Stepwise heating analyses of rare gases from pile-irradiated rocks 10044 and 10057
Ar, Kr and Xe emanation during stepwise heating of lunar rocks under slow neutron irradiation in pile, using mass spectroscopy
Davis, P. K.↗
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Trapping of noble gases in proton-irradiated silicate smokes
We have measured Ne, Ar, Kr, and Xe in Si2O3 'smokes' that were condensed on Al substrates, vapor-deposited with various mixtures of CH4, NH3, H2O3 and noble gases at 10 K and subsequently irradiated with 1 MeV protons to simulate conditions during grain mantle formation in interstellar clouds. Neither Ne nor Ar is retained by the samples upon warming to room temperature, but Xe is very efficiently trapped and retained. Kr is somewhat less effectively retained, typically depleted by factors of about 10-20 relative to Xe. Isotopic fractionation favoring the heavy isotopes of Xe and Kr of about 5-10-percent/amu is observed. Correlations between the specific chemistry of the vapor deposition and heavy noble gas retention are most likely the result of competition by the various species for irradiation-produced trapping sites. The concentration of Xe retained by some of these smokes exceeds that observed in phase Q of meteorites and, like phase Q, they do not seem to be carriers of the light noble gases.
Nichols, R. H., Jr.↗
Cosmic-ray-produced Kr in St. Severin core AIII
Kr isotopic abundances in 10 samples from core AIII of the St. Severin chondrite are reported, and the variation with depth of cosmic-ray produced Kr is discussed. It is shown that the ratio (Kr-78/Kr-83)c changes with depth and can be used as an irradiation hardness monitor. Cosmic-ray-produced Kr and Ne in the St. Severin core are compared with ratios observed in bulk chondrites. A linear correlation between (Ne-22/Ne-21)c and (Kr-78/Kr-83)c exists for bulk samples of chondrites of varying preatmospheric size, but does not exist in the St. Severin core. The calculated Kr-83 production rates, P83, are similar in H, L, and LL chondrites for samples of comparable shielding conditions. However, P83 rates increase by a factor of about 2 with shielding depth. The maximum observed P83 values correspond to (Kr-78/Kr-83)c factor of about 2 with shielding depth. The maximum observed P83 values correspond to (Kr-78/Kr-83)c less than about 0.14.
Lavielle, B.↗
A long-term change of the AR/KR/XE fractionation in the solar corpuscular radiation
Solar noble gases in an ilmenite separate from breccia 79035 (antiquity greater than 1 Ga) were analyzed by closed system stepped etching (CSSE). All five gases show the familiar two-component structure: first solar-wind (SW) gases are released, followed by gases from solar energetic particles (SEP). Element patterns in 79035 are similar to those of 71501 ilmenite. SW-He-Ne were partly lost, but SEP-He-Ne-Ar are retained (nearly) unfractionated. Constant Ar/Kr/Xe ratios indicate that ilmenites contain an unfractionated sample of the heavy SW-SEP noble gases. Ar/Kr/Xe ratios in the solar corpuscular radiation are, however, different from 'solar system' values, whereby the Kr/Xe difference in 79035 is about twice as large as in 71501. We propose that Xe is less fractionated than Kr and Ar, though its first ionization potential (FIP) is higher than the 'cutoff' at approximately 11.5 eV, above which all elements in SEP are usually assumed to be depleted by a roughly constant factor. SW-Ne may be isotopically slightly heavier in the ancient SW trapped by 79035, as proposed earlier. In this work we extend our previous CSSE studies of solar noble gases including Kr and Xe to a lunar sample irradiated at least 1 Ga ago (breccia 79035, ilmenite separate, 42-64 microns). This sample was particularly gently etched in the first steps. Surprisingly, the first three steps, each releasing less than or equal to 0.5% of the total 36-Ar, showed an SEP-like trapped component plus relatively large concentrations of cosmogenic gases. Steps 4ff contain much less cosmogenic and more solar gas with a SW-like isotope pattern. Thus, a very minor easily etchable phase that has completely lost its SW-gases must be responsible for steps 1-3. We will not discuss these steps here and refer to the actual step 4 as the 'initial' etching step.
Wieler, R.↗
Characteristics of tracks of ions of 14 less than or equal to Z less than or equal to 36 in common rock silicates.
Identification of heavy ion tracks in minerals by measurements of track etch rates and total etchable track lengths were irradiated with beams of Si, Cl, Ti, Fe, Zn, and Kr at energies up to 10.35 MeV/nucleon. Nine minerals commonly used to study fossil cosmic ray tracks in meteorites and lunar samples. From measurements of etched track length as a function of residual range, response curves for various minerals were determined as a function of ionization rate, using the expression previously derived by Price et al. (1968). These curves increase smoothly with ionization rate instead of rising abruptly at some critical value as was previously thought. It is shown that the track etch rate concept accounts qualitatively for total etchable track length distributions, but that the positions of the peaks of different elements in these histograms occur at shorter lengths for fossil tracks than for fresh tracks. Annealing data indicate that, at maximum lunar surface temperatures, tracks in olivine, orthopyroxenes, and feldspars may be significantly shortened, whereas tracks in clinopyroxenes will not be affected.
Price, P. B.↗
Neutron capture effects in lunar gadolinium and the irradiation histories of some lunar rocks.
The Gd isotopic composition in 19 lunar rock and soil samples from three Apollo sites is reported. The analytical techniques and the high precision mass spectrometric measurements are discussed. Enrichments in the Gd-158 oxide to G-157 oxide ratio due to neutron capture range up to 0.75%. Integrated 'thermal' neutron fluxes derived from the isotopic anomalies of Gd are compared with spallation Kr data from aliquot samples to construct a model which gives both average cosmic-ray irradiation depths and effective neutron exposure ages for some rocks. Rock 14310 is the first lunar sample where Kr anomalies due to resonance neutron capture in Br are observed. A Kr-81/Kr exposure age of 262 (plus or minus 7)m.y. is calculated for this rock.
Lugmair, G. W.↗
Spallogenic Ne, Kr, and Xe from a depth study of 12002
Isotopic abundances and concentrations of spallogenic Ne, Kr and Xe in Apollo 12 rock 12002, constructing three stage model of irradiation history
Alexander, E. C., Jr.↗
Cosmic-ray exposure history of North Ray and South Ray material
Cosmic-ray exposure ages for two breccias, 68815 and 69935, in the vicinity of South Ray Crater give consistent values of 2.0 plus or minus 0.2 m.y. when measured by the Kr-81-Kr, Na-22-Ne, and particle track methods. These also agree with estimates of exposure ages made by others using microcrater counts on six rocks in the same vicinity, including 69935. It is likely that this represents the age of South Ray Crater. Soils from stations close to South Ray Crater appear to be mature, well-irradiated materials containing little, if any, of a 2 m.y. component. Reviewing various lines of evidence, it is concluded that there are no compelling reasons to believe that so-called South Ray soils contain a large fraction of South Ray ejecta. However, if they do contain such ejecta, this material must have been well irradiated in situ prior to being thrown out in the South Ray event. A chip from a large boulder on the rim of North Ray Crater gives a Kr-81-Kr age of 50.6 plus or minus 3.8 m.y. Similar ages are found by the Na-22-Ne and the particle track methods. The agreement of this result with other data on large North Ray boulders fixes the age of North Ray Crater as 50 m.y.
Behrmann, C.↗
Cosmic ray exposure ages of chondrites, pre-irradiation and constancy of cosmic ray flux in the past
Calibration of the production rate of the Ne-21 nuclide was accomplished by 4 methods based on (Al-26)-age, (Mn-53)-age, Kr-81/Kr-83, and Na-22/Ne-22. These production rates are normalized to a shielding parameter ratio Ne-22/Ne-21 = 1.11 and to the chemical composition of L chondrites; a value of P(21)(1.11) = 0.31 is suggested, and a production rate equation derived in terms of the 'F' parameters for L, LL, and H chondrites. The Al-26 half-life measurements are considered to evaluate the effects resulting from preirradiation of meteorites and to examine the data on the constancy of the cosmic ray flux in the light of current astronomical observations.
Nishizumi, K.↗
Predicted versus observed cosmic-ray-produced noble gases in lunar samples - Improved Kr production ratios
New sets of cross sections for the production of krypton isotopes from targets of Rb, Sr, Y, and Zr have been constructed primarily on the bases of experimental excitation functions for Kr production from Y. These cross sections were used to calculate galactic-cosmic-ray and solar-proton production rates for Kr isotopes in the moon. The paper reports spallation Kr data obtained from ilmenite separates of rocks 10017 and 10047. Production rates and isotopic ratios for cosmogenic Kr observed in ten well-documented lunar samples and in ilmenite separates and bulk samples from several lunar rocks with long but unknown irradiation histories were compared with predicted rates and ratios. The agreements were generally quite good.
Regnier, S.↗
Sulfur Isotopes in Gas-rich Impact-Melt Glasses in Shergottites
Large impact melt glasses in some shergottites contain huge amounts of Martian atmospheric gases and they are known as gas-rich impact-melt (GRIM) glasses. By studying the neutron-induced isotopic deficits and excesses in Sm-149 and Sm-150 isotopes resulting from Sm-149 (n,gamma) 150Sm reaction and 80Kr excesses produced by Br-79 (n,gamma) Kr-80 reaction in the GRIM glasses using mass-spectrometric techniques, it was shown that these glasses in shergottites EET79001 and Shergotty contain regolith materials irradiated by a thermal neutron fluence of approx.10(exp 15) n/sq cm near Martian surface. Also, it was shown that these glasses contain varying amounts of sulfates and sulfides based on the release patterns of SO2 (sulfate) and H2S (sulfide) using stepwise-heating mass-spectrometric techniques. Furthermore, EMPA and FE-SEM studies in basaltic-shergottite GRIM glasses EET79001, LithB (,507& ,69), Shergotty (DBS I &II), Zagami (,992 & ,994) showed positive correlation between FeO and "SO3" (sulfide + sulfate), whereas those belonging to olivine-phyric shergottites EET79001, LithA (,506, & ,77) showed positive correlation between CaO/Al2O3 and "SO3".
Rao, M. N.↗
Isotopic anomalies and proton irradiation in the early solar system
Nuclear cross sections relevant to the various isotopic-abundance anomalies found in solar-system objects are evaluated in an attempt to set constraints on the hypothesized mechanism of irradiation of forming planetesimals by energetic protons from the young sun. A power-law proton spectrum is adopted, attention is restricted to proton energies less than about 20 MeV, and average cross sections are calculated for several reactions that might be expected to lead to the observed anomalies. The following specific anomalies are examined in detail: Al-26, Na-22, Xe-126, I-129, Kr-80, V-50, Nb-92, La-138, Ta-180, Hg-196, K-40, Ar-36, O-17, O-18, N-15, C-13, Li, Be, and B. It is suggested that the picture of presolar-grain carriers accounts for the facts more naturally than do irradiation models.
Clayton, D. D.↗
Noble gases in 60009-60010 drive tube samples - Trapped gases and irradiation history
Concentrations and isotopic composition of noble gases are reported for grain size separates: nine soils from the 60010-60009 double drive tube, two soils from the 60007 drill core section, and surface soil 65501. Data are reported on concentrations of solar wind gases, surface-correlated gases (involving solar wind and lunar atmosphere), surface maturity indices, cosmogenic gases, possible soil mixing, and irradiation by cosmic rays. Good correlation is found between solar wind gases in 60009 soils and such surface maturity indices as petrographic agglutinates, magnetic soil fraction, and fine-grained iron. Cosmogenic He-3, Ne-21, Ar-38, Kr-80, and Xe-126 all display close correlations in the drive tube soils.
Bogard, D. D.↗
Isotopic Evidence for a Martian Regolith Component in Martian Meteorites
Noble gas measurements in gas-rich impact-melt (GRIM) glasses in EET79001 shergottite showed that their elemental and isotopic composition is similar to that of the Martian atmosphere [1-3]. The GRIM glasses contain large amounts of Martian atmospheric gases. Those measurements further suggested that the Kr isotopic composition of Martian atmosphere is approximately similar to that of solar Kr. The (80)Kr(sub n) - (80)Kr(sub M) mixing ratio in the Martian atmosphere reported here is approximately 3%. These neutron-capture reactions presumably occurred in the glass-precursor regolith materials containing Sm- and Br- bearing mineral phases near the EET79001/ Shergotty sites on Mars. The irradiated materials were mobilized into host rock voids either during shock-melting or possibly by earlier aeolian / fluvial activity.
Rao, M. N.↗
Cosmic-ray exposure history at the Apollo 16 and other lunar sites - Lunar surface dynamics
Concordant Kr-81/Kr exposure ages for four station 11 breccias indicate an age of 50.3 plus or minus 0.8 m.y. for North Ray Crater. Ray structures visible from orbital photography suggest that stations 8 and 9 should contain a substantial amount of South Ray ejecta. Concordant Kr-81/Kr exposure ages at these sites indicate an age for South Ray Crater of 2.04 plus or minus 0.08 m.y. Surface effects show good general agreement with this young age, but discrepancies on a sample-by-sample basis seem to indicate that extensive presurface irradiations must have occurred.
Drozd, R. J.↗
Single event upset vulnerability of selected 4K and 16K CMOS static RAM's
Upset thresholds for bulk CMOS and CMOS/SOS RAMS were deduced after bombardment of the devices with 140 MeV Kr, 160 MeV Ar, and 33 MeV O beams in a cyclotron. The trials were performed to test prototype devices intended for space applications, to relate feature size to the critical upset charge, and to check the validity of computer simulation models. The tests were run on 4 and 1 K memory cells with 6 transistors, in either hardened or unhardened configurations. The upset cross sections were calculated to determine the critical charge for upset from the soft errors observed in the irradiated cells. Computer simulations of the critical charge were found to deviate from the experimentally observed variation of the critical charge as the square of the feature size. Modeled values of series resistors decoupling the inverter pairs of memory cells showed that above some minimum resistance value a small increase in resistance produces a large increase in the critical charge, which the experimental data showed to be of questionable validity unless the value is made dependent on the maximum allowed read-write time.
Kolasinski, W. A.↗
Heavy-element abundances from a neutron burst that produces Xe-H
We examine quantitatively the suggestion that the heavy anomalous isotopes of Xe-HL found in meteoritic diamonds were produced by a short intense neutron burst and then implanted into the diamonds. Using a large nuclear reaction network we establish one (out of many) neutron irradiation hostories that successfully reproduces the heavy isotopes of Xe-HL, and then evaluate what that same history would produce in every heavy element. This has become more relevant following recent measurement of anomalous Ba and Sr in those same diamond samples. Therefore we offer these calculations as a guide to the anomalies to be expected in all elements if this scenario is correct. We also discuss several other aspects of the problem, especially the established contradictions for Ba, the observed Kr pattern, the near normalcy of Xe-129 and some related astrophysical ideas. In particular we argue from p-process theory that the observed deficit of Kr-78 in correlation with Xe-(124-126) excess implicates Type II supernovae as the diamond sources.
Howard, W. M.↗
Trapped solar and cosmogenic noble gas abundances in Apollo 15 and 16 deep drill samples
Abundances and isotopic compositions of all the stable noble gases (He, Ne, Ar, Kr, Xe) were measured at different depths of the Apollo 15 and Apollo 16 deep drill cores, and in several surface fines and breccias. All samples analyzed from both drill cores were found to contain large concentrations of solar wind implanted gases. This means that even the deepest layers of both cores have experienced a lunar surface history. The Apollo 15 core data are consistent with a combined accretion plus static time of a few hundred million years, and also indicate variable pre-accretion irradiation of core material. Depth profiles of cosmogenic gases in the Apollo 16 core show considerably larger concentrations of cosmic gases below 65 cm depth than above. This pattern may be interpreted either as an accretionary process, or by a more recent deposition of regolith to the upper 70 cm of the core.
Bogard, D. D.↗