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Availability Estimates of Low-Cost, Dispatch-Constrained Electricity (LDE)

This dataset accompanies the report "Potential Availability of and Supply Curves for Low-Cost, Dispatch-Constrained Electricity", which provides initial estimates of the quantity and availability of the potential low-cost, dispatch-constrained electricity (LDE) resource in the United States under scenarios with high variable renewable energy (VRE) penetrations. The analysis also estimates supply curves that can be used in subsequent analysis of the opportunity to use the LDE. The estimated LDE resource could be used for various applications that value low-cost electricity and can operate at reduced capacity factors, including electrolytic hydrogen production and carbon capture. The analysis accompanying this dataset was performed in 2018-2019 to support an analysis of "The Technical and Economic Potential of the H2@Scale Concept within the United States" ( https://www.nlr.gov/docs/fy21osti/77610.pdf ). This dataset includes the quantity of estimated LDE resource for each hour of the year in 2050, aggregated to both the national level and the ReEDS balancing area level. As described in the accompanying report, the ReEDS model was used to project the evolution of the power sector over time. Links to the mapping of ReEDS balancing areas to states and ReEDS balancing area shape files are provided. This dataset also includes the report figure data.

08 HYDROGEN↗

Potential Availability of and Supply Curves for Low-Cost, Dispatch-Constrained Electricity

Among other changes, variable renewable energy (VRE) - primarily wind and solar photovoltaics - is achieving a growing share of total generation. High VRE penetrations may result in an increased level of curtailment and thus suppress the value of additional VRE. This VRE, that either would not be built due to price suppression or would be curtailed, can be considered a resource that we define as low-cost, dispatch-constrained electricity (LDE). LDE could be used for various applications which value low-cost electricity and can operate at reduced capacity factors. Examples include electrolytic hydrogen production and carbon capture. This report provides initial estimates of the quantity and availability of the potential LDE resource in the U.S. under scenarios with high VRE penetrations. It also provides supply curves that can be used in subsequent analysis of the opportunity to use the LDE. We modeled several scenarios using capacity expansion and production cost models for LDE prices ranging from $\$ $0/MWh to $\$ $30/MWh. These LDE prices, coupled with low renewable energy cost assumptions, resulted in VRE penetrations ranging from 48-66% in 2050. The resulting LDE supplies range from 100 - 300 TWh/yr at a price of $\$ $0/MWh to 3,500 - 4,200 TWh/yr at $\$ $30/MWh. Increasing LDE prices increases wind and photovoltaics deployment; however, other generation technology capacities do not decrease equivalently in our models. Thus, additional generation is available but the capacity of traditional dispatchable generation is only reduced slightly. The available LDE is concentrated in the central and southwest U.S. regions because of their high wind and solar resources.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Electrolysis' Potential Value for Supporting the Electrical Grid

The H2@Scale concept includes a value proposition for electrolysis that benefits both hydrogen markets and the electricity system. Electrolysis has the potential to be an alternative low-cost hydrogen source by using low-price electricity that may be available for only a limited number of hours annually. It also has the potential to provide value to the grid through use of that low-cost electricity. By doing so, electrolysis can create a price floor which could support additional investment in low-cost, dispatch-constrained electricity (LDE) generation such as photovoltaic solar, wind, and nuclear. The rapid-response characteristics of low-temperature electrolysis enables it to also provide ancillary services to the grid such as operating reserves and frequency control. We evaluate the economic performance of water electrolysis in a selection of electricity markets - both current and potential future markets. To perform that evaluation, we collect locational marginal prices (LMPs) in each market, calculate levelized hydrogen costs, and compare them to cost estimates of producing hydrogen via steam methane reforming of natural gas. Those calculations also include electolyzer capital and operating costs. We perform the calculations across a range of capacity factors to identify the minimum levelized hydrogen cost in that range. We discuss the implications of that capacity factor for each market analyzed. For a couple of the analyzed electricity markets, we include the potential value of providing ancillary services in the calculation and discuss those impacts. LDE generation has been shown to suppress electricity prices because it generates electricity when the resource is available (i.e., the sun is shining, wind is blowing, nuclear heat is being produced) and the generation cannot be reduced without an economic penalty. Price suppression is likely to reduce investment in those technologies due to reductions in projected income of each marginal unit. If electrolyzers are willing to pay for the LDE, it could provide a price floor for electricity. We analyze how setting a price for LDE could impact the electricity generation fleet, the availability of LDE, and the potential levelized costs of producing hydrogen using that LDE. Among other results, we will present a set of supply curves showing potential production costs and availability for hydrogen produced from LDE in a future with high penetrations of renewable electricity on the grid.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Control of Quantized Spontaneous Emission from Single GaAs Quantum Dots Embedded in Huygens’ Metasurfaces

Advancements in photonic quantum information systems (QIS) have driven the development of high-brightness, on-demand, and indistinguishable semiconductor epitaxial quantum dots (QDs) as single photon sources. Strain-free, monodisperse, and spatially sparse local-droplet-etched (LDE) QDs have recently been demonstrated as a superior alternative to traditional Stranski–Krastanov QDs. However, integration of LDE QDs into nanophotonic architectures with the ability to scale to many interacting QDs is yet to be demonstrated. Here, we present a potential solution by embedding isolated LDE GaAs QDs within an Al 0.4 Ga 0.6 As Huygens’ metasurface with spectrally overlapping fundamental electric and magnetic dipolar resonances. We demonstrate for the first time a position- and size-independent, 1 order of magnitude increase in the collection efficiency and emission lifetime control for single-photon emission from LDE QDs embedded within the Huygens’ metasurfaces. Our results represent a significant step toward leveraging the advantages of LDE QDs within nanophotonic architectures to meet the scalability demands of photonic QIS.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

H2@Scale: Economic Potential of Hydrogen as an Energy Intermediate

The H2@Scale concept envisions hydrogen as an energy intermediate across multiple energy sectors. The concept is motivated both by the opportunity to produce hydrogen from low-cost energy resources, and by the many potential applications of hydrogen, including as energy for transportation - used directly in fuel cell electric vehicles (FCEVs), as a feedstock for synthetic fuels, and to upgrade oil and biomass - feedstock for industry (e.g., for ammonia production, metals refining, and other end uses), heat for industry and buildings, and electricity storage. A key hydrogen production opportunity is using variable renewable electricity (i.e., electricity generated by wind turbines or solar photovoltaic panels) during hours when generation exceeds the load on the grid as a source of low-cost, dispatch constrained electricity (LDE). In addition to producing low-cost hydrogen, electrolysis can also serve as a form of responsive load on the electric grid, which can enhance grid stability, reduce curtailment, and create a supplementary revenue stream for generators. The future use and adoption of hydrogen across end-use applications depends both the cost of hydrogen production and on each application's threshold price (i.e., the maximum price each application will pay for hydrogen - above that price, the application has an alternative that is more economic). We estimate economic potential of the hydrogen market - the quantity of hydrogen at an equilibrium price at which suppliers are willing to produce and consumers are willing to buy the same quantity of hydrogen - by developing supply and demand curves for hydrogen production and use. The demand curves are based on the threshold price for various quantities of hydrogen in each market, which is affected by projected prices for alternatives that could provide the same service (e.g., fuel for vehicles, feedstock for metals refining). The supply curves include hydrogen produced via natural gas steam methane reforming, high-temperature electrolysis coupled with nuclear power plants, biomass gasification, and low-temperature electrolysis using LDE. We use a range of market and technology-advancement assumptions to estimate the economic potential for five scenarios in the mid 21st century timeframe, and the corresponding impacts on energy use and emissions. We estimate hydrogen's economic potential to be 14-48 MMT/yr in the contiguous United States - corresponding to 1.5-5 times current annual consumption - depending on key assumptions about the future market conditions and the success of hydrogen production research and development (R&D) in our five scenarios. As a result of the estimated economic potential markets, we also approximate that grid-integrated electrolysis can increase the penetration of wind generation in the electricity market by providing a value stream for LDE, and that total U.S. fossil fuel use could decline below a scenario with high renewable penetration on the grid. We find that hydrogen has potential to provide technical and economic synergies when integrated across multiple sectors of the U.S. energy system, but continued R&D, infrastructure, and market development for LDE are required.

08 HYDROGEN↗

Trends in spatial correlations, two-phase coexistence, and criticality in a class of type-2 Schloegl models for autocatalysis

A class of type-2 Schloegl models is considered for particles on a square lattice with variable-range cooperativity. These models involve: (i) spontaneous particle annihilation at rate p; (ii) autocatalytic particle creation at unoccupied sites (i, j) with n ⩾ 2 particles within a specified neighborhood, Ω 𝑁 (i, j), of sites at rate $k_n$ = $\frac{^{(^n_2)}}{_{(^N_2)}}$ = $\frac{n{(n-1)}}{_{N(N-1)}}$; and (iii) possible spontaneous particle creation at unoccupied sites at “small” rate ɛ ⩾ 0. In some cases, Ω 𝑁 just includes all symmetry-equivalent sites at a single specific distance 𝑑 (in units of lattice constants) from the unoccupied site, e.g., 𝑑 = 1 (nearest-neighbor sites) where 𝑁 = 4, or 𝑑 = √5 (or √13 or…) where 𝑁 = 8. In other cases, Ω 𝑁 includes sites multiple distances from the unoccupied site, e.g., 𝑑 = {1,√2}, where 𝑁 = 8. Kinetic Monte Carlo (KMC) simulation reveals that these models exhibit a nonequilibrium discontinuous phase transition between high- and low-density states below a critical point, ɛ < ɛ c , with generic two-phase coexistence (2PC) at least for smaller 𝑁. With some exceptions, there is an approach toward mean-field behavior with increasing 𝑁 (so the regime of generic 2PC shrinks, and ɛ c approaches the mean-field value of 1/27). Additional insight into trends is provided by analysis of the exact master equations for the models via hierarchical truncation. These truncations utilize suitably tailored pair approximations which reflect the dominant nonequilibrium spatial correlations. These correlations in turn are shown to reflect the details of the autocatalytic particle creation process. For spatially heterogeneous states, the truncations produce coupled sets of lattice differential equations (LDE) which can describe orientation-dependent propagation of an interface between high- and low-density steady states for ɛ < ɛ c . Pair approximation values of 𝑝 = 𝑝 eq where the interface is stationary, and its orientation-dependence, are in semiquantitative agreement with KMC results. In conclusion, this comparison accounts for propagation failure in the LDE which complicates interpretation.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

The Technical and Economic Potential of the H2@Scale Hydrogen Concept within the United States

The U.S. energy system is evolving as society and technologies change. Renewable electricity generation - especially from wind and solar - is growing rapidly, and alternative energy sources are being developed and implemented across the residential, commercial, transportation, and industrial sectors to take advantage of their cost, security, and health benefits. Systemic changes present numerous challenges to grid resiliency and energy affordability, creating a need for synergistic solutions that satisfy multiple applications while yielding system-wide cost and emissions benefits. One such solution is an integrated hydrogen energy system. This is the focus of H2@Scale - a U.S. Department of Energy (DOE) initiative led by the Office of Energy Efficiency and Renewable Energy’s Hydrogen and Fuel Technologies Office. H2@Scale brings together stakeholders to advance affordable hydrogen production, transport, storage, and utilization in multiple energy sectors. The H2@Scale concept involves hydrogen as an energy intermediate. Hydrogen can be produced from various conventional and renewable energy sources including as a responsive load on the electric grid. Hydrogen has many current applications and many more potential applications, such as energy for transportation - used directly in fuel cell electric vehicles (FCEVs), as a feedstock for synthetic fuels, and to upgrade oil and biomass - feedstock for industry (e.g., for ammonia production, metals refining, and other end uses), heat for industry and buildings, and electricity storage. Owing to its flexibility and fungibility, a hydrogen intermediate could link energy sources that have surplus availability to markets that require energy or chemical feedstocks, benefiting both. This document builds upon a growing body of analyses of hydrogen as an energy intermediate by reporting the results from our initial analysis of the potential impacts of the H2@Scale vision by the mid-21 st century for the 48 contiguous U.S. states. Previous estimates have been based on expert elicitation and focused on hydrogen demands. We build upon them, first, by estimating hydrogen’s serviceable consumption potential for possible hydrogen applications and the technical potential for producing hydrogen from various resources. We define the serviceable consumption potential as the quantity of hydrogen that would be consumed to serve the portion of the market that could be captured without considering economics (i.e., if the price of hydrogen were $0/kg over an extended period); thus, it can be considered an upper bound for the size of the market. We define the technical potential as the resource potential constrained by real-world geography and system performance, but not by economics. We then compare the cumulative serviceable consumption potential with the technical potential of a number of possible sources. Second, we estimate economic potential: the quantity of hydrogen at an equilibrium price at which suppliers are willing to sell and consumers are willing to buy the same quantity of hydrogen. We believe this method provides a deeper understanding than was available in the previous analyses. We develop economic potentials for multiple scenarios across various market and technology-advancement assumptions.

08 HYDROGEN↗

The Technical and Economic Potential of Hydrogen within the United States

Hydrogen markets have an opportunity to grow as its value as an energy intermediate increases. Hydrogen’s estimated serviceable consumption potential in the United States is 106 MMT/yr which is a ten-fold increase over the current market size. That opportunity is driven primarily by increased demands for metals refining, biofuel and hydrocarbon production, supplementing the natural gas system, seasonal storage for the electricity grid, and fuel cell electric vehicles. The U.S. has many renewable, nuclear, and fossil resources that each could meet that demand itself. The economic potential, which considers both costs to produce hydrogen and willingness of applications to pay for it, is 22 to 41 MMT/yr. The range is impacted by factors that impact the cost to produce including the price of natural gas and the cost of electrolyzers. It is also impacted by competition to provide the same services as hydrogen including electrification.

electrolysis↗