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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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Unveiling defect-mediated carrier dynamics in monolayer semiconductors by spatiotemporal microwave imaging

The optoelectronic properties of atomically thin transition-metal dichalcogenides are strongly correlated with the presence of defects in the materials, which are not necessarily detrimental for certain applications. For instance, defects can lead to an enhanced photoconduction, a complicated process involving charge generation and recombination in the time domain and carrier transport in the spatial domain. Here, we report the simultaneous spatial and temporal photoconductivity imaging in two types of WS 2 monolayers by laser-illuminated microwave impedance microscopy. The diffusion length and carrier lifetime were directly extracted from the spatial profile and temporal relaxation of microwave signals, respectively. Time-resolved experiments indicate that the critical process for photoexcited carriers is the escape of holes from trap states, which prolongs the apparent lifetime of mobile electrons in the conduction band. As a result, counterintuitively, the long-lived photoconductivity signal is higher in chemical-vapor deposited (CVD) samples than exfoliated monolayers due to the presence of traps that inhibits recombination. Overall, our work reveals the intrinsic time and length scales of electrical response to photoexcitation in van der Waals materials, which is essential for their applications in optoelectronic devices.

42 ENGINEERING↗

All-optical photoluminescence response of nitrogen-vacancy ensembles in diamond at low magnetic fields

All-optical (AO) microwave-free magnetometry using nitrogen-vacancy (N-𝑉) centers in diamond is attractive due to its broad applicability and reduced experimental complexity. In this work, we investigate room-temperature AO photoluminescence (PL) at low magnetic fields ( <2 mT) using diamonds with N-𝑉 ensembles at parts-per-million (ppm) concentrations. The measured AO-PL contrast features as a function of the applied magnetic field magnitude and direction are correlated with near-degenerate N-𝑉 electronic spin and hyperfine transitions from different N-𝑉 orientations within the diamond host. Reasonable agreement is found between low-field AO-PL measurements and model-based simulations of the effects of resonant dipolar interactions between N-𝑉 centers. The maximum observed AO-PL contrast depends on both the N-𝑉 concentration and the laser-illumination intensity at 532 nm. These results imply different optimal conditions for low-field AO N-𝑉 sensing compared to conventional optically detected magnetic resonance (ODMR) techniques, suggesting new research and application opportunities using AO measurements with lower system complexity, size, weight, and power.

Dipolar interaction↗

SHAPES - Spatial, high-accuracy, position-encoding sensor

Future space systems will require control sensors capable of real-time measurements of position coordinates of many structural locations. Applications for such a sensor include figure and vibration control, rendezvous and docking, and structure assembly verification. The paper discusses an experimental study of SHAPES (spatial, high-accuracy, position-encoding sensor), a 3D position sensor that provides range and two angular positions of laser-illuminated retroreflector targets that mark the locations to be measured. Simultaneous range measurements to multiple targets by a time-of-flight corelation of short laser pulses are made with a CCD-equipped streak tube. Angular positions are measured with a CCD camera. Position measurements of 24 targets with sub-millimeter range accuracy at a 10 Hz update rate have been demonstrated.

Nerheim, Noble M.↗

Laboratory calibration and characterization of video cameras

Some techniques for laboratory calibration and characterization of video cameras used with frame grabber boards are presented. A laser-illuminated displaced reticle technique (with camera lens removed) is used to determine the camera/grabber effective horizontal and vertical pixel spacing as well as the angle of nonperpendicularity of the axes. The principal point of autocollimation and point of symmetry are found by illuminating the camera with an unexpanded laser beam, either aligned with the sensor or lens. Lens distortion and the principal distance are determined from images of a calibration plate suitably aligned with the camera. Calibration and characterization results for several video cameras are presented. Differences between these laboratory techniques and test range and plumb line calibration are noted.

Burner, A. W.↗

Low-speed wind-tunnel investigation of a porous forebody and nose strakes for yaw control of a multirole fighter aircraft

Low-speed wind-tunnel tests were conducted in the Langley 12-Foot Low-Speed Tunnel on a model of the Boeing Multirole Fighter (BMRF) aircraft. This single-seat, single-engine configuration was intended to be an F-16 replacement that would incorporate many of the design goals and advanced technologies of the F-22. Its mission requirements included supersonic cruise without afterburner, reduced observability, and the ability to attack both air-to-air and air-to-ground targets. So that it would be effective in all phases of air combat, the ability to maneuver at angles of attack up to and beyond maximum lift was also desired. Traditional aerodynamic yaw controls, such as rudders, are typically ineffective at these higher angles of attack because they are usually located in the wake from the wings and fuselage. For this reason, this study focused on investigating forebody-mounted controls that produces yawing moments by modifying the strong vortex flowfield being shed from the forebody at high angles of attack. Two forebody strakes were tested that varied in planform and chordwise location. Various patterns of porosity in the forebody skin were also tested that differed in their radial coverage and chordwise location. The tests were performed at a dynamic pressure of 4 lb/ft(exp 2) over an angle-of-attack range of -4 deg to 72 deg and a sideslip range of -10 deg to 10 deg. Static force data, static pressures on the surface of the forebody, and videotapes of flow-visualization using laser-illuminated smoke were obtained.

Fears, Scott P.↗

Laser-Directed Ranging System Implementing Single Camera System for Telerobotics Applications

The invention relates generally to systems for determining the range of an object from a reference point and, in one embodiment, to laser-directed ranging systems useful in telerobotics applications. Digital processing techniques are employed which minimize the complexity and cost of the hardware and software for processing range calculations, thereby enhancing the commercial attractiveness of the system for use in relatively low-cost robotic systems. The system includes a video camera for generating images of the target, image digitizing circuitry, and an associated frame grabber circuit. The circuit first captures one of the pairs of stereo video images of the target, and then captures a second video image of the target as it is partly illuminated by the light beam, suitably generated by a laser. The two video images, taken sufficiently close together in time to minimize camera and scene motion, are converted to digital images and then compared. Common pixels are eliminated, leaving only a digital image of the laser-illuminated spot on the target. Mw centroid of the laser illuminated spot is dm obtained and compared with a predetermined reference point, predetermined by design or calibration, which represents the coordinate at the focal plane of the laser illumination at infinite range. Preferably, the laser and camera are mounted on a servo-driven platform which can be oriented to direct the camera and the laser toward the target. In one embodiment the platform is positioned in response to movement of the operator's head. Position and orientation sensors are used to monitor head movement. The disparity between the digital image of the laser spot and the reference point is calculated for determining range to the target. Commercial applications for the system relate to active range-determination systems, such as those used with robotic systems in which it is necessary to determine the, range to a workpiece or object to be grasped or acted upon by a robot arm end-effector in response to commands generated by an operator. In one embodiment, the system provides a real-time image of the target for the operator as the robot approaches the object. The system is also adapted for use in virtual reality systems in which a remote object or workpiece is to be acted upon by a remote robot arm or other mechanism controlled by an operator.

Wells, Dennis L.↗

Laboratory Calibration and Characterization of Video Cameras

Some techniques for laboratory calibration and characterization of video cameras used with frame grabber boards are presented. A laser-illuminated displaced reticle technique (with camera lens removed) is used to determine the camera/grabber effective horizontal and vertical pixel spacing as well as the angle of non-perpendicularity of the axes. The principal point of autocollimation and point of symmetry are found by illuminating the camera with an unexpanded laser beam, either aligned with the sensor or lens. Lens distortion and the principal distance are determined from images of a calibration plate suitable aligned with the camera. Calibration and characterization results for several video cameras are presented. Differences between these laboratory techniques and test range and plumb line calibration are noted.

Burner, A. W.↗

The Advanced Video Guidance Sensor: Orbital Express and the Next Generation

The Orbital Express (OE) mission performed the first autonomous rendezvous and docking in the history of the United States on May 5-6, 2007 with the Advanced Video Guidance Sensor (AVGS) acting as one of the primary docking sensors. Since that event, the OE spacecraft performed four more rendezvous and docking maneuvers, each time using the AVGS as one of the docking sensors. The Marshall Space Flight Center's (MSFC's) AVGS is a nearfield proximity operations sensor that was integrated into the Autonomous Rendezvous and Capture Sensor System (ARCSS) on OE. The ARCSS provided the relative state knowledge to allow the OE spacecraft to rendezvous and dock. The AVGS is a mature sensor technology designed to support Automated Rendezvous and Docking (AR&D) operations. It is a video-based laser-illuminated sensor that can determine the relative position and attitude between itself and its target. Due to parts obsolescence, the AVGS that was flown on OE can no longer be manufactured. MSFC has been working on the next generation of AVGS for application to future Constellation missions. This paper provides an overview of the performance of the AVGS on Orbital Express and discusses the work on the Next Generation AVGS (NGAVGS).

Howard, Richard T.↗

Low-Resolution Raman-Spectroscopy Combustion Thermometry

A method of optical thermometry, now undergoing development, involves low-resolution measurement of the spectrum of spontaneous Raman scattering (SRS) from N2 and O2 molecules. The method is especially suitable for measuring temperatures in high pressure combustion environments that contain N2, O2, or N2/O2 mixtures (including air). Methods based on SRS (in which scattered light is shifted in wavelength by amounts that depend on vibrational and rotational energy levels of laser-illuminated molecules) have been popular means of probing flames because they are almost the only methods that provide spatially and temporally resolved concentrations and temperatures of multiple molecular species in turbulent combustion. The present SRS-based method differs from prior SRS-based methods that have various drawbacks, a description of which would exceed the scope of this article. Two main differences between this and prior SRS-based methods are that it involves analysis in the frequency (equivalently, wavelength) domain, in contradistinction to analysis in the intensity domain in prior methods; and it involves low-resolution measurement of what amounts to predominantly the rotational Raman spectra of N2 and O2, in contradistinction to higher-resolution measurement of the vibrational Raman spectrum of N2 only in prior methods.

Nguyen, Quang-Viet↗

Probing a Spray Using Frequency-Analyzed Light Scattering

Frequency-analyzed laser-light scattering (FALLS) is a relatively simple technique that can be used to measure principal characteristics of a sheet of sprayed liquid as it breaks up into ligaments and then the ligaments break up into droplets. In particular, through frequency analysis of laser light scattered from a spray, it is possible to determine whether the laser-illuminated portion of the spray is in the intact-sheet region, the ligament region, or the droplet region. By logical extension, it is possible to determine the intact length from the location of the laser beam at the transition between the intact-sheet and ligament regions and to determine a breakup frequency from the results of the frequency analysis. Hence, FALLS could likely be useful both as a means of performing research on sprays in general and as a means of diagnostic sensing in diverse applications in which liquid fuels are sprayed. Sprays are also used for drying and to deposit paints and other coating materials.

Eskridge, Richard↗

Simultaneous Conoscopic Holography and Raman Spectroscopy

A new instrument was developed for chemical characterization of surfaces that combines the analytical power of Raman spectroscopy with the three-dimensional topographic information provided by conoscopic holography. The figure schematically depicts the proposed hybrid instrument. The output of the conoscopic holographic portion of the instrument is a topographical map of the surface; the output of the Raman portion of the instrument is hyperspectral Raman data, from which the chemical and/or biological composition of the surface would be deduced. By virtue of the basic principles of design and operation of the instrument, the hyperspectral image data would be inherently spatially registered with the topographical data. In conoscopic holography, the object and reference beams of classical holography are replaced by the ordinary and extraordinary components generated by a single beam traveling through a birefringent, uniaxial crystal. In the basic conoscopic configuration, a laser light is projected onto a specimen and the resulting illuminated spot becomes a point source of diffuse light that propagates in every direction. The laser beam is rasterscanned in two dimensions (x and y) perpendicular to the beam axis (z), and at each x,y location, the pattern of interference between the ordinary and extraordinary rays is recorded. The recorded interferogram constitutes the conoscopic hologram. Of particular significance for the proposed instrument is that the conoscopic hologram contains information on the z coordinate (height) of the illuminated surface spot. Hence, a topographical map of the specimen is constructed point-by-point by rastering the laser beam in the x and y directions and correlating the x and y coordinates with the z information obtained from the interferograms. Conoscopic imaging is an established method, and conoscopic laboratory instruments for surface metrology are commercially available. In Raman spectroscopy of a surface, one measures the spectrum of laser light scattered inelastically from a laser-illuminated spot on the surface. The wavelengths of the inelastically scattered light differ from that of the incident laser beam by amounts that correspond to the energies of molecular vibrations. The resulting vibrational spectrum can be used to identify the molecules. Raman spectroscopy is a standard laboratory technique for identifying mineralogical, biological, and other specific chemical compositions.

Schramm, Harry F.↗

Portable Airborne Laser System Measures Forest-Canopy Height

(PALS) is a combination of laser ranging, video imaging, positioning, and data-processing subsystems designed for measuring the heights of forest canopies along linear transects from tens to thousands of kilometers long. Unlike prior laser ranging systems designed to serve the same purpose, the PALS is not restricted to use aboard a single aircraft of a specific type: the PALS fits into two large suitcases that can be carried to any convenient location, and the PALS can be installed in almost any local aircraft for hire, thereby making it possible to sample remote forests at relatively low cost. The initial cost and the cost of repairing the PALS are also lower because the PALS hardware consists mostly of commercial off-the-shelf (COTS) units that can easily be replaced in the field. The COTS units include a laser ranging transceiver, a charge-coupled-device camera that images the laser-illuminated targets, a differential Global Positioning System (dGPS) receiver capable of operation within the Wide Area Augmentation System, a video titler, a video cassette recorder (VCR), and a laptop computer equipped with two serial ports. The VCR and computer are powered by batteries; the other units are powered at 12 VDC from the 28-VDC aircraft power system via a low-pass filter and a voltage converter. The dGPS receiver feeds location and time data, at an update rate of 0.5 Hz, to the video titler and the computer. The laser ranging transceiver, operating at a sampling rate of 2 kHz, feeds its serial range and amplitude data stream to the computer. The analog video signal from the CCD camera is fed into the video titler wherein the signal is annotated with position and time information. The titler then forwards the annotated signal to the VCR for recording on 8-mm tapes. The dGPS and laser range and amplitude serial data streams are processed by software that displays the laser trace and the dGPS information as they are fed into the computer, subsamples the laser range and amplitude data, interleaves the subsampled data with the dGPS information, and records the resulting interleaved data stream.

Nelson, Ross↗

Characterization and Calibration of an AERONET-OC Radiometer

The Ocean Color component of the global Aerosol Robotic Network (AERONET-OC) utilizes CE-318 sun photometers modified for above-water radiometry from fixed structures such as oil rigs, lighthouses and service platforms. Primarily, AERONET-OC measurements allow determination of the water-leaving radiance required for the validation of ocean color satellite data products. In this study, we characterized and calibrated one instrument from the AERONET-OC network, identified as AERONET #080. A laser-illuminated integrating sphere of known radiance enabled determination of the absolute radiance responsivity for 7 bands. We compared the results to calibrations from the AERONET facility at the Goddard Space Flight Center of the National Aeronautics and Space Administration and from the Joint Research Centre of the European Commission. These results agree within the estimated mean comparison uncertainty of 1.88 % (k = 2). We also assessed these results using calibrated lamp-illuminated integrating spheres and observed a spectral dependence to the comparison results that is unexplained.

B. C. Johnson↗

Atomistic Probing of Defect-Engineered 2H-MoTe 2 Monolayers

Point defects dictate various physical, chemical, and optoelectronic properties of two-dimensional (2D) materials, and therefore, a rudimentary understanding of the formation and spatial distribution of point defects is a key to advancement in 2D material-based nanotechnology. In this work, we performed the demonstration to directly probe the point defects in 2H-MoTe 2 monolayers that are tactically exposed to (i) 200 °C-vacuum-annealing and (ii) 532 nm-laser-illumination; and accordingly, we utilize a deep learning algorithm to classify and quantify the generated point defects. We discovered that tellurium-related defects are mainly generated in both 2H-MoTe 2 samples; but interestingly, 200 °C-vacuum-annealing and 532 nm-laser-illumination modulate a strong n-type and strong p-type 2H-MoTe 2 , respectively. While 200 °C-vacuum-annealing generates tellurium vacancies or tellurium adatoms, 532 nm-laser-illumination prompts oxygen atoms to be adsorbed/chemisorbed at tellurium vacancies, giving rise to the p-type characteristic. This work significantly advances the current understanding of point defect engineering in 2H-MoTe 2 monolayers and other 2D materials, which is critical for developing nanoscale devices with desired functionality.

2H-MoTe 2↗