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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Quadrupolar Kondo effect in uranium heavy-electron materials?

The possibility of an electric quadrupole Kondo effect for a non-Kramers doublet on a uranium (U) ion is a cubic metallic host is demonstrated by model calculations showing a Kondo upturn in the resistivity, universal quenching of the quadrupolar moment, and a heavy-electron anomaly in the electronic specific heat. With inclusion of excited crystal-field levels, some of the unusual magnetic-response data in the heavy-electron superconductor UBe13 may be understood. Structural phase transitions at unprecedented low temperatures may occur in U-based heavy-electron materials.

Cox, D. L.↗
NASA NTRS2011

Experimental Shock Transformation of Gypsum to Anhydrite: A New Low Pressure Regime Shock Indicator

The shock behavior of gypsum is important in understanding the Cretaceous/Paleogene event and other terrestrial impacts that contain evaporite sediments in their targets (e.g., Mars Exploration Rover Spirit detected sulfate at Gusev crater, [1]). Most interest focuses on issues of devolatilization to quantify the production of SO2 to better understand its role in generating a temporary atmosphere and its effects on climate and biota [2,3]. Kondo and Ahrens [4] measured induced radiation emitted from single crystal gypsum shocked to 30 and 40 GPa. They observed greybody emission spectra corresponding to temperatures in the range of 3,000 to 4,000 K that are a factor of 2 to 10 times greater than calculated pressure-density energy equation of state temperatures (Hugoniot) and are high enough to melt gypsum. Chen et al. [5] reported results of shock experiments on anhydrite, gypsum, and mixtures of these phases with silica. Their observations indicated little or no devolatilization of anhydrite shocked to 42 GPa and that the fraction of sulfur, by mass, that degassed is approx.10(exp -2) of theoretical prediction. In another report of shock experiments on calcite, anhydrite, and gypsum, Badjukov et al. [6] observed only intensive plastic deformation in anhydrite shock loaded at 63 GPa, and gypsum converted to anhydrite when shock loaded at 56 GPa but have not experimentally shocked gypsum in a step-wise manner to constrain possible incipient transformation effects. Schmitt and Hornemann [7] shock loaded anhydrite and quartz to a peak pressure of 60 GPa and report the platy anhydrite grains were completely pseudomorphed by small crystallized anhydrite grains. However, no evidence of interaction between the two phases could be observed and they suggested that recrystallization of anhydrite grains is the result of a solid-state transformation. They concluded that significant decomposition of anhydrite requires shock pressures higher than 60 GPa. Gupta et al. [8] reanalyzed the calcite and anhydrite shock wave experiments of Yang [9] using improved equations of state of porous materials and vaporized products. They determined the pressures for incipient and complete vaporization to be 32.5 and 122 GPa for anhydrite GPa which is a factor of 2 to 3 lower than reported earlier by Yang [9]. These studies are not in agreement regarding the onset of sulfate decomposition and documentation of shock effects in gypsum is incomplete.

Bell, Mary S.↗
NASA NTRS1976

The Skylab S019 ultraviolet spectra of HD 153919 (=3U 1700-37) and HDE 226868 (=Cyg X-1)

Ultraviolet spectra of HD153919 (=3U1700-37) and HDE226868 (=Cyg X-1) were obtained with the ultraviolet objective-prism spectrograph of Skylab Experiment S019. The data consist of unwidened spectra which extend to 1,600A for HD153919 and to 2,400A for HDE226868. The wavelength resolution is about 2A to 1,400A and 12A at 2,000A. For HD153919, an unwidened spectrum of fair quality and extending to a wavelength of 1,600A was obtained at 22 sup h 08 sup m on 1 September 1973. The energy distribution in this spectrum generally resembles that of other reddened O stars. A break in continuum intensity seems to occur at a wavelength of about 1,720A. There is a suggestion of an emission line on the longward edge of the break but this could be either a chance clumping of grains or else a photographic edge-effect caused by the break.

Kondo, Y.↗
NASA NTRS1994

Ground based NO2 and O3 measurements by visible spectrometer at Syowa Base (69 deg S), Antarctica

The column amounts of NO2 and ozone have been measured using visible spectroscopy at Syowa Base (69 deg S) since March 1990. Ozone was also measured at the same location with a Dobson spectrometer as well as ozonesondes being flown regularly. The characteristic features of the seasonal and diurnal variations of NO2 are presented. The column ozone values from the visible spectrometers are compared with the Dobson data. The very low values of NO2 in midwinter and early spring are consistent with the conditions predicted to be needed for heterogeneous ozone destruction in early spring. In late spring and summer of 1991, NO2 amounts were considerably smaller than in 1990, presumably due to the effect of Mt. Pinatubo eruption.

Kondo, Y.↗
NASA NTRS2016

Aircraft-Measured Indirect Cloud Effects from Biomass Burning Smoke in the Arctic and Subarctic

The incidence of wildfires in the Arctic and subarctic is increasing; in boreal North America, for example, the burned area is expected to increase by 200-300 over the next 50-100 years, which previous studies suggest could have a large effect on cloud microphysics, lifetime, albedo, and precipitation. However, the interactions between smoke particles and clouds remain poorly quantified due to confounding meteorological influences and remote sensing limitations. Here, we use data from several aircraft campaigns in the Arctic and subarctic to explore cloud microphysics in liquid-phase clouds influenced by biomass burning. Median cloud droplet radii in smoky clouds were 50 smaller than in background clouds. Based on the relationship between cloud droplet number (N(liq))/ and various biomass burning tracers (BBt/ across the multi-campaign dataset, we calculated the magnitude of subarctic and Arctic smoke aerosol-cloud interactions (ACI, where ACI = (1/3) x dln(N(liq))/dln(BBt)) to be 0.12 out of a maximum possible value of 0.33 that would be obtained if all aerosols were to nucleate cloud droplets. Interestingly, in a separate subarctic case study with low liquid water content (0.02 gm/ cu m) and very high aerosol concentrations (2000-3000 cu m) in the most polluted clouds, the estimated ACI value was only 0.06. In this case, competition for water vapor by the high concentration of CCN strongly limited the formation of droplets and reduced the cloud albedo effect, which highlights the importance of cloud feedbacks across scales. Using our calculated ACI values, we estimate that the smoke-driven cloud albedo effect may decrease shortwave radiative flux by 2 and 4 W/sq or more under some low and homogeneous cloud cover conditions in the subarctic, although the changes should be smaller in high surface albedo regions of the Arctic. We lastly show evidence to suggest that numerous northern latitude background Aitken particles can interact with combustion particles, perhaps impacting their properties as cloud condensation and ice nuclei. However, the influence of background particles on smoke-driven indirect effects is currently unclear.

Arctic↗
NASA NTRS1984

Electronic structure and properties of magnetic defects in Co(1+x)Al(1-x) and Fe(1+x)Al(1-x) alloys

CoAl and FeAl compounds are developed along two directions. Magnetic susceptibility and specific heat at low temperature on (NiCo)Al and (CoFe)Al ternary alloys are in good agreement with band calculations. Results on magnetization and specific heat under field at low temperature on nonstoichiometric compounds show clearly the importance of the nearest neighbor effects. In the case of CoAl, the isolated cobalt atoms substituting aluminum are characterized by a Kondo behavior, and, for FeAl, the isolated extra iron atoms are magnetic and polarize the matrix. Moreover, for the two compounds, clusters of higher order play a considerable part in the magnetic properties for CoAl, these clusters also seem to be characterized by a Kondo behavior, for FeAl, these clusters whose moment is higher than in the case of isolated atoms, could be constituted of excess parts of iron atoms.

Abbe, D.↗
NASA NTRS1976

Effects of radiation pressure on the equipotential surfaces in X-ray binaries

Equipotential surfaces incorporating the effect of radiation pressure were computed for the X-ray binaries Cen X-3, Cyg X-1 = HDE 226868, Vela XR-1 = 3U 0900-40 = HD 77581, and 3U 1700-37 = HD 153919. The topology of the equipotential surfaces is significantly affected by radiation pressure. In particular, the so-called critical Roche (Jacobian) lobes, the traditional figure 8's, do not exist. The effects of these results on modeling X-ray binaries are discussed.

Kondo, Y.↗
NASA NTRS1987

Microturbulence in the upper photosphere of Alpha Persei (F5 Ib) derived from ultraviolet spectral observations

High-resolution ultraviolet spectra of the moderate supergiant Alpha Per (F5 Ib) were studied to determine the dynamic state of its upper photosphere. It was found that the line-of-sight microturbulent velocity component in the region of origin of the UV spectrum is about 5 km/s, and is slightly smaller than the value derived from the visual spectrum. This is ascribed to dissipation of mechanical energy between the higher and lower layers where, respectively, the ultraviolet and visual light lines originate. Between these two levels, which are one scale height apart, the mechanical energy flux decreases to about 0.3 of its photospheric value. The consequent value for the (outward directed) turbulent acceleration is 24 cm/sec-squared, more than one half the observationally determined effective acceleration of gravity.

Spaan, F. H. P.↗
NASA NTRS1991

A cool supergiant with anomalous behavior of the 2800 Mg II doublet

The IUE ultraviolet spectrum for a supergiant of type G Ia, HD 135345, is obtained for the wavelength region 2000-3000 A. In the spectrum, the continuum as well as the feature of the Mg II doublet at 2800 A is found to be anomalous. The observed level of continuum increases toward short wavelengths to 2000 A, verifying that this supergiant is actually a binary system with a hot companion. The anomalies in the magnesium doublet are the complete absence of the chromospheric emission and the very small equivalent width of the doublet absorption: the equivalent width is 4 A, which is 7.5 times smaller than that for a typical G5 star. The main parameters of the binary system are obtained, namely, spectral classes, effective temperatures, ratio of radii, and visible magnitudes.

Gurzadian, G. A.↗
NASA NTRS1986

Scattered light in the IUE spectra of Epsilon Aurigae

Recent infrared photometry indicates that the alleged disk of particulate matter surrounding the mysterious secondary object in the Epsilon Aur system is cold, around 500 K. IUE spectra, on the other hand, contain significant flux in excess of that expected from an F0 Ia star in the far UV, which if interpreted as a hot secondary star leads to a possible contradiction with the IR data. Other models of the UV excess have been proposed, including the idea that the bulk of the short-wavelength flux is light scattered into the SWP camera from longer wavelengths. With the recent availability of a detailed generalized IUE descattering algorithm it is possible to thoroughly investigate the scattered-light contribution to the short-wavelength continuum. It is found that the IUE spectra are indeed partially contaminated by scattered light, but that even after correction for this instrumental effect a significant time-dependent UV excess is still present.

Altner, B.↗
NASA NTRS1973

The effect of Fe I absorption on the Mg II emission at 2795 A in alpha Orionis

The Fe I absorption line at 2795.01 A is derived from the observations of Mg II resonance emission in alpha Orionis by Kondo et al (1972). A spectrum is synthesized, including Mg II emission and self-absorption and also Fe I absorption, which accounts for the observed asymmetry in the Mg II 2795.5 line and for the discrepancy between the theoretical and observed intensity ratios of the two Mg II lines. The astrophysical significance of this strong Fe I absorption is discussed.

Modisette, J. L.↗
NASA NTRS1976

Mass flow in the O7f binary UW Canis Majoris. II

The far-ultraviolet spectrum of UW CMa was obtained from the telescope spectrometer on the Copernicus satellite at about phase 0.25 in order to supplement earlier observations of the same kind made near phase 0.75. Analysis of the data shows that the high-temperature gas giving rise to the P Cygni features in the far-ultraviolet spectrum is located primarily around the entire binary system and does not share in the motion of either component. The effects of radiation pressure on the Roche (Jacobian) equipotential surfaces and in generating a stellar wind are discussed.

Mccluskey, G. E., Jr.↗
NASA NTRS1999

Impact of Aircraft Emissions on Reactive Nitrogen over the North Atlantic Flight Corridor Region

The impact of aircraft emissions on reactive nitrogen in the upper troposphere (UT) and lowermost stratosphere (LS) was estimated using the NO(y)-O3 correlation obtained during the SASS Ozone and NO(x) Experiment (SONEX) carried out over the US continent and North Atlantic Flight Corridor (NAFC) region in October and November 1997. To evaluate the large scale impact, we made a reference NO(y)-O3 relationship in air masses, upon which aircraft emissions were considered to have little impact. For this purpose, the integrated input of NO(x) from aircraft into an air mass along a 10-d back trajectory (DELTA-NO(y)) was calculated based on the ANCAT/EC2 emission inventory. The excess NO(y) (dNO(y)) was calculated from the observed NO(y) and the reference NO(y)-O3 relationship. As a result, a weak positive correlation was found between the dNO(y) and DELTA-NO(y), and dNO(y) and NO(x)/NO(y) values, while no positive correlation between the dNO(y) and CO values was found, suggesting that dNO(y) values can be used as a measure of the NO(x) input from aircraft emissions. The excess NO(y) values calculated from another NO(y)-O3 reference relationship made using in-situ CN data also agreed with these dNO(y) values, within the uncertainties. At the NAFC region (45 N - 60 N), the median value of dNO(y) in the troposphere increased with altitude above 9 km and reached 70 pptv (20% of NO(y)) at 11 km. The excess NO(x) was estimated to be about half of the dNO(y) values, corresponding to 30% of the observed NO(x) level. Higher dNO(y) values were generally found in air masses where O3 = 75 - 125 ppbv, suggesting a more pronounced effect around the tropopause. The median value of dNO(y) in the stratosphere at the NAFC region at 8.5 - 11.5 km was about 120 pptv. The higher dNO(y) values in the LS were probably due to the accumulated effect of aircraft emissions, given the long residence time of affected air in the LS. Similar dNO(y) values were also obtained in air masses sampled over the US continent.

Koike, M.↗