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Materials Data on KPt by Materials Project

PtK crystallizes in the hexagonal P-6m2 space group. The structure is three-dimensional. K is bonded to six equivalent K and six equivalent Pt atoms to form distorted KK6Pt6 cuboctahedra that share corners with eighteen equivalent KK6Pt6 cuboctahedra, edges with six equivalent KK6Pt6 cuboctahedra, edges with twelve equivalent PtK6Pt6 cuboctahedra, faces with eight equivalent KK6Pt6 cuboctahedra, and faces with twelve equivalent PtK6Pt6 cuboctahedra. All K–K bond lengths are 3.00 Å. All K–Pt bond lengths are 3.19 Å. Pt is bonded to six equivalent K and six equivalent Pt atoms to form distorted PtK6Pt6 cuboctahedra that share corners with eighteen equivalent PtK6Pt6 cuboctahedra, edges with six equivalent PtK6Pt6 cuboctahedra, edges with twelve equivalent KK6Pt6 cuboctahedra, faces with eight equivalent PtK6Pt6 cuboctahedra, and faces with twelve equivalent KK6Pt6 cuboctahedra. All Pt–Pt bond lengths are 3.00 Å.

36 MATERIALS SCIENCE↗

Materials Data on K2Pt by Materials Project

K2Pt is Fluorite structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. K1+ is bonded to four equivalent Pt2- atoms to form a mixture of corner and edge-sharing KPt4 tetrahedra. All K–Pt bond lengths are 3.32 Å. Pt2- is bonded in a body-centered cubic geometry to eight equivalent K1+ atoms.

36 MATERIALS SCIENCE↗

Materials Data on KPt3 by Materials Project

KPt3 crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. K is bonded to twelve equivalent Pt atoms to form a mixture of distorted face and corner-sharing KPt12 cuboctahedra. There are six shorter (3.18 Å) and six longer (3.28 Å) K–Pt bond lengths. Pt is bonded in a 4-coordinate geometry to four equivalent K and six equivalent Pt atoms. There are two shorter (2.72 Å) and four longer (2.78 Å) Pt–Pt bond lengths.

36 MATERIALS SCIENCE↗