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Legacy Facility Risk Reduction - Challenges, Strategies, Partnerships, and Benefits Lawrence Livermore National Laboratory - 18463

As Lawrence Livermore National Laboratory (LLNL) carries out its national security missions, we strive to ensure our facility portfolio meets the latest technologies and addresses challenges presented by its aging infrastructure. Established in 1942 as a Naval Air Station, repurposed in 1952 by the Atomic Energy Commission (AEC), LLNL continues to host a robust National Nuclear Security Administration (NNSA) Research and Development (R and D) mission. As an aging site, many of its facilities have met their life cycle contribution. As process contaminated facilities are decommissioned, new challenges arise in their near-term stewardship and long-term disposition actions, presenting risk reduction opportunities. The challenge has been to determine approaches to steward such risks, stabilize, advocate for long-term mitigation, and take actions to eliminate risks. Encumbered within is the balance of priorities in supporting ongoing and emerging mission and those of past legacy activities. This paper will endeavor to highlight Challenges and Benefits presented by such a paradigm, where we identified Strategies and Partnerships working towards mutual Risk Reduction activities. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Abstract for CRADA among National Energy Technology Laboratory, Research Triangle Institute, Lawrence Livermore National Laboratory, and Los Alamos National Laboratory (AGMT-0921)

Through the Carbon Capture Simulation for Industry Impact (CCSI 2 ) project, the National Energy Technology Laboratory (NETL), Lawrence Livermore National Laboratory (LLNL), and Los Alamos National Laboratory (LANL) (herein collectively “the CCSI 2 team”) will collaborate through a CRADA with the Research Triangle Institute (RTI). This collaboration will develop a modeling framework of RTI’s Non-Aqueous Solvent (NAS) process using physical and thermodynamic data and models previously developed by RTI. RTI will provide existing models and data on its NAS system to inform the model construction effort by the CCSI 2 team.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

OPCW Twining Project Visit by the National Laboratory of Scientific and Technical Police (LNPST) to Lawrence Livermore National Laboratory Forensic Science Center (LLNL)

PURPOSE FOR TRIP Through the Organisation for Prohibition of Chemical Weapons (OPCW) Twinning and Assistance Program, Lawrence Livermore National Laboratory, Forensic Science Center (LLNL) has been paired with Morocco’s National Laboratory of Scientific and Technical Police (LNPST), with the goal of mentoring LNPST to become an OPCW Designated Laboratory. The purpose of this visit was for LLNL staff to mentor staff from LNPST as they participated in hands-on, laboratory-based exercises to analyze proficiency test samples prepared by LLNL. This visit was designed to help LNPST scientists strengthen their skills in OPCW proficiency testing.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Lawrence Livermore National Laboratory Site Annual Environmental Report 2020

Lawrence Livermore National Laboratory (LLNL) is a premier research laboratory that is part of the National Nuclear Security Administration (NNSA) within the U.S. Department of Energy (DOE). As a national security laboratory, LLNL is responsible for ensuring that the nation’s nuclear weapons remain safe, secure, and reliable. The Laboratory also meets other pressing national security needs, including countering the proliferation of weapons of mass destruction and strengthening homeland security, and conducting major research in atmospheric, earth, and energy sciences, bioscience and biotechnology, and engineering, basic science, and advanced technology. The Laboratory is managed and operated by Lawrence Livermore National Security, LLC (LLNS), and serves as a scientific resource to the U.S. government and a partner to industry and academia.

54 ENVIRONMENTAL SCIENCES↗

Lawrence Livermore National Laboratory Environmental Report 2021

The purposes of the Lawrence Livermore National Laboratory Environmental Report 2021 are to record Lawrence Livermore National Laboratory’s (LLNL’s) compliance with environmental standards and requirements, describe LLNL’s environmental protection and remediation programs, and present the results of environmental monitoring at the two LLNL sites—the Livermore Site and Site 300. The report is prepared for the U.S. Department of Energy (DOE) by LLNL’s Environmental Functional Area. Submittal of the report satisfies requirements under DOE Order 231.1B, “Environment, Safety and Health Reporting,” and DOE Order 458.1, “Radiation Protection of the Public and Environment.” The report is distributed electronically and is available at https://saer.llnl.gov/, the website for the LLNL annual environmental report. Previous LLNL annual environmental reports beginning with 1994 are also on the website. Some references in the electronic report text are underlined, which indicates that they are clickable links. Clicking on one of these links will open the related document, data workbook, or website. Sampling location maps throughout this report were created using ArcGIS® software by Esri. The report begins with an executive summary, which provides the purpose of the report and an overview of LLNL’s compliance and monitoring results. The first three chapters provide background information: Chapter 1 is an overview of the location, meteorology, and hydrogeology of the two LLNL sites; Chapter 2 is a summary of LLNL’s compliance with environmental regulations; and Chapter 3 is a description of LLNL’s environmental programs with an emphasis on the Environmental Management System including pollution prevention. The majority of the report covers LLNL’s environmental monitoring programs and monitoring data for 2021: effluent and ambient air monitoring and dose assessment (Chapter 4); waters, including wastewater, storm water runoff, surface water, rain, and groundwater (Chapter 5); and terrestrial, including soil, sediment, vegetation, foodstuff, ambient radiation, and special status wildlife and plants (Chapter 6). The remaining two chapters discuss LLNL’s groundwater remediation program (Chapter 7), and quality assurance for the environmental monitoring programs (Chapter 8). Complete monitoring data, which are summarized in the body of the report, are provided in Appendix A. The report uses Système International units, consistent with the federal Metric Conversion Act of 1975 and Executive Order 12770, “Metric Usage in Federal Government Programs” (1991). For ease of comparison to environmental reports issued prior to 1991, dose values and many radiological measurements are given in both metric and U.S. customary units. A conversion table is provided in the glossary. The report is the responsibility of LLNL’s Environmental Functional Area. Monitoring data were obtained through the combined efforts of the Environmental Functional Area; Environmental Restoration Department; Physical and Life Sciences Environmental Monitoring Radiological Laboratory; and the Radiation Protection Functional Area.

54 ENVIRONMENTAL SCIENCES↗

An Overview of Nondestructive Evaluation and Characterization at Lawrence Livermore National Laboratory

For more than 60 years, Lawrence Livermore National Laboratory (LLNL) has developed and employed advanced technologies in both nondestructive evaluation (NDE) and nondestructive characterization (NDC) to enhance national security. Additonally, the Laboratory established an extensive array of NDC capabilities that enable the inspection and characterization of virtually every element on the periodic table. This allows for the evaluation of structures of interest with densities ranging from ~20 mg/cm 3 to approximately 20 g/cm 3 , across length scales from nanometers to meters, and over time scales ranging from microseconds to decades. This paper provides an overview of the NDE and NDC activities at LLNL, illuminating current research and development interests in well-established areas such as weapons and explosives research, and in new areas such as additive manufacturing. Traditional NDC techniques, such as X-ray radiography and computed tomography, are also discussed. Furthermore, new approaches, such as X-ray phase-contrast imaging and X-ray ptychography, are examined.

36 MATERIALS SCIENCE↗

Ceramic High Efficiency Particulate Air (HEPA) Filter Research and Development at Lawrence Livermore National Laboratory

Ceramic high efficiency particulate air (HEPA) filter development program began at Lawrence Livermore National Laboratory (LLNL) over 20 years ago. Historical incidents motivated current safety systems at nuclear facilities. A ceramic filter that can survive a fire can provide robust, passive safety protection. Research has been conducted to improve the safety of nuclear facilities and to reduce operational and lifecycle costs, through ceramic filter technology that can survive fire conditions. Here, the research focused on applications in both new facilities as well as meeting operational requirements necessary to retrofit filters into existing DOE facilities. The research has developed multiple filter technologies spanning traditional HEPA filter materials to advanced manufacturing technologies (e.g., electrospinning, additive manufacturing, etc.). This communication will present highlights of selected development efforts for ceramic HEPA filter research, current state-of-the-art for ceramic filters, and future needs including technical, regulatory, and commercial efforts.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Lawrence Livermore National Laboratory (2022 Annual Site Environment Report (ASER))

Lawrence Livermore National Laboratory (LLNL) is a premier research laboratory that is part of the National Nuclear Security Administration (NNSA) within the U.S. Department of Energy (DOE). As a national security laboratory, LLNL is responsible for ensuring that the nation’s nuclear weapons remain safe, secure, and reliable. The Laboratory also meets other pressing national security needs including countering the proliferation of weapons of mass destruction, strengthening homeland security, and conducting major research in atmospheric, earth, and energy sciences, bioscience and biotechnology, and engineering, basic science, and advanced technology. The Laboratory is managed and operated by Lawrence Livermore National Security, LLC (LLNS) and serves as a scientific resource to the U.S. government and a partner to industry and academia.

54 ENVIRONMENTAL SCIENCES↗

Status of Mercury and Imp: Two Monte Carlo Transport Codes Developed Using Shared Infrastructure at Lawrence Livermore National Laboratory

The Monte Carlo Transport Project at Lawrence Livermore National Laboratory develops two Monte Carlo transport codes used in production by a sizable internal user community. Mercury is a Monte Carlo particle transport code used to model the interaction of neutrons, gammas, and light ions with a material. Imp is an implicit Monte Carlo thermal x-ray photon transport code used to model the interaction of x-ray photons with a material. This paper describes the two codes and highlights recent developments.

Pozulp, Michael↗

Precision and manufacturing at the Lawrence Livermore National Laboratory

Precision Engineering is one of the Lawrence Livermore National Laboratory's core strengths. This paper discusses the past and present current technology transfer efforts of LLNL's Precision Engineering program and the Livermore Center for Advanced Manufacturing and Productivity (LCAMP). More than a year ago the Precision Machine Commercialization project embodied several successful methods of transferring high technology from the National Laboratories to industry. Currently, LCAMP has already demonstrated successful technology transfer and is involved in a broad spectrum of current programs. In addition, this paper discusses other technologies ripe for future transition including the Large Optics Diamond Turning Machine.

Saito, Theodore T.↗

Performance Audit Report: Automated Meteorological Monitoring Stations, Lawrence Livermore National Laboratory

The Waste and Air Quality Offices Group at the Lawrence Livermore National Laboratory operates two main meteorological monitoring sites near Livermore, California. The primary met tower (Site 200) is located in the northwest corner of the lab and consists of a fifty-two (52) meter tower with vertical wind speed sensors, horizontal wind speed and direction sensors and air temperature sensors at fifty-two (52) meters, twenty-three (23) meters and ten (10) meters. In addition, there is a temperature and humidity probe at ten (10) meters. At two (2) meters there are upward and downward facing solar and infrared radiation sensors, an air temperature sensor, barometric pressure sensor and a temperature and relative humidity probe. At ground level there is a tipping bucket rain gauge located to the southwest of the tower. The datalogger, communication peripherals and the barometric pressure sensor are housed in a small building near the tower. The Site 300 met site is located approximately 10 miles east of Livermore within the boundary of the LLNL blast test site. This site also consists of a 52-meter tower which is configured the same as the 52-meter tower at Site 200. There is also a building at this site that houses the datalogger, communication peripherals and the barometric pressure sensor. At both Site 200 and Site 300, data are collected by Ethernet with telephone modem collection as a backup. The data collection interval for both sites is fifteen (15) minutes via workstations running Loggernet software located at the main lab facility. The audits of the Lawrence Livermore National Laboratory’s two automated meteorological stations located near Livermore, California were performed on October 24 & 25, 2023. These audits were performed under the guidelines of the Quality Assurance Handbook for Air Pollution Measurement Systems, Volume IV, Version 2 and the On-Site Meteorological Program Guidance for Regulatory Modeling Applications, U.S. EPA.

54 ENVIRONMENTAL SCIENCES↗

Lawrence Livermore National Laboratory (LLNL) Laboratory Directed Research and Development (LDRD) Annual Report (FY 2023)

As Lawrence Livermore National Laboratory’s most significant resource for supporting internally directed research and development, the LDRD Program provides investments in cutting-edge science and technology that allow the Laboratory to attract and retain the world’s most talented scientists and engineers and enables them to expand the frontiers of knowledge and anticipate emerging national security challenges. In this annual report, we summarize how Lawrence Livermore National Laboratory (LLNL) uses LDRD investments to advance our knowledge in strategic science and technology domains, develop our world-class workforce, and foster innovation in key programmatic areas.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Statistically Significant Evidence of a Release of Zinc from Pit 1 at the Lawrence Livermore National Laboratory Experimental Test Site 300 (90-Day Report)

Lawrence Livermore National Laboratory (LLNL) is submitting this 90-Day Report in accordance with Waste Discharge Requirements Order No. 93-100, Provision 4. This letter report is provided in reference to several seven-day letters in which LLNL reported that ground water sample analytical results from monitoring wells Kl-05, Kl-08, Kl-09, and W-PITl-2326 indicated "statistically significant evidence of a release" of zinc from LLNL's Site 300 Experimental Test Facility landfillPit 1 (Figure 1).

54 ENVIRONMENTAL SCIENCES↗

Mesocarnivore Surveys on Lawrence Livermore National Laboratory Site 300 Alameda and San Joaquin Counties, California

Lawrence Livermore National Laboratory (LLNL), operated under cooperative agreement between the University of California and the U. S. Department of Energy, administers and operates an approximately 11 mi2 (2$ km2) test site in the remote hills at the northern end of the South Coast Ranges of Central California. Known as Site 300, this expanse of rolling hills and canyons supports a diverse array of grassland communities typical of lowland central California. The facility serves a variety of functions related to testing non-nuclear explosives, lasers, and weapons subsystems. The primary purpose of this project was to determine the presence of any mesocamivores on Site 300 that use the property for foraging, denning, and other related activities. The surveys occurred from mid-September to mid-October, 2002.

54 ENVIRONMENTAL SCIENCES↗

Lawrence Livermore National Laboratory Annual Environmental Report 2019

The purposes of the Lawrence Livermore National Laboratory (LLNL) Environmental Report 2019 are to record LLNL's compliance with environmental standards and requirements, describe LLNL’s environmental protection and remediation programs, and present the results of environmental monitoring at the two LLNL sites—the Livermore Site and Site 300. The report is prepared for the U.S. Department of Energy (DOE) by LLNL’s Environmental Functional Area. Submittal of the report satisfies requirements under DOE Order 231.1B, “Environment, Safety and Health Reporting,” and DOE Order 458.1, “Radiation Protection of the Public and Environment.” The report begins with an executive summary, which provides the purpose of the report and an overview of LLNL’s compliance and monitoring results. The first three chapters provide background information: Chapter 1 is an overview of the location, meteorology, and hydrogeology of the two LLNL sites; Chapter 2 is a summary of LLNL’s compliance with environmental regulations; and Chapter 3 is a description of LLNL’s environmental programs with an emphasis on the Environmental Management System including pollution prevention. The majority of the report covers LLNL’s environmental monitoring programs and monitoring data for 2019: effluent and ambient air monitoring and dose assessment (Chapter 4); waters, including wastewater, storm water runoff, surface water, rain, and groundwater (Chapter 5); and terrestrial, including soil, sediment, vegetation, foodstuff, ambient radiation, and special status wildlife and plants (Chapter 6). The remaining two chapters discuss LLNL’s groundwater remediation program (Chapter 7), and quality assurance for the environmental monitoring programs (Chapter 8). Complete monitoring data, which are summarized in the body of the report, are provided in Appendix A.

54 ENVIRONMENTAL SCIENCES↗