Materials Data on Rb3Ir(NO2)6 by Materials Project
Rb(RbO6)2Ir(N2)3 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of twenty-four ammonia molecules, four iridium molecules, four rubidium molecules, and one RbO6 framework. In the RbO6 framework, Rb1+ is bonded in a distorted q4 geometry to twelve equivalent O2- atoms. All Rb–O bond lengths are 2.90 Å. O2- is bonded in a 3-coordinate geometry to two equivalent Rb1+ and one O2- atom. The O–O bond length is 1.29 Å.
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