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Io's sodium emission profiles - Variations due to Io's phase and magnetic latitude
We present recent measurements of high-resolution sodium D2 emission line profiles of Io's atmosphere and cloud. The high-velocity skirts of these profiles are strongest when Io is on the magnetic equator where protons and heavy ions, which sputter atoms from Io's surface, are concentrated. The skirts are most prominent on the long-wavelength side of the line when Io is west of Jupiter, and they are most prominent on the short-wavelength side of the line when Io is east of Jupiter. Our observations also indicate that there is a shift in the emission peak with respect to Io which is correlated with Io's orbital phase angle.
The Io GIS Database 1.0: A Proto-Io Planetary Spatial Data Infrastructure
We collected a set of published, higher-order data products of Jupiterʼs volcanic moon Io and assembled them in an ArcGISTM database we are calling the Io GIS Database, version 1.0. The purpose of this database is to collect image, topographic, geologic, and thermal emission data of Io in one geospatially registered location to form the data component of an Io planetary spatial data infrastructure (PSDI). The goals of an Io PSDI are (1) to make higher-order data products more accessible and usable to the broader planetary science community, particularly to new scientists that were not associated with the projects that obtained the data; (2) to enable new scientific studies with the data; and (3) to create a tool to support observation planning for future Io-focused planetary missions. In this paper we describe the motivation behind our project, discuss the data sets acquired for this first version of the database, and demonstrate how they can be used. We conclude with a discussion of how our database relates to other PSDIs, our plans for future updates, and a request for additional Io data sets.
Spin and Orbital Effects on Asymmetric Exchange Interaction in Polar Magnets: M(IO 3 ) 2 (M = Cu and Mn)
We report magnetic polar materials feature an astonishing range of physical properties, such as magnetoelectric coupling, chiral spin textures, and related new spin topology physics. This is primarily attributable to their lack of space inversion symmetry in conjunction with unpaired electrons, potentially facilitating an asymmetric Dzyaloshinskii–Moriya (DM) exchange interaction supported by spin–orbital and electron–lattice coupling. However, engineering the appropriate ensemble of coupled degrees of freedom necessary for enhanced DM exchange has remained elusive for polar magnets. Here, we study how spin and orbital components influence the capability of promoting the magnetic interaction by studying two magnetic polar materials, α-Cu(IO 3 ) 2 ( 2 D) and Mn(IO 3 ) 2 ( 6 S), and connecting their electronic and magnetic properties with their structures. The chemically controlled low-temperature synthesis of these complexes resulted in pure polycrystalline samples, providing a viable pathway to prepare bulk forms of transition-metal iodates. Rietveld refinements of the powder synchrotron X-ray diffraction data reveal that these materials exhibit different crystal structures but crystallize in the same polar and chiral P2 1 space group, giving rise to an electric polarization along the b-axis direction. The presence and absence of an evident phase transition to a possible topologically distinct state observed in α-Cu(IO 3 ) 2 and Mn(IO 3 ) 2 , respectively, imply the important role of spin–orbit coupling. Neutron diffraction experiments reveal helpful insights into the magnetic ground state of these materials. While the long-wavelength incommensurability of α-Cu(IO 3 ) 2 is in harmony with sizable asymmetric DM interaction and low dimensionality of the electronic structure, the commensurate stripe AFM ground state of Mn(IO 3 ) 2 is attributed to negligible DM exchange and isotropic orbital overlapping. The work demonstrates connections between combined spin and orbital effects, magnetic coupling dimensionality, and DM exchange, providing a worthwhile approach for tuning asymmetric interaction, which promotes evolution of topologically distinct spin phases.
Discovery of an Io-correlated energy source for Io's hot plasma torus
Energy flowing into Io's hot plasma torus from a local-time correlated source and from an Io-related source are discussed, and a correlation of the brightness of the ansae of the torus with the apparent orbital phase of Io is reported. It is shown that the energy flows cause an azimuthal modulation of the brightness of the torus that is correlated with the position of Io, and the plasma downstream from Io is shown to be brighter in S III 685-A emission, which indicates a higher electron temperature. Differences in electron temperature inferred from spectral analyses account for all observed differences in brightness, implying that no change in the composition or density of the hot plasma occurs. The mechanism regulating the Io-related source is clearly distinct from the mechanism driving the local time source, although both draw on the same pool of energy, and the combination of the two sources is easily capable of supplying all the energy radiated by the torus.
Competitive TcO4-, IO3-, and CrO42- Incorporation into Ettringite
Ettringite is a naturally occurring mineral found in cementitious matrices that is known for its ability to incorporate environmentally mobile oxyanion contaminants. To better assess this immobilization mechanism for contaminants within cementitious waste forms intended for nuclear waste storage, this work explores how mixed oxyanion contaminants compete for ettringite incorporation and influence the evolving mineralogy. Ettringite was precipitated in the presence of TcO4-, IO3-, and/or CrO42-, known contaminants of concern to nuclear waste treatment, over pre-determined precipitation periods. Solution analyses quantified contaminant removal and the collected solid was characterized using bulk and microprobe XRD coupled with PDF and microprobe XRF analyses. Results suggest that =96% IO3- is removed from solution, regardless of ettringite precipitation time or the presence of TcO4- or CrO42-. However, TcO4- removal remained <20%, was not significantly improved with longer ettringite precipitation times, and significantly decreased in the presence of IO3-. When IO3- is comingled with CrO42, gypsum is formed as a secondary mineral phase, which results in oxyanion partitioning among mineral phases, e.g., IO3- incorporation into ettringite and CrO42- incorporation into gypsum via SO42- substitution. Results from this work exemplify the importance of competitive immobilization when assessing waste form performance and environmental risk of contaminant release.
'Alfven wing' models of the induced electrical current system at Io - A probe of the ionosphere of Io
A novel class of models of the Alfven wing interaction between the Io plasma torus and Io's ionosphere has been developed and used to compute the magnetic field fluctuations at the position of the Voyager 1 flyby. These computations of the magnetic field signature are compared with the magnetic field measurements made during the flyby, and the differences between the model and observations are used as a probe of the structure of Io's ionosphere. The results of this model fitting indicate that a significant atmospheric neutral column density is required over a major part of the trailing hemisphere. This can be consistent with the cold-trap model for Io's neutral atmoshpere only if the major plumes near the center of the trailing hemisphere provide significant volumetric coverage. The Io plasma torus charged-mass density required for a proper match to the data is larger than earlier estimates based on the width of the Alfven wing signature.
Kinetics and mechanism of the IO + IO reaction
The flash photolysis-absorption technique has been used to measure the rate constant for the reaction IO + IO over the temperature range 250-373 K and pressure range 20-700 torr of N2. The rate constant for the overall reaction was found to be independent of pressure and equal to 1.73 x 10 to the -12th exp (1020 + or - 200)/T cu cm/molecule s. Branching ratios for the reaction channels forming 2I + O2, I2 + O2, and I2O2, were found to be pressure dependent, with the I2 channel accounting for less than 5 percent of the total reaction over the observed pressure range. A stable reaction product was observed between 230 and 300 nm which was formed on a long time scale compared to IO disappearance. The rate constant for the reaction I + O3 + yields to IO + O2 was measured at 298 K and found to be (9.5 + or - 1.5) x 10 to the -13th cu cm/molecule s.
Mass-injection rate from Io into the Io plasma torus
Theoretical arguments to the effect that both plasma and energy are supplied to the Jovian magnetosphere from primarily internal sources are presented. Two major assumptions are made: (1) that Io is the source of plasma for the Jovian magnetosphere, and that the outward flow of plasma from the torus is the means of drawing from the kinetic energy of rotation of Jupiter to drive magnetospheric phenomena; thereby obtaining a new, independent estimate of the rate of mass injection from Io into the Io plasma torus, and (2) that the solar wind supplies neither plasma nor energy to the Jovian magnetosphere in significant amounts. A lower limit to the rate of mass injection into the torus, which on the average must equal the rate of mass loss from the torus, is therefore derivable through adoption of a value for the power expended to drive the various magnetospheric phenomena.
Io's surface - Its phase composition and influence on Io's atmosphere and Jupiter's magnetosphere
The evidence and interpretations pertaining to the surface phase composition of Io and the mechanisms by which Io's surface influences its atmosphere are discussed. The mechanism by which Io's surface and/or atmosphere supplies neutral and ionic species to the region around the satellite and ultimately to the Jovian magnetosphere is also discussed. A model is suggested in which the global SO2 gas abundance is primarily controlled by buffering in the brightest, coldest regions. The net SO2 flux across the disk is limited by regional cold trapping on high albedo regions and possibly by the resistance of a tenuous non-SO2 residual atmosphere. The continuing migration of SO2 toward cooler regions and those lacking SO2 sources is opposed by SO2 destruction and planetary ejection processes, including sputtering, thus preventing buildup of thick, ubiquitous SO2 coverage.
Discovery of Soft X-Ray Emission from Io, Europa and the Io Plasma Torus
The Chandra X-ray Observatory observed the Jovian system for about 24 hours on 25-26 Nov 1999 with the Advanced CCD Imaging Spectrometer (ACIS), in support of the Galileo flyby of Io, and for about 10 hours on 18 Dec 2000 with the imaging array of the High Resolution Camera (HRC-I), in support of the Cassini flyby of Jupiter. Analysis of these data have revealed soft (0.25--2 keV) x-ray emission from the moons Io and Europa, probably Ganymede, and from the Io Plasma Torus (IPT). Bombardment by energetic (greater than 10 keV) H, O, and S ions from the region of the IPT seems the likely source of the x-ray emission from the Galilean moons. According to our estimates, fluorescent x-ray emission excited by solar x-rays is about an order of magnitude too weak even during flares from the active Sun to account for the observed x-ray flux from the IPT. Charge-exchange processes, previously invoked to explain Jupiter's x-ray aurora and cometary x-ray emission, and ion stripping by dust grains both fall by orders of magnitude. On the other hand, we calculate that bremsstrahlung emission of soft X-rays from non-thermal electrons in the few hundred to few thousand eV range accounts for roughly one third of the observed x-ray flux from the IPT. Extension of the far ultraviolet (FUV) IPT spectrum likely also contributes.
Chandra Observations of Io and the Io Plasma Torus
Chandra observed the Jovian system for approximately 1 day with ACIS-S in Nov, 1999, and approximately 10 hours with HRC-I in Dec, 2000. Among the many results of great interest to planetary scientists are the detection of x-ray emission from the Io Plasma Torus (IPT) and, very faintly, associated with the Jovian moon Io itself. The IPT is an almost self-generating donut of S and O ions in Io's orbit that ultimately derive from volcanoes on the surface. While EUV and visible emissions from the IPT are relatively well understood to result from low charge state transitions of S and O and from electron impact, the x-ray emissions are too energetic to be explained this way and seem to require the presence of higher charge states of S and O. We present current ideas as to origins of these x-ray emissions.
Th(VO 3 ) 2 (SeO 3 ) and Ln(VO 3 ) 2 (IO 3 ) (Ln = Ce, Pr, Nd, Sm, and Eu): unusual cases of aliovalent substitution
Here Th(VO 3 ) 2 (SeO 3 ) and Ln(VO 3 ) 2 (IO 3 ) (Ln = Ce, Pr, Nd, Sm, and Eu) have been prepared and characterized. Surprisingly, these compounds are isotypic and rather extreme examples of aliovalent substitution (Th IV vs. Ln III ; Se IV O 3 2- vs. I V O 3 -) are possible in this structure type.
Discovery of Soft X-Ray Emission From Io, Europa and the Io Plasma Torus
We report the discovery of soft (0.25 - 2 keV) x-ray emission from the moons Io and Europa, probably Ganymede, and from the Io Plasma Torus (IPT). Bombardment by energetic (greater than 10 keV) H, O, and S ions from the region of the IPT seems the likely source of the x-ray emission from the Galilean moons. According to our estimates, fluorescent x-ray emission excited by solar x-rays, even during flares from the active Sun, charge-exchange processes, previously invoked to explain Jupiter's x-ray aurora and cometary x-ray emission, and ion stripping by dust grains fall to account for the observed emission. On the other hand, bremsstrahlung emission of soft X-rays from non-thermal electrons in the few hundred to few thousand eV range may account for a substantial fraction of the observed x-ray flux from the IPT.
GLANCED-IO: Taming IO Optimization for Deep Learning at Scale
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The Io GIS Database 1.0: A Proto-Io Planetary Spatial Data Infrastructure
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