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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Assessment of geophysical monitoring methods for detection of brine and CO 2 leakage in drinking water aquifers

Here, we evaluated and compared the effectiveness of four surface-based geophysical monitoring methods to downhole pressure and chemical methods to detect brine and CO 2 leakage in underground sources of drinking water overlying a CO 2 storage reservoir. This assessment uses synthetic monitoring data generated from 400 simulated aquifer impact data sets. Here, the six monitoring techniques can detect impacted groundwater once 20,000 tonnes of CO 2 have leaked into the drinking water resource. Geophysical methods are most effective at detecting shallow plumes. Although downhole monitoring methods outperform geophysical methods in detecting deep plumes, geophysical methods may help reduce the false negative during the post injection site care because they detect impacted groundwater where downhole sensors may be absent.

58 GEOSCIENCES↗

Transformer Leakage Inductance Design Methodology

The leakage inductance exhibited by a transformer depends on its winding geometry, which generally involves the selection of several key design parameters in addition to the winding structure and the interleaving configuration. With few resources explaining the effects of these design choices on the observed leakage inductance, numerous trial-and-error iterations become necessary to realize the desired leakage inductance. This paper explores more than a hundred winding geometries feasible in a 2-winding transformer comprising the same magnetic core, number of turns, and wire gauge, and finds the leakage inductance for each unique design using 2-D finite element method (FEM) simulations in association with the semi-analytical double- 2-D model. These leakage inductances are plotted and further analyzed to understand the effects of different design parameters on the effective leakage inductance. The results presented herein and the conclusions drawn from this research can serve as a valuable resource for future design practitioners from both industry and academia.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Novel Transformer with Variable Leakage and Magnetizing Inductances

This paper introduces the concept of a novel variable inductance transformer (VIT) whose leakage and magnetizing inductances can be varied dynamically and independently to aid the advancement of research in isolated power electronic converters. In this transformer, the leakage inductance can be varied by varying the length of overlap between the primary and secondary windings, while the magnetizing inductance can be varied by varying the air gap between the core legs. Individual controls for the two inductances ensure that one can be varied independent of the other, as needed to satisfy different power conversion objectives. In this paper, the analytical models of the variable leakage and magnetizing inductances are presented. Analytical results are compared with those obtained from Finite Element Method (FEM) and an experimental prototype of a VIT. Analytical solutions of the variable leakage inductance present an error of less than 2.35 % when compared to FEM solutions, while the analytical solutions of the variable magnetizing inductance present a maximum error of 1.82 % when compared to experimental measurements.

image method, leakage inductance, magnetizing indu↗

New Hybrid Model for Evaluating the Frequency-Dependent Leakage Inductance of a Variable Inductance Transformer (VIT)

Skin and proximity effects can cause a significant drop in the effective leakage inductance of a transformer when the operating frequency is increased. Although the magnetic image method-based double-2-D model can calculate the lowfrequency leakage inductance with sufficient accuracy, it is inherently a frequency-independent model. While Dowell’s 1-D model uses frequency-dependent relations to account for both skin and proximity effects, its accuracy is severely affected by the assumed winding geometry. In this paper, a hybrid model is proposed that uses superposition to combine a modified Dowell’s model with the double-2-D model. The proposed model is investigated on a variable inductance transformer (VIT)—a partially-filled transformer whose leakage inductance can be varied by moving one of the windings mechanically. The frequency-dependent leakage inductances of the VIT evaluated using the hybrid model are in excellent agreement with the corresponding finite element method (FEM) simulated and experimentally measured values, thereby validating the proposed hybrid model.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Potential Chemical Impacts of CO2 Leakage on Underground Source of Drinking Water Assessed by Quantitative Risk Analysis

Many geologic carbon storage site options include not only excellent storage reservoirs bounded by effective seal layers, but also Underground Sources of Drinking Water (USDWs). An effective risk assessment and mitigation plan provides maximum protection for USDWs, to respect not only current policy but also to accommodate likely future USDW-specific regulatory protections. The goal of this study is to quantify possible risks to USDWs, specifically risks associated with chemical impacts on USDWs. Reactive transport models involve tremendous computational expense. Therefore, a secondary purpose of this study is to develop, calibrate and test reduced order models specifically for assessing risks of USDW chemical impacts by CO2 leakage from a storage reservoir. In order to achieve these goals, a geochemical model was developed to interpret changes in water chemistry following CO2 intrusion. A response surface methodology (RSM) based on these geochemical simulations was used to quantify associated risks. The case study example for this analysis is the Ogallala aquifer overlying the Farnsworth unit (FWU), an active commercial-scale CO2-enhanced oil recovery field. Specific objectives of this study include: (1) to understand how CO2 leakage is likely to influence geochemical processes in aquifer sediments; (2) to quantify potential risks to the Ogallala groundwater aquifer due to CO2 leakage from the FWU oil reservoir; and (3) to identify water chemistry factors for early detection criteria. Results indicate that the leakage rate would most likely range between 10-14 – 10-10 kg/(m2·year) for typical and likely leakage pathway permeability ranges. Within this range of CO2 leakage rate, groundwater quality is not likely to be significantly impacted. The worst-case scenario yields trace metal concentrations approximately twice as much as the initial value, but these predicted concentrations are still less than one-fifth of regulation-stipulated maximum contamination levels and do not exceed the no-impact thresholds. Finally, the results of this analysis suggest that pH may be an effective geochemical indicator of CO2 leakage.

CO2 leakage, USDWs, Groundwater quality, Risk anal↗

Toward Understanding Tip Leakage Flows in Small Compressor Cores Including Stator Leakage Flow

The focus of this work was to provide additional data to supplement the work reported in NASA/CR-2015-218868 (Berdanier and Key, 2015b). The aim of that project was to characterize the fundamental flow physics and the overall performance effects due to increased rotor tip clearance heights in axial compressors. Data have been collected in the three-stage axial research compressor at Purdue University with a specific focus on analyzing the multistage effects resulting from the tip leakage flow. Three separate rotor tip clearances were studied with nominal tip clearance gaps of 1.5 percent, 3.0 percent, and 4.0 percent based on a constant annulus height. Overall compressor performance was previously investigated at four corrected speedlines (100 percent, 90 percent, 80 percent, and 68 percent) for each of the three tip clearance configurations. This study extends the previously published results to include detailed steady and time-resolved pressure data at two loading conditions, nominal loading (NL) and high loading (HL), on the 100 percent corrected speedline for the intermediate clearance level (3.0 percent). Steady detailed radial traverses of total pressure at the exit of each stator row are supported by flow visualization techniques to identify regions of flow recirculation and separation. Furthermore, detailed radial traverses of time-resolved total pressures at the exit of each rotor row have been measured with a fast-response pressure probe. These data were combined with existing three-component velocity measurements to identify a novel technique for calculating blockage in a multistage compressor. Time-resolved static pressure measurements have been collected over the rotor tips for all rotors with each of the three tip clearance configurations for up to five loading conditions along the 100 percent corrected speedline using fast-response piezoresistive pressure sensors. These time-resolved static pressure measurements reveal new knowledge about the trajectory of the tip leakage flow through the rotor passage. Further, these data extend previous measurements identifying a modulation of the tip leakage flow due to upstream stator wake propagation. Finally, a novel instrumentation technique has been implemented to measure pressures in the shrouded stator cavities. These data provide boundary conditions relating to the flow across the shrouded stator knife seal teeth. Moreover, the utilization of fast-response pressure sensors provides a new look at the time-resolved pressure field, leading to instantaneous differential pressures across the seal teeth. Ultimately, the data collected for this project represent a unique data set which contributes to build a better understanding of the tip leakage flow field and its associated loss mechanisms. These data will facilitate future engine design goals leading to small blade heights in the rear stages of high pressure compressors and aid in the development of new blade designs which are desensitized to the performance penalties attributed to rotor tip leakage flows.

Berdanier, Reid A.↗

Enabling site-specific well leakage risk estimation during geologic carbon sequestration using a modular deep-learning-based wellbore leakage model

Geologic carbon sequestration (GCS) is a promising technology for mitigating net carbon emissions and growing climate concern by storing CO 2 in reservoirs. Oil and gas brownfields are an attractive option for CO 2 storage, but these sites have many historical wellbores from petroleum production and can be a potential leakage pathway for CO 2 or formation brine. Therefore, risk management of GCS operations requires an assessment of potential well leakage. Due to the high uncertainty of the system, stochastic approaches are ideal for quantifying the range of risk behaviors, but they must be computationally efficient in the face of complex physics. Here, we develop a new physics-centric deep learning wellbore model to predict the leakage of CO 2 and brine through leaky wellbores. Multi-physics numerical simulations were used to generate data sets, and physics-informed features were introduced. Neural networks were optimized with an automated searching algorithm. Feature analysis quantifies the impact of each feature on model prediction and confirms the role of physics-inspired parameters. The model shows high predictive performance across a wide range of geologic and injection conditions and well attributes. In conclusion, a case study illustrates how the model is applied to assess well leakage in GCS operations.

58 GEOSCIENCES↗

Diatom Physiology Controls Silicic Acid Leakage in Response to Iron Fertilization

We explore how the iron dependence of the Si:P uptake ratio R Si:P of diatoms controls the response of the global silicon cycle and phytoplankton community structure to Southern Ocean iron fertilization. We use a data‐constrained model of the coupled Si‐P‐Fe cycles that features a mechanistic representation of nutrient colimitations for three phytoplankton classes and that is embedded in a data‐assimilated global ocean circulation model. We consider three parameterizations of the iron dependence of R Si:P , all of which are consistent with the available field data and allow equally good fits to the observed nutrient climatology but result in very different responses to iron fertilization: Depending on how sharply R Si:P decreases with increasing iron concentration, iron fertilization can either cause enhanced silicic acid leakage from the Southern Ocean or strengthened Southern Ocean silicon trapping. Enhanced silicic acid leakage occurs if decreases in R Si:P win over increases in diatom growth, while the converse causes strengthened Southern Ocean silicon trapping. Silicic acid leakage drives a floristic shift in favor of diatoms in the subtropical gyres and stimulates increased low‐latitude opal export. The diatom contribution to global phosphorus export increases, but the lower diatom silicon requirement under iron‐replete conditions reduces the global opal export. Regardless of R Si:P parameterization, the global response of the biological phosphorus and silicon pumps is dominated by the Southern Ocean. The Si isotope signature of opal flux becomes systematically lighter with increasing iron‐induced silicic acid leakage, consistent with sediment records from iron‐rich glacial periods.

Holzer, Mark↗

Electrochemical mechanisms of leakage-current-enhanced delamination and corrosion in Si photovoltaic modules

This paper analyzes the mechanisms for corrosion and delamination observed in Si photovoltaic modules subjected to high temperature and humidity with a negative-ground bias testing. Based on the thermodynamic data, the ionic component of the leakage current causes reduction reactions of water on the cathodic metallization, producing hydrogen gas and hydroxide ions. Ag fingers are strong catalysts for this reduction reaction compared to other materials used in solar cells and can be the initiation sites of corrosion and delamination caused by the electrochemical reactions. The produced hydrogen gas accumulates inside the module potentially producing a high gas pressure that can promote delamination, which is often preferentially initiated on metallization where the adhesion strength is lower [1], [2], [3]. The local basicity near the metal surface increases due to the hydroxide ion generation. Thus, the environment inside the encapsulant can be alkaline despite the presence of acetic acid decomposition products from the encapsulant. Corrosion of materials such as Si used in solar cells occurs and the extent depends on their corrosion resistance to the alkaline solution. This suggests that corrosion and delamination are interactive and promote the formation and propagation of one another.

14 SOLAR ENERGY↗

Effects of Channel Implant Variation on Radiation-Induced Edge Leakage Currents in n-Channel MOSFETs

The effects of radiation-induced defects and statistical variation in the dose and energy of MOSFET channel implants in a modern bulk CMOS technology are modeled using a process simulator in combination with analytical computations. The model integrates doping profiles obtained from process simulations and experimentally determined defect potentials into implicit surface potential equations. Solutions to these equations are then used to model radiation-induced edge leakage currents in 90-nm bulk CMOS n-channel MOSFETs. The results indicate that slight variations in the channel implant parameters can have a significant impact on the doping profile along the shallow trench isolation sidewall and thus the radiation-induced edge leakage currents.

42 ENGINEERING↗

Electrical current leakage and open-core threading dislocations in AlGaN-based deep ultraviolet light-emitting diodes

Electrical current transport through leakage paths in AlGaN-based deep ultraviolet (DUV) light-emitting diodes (LEDs) and their effect on LED performance are investigated. Open-core threading dislocations, or nanopipes, are found to conduct current through nominally insulating Al{sub 0.7}Ga{sub 0.3}N layers and limit the performance of DUV-LEDs. A defect-sensitive phosphoric acid etch reveals these open-core threading dislocations in the form of large, micron-scale hexagonal etch pits visible with optical microscopy, while closed-core screw-, edge-, and mixed-type threading dislocations are represented by smaller and more numerous nanometer-scale pits visible by atomic-force microscopy. The electrical and optical performances of DUV-LEDs fabricated on similar Si-doped Al{sub 0.7}Ga{sub 0.3}N templates are found to have a strong correlation to the density of these nanopipes, despite their small fraction (<0.1% in this study) of the total density of threading dislocations.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Detection and modeling of leakage current in AlGaN-based deep ultraviolet light-emitting diodes [Detection and modeling of leakage current in AlGaN-based UV LEDs]

Current-voltage (IV) characteristics of two AlGaN-based deep ultraviolet (DUV) light-emitting diodes (LEDs) with differing densities of open-core threading dislocations (nanopipes) are analyzed. A three-diode circuit is simulated to emulate the forward-bias IV characteristics of the DUV-LEDs, but is only able to accurately model the lower leakage current, lower nanopipe density DUV-LED. It was found that current leakage through the nanopipes in these structures is rectifying, despite nanopipes being previously established as inherently n-type. Using defect-sensitive etching, the nanopipes are revealed to terminate within the p-type GaN capping layer of the DUV-LEDs. As a result, the circuit model is modified to account for another p-n junction between the n-type nanopipes and the p-type GaN, and an excellent fit to the forward-bias IV characteristics of the leaky DUV-LED is achieved.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Identifying attributes of CO 2 leakage zones in shallow aquifers using a parametric level set method: Original Research Article: Identifying attributes of CO 2 leakage zones in shallow aquifers using a parametric level set method

Leakage through abandoned wells and geologic faults poses the greatest risk to CO 2 storage permanence. For shallow aquifers, secondary CO 2 plumes emanating from the leak zones may go undetected for a sustained period of time and has the greatest potential to cause large-scale and long-term environmental impacts. Identification of the attributes of leak zones, including their shape, location, and strength, is required for environmental risk assessment. This study applies a parametric level set (PaLS) method to characterize leak zones. Level set methods are appealing for tracking topological changes and recovering unknown shapes of objects. However, level set evolution using the conventional level set methods is computationally challenging. In PaLS, the level set function is approximated by using a weighted sum of basis functions and the level set evolution problem is replaced by an optimization problem. The efficacy of PaLS is demonstrated by reconstructing attributes of a CO 2 leak zone in a carbonate aquifer. Our results show that PaLS is a robust source identification method that can recover the approximate leak zone locations in the presence of measurement errors, model parameter uncertainty, and inaccurate guesses of source flux strengths. Accurate delineation of source geometry is achievable when a relatively dense observation network is used. The PaLS-based, source recovery framework introduced in this work is generic and can be adapted for any reactive transport model by simply switching the pre- and post-processing routines.

54 ENVIRONMENTAL SCIENCES↗