton dominated surface waters (0.0101 plus or minus 0.002) and higher in near-bottom waters (0.0191 plus or minus 0.0045) with low Chl. Average percent differences in remote sensing reflectance R (sub rs) derived form modeled and in-eater radiometric measurements were highest in the blue wavebands (52%) and at sampling stations with a ore stratified water column. Estimates of Chl and CDOM absorption derived from SeaWiFS images generated using regional empirical algorithms were highly correlated to in situ data.

D'Sa Eurico J.↗

Financial feasibility of water conservation in agriculture

Global water use for food production needs to be reduced to remain within planetary boundaries, yet the financial feasibility of crucial measures to reduce water use is poorly quantified. Here, we introduce a novel method to compare the costs of water conservation measures with the added value that reallocation of water savings might generate if used for expansion of irrigation. Based on detailed water accounting through the use of a high-resolution hydrology-crop model, we modify the traditional cost curve approach with an improved estimation of demand, increasing marginal cost per water conservation measure combination and add a correction to control for impacts on downstream water availability. We apply the method to three major river basins in the Indo-Gangetic plain (Indus, Ganges and Brahmaputra), a major global food producing region but increasingly water stressed. Our analysis shows that at basin level only about 10% (Brahmaputra) to just over 20% (Indus and Ganges) of potential water savings would be realised; the equilibrium price for water is too low to make the majority of water conservation measures cost effective. The associated expansion of irrigated area is moderate, about 7% in the Indus basin, 5% in the Ganges and negligible in the Brahmaputra, but farmers' gross profit increases more substantially, by 11%. Increasing the volumetric cost of irrigation water influences supply and demand in a similar way and has little influence on water reallocation. Controlling for the impact on return flows is important and more than halves the amount of water available for reallocation.

Geography / Land Utilization↗

A Moderate D/H Ratio for a Surficial Water Reservoir on Mars

Martian surface morphology implies that Mars was once warm enough to maintain persistent liquid water on its surface and that water played a significant role in the formation of weathered/altered terrains [e.g., 1, 2, 3]. Volatiles exhaled by volcanic activity would have been the dominant greenhouse gases and would have significantly affected the Martian climate. The enrichment of some volatile elements in the atmosphere, which would have dissolved in surface water, could also have influenced water chemistry (e.g., acidity) and played a significant role in weathering and aqueous alteration processes. While much of this picture is qualitative, Martian meteorites contain records of major Martian volatile reservoirs. This study characterizes Martian surficial volatile reservoirs based on in situ ion microprobe analyses of volatile abundances and H-isotopes of glassy phases (groundmass glass [GG] and impact melt [IM]) in Martian basalts (shergottites). Although these meteorites are of igneous origin, some glassy phases underwent impact-induced modification that trapped surficial and atmospheric volatile components [4, 5]; e.g., inert gases contained in IMs from EETA79001 (EETA79) match the relative abundances of modern Martian atmosphere [6]. Analyses of these glassy phases demonstrate that surficial volatile reservoirs have distinct D/H ratios from their magmatic volatiles.

Usui, Tomohiro↗

Influence of liquid water and water vapor on antimisting kerosene (AMK)

Experiments have been performed to evaluate the compatibility of liquid water and water vapor with antimisting kerosenes (AMK) containing polymer additive FM-9 developed by Imperial Chemical Industries. This effort consists of the determination of water solubility in AMK, influence of water on restoration (degradation) of AMK, and effect of water on standard AMK quality control methods. The principal conclusions of this investigation are: (1) the uptake of water in AMK critically depends upon the degree of agitation and can be as high as 1300 ppm at 20 C, (2) more than 250 to 300 ppm of water in AMK causes an insoluble second phase to form. The amount of this second phase depends on fuel temperature, agitation, degree of restoration (degradation) and the water content of the fuel, (3) laboratory scale experiments indicate precipitate formation when water vapor comes in contact with cold fuel surfaces at a much lower level of water (125 to 150 ppm), (4) precipitate formation is very pronounced in these experiments where humid air is percolated through a cold fuel (-20 C), (5) laboratory tests further indicate that water droplet settling time is markedly reduced in AMK as compared to jet A, (6) limited low temperature testing down to -30 C under laboratory conditions indicates the formation of stable, transparent gels.

Yavrouian, A. H.↗

A Novel Framework for Quantifying past Methane Recycling by Sphagnum-Methanotroph Symbiosis Using Carbon and Hydrogen Isotope Ratios of Leaf Wax Biomarkers

The concentration of atmospheric methane is strongly linked to variations in Earth's climate. Currently, we can directly reconstruct the total atmospheric concentration of methane, but not individual terms of the methane cycle. Northern wetlands, dominated by Sphagnum, are an important contributor of atmospheric methane, and we seek to understand the methane cycle in these systems. We present a novel method for quantifying the proportion of carbon Sphagnum assimilates from its methanotrophic symbionts using stable isotope ratios of leaf-wax biomarkers. Carbon isotope ratios of Sphagnum compounds are determined by two competing influences, water content and the isotope ratio of source carbon. We disentangled these effects using a combined hydrogen and carbon isotope approach. We constrained Sphagnum water content using the contrast between the hydrogen isotope ratios of Sphagnum and vascular plant biomarkers. We then used Sphagnum water content to calculate the carbon isotope ratio of Sphagnum's carbon pool. Using a mass balance equation, we calculated the proportion of recycled methane contributed to the Sphagnum carbon pool, 'PRM.' We quantified PRM in peat monoliths from three microhabitats in the Mer Bleue peatland complex. Modern studies have shown that water table depth and vegetation have strong influences on the peatland methane cycle on instrumental time scales. With this new approach, delta C-13 of Sphagnum compounds are now a useful tool for investigating the relationships among hydrology, vegetation, and methanotrophy in Sphagnum peatlands over the time scales of entire peatland sediment records, vital to our understanding of the global carbon cycle through the Late Glacial and Holocene.

air pollution↗

Microbiological concerns and methodological approaches related to bacterial water quality in spaceflight

A number of microbiological issues are of critical importance to crew health and system performance in spacecraft water systems. This presentation reviews an army of these concerns which include factors that influence water treatment and disinfection in spaceflight such as biofilm formation and the physiological responses of bacteria in clean water systems. Factors associated with spaceflight like aerosol formation under conditions of microgravity are also discussed within the context of airborne infections such as Legionellosis. Finally, a spectrum of analytical approaches is reviewed to provide an evaluation of methodological alternatives that have been suggested or used to detect microorganisms of interest in water systems. These range from classical approaches employing colony formation on specific microbiological growth media to direct (i.e. microscopic) and indirect (e.g. electrochemical) methods as well as the use of molecular approaches and gene probes. These techniques are critically evaluated for their potential utility in determining microbiological water quality through the detection of microorganisms under the influence of ambient environmental stress inherent in spaceflight water systems.

Pyle, Barry H.↗

Water permeation and electrical properties of pottants, backings, and pottant/backing composites

It is reported that the interface between plastic film back covers and ethylene vinyl acetates (EVA) or polyvinyl butyral (PVB) in photovoltaic modules can influence water permeation, and electrial properties of the composites such as leakage current and dielectric constant. The interface can either be one of two dissimilar materials in physical contact with no intermixing, or the interface can constitute a thin zone which is an interphase of the two materials having a gradient composition from one material to the other. The former condition is described as a discrete interface. A discrete interface model was developed to predict water permeation, dielectric strength, and leakage current for EVA, ethylene methyl acrylate (EMA), and PVB coupled to Tedlar and mylar films. Experimental data was compared with predicted data.

Orehotsky, J.↗

Determining Trends in Impervious Cover for the Mobile Bay, AL Region for 1974-2008, Based on a Landsat Time Series

This presentation will discuss the development and use of Landsat-based impervious cover products in conjunction with land use land cover change products to assess multi-decadal urbanization across the Mobile Bay region at regional and watershed scales. This nationally important coastal region has undergone a variety of ephemeral and permanent land use land cover change since the mid-1970s, including gradual but consequential increases in urban surface cover. This urban sprawl corresponds with increased regional percent impervious cover. The region s coastal zone managers are concerned about the increasing percent impervious cover, since it can negatively influence water quality and is an important consideration for coastal conservation and restoration work. In response, we processed multi-temporal Landsat data to compute maps of percent impervious cover for multiple dates from 1974 through 2008, roughly at 5-year intervals. Each year of product was classified using one single date of leaf-on and leaf-off Landsat data in conjunction with Cubist software. We are assessing Landsat impervious cover product accuracy through comparisons to available reference data, including available NLCD impervious cover products from the USGS, raw Landsat data, plus higher spatial resolution aerial and satellite data. In particular, we are quantitatively comparing the 2008 Landsat impervious cover products to those from QuickBird 2.4-meter multispectral data. Initial visual comparisons with the QuickBird impervious cover product suggest that the 2008 Landsat product tends to underestimate impervious cover for high density urban areas and to overestimate impervious cover in established residential subdivisions mixed with forested cover. Landsat TM and ETM data appears to produce more accurate impervious cover products compared to those using lower resolution Landsat MSS data. Although imperfect, these Landsat impervious cover products have helped the Mobile Bay National Estuary Program visualize basic urbanization trends for multiple HUC-12 watersheds of concern to them and their constituents

Spruce, Joseph P.↗

Improved Hydrology over Peatlands in a Global Land Modeling System

Peatlands of the Northern Hemisphere represent an important carbon pool that mainly accumulated since the last ice age under permanently wet conditions in specific geological and climatic settings. The carbon balance of peatlands is closely coupled to water table dynamics. Consequently, the future carbon balance over peatlands is strongly dependent on how hydrology in peatlands will react to changing boundary conditions, e.g. due to climate change or regional water level drawdown of connected aquifers or streams. Global land surface modeling over organic-rich regions can provide valuable global-scale insights on where and how peatlands are in transition due to changing boundary conditions. However, the current global land surface models are not able to reproduce typical hydrological dynamics in peatlands well. We implemented specific structural and parametric changes to account for key hydrological characteristics of peatlands into NASA's GEOS-5 Catchment Land Surface Model (CLSM, Koster et al. 2000). The main modifications pertain to the modeling of partial inundation, and the definition of peatland-specific runoff and evapotranspiration schemes. We ran a set of simulations on a high performance cluster using different CLSM configurations and validated the results with a newly compiled global in-situ dataset of water table depths in peatlands. The results demonstrate that an update of soil hydraulic properties for peat soils alone does not improve the performance of CLSM over peatlands. However, structural model changes for peatlands are able to improve the skill metrics for water table depth. The validation results for the water table depth indicate a reduction of the bias from 2.5 to 0.2 m, and an improvement of the temporal correlation coefficient from 0.5 to 0.65, and from 0.4 to 0.55 for the anomalies. Our validation data set includes both bogs (rain-fed) and fens (ground and/or surface water influence) and reveals that the metrics improved less for fens. In addition, a comparison of evapotranspiration and soil moisture estimates over peatlands will be presented, albeit only with limited ground-based validation data. We will discuss strengths and weaknesses of the new model by focusing on time series of specific validation sites.

Bechtold, M.↗

Diverging Trends in Rain-on-Snow Over High Mountain Asia

Rain-on-snow (ROS) over snow-dominated regions such as High Mountain Asia (HMA) modulates snowmelt and runoff and is key contributor in influencing water availability and hazards (e.g., floods and landslides). We studied the trends in ROS in HMA over the past two decades from 2001 to 2018 using the land surface model Noah-MP driven by an ensemble precipitation data set. Our results show that changes in precipitation phase and rainfall are altering ROS. Because of the strong physical heterogeneity and atmospheric dynamics of HMA, ROS characteristics and trends are region-dependent and ROS occurs predominantly over the Indus, Ganges-Brahmaputra, and northwestern basins. In the Indus, ROS representing ∼5% of the annual precipitation and ∼20% of the annual snowmelt, has an increasing trend. This is contrary to the Ganges-Brahmaputra characterized by decreasing ROS trends, where it represents ∼11% of the annual precipitation and ∼60% of the annual snowmelt. In the northwestern basins, ROS has bidirectional trends due to elevation patterns and trends in rainfall, and it constitutes ∼5 to ∼10% of the annual precipitation. Increasing trends in ROS over Indus contribute to reducing the snowpack in late summer, with concerns of reduced water availability and increased groundwater exploitation. Similarly, because of its high amount and contribution to snowmelt, the decreasing ROS trends in the Ganges-Brahmaputra will have consequences of decreased recharge from the headwaters and exacerbated use of groundwater unless increasing trends in rainfall compensate for the decreasing snowmelt. These results provide new insights on ROS-driven changes in the hydrological cycle over HMA.

rain-on-snow↗

Cardiovascular response to apneic immersion in cool and warm water

The influence of prior exposure to cool water and the influence of lung volume on the responses to breath holding were examined. The bradycardia and vasoconstriction that occur during breath-hold diving in man are apparently the resultant of stimuli from apnea, relative expansion of the thorax, lung volume, esophageal pressure, face immersion, and thermal receptor stimulation. It is concluded that the bradycardia and vasoconstriction associated with breath holding during body immersion are not attenuated by a preexisting bradycardia and vasoconstriction due to cold.

Folinsbee, L.↗

Evaluating Observation Influence on Regional Water Budgets in Reanalyses

The assimilation of observations in reanalyses incurs the potential for the physical terms of budgets to be balanced by a term relating the fit of the observations relative to a forecast first guess analysis. This may indicate a limitation in the physical processes of the background model, or perhaps inconsistencies in the observing system and its assimilation. In the MERRA reanalysis, an area of long term moisture flux divergence over land has been identified over the Central United States. Here, we evaluate the water vapor budget in this region, taking advantage of two unique features of the MERRA diagnostic output; 1) a closed water budget that includes the analysis increment and 2) a gridded diagnostic output data set of the assimilated observations and their innovations (e.g. forecast departures). In the Central United States, an anomaly occurs where the analysis adds water to the region, while precipitation decreases and moisture flux divergence increases. This is related more to a change in the observing system than to a deficiency in the model physical processes. MERRAs Gridded Innovations and Observations (GIO) data narrow the observations that influence this feature to the ATOVS and Aqua satellites during the 06Z and 18Z analysis cycles. Observing system experiments further narrow the instruments that affect the anomalous feature to AMSUA (mainly window channels) and AIRS. This effort also shows the complexities of the observing system, and the reactions of the regional water budgets in reanalyses to the assimilated observations.

Atmospheric Reanalysis↗