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Results for “Ion association”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1996

Substorm associated ion acceleration in the dynamic magnetotail

Ion acceleration and flux increase associated with substorm energetic particle injections are investigated on the basis of geosynchronous observations and test proton orbits in the dynamic fields of a three dimensional magnetohydrodynamic simulation of neutral line formation and dipolarization in the magnetotail. The energetic particle flux changes obtained from the test particle orbits agree well with observations that demonstrate rapid ion flux increases at energies of above 20 keV. The injection region inferred from the test particles has a sharp earthward boundary and a sharp ragged tailward boundary. The earthward portion of the enhanced ion flux can be traced to the enhanced cross-tail electric field associated with the near-earth x-type neutral line. Due to the rapid earthward motion of accelerated ions away from the neutral line, this boundary is displaced earthward to where the energetic ions become more adiabatic in the stronger dipolar field.

Birn, J.↗
NASA NTRS1987

Enhancements of energetic ions associated with travelling compression regions in the deep geomagnetic tail

This paper presents a representative example of an enhancement in energetic ion flux associated with the International Sun-Earth Explorer 3 (ISEE 3) spacecraft's encounter with a traveling compression region (TCR). Data from the energetic particle anisotropy spectrometer (EPAS) instrument on ISEE 3 are studied, along with magnetic field data from the vector helium magnetometer. It is concluded that the ion enhancements seen are spatial in nature, thus supporting the idea that TCRs are the lobe signatures of plasmoids moving along the magnetotail, away from earth.

Murphy, N.↗
NASA NTRS1983

Characteristics of thermal and suprathermal ions associated with the dayside plasma trough as measured by the dynamics explorer retarding ion mass spectrometer

The thermal and suprathermal ion populations present in the refilling regions after a magnetic storm are examined using retarding ion mass spectrometer (RIMS) data from the Dynamics Explorer 1 spacecraft. The RIMS instrument is described, and data are presented and discussed in detail for the outer plasmasphere, plasmapause, depleted dayside magnetosphere, and dayside cusp. Three distinct populations were observed: thermal ions, warm anisotropic plasma, and the polar wind. The characteristics of these populations are considered, including the densities, temperatures, and density ratios. Aspects of the ionospheric plasma outflow are discussed, including the field-aligned flow speed, the ionospheric plasma escape flux, plasmaspheric refilling, and wave-particle phenomena.

Sojka, J. J.↗
NASA NTRS1982

The two-dimensional structure of diffuse ions associated with the earth's bow shock

The lateral distribution of upstream, diffuse energetic ions resulting from shock acceleration at an idealized model bow shock is investigated, where the model consists of a uniform planar shock along which steady source ion injection takes place over a finite region of the shock. The solution exhibits growth toward a peak ion concentration whose location beneath the point of initial magnetic connection with the shock is sensitive to the model parameters. It is found that a plateau forms if the source size is large in comparison to the scale length of ion distribution function's growth, and that cross-field diffusion strongly enhances the diffuse ion concentration near the leading edge of the source.

Skadron, G.↗
NASA NTRS1991

MeV/n ions associated with corotating high-speed solar wind streams at less than 1 AU during 1978 to 1986

Data from the Goddard Space Flight Center experiments on the ISEE 3/ICE, IMP 8, and Helios 1 spacecraft are used to investigate ion enhancements of more than 1 MeV/n associated with corotating high-speed solar wind streams at least 1 AU during 1978-1986. The observations are consistent with ion acceleration from the solar wind by corotating shocks in the outer heliosphere.

Richardson, I. G.↗
NASA NTRS2023

Analyses of ∼0.05-2 Mev Ions Associated With the 2022 February 16 Esp Event Observed by Parker Solar Probe

We present analyses of 0.05–2 MeV ions from the 2022 February 16 energetic storm particle event observed by Parker Solar Probe's (PSP) IS⊙IS/EPI-Lo instrument at 0.35 au from the Sun. This event was characterized by an enhancement in ion fluxes from a quiet background, increasing gradually with time with a nearly flat spectrum, rising sharply near the arrival of the coronal mass ejection (CME) driven shock, becoming nearly a power-law spectrum, then decaying exponentially afterwards, with a rate that was independent of energy. From the observed fluxes, we determine diffusion coefficients, finding that far upstream of the shock the diffusion coefficients are nearly independent of energy with a value of 10 20 cm 2 /s. Near the shock, the diffusion coefficients are more than one order of magnitude smaller and increase nearly linearly with energy. We also determine the source of energetic particles, by comparing ratios of the intensities at the shock to estimates of the quiet time intensity to predictions from diffusive shock acceleration theory. We conclude that the source of energetic ions is mostly the solar wind for this event. We also present potential interpretations of the near-exponential decay of the intensity behind the shock. One is that we suggest the shock was over-expanding when it crossed PSP and the energetic particle intensity decreased behind the shock to fill the expanding volume. Over-expanding CMEs could well be more common closer to the Sun, and this is an example of such a case.

Joe Giacalone↗
NASA NTRS2023

Analyses of ∼0.05–2 MeV Ions Associated with the 2022 February 16 Energetic Storm Particle Event Observed By Parker Solar Probe

We present analyses of 0.05–2 MeV ions from the 2022 February 16 energetic storm particle event observed by Parker Solar Probeʼs (PSP) ISeIS/EPI-Lo instrument at 0.35 au from the Sun. This event was characterized by an enhancement in ion fluxes from a quiet background, increasing gradually with time with a nearly flat spectrum, rising sharply near the arrival of the coronal mass ejection (CME)–driven shock, becoming nearly a power-law spectrum, then decaying exponentially afterward, with a rate that was independent of energy. From the observed fluxes, we determine diffusion coefficients, finding that far upstream of the shock the diffusion coefficients are nearly independent of energy, with a value of 10 20 cm 2 s −1 . Near the shock, the diffusion coefficients are more than 1 order of magnitude smaller and increase nearly linearly with energy. We also determine the source of energetic particles, by comparing ratios of the intensities at the shock to estimates of the quiet-time intensity to predictions from diffusive shock acceleration theory. We conclude that the source of energetic ions is mostly the solar wind for this event. We also present potential interpretations of the near-exponential decay of the intensity behind the shock. One possibility we suggest is that the shock was over expanding when it crossed PSP and the energetic particle intensity decreased behind the shock to fill the expanding volume. Over expanding CMEs could well be more common closer to the Sun, and this is an example of such a case.

Interplanetary particle acceleration↗
NASA NTRS1995

Magnetic structure of slow shocks and the associated ion dissipation

The kinetic structure of slow magnetosonic shocks obtained from 1- and 2-D hybrid (fluid electrons, particle ions) simulations is discussed. The magnetic structure of the shock varies considerably with the Mach number. At low Mach numbers, the shock may be laminar with no associated waves, whereas, at high Mach numbers the shock may be unsteady with Alfvenic turbulence in the upstream and the downstream regions. The nature of ion dissipation also varies with the Mach number. At weak laminar shocks, ion dissipation consists of adiabatic heating and reflection of a small number of ions back into the upstream. At stronger shocks, particle scattering by Alfven/ion-cyclotron waves in the upstream contributes to the heating which continues well into the downstream region.

Omidi, N.↗
NASA NTRS2020

Characteristics of Escaping Magnetospheric Ions Associated with Magnetic Field Fluctuations

The four Magnetospheric Multiscale (MMS) spacecraft observed a hot ow anomaly (HFA) at the boundary of the quasi-parallel and quasi-perpendicular bow shock and energetic (E > 50 keV) ion bursts exhibitinginverse dispersion in the magnetosheath on 28 December 2015. We consider the possibility that the ions seen both upstream in the foreshock and down-stream in the magnetosheath originate from the magnetosphere. The ion composition ratios, flux levels, and the spectral slopes of the energetic ion energy spectra observed in the region upstream from the bow shock and in themagnetosheath are similar to those in the outer magnetosphere but significantly differ from those seen further upstream from the bow shock at ACE. We can exclude an explanation of the particle source in terms of HFA acceleration. A simulation shows that escaping magnetospheric ions can be scattered and transported across the magnetosheath. Ground magnetometer observations indicate that a solar wind pressure decrease subsequently allows the bow shock to move outward past the MMS spacecraft placing them in the magnetosheath. This was followed by a pressure increase in the magnetosphere. We posit that the enhanced pressure applied to the magnetosphere accelerates the escaping magnetospheric ions (the betatron acceleration), resulting in the inverse dispersion.

S. H. Lee↗
NASA NTRS1985

A new mechanism for excitation of electrostatic ion cyclotron waves and associated perpendicular ion heating

A new mechanism for exciting the kinetic ion cyclotron waves in the presence of a nonuniform electric field perpendicular to the external magnetic field is given. Application of this instability to various space plasmas is discussed. The new instability mechanism may provide a more efficient agent for perpendicular ion heating than other EIC generation processes, since the linear growth rate is insensitive to the temperature ratio.

Ganguli, G.↗
NASA NTRS1991

ISEE 1 observations of electrostatic ion cyclotron waves in association with ion beams on auroral field lines from about 2.5 to 4.5 R(E)

Quasi-monochromatic waves at about the hydrogen cyclotron frequency were observed as the ISEE 1 satellite traversed auroral field lines at radial distances of about 2.5-4.5 R(E) near midnight on June 19, 1981. Waves and both lower and higher frequencies were observed at higher altitudes, and possible electrostatic helium cyclotron and oxygen cyclotron waves occurred at lower altitudes. Upflowing hydrogen and oxygen beams and field-aligned currents occurred simultaneously. The features of the waves are most consistent with the current-driven mode. In addition, numerical studies of the linear dispersion relation, using parameters based on the observations, show that both the parallel and oblique two-stream modes and the ion-beam-driven modes were stable while oblique current-driven modes were unstable. The O(+) and H(+) distributions provide evidence for interactions with local electrostatic ion cyclotron waves and for the H(+)-O(+) two-stream instability at altitudes below the satellite.

Catell, C. A.↗
NASA NTRS1992

Energetic Ion Events Associated with Travelling Compression Regions

Preliminary results from the first extended study of energetic ion enhancements associated with the signatures of Traveling Compression Regions (TCR's) in the deep tail, using data from the ISEE 3 satellite, are presented. It is found that 46% of TCR signatures can be associated with an ion enhancement, indicating that the spacecraft entered the plasma sheet boundary layer as a result of a plasmoid passage down the tail. Events with ion enhancements are found to be on average a factor of approximately 2 larger in amplitude than those without, but there is no clear difference in the event duration. Almost all ion associated TCR's tailward of 100 Re show strong tailward streaming, indicating that the plasmoids are completely disconnected from the Earth. Most events Earthward of -80 Re show Earthward streaming, or no clear anisotropy, suggesting that the plasmoids may not be completely disconnected at the distances. A curious aspect of the data set, that a significant number of TCR's are associated with a turning off, or on, of the ion enhancement, is reported.

Owen, Chris J.↗
DOE OSTI2021

Molecular Level Differences in Ionic Solvation and Transport Behavior in Ethylene Oxide-Based Homopolymer and Block Copolymer Electrolytes

Block copolymer electrolytes (BCE) such as polystyrene-block-poly(ethylene oxide) (SEO) blended with lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) and composed of mechanically robust insulating and rubbery conducting nanodomains are promising solid-state electrolytes for Li batteries. Here, we compare ionic solvation, association, distribution, and conductivity in SEO-LiTFSI BCEs and their homopolymer PEO-LiTFSI analogs toward a fundamental understanding of the maximum in conductivity and transport mechanisms as a function of salt concentration. Ionic conductivity measurements reveal that SEO-LiTFSI and PEO-LiTFSI exhibit similar behaviors up to a Li/EO ratio of 1/12, where roughly half of the available solvation sites in the system are filled, and conductivity is maximized. As the Li/EO ratios increase to 1/5 the conductivity, of the PEO-LiTFSI drops nearly 3-fold, while the conductivity of SEO-LiTFSI remains constant. FTIR spectroscopy reveals that additional Li cations in the homopolymer electrolyte are complexed by additional EO units when the Li/EO ratio exceeds 1/12, while in the BCE, the proportion of complexed and uncomplexed EO units remains constant; Raman spectroscopy data at the same concentrations show that Li cations in the SEO-LiTFSI samples tend to coordinate more to their counteranions. Atomistic-scale molecular dynamics simulations corroborate these results and further show that associated ions tend to segregate to the SEO-LiTFSI domain interfaces. The opportunity for "excess" salt to be sequestered at BCE interfaces results in the retention of an optimum ratio of uncompleted and complexed PEO solvation sites in the middle of the conductive nanodomains of the BCE and maximized conductivity over a broad range of salt concentrations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1990

An estimating formula for ion-atom association rates in gases

A simple estimating formula is derived for rate coefficients of three-body ion atom association in gases and compare its predictions to experimental data on ion association and three-body radiative charge transfer reactions of singly- and doubly-charged rare-gas ions. The formula appears to reproduce most experimental data quite well. It may be useful for estimating the rates of reactions that have not been studied in the laboratory.

Chatterjee, B. K.↗
DOE OSTI2021

Observations of Density Cavities and Associated Warm Ion Flux Enhancements in the Inner Magnetosphere

We present a statistical study of density cavities observed in the inner magnetosphere by the Van Allen Probes during four one-month periods: February 2013, July 2013, January 2014, and June 2014. These periods were chosen to allow the survey of all magnetic local times. We find that density cavities are a recurrent feature of the density profiles of in situ measurements in the inner magnetosphere. We further investigate the correlation between the density cavities and the enhancement of fluxes of warm ions with energies of 10–100 eV. The results show that warm ion flux enhancements associated with the density cavities were observed more frequently for H + , then for He + and the least frequently for O + . The occurrences of the associated flux enhancements were increased when considering only the cavities inside the plasmasphere. Possible mechanisms responsible for the observed warm ion flux enhancements and the role of density cavities on these ion flux enhancements are discussed.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1987

Magnetosheath quasi-trapped distributions and ion flows associated with reconnection

Using a sample of ISEE 1 and 2 magnetopause crossings previously identified as times of quasi-steady reconnection, flows of medium energy ions in the magnetosheath are identified. The paper then investigates the particle pitch angle distribution immediately before and after each of these events for the signature of quasi-trapped distributions of energetic ions. Several of the ion flows identified were observed simultaneously with previously identified flux transfer events (FTEs). While FTEs identified from the magnetometer tracings typically show evidence of ion flows, the converse is not necessarily true. However, all properties of the magnetosheath ion flows are the same regardless of whether an FTE can be identified from the magnetometer data. Evidence is found for small-scale reconnection processes (FTEs, ion flows) embedded within a larger region of interconnected field, which is traced out by the quasi-trapped particles. Quasi-trapped distributions of medium-energy ions are seen to sandwich reconnection-associated ion flows in the magnetosheath. The results of this survey have been used to suggest a morphology for reconnection events that incorporates both large- and small-scale features.

Neff, J. E.↗
NASA NTRS2001

Potential Evaporite Biomarkers from the Dead Sea

The Dead Sea is located on the northern branch of the African-Levant Rift systems. The rift system, according to one model, was formed by a series of strike slip faults, initially forming approximately two million years ago. The Dead Sea is an evaporite basin that receives freshwater from springs and from the Jordan River. The Dead Sea is different from other evaporite basins, such as the Great Salt Lake, in that it possesses high concentrations of magnesium and has an average pH of 6.1. The dominant cation in the Great Salt Lake is sodium, and the pH is 7.7. Calcium concentrations are also higher in the Dead Sea than in the Great Salt Lake. Both basins are similar in that the dominant anion is chlorine and the salinity levels are approximately 20 %. Other common cations that have been identified from the waters of the Dead Sea and the Great Salt Lake include sodium and potassium. A variety of Archea, Bacteria, and a single genus of a green algal, Dunaliella, has been described from the Dead Sea. Earlier studies concentrated on microbial identification and analysis of their unique physiology that allows them to survive in this type of extreme environment. Potential microbial fossilization processes, microbial fossils, and the metallic ions associated with fossilization have not been studied thoroughly. The present study is restricted to identifying probable microbial morphologies and associated metallic ions. XRD (X Ray Diffraction) analysis indicates the presence of halite, quartz, and orthoclase feldspar. In addition to these minerals, other workers have reported potassium chloride, magnesium bromide, magnesium chloride, calcium chloride, and calcium sulfate. Halite, calcium sulfate, and orthoclase were examined in this report for the presence of microbes, microbially induced deposits or microbial alteration. Neither the gypsum nor the orthoclase surfaces possesses any obvious indications of microbial life or fossilization. The sand-sized orthoclase particles are weathered with 122 extensive fan-shaped mineral deposits. The gypsum deposits are associated with halite minerals and also exhibit extensive weathering. Halite minerals represent the only substrates that have probable rod-shaped microbial structures with long, filamentous, apical extensions. EDS (energy dispersive x-ray) analysis of the putative microbes indicates elevated calcium levels that are enriched with magnesium. The rod-shaped structures exhibit possible fossilization stages. Rhombohedralshaped minerals of magnesium-enriched calcium carbonate are deposited on the microbial surfaces, and eventually coat the entire microbial surface. The sodium chloride continues to crystallize on nearby halite surface and even crystallizes on the fossilized microbial remains. The putative fossils are found exclusively on halite surfaces, and all contained elevated levels of calcium magnesium cations. Both of these metallic cations are associated with microbial activity and fossilization. Their morphological diversity is low in comparison with the reported living Dead Sea microbial population. If we examine the fossil record for multicellular organisms, fossilization rates are lower for soft-bodied organisms than for those possessing hard parts, i.e. shells, bones. For example, smaller, single celled organisms would have a smaller chance of fossilization; their fossilized shapes could be mistaken for abiotic products. Another consideration is that dead organisms in the water column are probably utilized as a food source by other microbes before fossilization processes are completed. This may be an important consideration as we attempt to model and interpret ancient microbial environments either on Earth or on Mars.

Morris, Penny A.↗