SEARCH · Search NASA
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Implosive collapse of liners containing gas to transfer chemical energy of explosive to kinetic and internal energy of gas
Various methods of calculating the internal energy of diatomic molecules are studied. An accurate and efficient method for computing the eigenvalues of the vibrational Schroedinger equation for an arbitrary potential is developed. The method is based on a finite-element discretization using the cubic Lobatto element. A combination of spectrum slicing and the Laguerre algorithm is used to solve for the eigenvalues. A simple method to compute the quasi-bound states is presented. For N2 molecules, all vibrational-rotational states of eleven available electronic potentials are computed, and summed to obtain the exact internal energy function with temperature. The total computation required 314 seconds of CPU-time on NASA's Cray 2 computer. Various approximate models are discussed and compared with the exact numerical simulation. It is shown that the splitting of the macroscopic internal energy into separate electronic, rotational, and vibrational energies is not justified at high temperatures.
Jupiter luminosity as indication of internal energy magnitude, comparing limb darkening with predicted brightness distribution
Functions for calculation of entropy, enthalpy, & internal energy of real fluids using state equations and specific heats
Radiative interactions between absorbing-emitting and flowing media with internal energy generation
Radiative interactions between absorbing-emitting and flowing media with internal energy generation
The discovery of broad CO wings in four high-latitude molecular clouds which do not have associated internal energy sources is reported. The velocity width of the wings is as much as five times greater than the width of the cloud cores. Neither visible stars brighter than the background population, optical nebulosity, nor IRAS point sources are found at the position of the wings, except for one case with an IRAS source 3 arcmin from the peak position of the wings. The possibility that the wings are the result of conductive interfaces resulting from cold molecular clouds in a hotter ambient medium is examined, and it is concluded that the expected column density of such gas is more than three orders of magnitude smaller than that observed.
A new model for chemical reactions, the Quantum-Kinetic (Q-K) model of Bird, has recently been introduced that does not depend on macroscopic rate equations or values of local flow field data. Subsequently, the Q-K model has been extended to include reactions involving charged species and electronic energy level transitions. Although this is a phenomenological model, it has been shown to accurately reproduce both equilibrium and non-equilibrium reaction rates. The usefulness of this model becomes clear as local flow conditions either exceed the conditions used to build previous models or when they depart from an equilibrium distribution. Presently, the applicability of the relaxation technique is investigated for the vibrational internal energy mode. The Forced Harmonic Oscillator (FHO) theory for vibrational energy level transitions is combined with the Q-K energy level transition model to accurately reproduce energy level transitions at a reduced computational cost compared to the older FHO models.
Differential reaction cross section and internal excitation function from K and Br molecule crossed beam velocity analysis
Infrared observations of the Io eclipse of April 12, 1980, in five broad bands from 3 to 30 microns define the thermal emission spectrum both during and after eclipse. A substantial fraction of the emitted radiation during eclipse arises from hot spots; the equivalent global average heat flow is 1.5 + or - 0.3 W/sq m, corresponding to an internal source of (6 + or - 1) x 10 to the 13th W. The hot spot spectra can be matched by components with color temperatures of 200-600 K covering 1-2% of the surface. Comparison with observations over the past eight years suggests that, while the flux at the hottest temperatures may be highly variable, there is no evidence for major changes in the total heat flow, which is emitted primarily in the spectral region 10-20 microns. The heating curves of the surface were observed at 10 and 20 microns; when corrected for the hot spot contribution they indicate a typical global thermal inertia for Io of 0.0002 + or - 0.0001 cal/sq cm sec(exp 1/2) K, similar to that of the other Galilean satellites.
Velocity distribution measurement of excited potassium bromide formed in reactive collision between crossed beams of K and HBr as function of scattering angle for selected K velocity
Human body as source of power for implanted electronic devices
The problem of nonlinear rarefied Couette flow with heat transfer has been studied for both monatomic and diatomic gases using the Boltzmann equation with the Bhatnagar-Gross-Krook type models as the governing equation and the method of discrete ordinates as a tool. The calculated results have been compared with the existing experimental data in order to test the accuracy and the applicability of the statistical models for this one-dimensional problem. The calculated density results are found to be in good agreement with available experimental data; the calculated heat flux solution for the linear case is found to always be lower than the experimental data of Teagan and Springer. The comparisons made here indicate that the statistical models are indeed reasonably accurate so that their use is justified in the type of problems investigated.
Energy flow in a molecular system such as CD3Cl or CD3H representing a chemical activation experiment is studied by the method of classical trajectories. A correlation function method is used to obtain energy distributions before and after the breakup of the activated molecule. The energy distribution in the final product is found to be randomly distributed for a surface with no exit channel barrier or strong intermode couplings. Nonrandom energy distributions result when these special forces are present. Product channel barriers result in an excess of translational energy and exit channel intermode couplings result in nonrandom vibrational distributions.
The C2 and C3 radicals are prominent emission in the visible region of cometary spectra. Observational evidence exists that suggests these radicals are formed as granddaughter fragments in the photolysis of more stable molecules. Likely candidates for these parent molecules ar C2H2, C3H4 (allene), and CH3C2H (propyne). Recent laboratory studies were performed on all of these parent molecules and they indicate that they can indeed produce the observed cometary radicals. In the case of C2H2, the laboratory evidence suggest that C2 is formed via the following mechanisms: (1) C2H2 + photon(193 nm) yields C2H + H; and (2) C2H + photon(193 nm) yields C2 + H. Evidence is presented to show that the C2 radical produced in the second reaction occurs in a variety of electronic, vibrational, and rotational states. It is argued that this is a result of conical intersections in the potential energy curves and the density of states associated with these curves. Since this is a property of the C2H radical similar initial product state distributions are expected to occur in comets. This means that any models of the C2 emission may have to start off with rotationally excited C2 radicals in both the singlet and the triplet manifolds. When C3H4 (allene) and CH3C2H (propyne) were photolyzed, the C3 radical is formed. In the allene case, laboratory evidence shows that the C3 radical is formed via the following mechanism: (1) C3H4 + photon(193 nm) yields C3H2 + H2; and (2) C3H2 + photon(193 nm) yields C3 + H2. More C3 is formed in the case of allene than in the propyne case, even though the absorption cross section for propyne is a factor of 2 larger. This suggests that competing dissociation pathways are present during the photolysis of propyne that are not available to allene. The observed quantum state distributions of the C3 product were the same for both parent molecules, indicating that the same intermediate state is involved. These observations can be understood if the excited propyne formed in the initial absorption step isomerizes to excited allene before it dissociates to the same daughter compound. This postulate was tested by comparing RRKM calculations of the isomerization rate of excited propyne versus the decomposition rate to other products.
For a two-fluid model of dilute solutions of He-3 in liquid He-4, a thermodynamic potential is constructed that provides a Lagrangian for deriving equations of motion by a variational procedure. This Lagrangian is defined for uniform velocity fields as a (negative) Legendre transform of total internal energy, and its primary independent variables, together with their thermodynamic conjugates, are identified. Here, similarities between relations in classical physics and quantum statistical mechanics serve as a guide for developing an alternate expression for this function that reveals its character as the difference between apparent kinetic energy and intrinsic internal energy. When the He-3 concentration in the mixtures tends to zero, this expression reduces to Zilsel's formula for the Lagrangian for pure liquid He-4. An investigation of properties of the intrinsic internal energy leads to the introduction of intrinsic chemical potentials along with other intrinsic variables for the mixtures. Explicit formulas for these variables are derived for a noninteracting elementary excitation model of the fluid. Using these formulas and others also derived from quantum statistical mechanics, another equivalent expression for the Lagrangian is generated.
In this paper, the budget terms in the transport equations of the Reynolds stresses, the turbulent kinetic energy (TKE), the internal energy, and the turbulent heat flux are computed using a direct numerical simulation (DNS) database of hypersonic turbulent boundary layers (TBLs) subject to favorable pressure gradients (FPG). Study of the Reynolds stress and TKE budgets shows that FPG has a damping effect on turbulence production, transport, and destruction. The semilocal scaling fails to collapse the Reynolds stress and TKE budget terms between the zero pressure gradient (ZPG) and the strong FPG cases, suggesting that the mechanical nonequilibrium due to FPG leads to changes in Reynolds-stress and TKE transport that cannot be captured by Morkovin’s hypothesis. Minimal change is seen in the internal energy budget in the presence of FPG, indicating a minimal impact due to FPG on the mean thermal field. While the near-wall transport of wall-normal turbulent heat flux is largely governed by the balance between the turbulent viscous-thermal transport term and the turbulent viscous-thermal dissipation term, the transport of the streamwise turbulent heat flux is influenced by contributions from almost all of the budget terms. For the strong FPG case in particular, production due to both the mean and the fluctuating strain rates begins to play a significant role in the near-wall transport of the streamwise turbulent heat flux, and their inclusion or modeling may be required to accurately predict turbulent heat fluxes for a strong FPG.
Numerical simulations are used to study compressible turbulence with microscale Reynolds numbers up to 40 and rms Mach numbers M up to 0.9. The flows are randomly forced, with energy supplied to either the rotational or compressive components of kinetic energy, which is then transferred to internal energy through the pressure-dilatation interaction and viscous dissipation terms. Coupling between the two components of kinetic energy by the advection term is relatively weak, and most energy introduced to either component by the external force is transferred, without passing through the other component, to internal energy. A statistically quasi-equilibrium of kinetic energy is realized while internal energy increases steadily. The spectral form of the rotational component of velocity, which hardly depends on M, is very close to that for incompressible flow. On the other hand, the compressive component depends strongly on M, especially at large wave numbers.