Innovative Pathways Program Highlights
This fact sheet provides a brief synopsis of the 11 projects under DOE's Innovative Pathways Program.
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This fact sheet provides a brief synopsis of the 11 projects under DOE's Innovative Pathways Program.
Project Objectives: The focus for the entirety of the last quarter was on the completion of the pilot loan funding within our portfolio, and the closing out of our DOE-CAP Grant: “Innovative Pathways: Transforming Impact Investments to Working Capital for Early Stage Cleantech Companies.” The fourteenth quarter (Q14) of the program performance was also dedicated toward two main activities: the continued fundraising efforts for a formalized LACI debt fund, as well as finalization of the lending processes for pilot underwriting amongst the LACI Team and with Mission Driven Finance. This quarter marked key successes around the workflows of the DOE-CAP grant, specifically around fund capitalization efforts. Activities during the thirteenth quarter included: 1. Finalization of the DOE-CAP grant activities and work-flows; 2. Due diligence, underwriting and issuance of one (1) loan in Q1 2021 and three (3) in Q4 2020 for technology providers in grant-funded zero emissions mobility & community pilots, in partnership with LACI and local organizations, totaling ten (10) total loans; 3. Development of fundraising and marketing materials, and distribution to 30+ possible funding sources over the course of Q13 & Q14; and 4. Reinvigoration of conversations with Mission Driven Finance, the prospective underwriting partner for key activities and governance documents, and finalization of all loan processing activities once the fund is capitalized
This exploratory analysis characterizes the balance-of-system (BOS) cost reduction opportunity for small, commercial, medium, and large distributed wind systems. To do this, we used the National Renewable Energy Laboratory’s (NREL’s) Land-based Balance of System Systems Engineering (LandBOSSE) model (Eberle et al. 2019). This model calculates the capital expenditures (CapEx) associated with installation and the system components (e.g., foundation and electrical infrastructure) other than the rotor nacelle assembly and tower. Then, building on the cost reduction potential assessment, we provide a more qualitative evaluation of prospective technology innovation concepts that may enable realization of those cost reductions for distributed wind systems.
This article shows a study on an alternative pathway for the fabrication of a complete 1.3 GHz SRF cavity, aiming at improving production reliability, reducing the use of chemical polishing (EP or BCP) which is a costly and safety-critical step, and preserving surface quality after forming. Unlike the conventional pathway, the fabrication process is performed after polishing. This point is crucial as the used polishing technology could be applied only to flat geometries. The performed investigation demonstrates that damages during the fabrication process are considered minor, localized, and limited to the near-surface. Moreover, these studies confirm that the damaged layer (100-200 µm) is mainly caused by the rolling process, and not by the subsequent fabrication steps. A laser confocal microscope and SEM-EBSD technique were used to compare samples before and after forming. The preliminary results are discussed and presented in this paper.
This article shows a study on an alternative pathway for the fabrication of a complete 1.3 GHz SRF cavity, aiming at improving production reliability, reducing the use of chemical polishing (EP or BCP) which is a costly and safety-critical step, and preserving surface quality after forming. Unlike the conventional pathway, the fabrication process is performed after polishing. This point is crucial as the used polishing technology could be applied only to flat geometries. The performed investigation demonstrates that damages during the fabrication process are considered minor, localized, and limited to the near-surface. Moreover, these studies confirm that the damaged layer (100-200 µm) is mainly caused by the rolling process, and not by the subsequent fabrication steps. A laser confocal microscope and SEM-EBSD technique were used to compare samples before and after forming. The preliminary results are discussed and presented in this paper.
Through Net Zero World, the National Renewable Energy Laboratory (NREL), the National Energy Secretariat of Argentina, La Pampa's Energy and Mining Secretariat, Pampetrol, and the Administracion Provincial de Energia de La Pampa (APELP) conducted an integrated analysis of the power system of the La Pampa province in Argentina. The study assessed the impact that solar and battery energy storage systems could have on the region grid's reliability and electricity costs, providing insights into long-term decarbonization strategies across Argentina. The analysis demonstrated that these systems are expected not only to help with decarbonization efforts but also to bolster grid resiliency, reduce line losses, and improve voltage regulation while lowering electricity costs. The paper offers a replicable framework for similar studies across other Argentine provinces, which could inform a national grid reliability plan and promote regional coordination. Such coordination will play a key role in supporting a nationwide clean energy transition as Argentina increases its share of renewable energy. By coordinating subnational energy plans with national strategies, Argentina can secure a resilient clean energy future, leveraging the substantial renewable resources available across its provinces.
Now more than ever, particle physics is an international, even global, endeavor. The experiments needed to address the most profound questions of our field often require resources and cooperation at a global scale and can take more than a decade to design and build. We found the scope of our charge and the responsibility it represents humbling. Throughout our deliberations, we were aware that the impact of our recommendations would be felt past the end of the next decade and beyond the borders of the US particle physics program. The recommended program reflects the consensus of the panel.
Lawrence Berkeley National Laboratory retained DNV GL Energy USA, Inc. (“DNV GL”) to study the key challenges associated with manufacturing and deploying next generation, increasingly larger, land-based wind turbine blades. This study includes quantitative analyses exploring the costs and benefits of three potential pathways to enable use of wind turbine blades that are too large to be transported using traditional methods on existing road and rail infrastructure. The three innovation pathways considered in this study are: innovative transportation, segmented (hybrid) blades, and on-site manufacturing. Analysis of these pathways is intended to ultimately identify unique, high-value research and development (R&D) the U.S. Department of Energy (DOE) could undertake to enable use of “supersized” blades. This study is not intended, nor should it be interpreted as selecting a “best” or “preferred” innovation pathway. The study focuses on wind turbine blades and is not a detailed study of alternative wind turbine design or an optimization study intended to close specific knowledge gaps. This project provides supplemental information for use in DOE’s Big Adaptive Rotor project, led by Sandia National Laboratory. The Big Adaptive Rotor project is a detailed study of alternative wind turbine designs and systems. This report presents the results of DNV GL’s analyses and recommendations; it does not necessarily represent the opinions of the U.S. DOE or consensus among various national laboratories.
The Big Adaptive Rotor (BAR) Project looks at potential innovative pathways for future land-based wind turbine technology. BAR is led by the National Renewable Energy Laboratory and is sponsored by the Wind Energy Technology Office of the US Department of Energy. This talk will describe innovations and challenges faced by the teams working on BAR. The innovations include numerical models predicting the stability and performance of highly flexible blades, downwind rotors to maximize wind farm power, and controlled bending of 100-meter-long blades during rail transport. The challenges of developing predictive numerical models and formulating successful value propositions supporting new technologies such as distributed aero control devices will also be discussed.
Background: One of the European Union directives indicates that 10% of all fuels must be bio-synthesized by 2020. In this regard, biobutanol—natively produced by clostridial strains—poses as a promising alternative biofuel. One possible approach to overcome the difculties of the industrial exploration of the native producers is the expression of more suitable pathways in robust microorganisms such as Escherichia coli. The enumeration of novel pathways is a powerful tool, allowing to identify non-obvious combinations of enzymes to produce a target compound. Results: This work describes the in silico driven design of E. coli strains able to produce butanol via 2-oxoglutarate by a novel pathway. This butanol pathway was generated by a hypergraph algorithm and selected from an initial set of 105,954 diferent routes by successively applying diferent flters, such as stoichiometric feasibility, size and novelty. The implementation of this pathway involved seven catalytic steps and required the insertion of nine heterologous genes from various sources in E. coli distributed in three plasmids. Expressing butanol genes in E. coli K12 and cultivation in High-Density Medium formulation seem to favor butanol accumulation via the 2-oxoglutarate pathway. The maximum butanol titer obtained was 85±1 mg L-1 by cultivating the cells in bioreactors. Conclusions: In this work, we were able to successfully translate the computational analysis into in vivo applications, designing novel strains of E. coli able to produce n-butanol via an innovative pathway. Our results demonstrate that enumeration algorithms can broad the spectrum of butanol producing pathways. This validation encourages further research to other target compounds.
The dual need to remove CO 2 from our emissions and treat alkaline industrial residues such as ash materials motivate the design of innovative pathways to simultaneously capture and convert CO 2 into mineralized carbonates. Direct carbon mineralization is one approach that addresses the need to simultaneously treat alkaline industrial residues and mineralize CO 2 emissions. Low CO 2 solubility in water and slow kinetics at ambient temperature have challenged the direct carbon mineralization of alkaline industrial residues. Here, to address these challenges, the use of CO 2 capture solvents that enhance CO 2 solubility and facilitate accelerated carbon mineralization of fly ash at temperatures below 90 °C is investigated. Calcium carbonate formation results in the inherent regeneration of the solvent. The carbon mineralization extents of non-calcium carbonate content in fly ash were 50% and 51% and in waste ash were 58% and 62% in 2.5 M sodium glycinate and 30 wt% MEA solutions, respectively. The experiments were performed at 50 °C for 3 hours with CO 2 partial pressure of 1 atm in a continuously stirred slurry environment with 15 wt.% solid. Furthermore, nanoscale CaCO 3 is successfully synthesized from dissolved calcium using CO 2 -loaded sodium glycinate and surfactants such as CTAB (Cetyl Trimethyl Ammonium Bromide). Surfactants such as CTAB bind to the calcium carbonate surface and regulate the growth of calcium carbonate particles. These innovative approaches demonstrate the feasibility of directly storing CO 2 in fly ash and waste ash as calcium carbonate and producing nanoscale calcium carbonate using regenerable CO 2 capture solvents.
After reflecting on the history of ocean wave energy research and technology development, the most prominent classification schemes for wave energy converter (WEC) technology concepts are produced, highlighting the diversity of WEC technologies that were or are under development at different levels of maturity and intensity. Three advanced WEC technology examples are provided in this article. The ocean wave energy resource is addressed with respect to its global energy potential, local variability, and issues associated with the established forms of spectral power presentation. The spectrum of theoretical modeling approaches is described, along with the range of simulation tasks and related tools. This article also covers the specific aspects of the physical modeling and scaled model testing of WES systems and subsystems. Following a comparison of the engineering and design challenges of wave energy and wind energy technology development, the WEC technology development status and process is described and analyzed. Finally, the requirements for successful WEC technology development for achieving economic WEC technology and energy production under commercial conditions are discussed, including a number of possible development and innovation pathways.
Abstract Combining surface‐initiated, TdT (terminal deoxynucleotidyl transferase) catalyzed enzymatic polymerization (SI‐TcEP) with precisely engineered DNA origami nanostructures (DONs) presents an innovative pathway for the generation of stable, polynucleotide brush‐functionalized DNA nanostructures. We demonstrate that SI‐TcEP can site‐specifically pattern DONs with brushes containing both natural and non‐natural nucleotides. The brush functionalization can be precisely controlled in terms of the location of initiation sites on the origami core and the brush height and composition. Coarse‐grained simulations predict the conformation of the brush‐functionalized DONs that agree well with the experimentally observed morphologies. We find that polynucleotide brush‐functionalization increases the nuclease resistance of DONs significantly, and that this stability can be spatially programmed through the site‐specific growth of polynucleotide brushes. The ability to site‐specifically decorate DONs with brushes of natural and non‐natural nucleotides provides access to a large range of functionalized DON architectures that would allow for further supramolecular assembly, and for potential applications in smart nanoscale delivery systems.
Combining surface-initiated, TdT (terminal deoxynucleotidyl transferase) catalyzed enzymatic polymerization (SI-TcEP) with precisely engineered DNA origami nanostructures (DONs) presents an innovative pathway for the generation of stable, polynucleotide brush-functionalized DNA nanostructures. Here we demonstrate that SI-TcEP can site-specifically pattern DONs with brushes containing both natural and non-natural nucleotides. The brush functionalization can be precisely controlled in terms of the location of initiation sites on the origami core and the brush height and composition. Coarse-grained simulations predict the conformation of the brush-functionalized DONs that agree well with the experimentally observed morphologies. We find that polynucleotide brush-functionalization increases the nuclease resistance of DONs significantly, and that this stability can be spatially programmed through the site-specific growth of polynucleotide brushes. The ability to site-specifically decorate DONs with brushes of natural and non-natural nucleotides provides access to a large range of functionalized DON architectures that would allow for further supramolecular assembly, and for potential applications in smart nanoscale delivery systems.
Existing pavement de-icing methods result in high installation and maintenance costs, traffic delays, excessive weariness and corrosion, and negative environmental and safety impacts. To overcome these challenges, this paper presents an innovative pathway to designing and constructing smart self-heating pavements using a low-cost coal-char bearing asphalt material. The conductive asphalt incorporates coal char, i.e., a key byproduct of the coal pyrolysis process, into the Stone Mastic Asphalt (SMA) mixture. This asphalt containing coal-derived solid carbon exhibits highly tailorable electrical conductivity, satisfactory mechanical and thermophysical properties, and superior cost-efficiency as compared to other conductive pavement materials. The de-icing performance was also demonstrated by laboratory experiments on a bench-scale prototype. Furthermore, an efficient thermal network model was developed and validated by experiments to investigate the transient thermal behavior and energy performance of the Ohmic heating pavement system. Furthermore, the whole-year energy simulation case studies were conducted on a bridge pavement with an annual energy use of 24.6–1444.8 kWh/m 2 , showcasing its potential in field applications across cool humid, cold humid, and subarctic/arctic climate zones.
Due to their exceptional mechanical and thermal properties under high temperature conditions, for the first time, a novel vascular (embedded channels) Carbon/Carbon (C/C) composite was developed for use as a modular concentrated solar power (CSP) gas receiver. The fabrication process involves the combination of the vaporization of sacrificial component (VaSC) technique with conventional methods to produce C/C composites with well preserved channels. Different heat treatments were evaluated together with X-ray diffraction (XRD) analysis to determine optimal fabrication conditions that maintains the material and channel’s integrity. Mechanical testing confirms that structural integrity is maintained, with statistical analyses indicating no compromise in flexural strength or modulus. Furthermore, this research introduces an innovative pathway for efficient CSP gas receivers, which can bridge the gap towards improved energy generation efficiency in next-gen CSP plants through higher operating temperatures with the use of C/C composites.
Understanding the formation mechanism of nanocrystals in solution is very fundamental to the development of materials science. For a metal nanocrystal, the cluster mediated formation mechanism is still poorly understood. Particularly, identifying what types of clusters are dominant and how they evolve into a nanocrystal in the early nucleation stage remains a great challenge. Here, using liquid-cell transmission electron microscopy, we directly observe the formation of ultra-small Au clusters (~0.84 nm) in the presence of PAA-Na. These clusters, which correspond to the size of Au13 cluster, coalesce to form nanocrystals. Our molecular dynamics simulations suggest Au13 in an aqueous environment have higher stability when compared to other cluster sizes and provide atomistic details of growth by cluster coalescence. Collectively, our demonstration of Au13 as the dominant species with elaboration of their coalescence kinetics sheds light on nonclassical nanocrystal formation mechanisms and offers useful guidelines for designing innovative pathways for synthesis of nanomaterials.
Sourcing rare earth elements (REEs) from unconventional feedstocks has substantial environmental and societal-economic benefits, but its economic viability remains unclear. Here, we propose a framework for assessing the economic viability of unconventional REE feedstocks. Here, we first develop a database of capital and operating expenses for REE recovery and establish consistent process unit costs for common stages in the conventional supply chain. We then use market prices to develop well-defined methods for determining diverse product values. Finally, we report the effects of economies of scale and feedstock purity on capital and operating costs. These tools can reduce the uncertainty in the assessment of the economic viability of producing REE from unconventional feedstocks, determine the value of innovative pathways for REE production from diverse sources, and inform research priorities across a wide range of REE product development stages, contributing to a sustainable REE supply.