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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Long, paired A'A/Pahoehoe flows of Mauna Loa: Volcanological significance and insights they provide into volcano plumbing systems

The long lava flows of Mauna Loa, Hawaii have been cited as Earth's closed analogs to the large Martian flows. It is therefore important to understand the flow mechanics and characteristics of the Mauna Loa flows and to make use of these in an attempt to gain insights into Martian eruptive processes. Two fundamentally different kinds of long lava flows can be distinguished on Hawaiian volcanoes as in Martian flows. The two kinds may have identical initial viscosities, chemical compositions, flow lengths, and flow volumes, but their flow mechanisms and thermal energy budgets are radically different. One travels a distance set by the discharge rate as envisaged by Walker and Wadge, and the other travels a distance set mainly by the eruption duration and ground slope. In the Mauna Loa lavas, yield strength becomes an important flow morphology control only in the distal part of a'a lavas. The occurrence of paired flows on Mauna Loa yields insights into the internal plumbing systems of the volcano, and it is significant that all of the volume of the a'a flow must be stored in a magma chamber before eruption, while none of the volume of the pahoehoe needs to be so stored. Differentiation between the two kinds of flows on images of Martian volcanoes is possible and hence an improved understanding of these huge structures is acquired.

Rowland, Scott K.↗
NASA NTRS1988

Infrared Measurements of Atmospheric Gases Above Mauna Loa, Hawaii, in February 1987

Infrared solar absorption spectra recorded at 0.02/ cm resolution from the National Oceanic and Atmospheric Administration (NOAA) Geophysical Monitoring for Climate Change (GMCC) program station at Mauna Loa, Hawaii (latitude 19.5 deg N, longitude 155.6 deg W, elevation 3.40 km), in February 1997 have been analyzed to determine simultaneous total vertical column amounts for 13 atmospheric gases. Average tropospheric concentrations of CO2, N2O, CH4, and CHCIF2 and the daytime diurnal variations or the total columns of NO and NO2 have also been inferred. The retrieved total columns (in molecules /sq cm) of the nondiurnally varying gases are 1.6 +/- 0.2 x 10(exp 15) for HCl, 5.9 +/- 1.2 x 10(exp 15) for HNO3, 2.0 +/- 0.2 x 10(exp 21) for H2O16, 4.4 +/- 0.7 x 10(exp 18) for H2O18, 2.7 +/- 0.1 x 10(exp 17) for HDO, 2.3 +/- 0.2 x 10(exp 19) for CH4, 5.0 +/- 0.5 x 10(exp 21) for CO2, 6.7 +/- 0.8 x 10(exp 18) for O3, 4.3 +/- 0.4 x 10(exp 18) for N2O, 1.0 +/- 0.2 x 10(exp 16) for C2H6, and 9.7 +/- 2.5 x 10(exp 14) for CHClF2. We compare the total column measurements of HCl and HNO3 with previously reported ground-based, aircraft, and satellite measurements. The results for HCl are or particular interest because of the expected temporal increase in the concentration of this gas in the stratosphere. However, systematic differences among stratospheric HCl total column measurements from 1978 to 1980 and the absence of observations of free tropospheric HCl above Mauna Loa make it impossible to obtain a reliable estimate of the trend in the total burden of HCl. The measured HNO3 total column is consistent with aircraft measurements from approx. 12 km altitude. The O3 total column deduced from the IR spectra agrees with correlative Mauna Loa Umkehr measurements within the estimated error limits. The column-averaged D/H ratio of water vapor is (68 +/- 9) x- 10(exp -6), which is 0.44 +/- 0.06 times the reference value of 155.76 x 10(exp -6) for standard mean ocean water (SMOW). This large depletion in the D content of water vapor is similar to published measurements of the upper troposphere and lower stratosphere. Average tropospheric concentrations deduced for CO2, N2O, and CH4 are in good agreement with correlative NOAA GMCC surface data, indicating consistency between the measurement techniques for determining tropospheric volume mixing ratios. Results of the present study indicate that Mauna Loa is a favorable site for infrared monitoring of atmospheric gases. The site is particularly favorable for monitoring the tropospheric volume mixing ratios of long-lived gases, since the high altitude of the tropopause reduces corrections required to account for the decrease in volume mixing ratio in the stratosphere.

Rinsland, C. P.↗
NASA NTRS1982

Measurements of stratospheric aerosols over Mauna Loa, Hawaii and Boulder, Colorado

The direct solar radiation transmission record at Mauna Loa, dating from 1958 to the present, revealed with remarkable precision the presence of stratospheric aerosol from volcanic activity. This record can be used to quantify the intensity of the stratospheric volcanic aerosol perturbation following a significant eruption in reference to the Agung event in 1963. The Mount St. Helens' stratospheric cloud was first detected by lidar at 18 km over Mauna Loa on 17 July. The atmospheric transmission was seen to decrease slightly after that time, but only a few tenths of 1 percent. Although it is still fairly early to draw a definite conclusion on the ultimate magnitude of the Mount St. Helens stratospheric aerosol from the Mauna Loa results, it can be stated that the stratospheric aerosol optical depth presently observed is comparable with that observed from Fuego which erupted in 1974. At Boulder, Colorado, the atmospheric debris from Mount St. Helens was observed by lidar on a number of occasions. Also, observations of the diffuse, total and direct transmission of solar radiation were made on June 3 and 4. The latter set of observations is useful for deriving information on the scattering properties of the volcanic cloud. The lidar and solar radiation data are presented and some of their special features are discussed.

Deluisi, J. J.↗
NASA NTRS1984

The 1950 sulfur flow of Mauna Loa: Considerations for Io

Some of the geological relationships observed in the Mauna Loa sulfur flow may apply in considering volcanic processes on Io. Given the presence of sulfur/sulfur compounds in the eruption plumes and on the surface of Io, it is likely that extensive secondary deposits of sulfur exist, some of which may be of fumarolic origin and analogous to the Mauna Loa deposit. Given the likelihood of silicate volcanism of Io based on the inferred material properties of some flows, and the attendant high temperatures for silicate volcanism, it is likely that the secondary surface deposits of sulfur would have been mobilized without being heated to the high viscosity stage. Mobilized sulfur flows on Io may flow long distances as a result of: (1) low viscosities in the melting range; (2) sustained effusion resulting from continued heating source area; (3) continued remobilization within the flow as a consequence of surges from the source; and (4) extension via lava tubes, or similar conduits through which there is little heat loss. Sulfur flows may form a relatively thin veneer over silicate flows and other surface units, given their fluidity and low mobilization temperature. Active splashing and splattering may spread sulfur over a wider area contributing the bright blooms observed in association with some Ionian flows.

Greeley, R.↗
NASA NTRS1986

Features of stratospheric aerosol lidar observations at Mauna Loa, 1974 - 1985

Lidar observations of the stratospheric aerosol over Mauna Loa were begun in the fall of 1974 and have continued to the present. An analysis of these observations has yielded interesting features of the stratospheric aerosol profile that change according to perturbed (from volcanic activity) and quiescent conditions. In the Mauna Loa lidar record there are two major perturbations that are contrasted, Fuego and El Chichon. The variations in relative aerosol cloud thickness, altitude of the maximum concentration and nonsymmetry are compared for the quiescent and perturbed time periods. Also, a climatology of annual average aerosol profiles is descrbied. A brief description will be given of procedures used to validate the lidar optical thickness information.

Delusi, J. J.↗
NASA NTRS1987

Disruption of the Mauna Loa magma system by the 1868 Hawaiian earthquake - Geochemical evidence

To test whether a catastrophic earthquake could affect an active magma system, mean abundances (adjusted for 'olivine control') of titanium, potassium, phosphorus, strontium, zirconium, and niobium of historic lavas erupted from Mauna Loa Volcano, Hawaii, after 1868 were analyzed and were found to decrease sharply relative to lavas erupted before 1868. This abrupt change in lava chemistry, accompanied by a halved lava-production rate for Mauna Loa after 1877, is interpreted to reflect the disruptive effects of a magnitude 7.5 earthquake in 1868. This interpretation represents a documentable case of changes in magmatic chemical variations initiated or accelerated by a major tectonic event.

Tilling, Robert I.↗
NASA NTRS1988

Infrared measurements of atmospheric gases above Mauna Loa, Hawaii, in February 1987

The IR absorptions spectra of 13 minor and trace atmospheric gases, recorded by the NOAA's Geophysical Monitoring for Climate Change (GMCC) program station at Mauna Loa, Hawaii, for four days in February 1987, were analyzed to determine simultaneous total vertical column amounts for these gases. Comparisons with other data indicate that the NOAA GMCC surface volume mixing ratios are good measures of the mean volume mixing ratios of these gases in the troposphere and that Mauna Loa is a favorable site for IR monitoring of atmospheric gases. The ozone total columns deduced from the IR spectra agreed with the correlative Umkehr observations.

Rinsland, C. P.↗
NASA NTRS1993

Determination of Total Ozone over Mauna Loa Using Very High Resolution Infrared Solar Spectra

A very high resolution infrared Fourier transform spectrometer has been used to record solar spectra at the Mauna Loa Observatory in Hawaii. Spectra are normally taken one day a week at sunrise. These spectra have been analyzed for ozone and N2O total columns, and the ozone column compared with the value reported by tile Mauna Loa Dobson spectrophotometer. Aside from the FTIR reporting about 5% lower values than the Dobson (which may be due to a systematic difference in the treatment of tropospheric ozone), the FTIR and Dobson agree to within 2.7% (RMS) during this period.

David, Shelle J.↗
NASA NTRS2014

Diurnal Variations of Stratospheric Ozone Measured by Ground-Based Microwave Remote Sensing at the Mauna Loa NDACC Site: Measurement Validation and GEOSCCM Model Comparison

There is presently renewed interest in diurnal variations of stratospheric and mesospheric ozone for the purpose of supporting homogenization of records of various ozone measurements that are limited by the technique employed to being made at certain times of day. We have made such measurements for 19 years using a passive microwave remote sensing technique at the Mauna Loa Observatory (MLO) in Hawaii, which is a primary station in the Network for Detection of Atmospheric Composition Change (NDACC). We have recently reprocessed these data with hourly time resolution to study diurnal variations. We inspected differences between pairs of the ozone spectra (e.g., day and night) from which the ozone profiles are derived to determine the extent to which they may be contaminated by diurnally varying systematic instrumental or measurement effects. These are small, and we have reduced them further by selecting data that meet certain criteria that we established. We have calculated differences between profiles measured at different times: morning-night, afternoon-night, and morning-afternoon and have intercompared these with like profiles derived from the Aura Microwave Limb Sounder (Aura-MLS), the Upper Atmosphere Research Satellite Microwave Limb Sounder (UARS-MLS),t he Superconducting Submillimeter-Wave Limb-Emission Sounder (SMILES), and Solar Backscatter Ultraviolet version 2 (SBUV2) measurements. Differences between averages of coincident profiles are typically less than 1.5 percent of typical nighttime values over most of the covered altitude range with some exceptions. We calculated averages of ozone values for each hour from the Mauna Loa microwave data, and normalized these to the average for the first hour after midnight for comparison with corresponding values calculated with the Goddard Earth Observing System Chemistry Climate Model (GEOSCCM). We found that the measurements and model output mostly agree to better than 1.5 percent of the midnight value, with one noteworthy exception: The measured morning-night values are significantly (2-3 percent) higher than the modeled ones from 3.2 to 1.8 hPa (approximately 39-43 km), and there is evidence that the measured values are increasing compared to the modeled values before sunrise in this region.

GEOSCCM model comparison↗
NASA NTRSDate not supplied

Identifying Sources of Sulfate Preserved in High Elevation Lava Tubes From Mauna Loa, Hawaii

Volcanic sulfates record a history of their formation pathways in their triple oxygen isotope compositions, making them a powerful target for understanding atmospheric chemistry. To understand how these isotopic signals may be preserved in sulfate minerals, we investigate multiple O and S isotopes of thenardite, mirabilite, and gypsum from in a Mars analog environment: a pair of lava tubes near the summit of Mauna Loa, Hawaii. Based on 16 O-, 17 O- 18 O compositions, the primary oxygen sources for sulfates in the lava tube are atmospheric oxygen (O 2 ), peroxide (H 2 O 2 ), and ozone (O 3 ). We suggest the isotopic signature of O 2 originates from combustion of reduced sulfur gases and/or elemental sulfur at the eruptive source or within the lava tube soon after skylight collapse. Sulfate with isotopic signatures of peroxide and ozone are typically expected from aqueous reactions in cloud droplets. Chemical modeling indicates the observed proportion of ozone sourced sulfate requires pH greater than ~5.4, higher than measured cloud water pH, instead suggesting the observed O 3 signature could not have formed in cloud water droplets. We interpret that sulfate possessing an ozone signature in the lava tube sulfates formed on wetted surfaces of the lava tubes with alkalinity from alteration of basaltic glass. Furthermore, the oxygen and sulfur isotopes of the sulfate are uncorrelated. Multiple sulfur isotopes ( 32 S- 33 S- 34 S- 36 S) from the Mauna Loa sulfates are consistent with ocean island basalt from Pitcairn, suggesting the sulfate-sulfur has not been modified compared to its volcanic source. The findings of this study indicate that oxidation by ozone plays a key role in the formation of sulfate within lava tubes. We also find that combustion is a significant pathway toward sulfuric acid formation in volcanic environments. Similar signatures should be expected on other planets if volcanism is a significant sulfate source, as has been suggested for Mars. If true, sulfates in returned samples from Mars may hold key information on pO 2 , pCO 2 and planetary scale oxygen fluxes at the time of sulfate formation.

Justin Hayles↗
NASA NTRS2020

Causes of slowing‐down seasonal CO2 amplitude at Mauna Loa

Changing amplitude of the seasonal cycle of atmospheric CO2 (SCA) in the northern hemisphere is an emerging carbon cycle property. Mauna Loa (MLO) station (20°N, 156°W), which has the longest continuous northern hemisphere CO2 record, shows an increasing SCA before the 1980s (p < .01), followed by no significant change thereafter. We analyzed the potential driving factors of SCA slowing‐down, with an ensemble of dynamic global vegetation models (DGVMs) coupled with an atmospheric transport model. We found that slowing‐down of SCA at MLO is primarily explained by response of net biome productivity (NBP) to climate change, and by changes in atmospheric circulations. Through NBP, climate change increases SCA at MLO before the 1980s and decreases it afterwards. The effect of climate change on the slowing‐down of SCA at MLO is mainly exerted by intensified drought stress acting to offset the acceleration driven by CO2 fertilization. This challenges the view that CO2 fertilization is the dominant cause of emergent SCA trends at northern sites south of 40°N. The contribution of agricultural intensification on the deceleration of SCA at MLO was elusive according to land–atmosphere CO2 flux estimated by DGVMs and atmospheric inversions. Our results also show the necessity to adequately account for changing circulation patterns in understanding carbon cycle dynamics observed from atmospheric observations and in using these observations to benchmark DGVMs.

Mauna Loa↗
DOE OSTI2022

Impact of Changing Winds on the Mauna Loa CO 2 Seasonal Cycle in Relation to the Pacific Decadal Oscillation

Abstract Long‐term measurements at the Mauna Loa Observatory (MLO) show that the CO 2 seasonal cycle amplitude (SCA) increased from 1959 to 2019 at an overall rate of 0.22 0.034 ppm decade −1 while also varying on interannual to decadal time scales. These SCA changes are a signature of changes in land ecological CO 2 fluxes as well as shifting winds. Simulations with the TM3 tracer transport model and CO 2 fluxes from the Jena CarboScope CO 2 Inversion suggest that shifting winds alone have contributed to a decrease in SCA of −0.10 0.022 ppm decade −1 from 1959 to 2019, partly offsetting the observed long‐term SCA increase associated with enhanced ecosystem net primary production. According to these simulations and MIROC‐ACTM simulations, the shorter‐term variability of MLO SCA is nearly equally driven by varying ecological CO 2 fluxes (49%) and varying winds (51%). We also show that the MLO SCA is strongly correlated with the Pacific Decadal Oscillation (PDO) due to varying winds, as well as with a closely related wind index (U‐PDO). Since 1980, 44% of the wind‐driven SCA decrease has been tied to a secular trend in the U‐PDO, which is associated with a progressive weakening of westerly winds at 700 mbar over the central Pacific from 20°N to 40°N. Similar impacts of varying winds on the SCA are seen in simulations at other low‐latitude Pacific stations, illustrating the difficulty of constraining trend and variability of land CO 2 fluxes using observations from low latitudes due to the complexity of circulation changes.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1984

Utilization of SAGE aerosol profiles in the analysis of Mauna Loa stratospheric lidar data

A systematic approach to analyzing lidar data collected at NOAA's Mauna Loa Observatory (MLO) was developed which relies on parameters derived from SAGE satellite extinction profile measurements to verify boundary conditions applied to analysis. The approach also provides a means of assessing the uncertainties associated with the various inputs, so that the accuracy of the analysis of the MLO lidar data is available. The stratosphere during the 1980 to 1981 period was only mildly perturbed and could be easily represented by the SAMII/SAGE background aerosol model. The MLO lidar observations collected during this period provided stratospheric optical depths with uncertainties ranging between 15% and 25%. Uncertainties in the aerosol optical model contribute errors of 3% to 4% in the computed optical depths. Most of the optical depth uncertainty is associated with the calibration assumption in which no marked improvement can be expected.

Fernald, F. G.↗
NASA NTRS1985

Emplacement of Long Lava Flows on Mauna Loa (hawaii) and Alba (mars)

Spacecraft images revealed that extremely long lava flows (more than 200 km long) exist on the surface of Mars and Io. Compared to terrestial volcanic eruptions, the occurrence of these long flows is very unusual, and may hint at a different style of either magma production or eruption. Attempts to model the emplacement of the long flows on other planets, using a Bingham rheological model, were only partially successful. The objective is to conduct field measurements on long lava flows in Hawaii (where individual flows such as those of 1859 and 1881 exceed 40 km in length) in order to document and interpret their flow characteristics. In this way, a better understanding of the formation of long lava flows is sought as well as a determination of whether the Mauna Loa flows are terrestrial analogs to the long flows seen on Mars and Io.

Mouginismark, P. J.↗
NASA NTRS1984

The Mauna Loa sulfur flow as an analog to secondary sulfur flows on Io

Independent evidence suggests that both sulfur and silicate materials exist on the surface of Io. Spectral data indicate the presence of sulfur compounds, some of which are suggested to be of fumarolic origin. Morphological evidence and inferences of the physical properties of some land-forms suggest that silicate volcanism has occurred, which would involve temperatures 650 C or greater. Because the liquidus of sulfur is only about 115 C, it is likely that sulfur in close proximity to 'hot spots' or to active silicate volcanic areas on Io would be melted and mobilized as flows. The Mauna Loa sulfur flow may serve as an analog for such flows, as it consists of fumarolic sulfur that was melted as a consequence of a basaltic eruption and produced a small flow superimposed on silicate lavas.

Greeley, R.↗
NASA NTRS1983

The effect of El Chichon on the intensity and polarization of skylight at Mauna Loa

An empirical model of the stratospheric aerosol over Mauna Loa Observatory (MLO) has been developed, in order to study the effect of aerosol particles from the eruption of the El Chichon volcano on the intensity and degree of skylight polarization. The modeling computations were based on measurements of monthly mean optical thickness for July 1982, together with lidar measurements of the vertical distribution of aerosols. On the basis of the theoretical computations, it is shown that the number and location of polarization neutral points, and the location and magnitude of the peak polarization were both functions of the relatively narrow distribution of aerosol particle size near 0.4 microns.

King, M. D.↗