Search NASA⌕ Search

SEARCH · Search NASA

Results for “LEAD IONS”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Highly Efficient Removal of Lead Ions from Aqueous Solutions Using Chitosan/Rice Husk Ash/Nano Alumina with a Focus on Optimization by Response Surface Methodology: Isotherm, Kinetic, and Thermodynamic Studies

In the present study, an adsorbent named chitosan/rice husk ash/nano-γ alumina was prepared and used for the removal of lead ions from aqueous solutions. It was characterized by FESEM, FTIR, XRD, and BET. The important and interactive effects of some considered parameters, such as the initial lead ion concentration, pH, adsorbent mass and contact time, were estimated and optimized by using the central composite design (CCD). The Maximum adsorption efficiency of lead ions under optimum conditions, including the pH of 5, adsorbent mass of 0.01 g, the initial lead ion concentration of 30 ppm, and the contact time of 105 min, was achieved to be 90.98%. The adsorption kinetic was consistent with the pseudo-second-order model (R{sup 2} = 0.9967). The lead adsorption isotherms were well fitted to the Langmuir model, indicating the maximum adsorption capacity of 181.82 mg g{sup −1}. Thermodynamic parameters (R{sup 2}: 0.9200, ΔH°: − 22871.81 kJ mol{sup −1}, ΔG{sup °}: − 10.63 kJ mol{sup −1}, and ΔS{sup °}: 118.37 kJ mol{sup −1} K{sup −1}) were calculated and indicating adsorption process was exothermic and spontaneous in the temperature range of 283.15–313.15 k. The maintenance above 70% capacity of the adsorbent was observed by the regeneration study of chitosan/rice husk ash/nano-γ alumina after six cycles. Comparison of adsorption efficiency of the studied adsorbent and other adsorbents in the removal of lead ions was also done in this paper. Consequently, the excellent properties of the presented nanocomposite could make it an ideal adsorbent for the removal of lead ions from aqueous solutions. Graphical Abstract: .

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2019

Synthesis of calcium carbonate nanoparticles in erythrocytes enables efficient removal of extracellular lead ions

The “cyborg cells”, living cells with built-in nanoscaffolds, which could integrate the biological function of the cells with the functionality of nanomaterials, have been rarely explored. Here we report a method to construct “cyborg erythrocytes” through the in situ reaction of exogenous calcium and carbonate ions to generate calcium carbonate nanodots inside erythrocytes. The intracellular calcium carbonate nanodots combined with proteins are hidden under the membrane of erythrocytes, which can restrict migration and unexpected accumulation of nanodots in the body, improving the biosecurity of the nanodots. Most importantly, the calcium carbonate nanodots not only do not bring adverse effects on the nature of erythrocytes, but also endow erythrocytes with new properties. The in vitro and in vivo results show that the “cyborg erythrocytes” can remove 80% of lead ions in a blood poisoning model and reduce the lead level in the kidney and liver of mice through a precipitation transformation mechanism.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

Halide Heterogeneity Affects Local Charge Carrier Dynamics in Mixed-Ion Lead Perovskite Thin Films

The mechanisms and elemental composition that form the basis for the improved optical and electronic properties in mixed-ion perovskite solar cells are still not well understood compared to standard methylammonium lead triiodide perovskite devices. Here, we use synchrotron-based X-ray fluorescence to map the composition of perovskite thin films. To get insights into the elemental distribution during film growth, we fabricate films with three different thicknesses. To create a link between the composition and the electronic properties, we perform Kelvin probe force microscopy and time-resolved photoluminescence spectroscopy. We find that the elemental composition is highly dependent on the film thickness, in particular, that the I/Pb ratio is altered for single grains based on the film thickness. The difference in the I/Pb ratio reveals to be the root cause for the underlying difference in film lifetime and defect density influencing charge carrier dynamics. Our results provide an in-depth analysis approach combining macro- and nanoscale techniques to shed light onto the fundamental processes which help to further engineer perovskite thin films and improve device efficiencies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Selective single-atom adsorption for precision separation of lead ions in tap water via capacitive deionization

Capacitive deionization (CDI) offers a cost-effective and low-energy method for selective removal of Pb 2+ from drinking water. Modifying CDI electrode surfaces with functional groups presents a versatile approach to enhancing selective ion adsorption capacity. However, a comprehensive understanding of the selectivity and removal efficiency of Pb 2+ among diverse functional groups remains unexplored. Here, we investigated the effects of different functional groups (-SH, -COOH, and -NH 2 ) attached to the graphene oxide (GO) electrode surfaces on Pb 2+ selectivity and removal efficiency. Surprisingly, GO-COOH demonstrated single-atom adsorption of Pb 2+ , displaying superior removal efficiency and selectivity compared with -SH and -NH 2 , although -SH possesses significant chelation capability for Pb 2+ . Both density functional theory (DFT) calculations and X-ray pair distribution function (PDF) analyses confirmed that Pb 2+ exhibits a theoretically higher affinity to -COOH. Further, this research deepens our understanding of the interactions between functional groups and heavy metal ions, enabling selective and rapid separation of target cations for water purification.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Chemoresponsive Nanofluidic Pump That Turns Off in the Presence of Lead Ion

There are many applications that require the integration of a pump and a chemical sensor so that the solution being pumped can be analyzed in real time for a specific chemical species and the flow adjusted according to the measured concentration of that species. In this paper, we describe an alternative strategy: a chemoresponsive pump where a single device acts as both the sensor and pump simultaneously. We demonstrate this concept with a nanofluidic Pb 2+ -responsive pump that uses electroosmotic flow as the pumping technology, and a Pb 2+ -binding ionophore that allows the device to selectively respond to Pb 2+ . The pump yields high flow rates at low Pb 2+ concentrations (<1 μM), but flow rate decreases with concentrations above this threshold and ultimately goes to zero at concentrations above 100 μM.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Efficient Removal of Lead Ions from Aqueous Media Using Sustainable Sources Based on Marine Algae

The goal of this project is to explore a new method to efficiently remove Pb(II) ions from water by processing Undaria pinnatifida into immobilized beads using sodium alginate and calcium chloride. The resulting biosorbent was characterized by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDS). Using immobilized U. pinnatifida, we investigated the effect of various factors on Pb(II) ion removal efficiency such as temperature, pH, ionic strength, time, and underlying biosorption mechanisms. For Pb(II) ion biosorption studies, Pb(II) ion biosorption data were obtained and analyzed using Langmuir and Freundlich adsorption models. It is found that the maximum Pb(II) ion adsorption capacity (X m ) of U. pinnatifida was estimated to be ~5 times greater than that of activated carbon, indicating the superior Pb(II) ion removal capability of U. pinnatifida compared to activated carbon. In addition, a thermodynamic study indicates that biosorption processes are found to be endothermic and an increase in the Pb(II) ion solution temperature provides a more preferential reaction toward Pb(II) ion biosorption.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

A portable and reusable sensor system based on graphene for real-time and sensitive detection of lead ions in water

Long-term exposure to Pb 2+ can cause irreversible damage to the nervous, cardiovascular, and reproductive systems. Therefore, developing a fast and sensitive detection system capable of monitoring minuscule concentrations of Pb 2+ is essential. In this study, we demonstrated a fully portable sensor system enabling rapid, sensitive, and real-time monitoring of Pb 2+ . The sensor system adopted the remote-gate field-effect transistor (RGFET) detection scheme and was easy to operate, even for non-experts. The sensor system comprised two printed circuit boards (PCBs): a sensor PCB with a remote-gate electrode and an analyzer PCB with a metal-oxide-semiconductor field-effect transistor (MOSFET) transducer and peripheral electronics to manage sensor signals. To achieve a high sensitivity for Pb 2+ , we utilized graphene ink drop-casted on the sensor PCB as a sensing membrane. The graphene film was easy to deposit and remove, enabling the sensor PCB to be reused multiple times. The sensor system was further linked to a smartphone application that instantly monitors the sensor response, allowing for rapid point-of-use detection. The sensor exhibited a high sensitivity of 21.7% when the limit of detection (LOD) value of 1 nM (∼0.2 ppb) was detected, and the typical detection time for each sample was approximately 60 seconds. This portable sensor system advances sensing technologies and could potentially supplement expensive, laborious conventional sensing equipment.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2017

Luminescent properties of solid solutions in the PbF{sub 2}–Euf{sub 3} system and lead fluoroborate glass ceramics doped with Eu{sup 3+} ions

Lead fluoroborate glasses doped with Eu{sup 3+} are synthesized, studied, and used to produce glassceramics by heat treatment. The structure of glass-ceramics is determined by X-ray diffraction. The optical, mechanical, and luminescent properties of the glass-ceramics are studied. The structure and spectral-luminescent properties of solid solutions in the PbF{sub 2}–EuF{sub 3} system obtained by both solid-phase reaction and coprecipitation from solutions are investigated.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2000

Friction and Wear Properties of Selected Solid Lubricating Films: Ion-Plated Lead Films - Part 2

To evaluate commercially developed dry solid film lubricants for aerospace bearing applications, an investigation was conducted to examine the friction and wear behavior of ion-plated lead films in sliding contact with 6-mm-diameter American Iron and Steel Institute (AISI) 440C stainless steel balls. Unidirectional sliding friction experiments were conducted with a load of 5.9 N (600 g), a mean Hertzian contact pressure of 0.79 GPa (maximum Hertzian contact pressure of 1.2 GPa), and a sliding velocity of 0.2 m/s. The experiments were conducted at room temperature in three environments: ultrahigh vacuum (vacuum pressure, 7 x 10(exp -7 Pa), humid air (relative humidity, approx. 20 percent), and dry nitrogen (relative humidity, less then 1 percent). The resultant films were characterized by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and surface profilometry. Marked differences in the friction and wear of the ion-plated lead films investigated herein resulted from the environmental conditions. The main criteria for judging the performance of the ion-plated lead films were coefficient of friction and wear rate, which had to be less than 0.3 and on the order of 1(exp -6) cu mm/N.m or less, respectively. The ion-plated lead films met both criteria only in ultrahigh vacuum but failed in humid air and in dry nitrogen, where the coefficient of friction was higher than the criterion. Both the lead film wear rate and the ball wear rate met that criterion in all three environments. Adhesion and plastic deformation played important roles in the friction and wear of the ion-plated lead films in contact with 440C stainless steel balls in the three environments. All sliding involved adhesive transfer of materials: transfer of lead wear debris to the counterpart 440C stainless steel and transfer of 440C stainless steel wear debris to the counterpart lead.

Miyoshi, Kazuhisa↗
NASA NTRS1985

The plasma regime at comet Giacobini-Zinner

The paper reviews results on the plasma regime at Comet Giacobini-Zinner obtained by the International Cometary Explorer. The observations are consistent with the existence of a weak shock which may be pulsating, but do not exclude the suggestion that the shock, though present around the subsolar point, is an the process of decaying to a wave on the flanks. 'The pick-up' of cometary ions leads to ion cyclotron, mirror, beam, and electrostatic instabilities which cause strong turbulence in the inner coma.

Ogilvie, K. W.↗
NASA NTRS1992

Two dimensional PIC simulations of plasma heating by the dissipation of Alfven waves

Two dimensional plasma particle simulations of the evolution of large amplitude circularly polarized Alfven waves propagating parallel to the magnetic field show that the waves decay via both one- and two- dimensional parametric decay instabilities. For parameters studied, one-dimensional processes dominate the simulations, but two-dimensional decay processes, including the recently predicted filamentation instability are also observed. The daughter waves generated by the parametric decay are primarily damped by the ions, leading to ion heating. The parametric decay processes efficiently convert the ordered fluid ion motion in the Alfven wave into ion thermal energy. These processes may be important for the dissipation of Alfven waves in the solar wind, the corona and other space plasma environments. The computations were performed on the Intel Touchstone parallel supercomputer.

Liewer, P. C.↗
DOE OSTI2014

Preparation of a primary argon beam for the CERN fixed target physics

The fixed target experiment NA61 in the North Area of the Super Proton Synchrotron is studying phase transitions in strongly interacting matter. Up to now they used the primary beams available from the CERN accelerator complex (protons and lead ions) or fragmented beams created from the primary lead ion beam. To explore a wider range of energies and densities a request was made to provide primary argon and xenon beams. This paper describes the results of the setting up and 10 week test run of the Ar{sup 11+} beam from the 14.5 GHz ECR ion source and the linear accelerator (Linac3) at CERN.

43 PARTICLE ACCELERATORS↗
DOE OSTI2017

Fixed target project AFTER at the LHC beams for heavy ion and hadron physics

High intensity proton and lead ion beams at the LHC collider allow one to use the beam halo by placing a fixed target or a bent crystal for beam extraction. The particle energy in this case is just half that at the RHIC collider, but the luminosity exceeds the collider luminosity many times. It is also possible to install a polarized target in the extracted beam. The project AFTER is aimed at investigation of rare processes, polarization phenomena, determination of the parameters required for analysis of cosmic rays and neutrino astrophysics, detailed investigation of quarkonia production and suppression depending on the phase transition of matter to the quark-gluon phase.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2016

Development and testing of a pulsed helium ion source for probing materials and warm dense matter studies

The neutralized drift compression experiment was designed and commissioned as a pulsed, linear induction accelerator to drive thin targets to warm dense matter (WDM) states with peak temperatures of ∼1 eV using intense, short pulses (∼1 ns) of 1.2 MeV lithium ions. At that kinetic energy, heating a thin target foil near the Bragg peak energy using He{sup +} ions leads to more uniform energy deposition of the target material than Li{sup +} ions. Experiments show that a higher current density of helium ions can be delivered from a plasma source compared to Li{sup +} ions from a hot plate type ion source. He{sup +} beam pulses as high as 200 mA at the peak and 4 μs long were measured from a multi-aperture 7-cm-diameter emission area. Within ±5% variation, the uniform beam area is approximately 6 cm across. The accelerated and compressed pulsed ion beams can be used for materials studies and isochoric heating of target materials for high energy density physics experiments and WDM studies.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2019

Mechanisms of B Meson Suppression in Ultrarelativistic Heavy Ion Collisions

Different mechanisms of B meson suppression in lead ion collisions at an energy of the Large Hadron Collider √(s{sub NN}) = 5.02 TeV have been comparatively analyzed. It has been shown that the experimentally observed weak momentum dependence of the B meson suppression factor can be reproduced by the HYDJET++ model including the nuclear shadowing of initial parton distributions and radiative and collisional energy losses of heavy quarks in hot matter. A significant difference in the effects of the initial and final states on light and heavy hadron suppression has been revealed.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗