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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Petrology of Apollo 11 sample 10071 - A differentiated mini-igneous complex.

Sample 10071,33 is a thin section of Apollo 11 ferrobasalt showing an unusual dual texture. The major portion of the sample is very similar to other fine grained Apollo 11 basalts, but the thin section also includes materials with a distinct variolitic texture. The two areas are separated by a sharp boundary and the mineralogy and composition of the two textural types are quite distinct. The mineralogy and chemistry of the variolitic portion show it to be the product of rapid cooling of a liquid, intermediate between the typical Apollo 11 ferrobasalt and the associated Si and K-rich mesostasis. This liquid is the result of fractional crystallization of a magma of composition closely corresponding to the major portion of the 10071 system, followed by crystal-liquid separation. The sample provides strong and direct evidence for igneous differentiation on the lunar surface.

Drake, M. J.↗

Liquid cooling of aircraft engines

This report presents a method for solving the problem of liquid cooling at high temperatures, which is an intermediate method between water and air cooling, by experiments on a test-stand and on an airplane. A utilizable cooling medium was found in ethylene glycol, which has only one disadvantage, namely, that of combustibility. The danger, however is very slight. It has one decided advantage, that it simultaneously serves as protection against freezing.

Weidinger, Hanns↗

Fission Surface Power Technology Demonstration Unit Test Results

The Fission Surface Power (FSP) Technology Demonstration Unit (TDU) is a system-level demonstration of fission power technology intended for use on manned missions to Mars. The Baseline FSP systems consists of a 190 kWt UO2 fast-spectrum reactor cooled by a primary pumped liquid metal loop. This liquid metal loop transfers heat to two intermediate liquid metal loops designed to isolate fission products in the primary loop from the balance of plant. The intermediate liquid metal loops transfer heat to four Stirling Power Conversion Units (PCU), each of which produce 12 kWe (48 kW total) and reject waste heat to two pumped water loops, which transfer the waste heat to titanium-water heat pipe radiators. The FSP TDU simulates a single leg of the baseline FSP system using an electrically heater core simulator, a single liquid metal loop, a single PCU, and a pumped water loop which rejects the waste heat to a Facility Cooling System (FCS). When operated at the nominal operating conditions (modified for low liquid metal flow) during TDU testing the PCU produced 8.9 kW of power at an efficiency of 21.7 percent resulting in a net system power of 8.1 kW and a system level efficiency of 17.2 percent. The reduction in PCU power from levels seen during electrically heated testing is the result of insufficient heat transfer from the NaK heater head to the Stirling acceptor, which could not be tested at Sunpower prior to delivery to the NASA Glenn Research Center (GRC). The maximum PCU power of 10.4 kW was achieved at the maximum liquid metal temperature of 875 K, minimum water temperature of 350 K, 1.1 kg/s liquid metal flow, 0.39 kg/s water flow, and 15.0 mm amplitude at an efficiency of 23.3 percent. This resulted in a system net power of 9.7 kW and a system efficiency of 18.7 percent.

Facility Cooling System↗

Fission Surface Power Technology Demonstration Unit Test Results

The Fission Surface Power (FSP) Technology Demonstration Unit (TDU) is a system-level demonstration of fission power technology intended for use on manned missions to Mars. The Baseline FSP systems consists of a 190 kWt UO2 fast-spectrum reactor cooled by a primary pumped liquid metal loop. This liquid metal loop transfers heat to two intermediate liquid metal loops designed to isolate fission products in the primary loop from the balance of plant. The intermediate liquid metal loops transfer heat to four Stirling Power Conversion Units (PCU), each of which produce 12 kWe (48 kW total) and reject waste heat to two pumped water loops, which transfer the waste heat to titanium-water heat pipe radiators. The FSP TDU simulates a single leg of the baseline FSP system using an electrically heater core simulator, a single liquid metal loop, a single PCU, and a pumped water loop which rejects the waste heat to a Facility Cooling System (FCS). When operated at the nominal operating conditions (modified for low liquid metal flow) during TDU testing the PCU produced 8.9 kW of power at an efficiency of 21.7% resulting in a net system power of 8.1 kW and a system level efficiency of 17.2%. The reduction in PCU power from levels seen during electrically heated testing is the result of insufficient heat transfer from the NaK heater head to the Stirling acceptor, which could not be tested at Sunpower prior to delivery to GRC. The maximum PCU power of 10.4 kW was achieved at the maximum liquid metal temperature of 875 K, minimum water temperature of 350 K, 1.1 kg/s liquid metal flow, 0.39 kg/s water flow, and 15.0 mm amplitude at an efficiency of 23.3%. This resulted in a system net power of 9.7 kW and a system efficiency of 18.7 %.

fission power technology↗

High Energy Cutting and Stripping Utilizing Liquid Nitrogen

The Aerospace Industry has endeavored for decades to develop hybrid materials that withstand the rigors of mechanized flight both within our atmosphere and beyond. The development of these high performance materials has led to the need for environmentally friendly technologies for material re-work and removal. The NitroJet(TM) is a fluid jet technology that represents an evolution of the widely used, large-scale water jet fluid jet technology. It involves the amalgamation of fluid jet technology and cryogenics technology to create a new capability that is applicable where water jet or abrasive jet (water jet plus entrained abrasive) are not suitable or acceptable because of technical constraints such as process or materials compatibility, environmental concerns and aesthetic or legal requirements. The NitroJet(TM) uses ultra high-pressure nitrogen to cut materials, strip numerous types of coatings such as paint or powder coating, clean surfaces and profile metals. Liquid nitrogen (LN2) is used as the feed stream and is pressurized in two stages. The first stage pressurizes sub cooled LN2 to an intermediate pressure of between 15,000 and 20,000 psi at which point the temperature of the LN2 is about -250 F. The discharge from this stage is then introduced as feed to a dual intensifier system, which boosts the pressure from 15,000 - 20,000 psi up to the maximum operating pressure of 55,000 psi. A temperature of about -220 F is achieved at which point the nitrogen is supercritical. In this condition the nitrogen cuts, strips and abrades much like ultra high-pressure water would but without any residual liquid to collect, remove or be contaminated. Once the nitrogen has performed its function it harmlessly flashes back into the atmosphere as pure nitrogen gas. The system uses heat exchangers to control and modify the temperature of the various intake and discharge nitrogen streams. Since the system is hydraulically operated, discharge pressures can be easily varied over a very wide range providing considerable flexibility for various operations. The NitroJet(TM) is an advance on the nitrogen fluid jet technology initially developed at the Idaho National Engineering Laboratory in Idaho Falls, Idaho. NitroCision(R) first introduced the NitroJet(TM) into a commercial setting in 2003 and there has been considerable interest from many diverse sectors of government and industry since then. While the current system is an industrial system with the size and mass normally associated with industrial applications, a smaller system that is much more compact is being contemplated for those applications that do not need the full capabilities of the larger system. The NitroJet(TM) can be deployed as a fixed or mobile system with multiple end effectors capable of cutting, stripping, cleaning, and surface profiling either in robotic or manual applications.

Hume, Howard↗

Active Costorage of Cryogenic Propellants for Exploration

Long-term storage of cryogenic propellants is a critical requirement for NASA's effort to return to the moon. Liquid hydrogen and liquid oxygen provide the highest specific impulse of any practical chemical propulsion system, and thus provides the greatest payload mass per unit of launch mass. Future manned missions will require vehicles with the flexibility to remain in orbit for months, necessitating long-term storage of these cryogenic liquids. For decades cryogenic scientific satellites have used cryogens to cool instruments. In many cases, the lifetime of the primary cryogen tank has been extended by intercepting much of the heat incident on the tank at an intermediate-temperature shield cooled either by a second cryogen tank or a mechanical cryocooler. For an LH2/LO2 propellant system, a combination of these ideas can be used, in which the shield around the LO2 tank is attached to, and at the same temperature as, the LO2 tank, but is actively cooled so as to remove all heat impinging on the tank and shield. This configuration eliminates liquid oxygen boil-off and cuts the liquid hydrogen boil-off to a small fraction of the unshielded rate. This paper studies the concept of active costorage as a means of long-term cryogenic propellant storage. The paper describes the design impact of an active costorage system for the Crew Exploration Vehicle (CEV). This paper also compares the spacecraft level impact of the active costorage concept with a passive storage option in relation to two different scales of spacecraft that will be used for the lunar exploration effort, the CEV and the Earth Departure Stage (EDS). Spacecraft level studies are performed to investigate the impact of scaling of the costorage technologies for the different components of the Lunar Architecture and for different mission durations.

Canavan, Edgar R.↗

A variable conductance gas switch for intermediate temperature operation of liquid He/liquid N2 cryostats

A technique for establishing a stable intermediate temperature stage in liquid He/liquid N2 double vessel cryostats is described. The tertiary cold stage, which can be tuned to any temperature between 10 and 60 K, is ideal for cooling IR sensors for use in astronomy and physics applications. The device is called a variable-conductance gas switch. It is essentially a small chamber, located between the cold stage and liquid helium cold-face, whose thermal conductance may be controlled by varying the pressure of helium gas within the chamber. A key feature of this device is the large range of temperature control achieved with a very small (less than 10 mW) heat input from the cryogenic temperature control switch.

Rayner, J. T.↗

Study of active cooling for supersonic transports

The potential benefits of using the fuel heat sink of hydrogen fueled supersonic transports for cooling large portions of the aircraft wing and fuselage are examined. The heat transfer would be accomplished by using an intermediate fluid such as an ethylene glycol-water solution. Some of the advantages of the system are: (1) reduced costs by using aluminum in place of titanium, (2) reduced cabin heat loads, and (3) more favorable environmental conditions for the aircraft systems. A liquid hydrogen fueled, Mach 2.7 supersonic transport aircraft design was used for the reference uncooled vehicle. The cooled aircraft designs were analyzed to determine their heat sink capability, the extent and location of feasible cooled surfaces, and the coolant passage size and spacing.

Brewer, G. D.↗

Evolution of the Oxidation State of the Earth's Mantle: Challenges of High Pressure Quenching

The oxidation state of the Earth's mantle during formation remains an unresolved question, whether it was constant throughout planetary accretion, transitioned from reduced to oxidized, or from oxidized to reduced. We investigate the stability of Fe3+ at depth, in order to constrain processes (water, late accretion, dissociation of FeO) which may reduce or oxidize the Earth's mantle. Experiments of more mafic compositions and at higher pressures commonly form a polyphase quench intergrowth composed primarily of pyroxenes, with interstitial glass which hosts nearly all of the more volatile minor elements. In our previous experiments on shergottite compositions, variable fO2, T, and P is less than 4 GPa, Fe3+/TotFe decreased slightly with increasing P, similar to terrestrial basalt. For oxidizing experiments less than 7GPa, Fe3+/TotFe decreased as well, but it's unclear from previous modelling whether the deeper mantle could retain significant Fe3+. Our current experiments expand our pressure range deeper into the Earth's mantle and focus on compositions and conditions relevant to the early Earth. Experiments with Knippa basalt as the starting composition were conducted at 1-8 GPa and 1800 C, using a molybdenum capsule to set the fO2 near IW, by buffering with Mo-MoO3. TEM and EELS analyses revealed the run products from 7-8 GPa quenched to polycrystalline phases, with the major phase pyroxene containing approximately equal Fe3+/2+. A number of different approaches have been employed to produce glassy samples that can be measured by EELS and XANES. A more intermediate andesite was used in one experiment, and decompression during quenching was attempted after, but both resulted in a finer grained polyphase texture. Experiments are currently underway to test different capsule materials may affect quench texture. A preliminary experiment using liquid nitrogen to greatly enhance the rate of cooling of the assembly has also been attempted and this technique will be refined in further experiments.

Danielson, L. R.↗

Microencapsulated PCM slurries for heat transfer and energy storage in spacecraft systems

The technical feasibility for providing significantly enhanced heat transport and storage as well as improved thermal control has been investigated during several Small Business Innovative Research (SBIR) programs for NASA, the United States Air Force (USAF), and the Strategic Defense Initiative Organization (SDIO) using microencapsulated phase change materials (PCMs) in both aqueous and nonaqueous two-component slurries. In the program for SDIO, novel two-component coolant fluids were prepared and successfully tested at both low (300 K) and intermediate temperatures (460 to 700 K). The two-component fluid slurries of microencapsulated PCMs included organic particles in aqueous and nonaqueous liquids, as well as microencapsulated metals that potentially could be carried by liquid metals or used as powdered heat sinks. Simulation and experimental studies showed that such active cooling systems could be designed and operated with enhancements of heat capacity that exceeded 10 times or 1000 percent that for the base fluid along with significant enhancement in the fluid's heat capacity. Furthermore, this enhancement provided essentially isothermal conditions throughout the pumped primary coolant fluid loop. The results suggest that together with much higher fluid thermal capacity, greater uniformity of temperature is achievable with such fluids, and that significant reductions in pumping power, system size, and system mass are also possible.

Colvin, David P.↗

Recovering Residual Xenon Propellant for an Ion Propulsion System

Future nuclear-powered Ion-Propulsion- System-propelled spacecraft such as Jupiter Icy Moon Orbiter (JIMO) will carry more than 10,000 kg of xenon propellant. Typically, a small percentage of this propellant cannot be used towards the end of the mission because of the pressure drop requirements for maintaining flow. For large missions such as JIMO, this could easily translate to over 250 kg of unusable xenon. A proposed system, the Xenon Recovery System (XRS), for recovering almost all of the xenon remaining in the tank, would include a cryopump in the form of a condenser/evaporator that would be alternatively cooled by a radiator, then heated electrically. When the pressure of the xenon in the tank falls below 0.7 MPa (100 psia), the previously isolated XRS will be brought online and the gas from the tank would enter the cryopump that is initially cooled to a temperature below saturation temperature of xenon. This causes xenon liquefaction and further cryopumping from the tank till the cryopump is full of liquid xenon. At this point, the cryopump is heated electrically by small heaters (70 to 80 W) to evaporate the liquid that is collected as high-pressure gas (<7 MPa; 1,000 psia) in an intermediate accumulator. Check valves between the tank and the XRS prevent the reverse flow of xenon during the heating cycle. The accumulator serves as the high-pressure source of xenon gas to the Xenon Feed System (XFS) downstream of the XRS. This cycle is repeated till almost all the xenon is recovered. Currently, this system is being baselined for JIMO.

Ganapathi, Gani↗

Hydrogen production from coal using a nuclear heat source

A strong candidate for hydrogen production in the intermediate time frame of 1985 to 1995 is a coal-based process using a high-temperature gas-cooled reactor (HTGR) as a heat source. Expected process efficiencies in the range of 60 to 70% are considerably higher than all other hydrogen production processes except steam reforming of a natural gas. The process involves the preparation of a coal liquid, hydrogasification of that liquid, and steam reforming of the resulting gaseous or light liquid product. A study showing process efficiency and cost of hydrogen vs nuclear reactor core outlet temperature has been completed, and shows diminishing returns at process temperatures above about 1500 F. A possible scenario combining the relatively abundant and low-cost Western coal deposits with the Gulf Coast hydrogen users is presented which provides high-energy density transportation utilizing coal liquids and uranium.

Quade, R. N.↗

Chemistry of the CO dimer at low temperatures

Researchers conducted a series of experiments on the chlorine-catalyzed photodecomposition of O sub 3 both in the gas and in inert solvents such as CF sub 4 and CO sub 2 in the temperature range about 190 to 225 K. The liquid medium was chosen in order to minimize possible surface loss of long-lived ClO dimer, and to aid in the stabilization of transient excited intermediates. The mechanism of dimer formation was as follows: (1) Cl sub 2 + hv yields Cl + Cl; (2) Cl + O sub 3 yields ClO + O sub 2; (3) ClO + ClO yields Cl sub 2 O sub 2. The experiments were done in cooled low temperature cells, with irradiation from an Osram high pressure mercury arc, filtered to remove radiation below 325 nm. Spectral analysis was by means of a Cary Model 2200 UV spectrometer. The principal objectives were: (1) to determine the lifetime of the dimer as a function of temperature; (2) to observe spectral changes in the mixtures which could be attributed to dimer or related products; and (3) to observe chemical or photochemical reactions of the dimer.

Demore, W. B.↗

Massive Chromite in the Brenham Pallasite and the Fractionation of Cr During the Crystallization of Asteroidal Cores

Large (greater than or equal to 2 mm) chromite grains are present in IIIAB iron meteorites and in the main-group a pallasites (PMG), closely related to high-Au IIIAB irons, Pallasites seem to have formed by the intrusion of a highly evolved metallic magma from a IIIAB-like core into fragmented olivine of the overlying dunite mantle. High Cr contents are commonly encountered during the analyses of metallic samples of high-Au IIIAB irons and main-group pallasites, an indication that Cr contents were high in the intruding liquid and that Cr behaved as an incompatible element during the crystallization of the IIIAB magma, contrary to expectations based on the negative IIIAB Cr-Ni and Cr-Au trends among low-Au IIIAB irons. In a region about 10 cm across in the Brenham main-group pallasite massive chromite fills the interstices between olivine grains, the site normally occupied by metal in Brenham and other pallasites. The massive chromite may have formed as a late cumulus phase; because Fe-Ni was also crystallizing, its absence in the chromite-rich region suggests a separation associated with differences in liquid buoyancy. The coexisting chromite and olivine are zoned; in the olivine FeO is highest in pallasitic (olivine-metal) regions, lowest in rims adjacent to chromite, and intermediate in the cores of these olivines. Chromite shows the opposite zoning, with the highest FeO contents at grain edges adjacent to olivine. The observed gradients are those expected to form by Fe-Mg exchange between olivine and chromite during slow cooling at subsolidus temperatures. Compared to normal Brenham, contents of phosphoran olivine and phosphates are higher in the chromitic pallasitic region. We also report data for large-to-massive chromites present in PMG Molong and in high-Au IIIAB Bear Creek that, like Brenham, formed from a highly evolved magma. The Bear Creek chromite has a much lower Mg content than that in the pallasites, implying that, in the PMG, the Mg was extracted from the olivine during high-temperature reaction with the precipitating chromite. There are other circumstantial arguments indicating that Cr was incompatible in the metal during the crystallization of the IIIAB magma, with the concentration in die residual magma rising from an initial value of about 300 micrograms/g to a value around 700 micrograms/g when Bear Creek and Brenham were formed. We consider possible explanations for these negative Cr-Au and Cr-Ni trends and find the most probable one to be that they reflect sampling artefacts resulting from analysts avoiding visible chromite (and the commonly associated phase FeS) when choosing metal samples.

Wasson, John T.↗

Characterization of Aircraft Produced Soot and Contrails Near the Tropopause

Participation in the SUCCESS project primarily involved development and deployment of specific instruments for characterizing jet aircraft exhaust emissions as particulates and their subsequent evolution as contrail particles, either liquid or solid, as cirrus. Observations can be conveniently considered in two categories - close or distant from the aircraft. Thus close to the aircraft the exhaust is mixing through the engine turbulence with a much drier and colder environment and developing water/ ice supersaturation along the trail depending on circumstances (near field), whereas distant from the aircraft (far field) the exhaust has cooled essentially to ambient temperature, the turbulence has decayed and any particle growth or evaporation is controlled by the prevailing ambient conditions. Intermediate between these two regions the main aircraft vortices form (one on each side of the aircraft) which tend to inhibit mixing under some conditions, a region extending from a few aircraft lengths to sometimes a hundred times this distance. Our approach to the problem lay in experience gained in characterizing the smoke from hydrocarbon combustion in terms of its cloud forming properties and its potential influence on the radiation properties of the smoke and subsequent cloud from the viewpoint of reduction (absorbtion and scattering ) of solar radiation flux leading to significant global cooling (Hudson et al 1991; Hallett and Hudson 1991). Engine exhaust contains a much smaller proportion of the fuel carbon than is sometimes present in ordinary combustion (less than 0.01% compared with 10%) and influences condensation in quite different ways, to be characterized by the Cloud Condensation Nucleus, CCN - supersaturation spectrum. The transition to ice is to be related to the dilution of solution droplets to freeze by homogeneous nucleation at temperatures somewhat below -40C (Pueschel et al 1998). The subsequent growth of ice particles depends critically on temperature, supersaturation and to some extent pressure, as is demonstrated in an NSF funded project being carried out in parallel with the work reported here. As will be discussed below, nucleation processes themselves and also exhaust impurities also influence the growth of ice particles and may control some aspects of growth of ice in contrails. Instrumentation was designed to give insight into these questions and to be flown on the NASA DC- 8 as a platform. In addition a modest program was undertaken to investigate the properties of laboratory produced smoke produced under controlled conditions from the viewpoint of forming both CCN and CN. The composition of the smoke could inferred from a thermal characterization technique; larger particles were captured by formvar replicator for detailed analysis; ice particles were captured and evaporated in flight on a new instrument, the cloudscope, to give their mass, density and impurity content.

Hallett, John↗

Investigation of a para-ortho hydrogen reactor for application to spacecraft sensor cooling

The utilization of solid hydrogen in space for sensor and instrument cooling is a very efficient technique for long term cooling or for cooling at high heat rates. The solid hydrogen can provide temperatures as low as 7 to 8 K to instruments. Vapor cooling is utilized to reduce parasitic heat inputs to the 7 to 8 K stage and is effective in providing intermediate cooling for instrument components operating at higher temperatures. The use of solid hydrogen in place of helium may lead to weight reductions as large as a factor of ten and an attendent reduction in system volume. The results of an investigation of a catalytic reactor for use with a solid hydrogen cooling system is presented. Trade studies were performed on several configurations of reactor to meet the requirements of high reactor efficiency with low pressure drop. Results for the selected reactor design are presented for both liquid hydrogen systems operating at near atmospheric pressure and the solid hydrogen cooler operating as low as 1 torr.

Nast, T. C.↗