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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Universal liquid sample device and process for high resolution transmission electron microscope imaging and multimodal analyses of liquid sample materials

Liquid sample imaging devices and processes are disclosed for high resolution TEM imaging and multimodal analyses of liquid sample materials in situ under high vacuum that are compatible with standard type TEM chip membranes and TEM sample holders allowing TEM liquid sample imaging to be performed wherever a TEM instrument is accessible and at a substantially reduced cost compared to prior art systems and approaches.

36 MATERIALS SCIENCE↗

Sample processor for the automatic extraction of families of compounds from liquid samples and/or homogenized solid samples suspended in a liquid

A sample processor and method for the automatic extraction of families of compounds, known as extracts, from liquid and/or homogenized solid samples are disclosed. The sample processor includes a tube support structure which supports a plurality of extraction tubes, each containing a sample from which families of compounds are to be extracted. The support structure is moveable automatically with respect to one or more extraction stations, so that as each tube is at each station a solvent system, consisting of a solvent and reagents, is introduced therein. As a result an extract is automatically extracted from the tube. The sample processor includes an arrangement for directing the different extracts from each tube to different containers, or to direct similar extracts from different tubes to the same utilization device.

Jahnsen, Vilhelm J.↗

Cryogenic Liquid Sample Acquisition System for Remote Space Applications

There is a need to acquire autonomously cryogenic hydrocarbon liquid sample from remote planetary locations such as the lakes of Titan for instruments such as mass spectrometers. There are several problems that had to be solved relative to collecting the right amount of cryogenic liquid sample into a warmer spacecraft, such as not allowing the sample to boil off or fractionate too early; controlling the intermediate and final pressures within carefully designed volumes; designing for various particulates and viscosities; designing to thermal, mass, and power-limited spacecraft interfaces; and reducing risk. Prior art inlets for similar instruments in spaceflight were designed primarily for atmospheric gas sampling and are not useful for this front-end application. These cryogenic liquid sample acquisition system designs for remote space applications allow for remote, autonomous, controlled sample collections of a range of challenging cryogenic sample types. The design can control the size of the sample, prevent fractionation, control pressures at various stages, and allow for various liquid sample levels. It is capable of collecting repeated samples autonomously in difficult lowtemperature conditions often found in planetary missions. It is capable of collecting samples for use by instruments from difficult sample types such as cryogenic hydrocarbon (methane, ethane, and propane) mixtures with solid particulates such as found on Titan. The design with a warm actuated valve is compatible with various spacecraft thermal and structural interfaces. The design uses controlled volumes, heaters, inlet and vent tubes, a cryogenic valve seat, inlet screens, temperature and cryogenic liquid sensors, seals, and vents to accomplish its task.

Mahaffy, Paul↗

Preliminary EDS Liquid Sample Adapter Design Assurance Testing

A new liquid sample adapter design for the Explosive Destruction Systems has been developed. The design features a semi-transparent fluoropolymer tube coupled to the vessel high pressure sample valve with a closing quick connect fitting. The sample tubes are the pressure-limiting component. The tubes were hydrostatically tested to establish failure characteristics and pressure limits at ambient and operational temperatures. A group of tubes from two manufacturing lots were tested to determine the consistency of the commercial part. An upper pressure limit was determined for typical operations.

42 ENGINEERING↗

3D-printed sheet jet for stable megahertz liquid sample delivery at X-ray free-electron lasers

X-ray free-electron lasers (XFELs) can probe chemical and biological reactions as they unfold with unprecedented spatial and temporal resolution. A principal challenge in this pursuit involves the delivery of samples to the X-ray interaction point in such a way that produces data of the highest possible quality and with maximal efficiency. This is hampered by intrinsic constraints posed by the light source and operation within a beamline environment. For liquid samples, the solution typically involves some form of high-speed liquid jet, capable of keeping up with the rate of X-ray pulses. However, conventional jets are not ideal because of radiation-induced explosions of the jet, as well as their cylindrical geometry combined with the X-ray pointing instability of many beamlines which causes the interaction volume to differ for every pulse. This complicates data analysis and contributes to measurement errors. An alternative geometry is a liquid sheet jet which, with its constant thickness over large areas, eliminates the problems related to X-ray pointing. Since liquid sheets can be made very thin, the radiation-induced explosion is reduced, boosting their stability. These are especially attractive for experiments which benefit from small interaction volumes such as fluctuation X-ray scattering and several types of spectroscopy. Although their use has increased for soft X-ray applications in recent years, there has not yet been wide-scale adoption at XFELs. Here, gas-accelerated liquid sheet jet sample injection is demonstrated at the European XFEL SPB/SFX nano focus beamline. Its performance relative to a conventional liquid jet is evaluated and superior performance across several key factors has been found. This includes a thickness profile ranging from hundreds of nanometres to 60 nm, a fourfold increase in background stability and favorable radiation-induced explosion dynamics at high repetition rates up to 1.13 MHz. Its minute thickness also suggests that ultrafast single-particle solution scattering is a possibility.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Group extraction of organic compounds present in liquid samples

An extraction device is disclosed comprising a tube containing a substantially inert, chemically non-reactive packing material with a large surface area to volume ratio. A sample which consists of organic compounds dissolved in a liquid, is introduced into the tube. As the sample passes through the packing material it spreads over the material's large surface area to form a thin liquid film which is held on the packing material in a stationary state. A particular group or family of compounds is extractable from the sample by passing a particular solvent system consisting of a solvent and selected reagents through the packing material. The reagents cause optimum conditions to exist for the compounds of the particular family to pass through the phase boundary between the sample liquid and the solvent of the solvent system. Thus, the compounds of the particular family are separated from the sample liquid and become dissolved in the solvent of the solvent system. The particular family of compounds dissolved in the solvent, representing an extract, exits the tube together with the solvent through the tube's nozzle, while the rest of the sample remains on the packing material in a stationary state. Subsequently, a different solvent system may be passed through the packing material to extract another family of compounds from the remaining sample on the packing material.

Jahnsen, Vilhelm J.↗

Advanced Test Reactor Loop Activity Report: Gamma-Ray Emitting Radionuclides Concentrations and Decontamination Factors of ATR Loop Liquid Samples Cycle 173C-1

The gamma-ray emitting radionuclide concentration and decontamination factor results from gamma-ray spectrometry measurements of ATR loop liquid samples by the Radiation Measurements Laboratory (RML) are contained in this report for ATR Cycle 173C-1 from November 22, 2024, to January 21, 2025.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Gamma-Ray Emitting Radionuclides Concentrations and Decontamination Factors of ATR Loop Liquid Samples Cycle 171B

This report contains the gamma-ray emitting radionuclides concentration and decontamination factor results from gamma-ray spectrometry measurements of ATR loop liquid samples by the Radiation Measurements Laboratory (RML) for ATR Cycle 171B Jun. 20, 2023, to Sep. 27, 2023. This report consists of five subsections, one for each loop. Each subsection contains the results for each sampling of the loop along with the date and time of sampling, spectral data identifications, sample type, and reactor power (MW). The results are reported in units of disintegrations per minute per milliliter of sample. The results are obtained with the gamma-ray spectral data analysis routines of the RML computer. Some of this report is also generated by RML data storage and handling routines.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Gamma-Ray Emitting Radionuclides Concentrations and Decontamination Factors of ATR Loop Liquid Samples: Cycle 172A

This report contains the gamma-ray emitting radionuclides concentration and decontamination factor results from gamma-ray spectrometry measurements of ATR loop liquid samples by the Radiation Measurements Laboratory (RML) for ATR Cycle 172A running March 2, 2024, to March 16, 2024. This report consists of five subsections, one for each loop. Each subsection contains the results for each sampling of the loop along with the date and time of sampling, spectral data identifications, sample type, and reactor power (MW). The results are reported in units of disintegrations per minute per milliliter of sample. The results are obtained with the gamma-ray spectral data analysis routines of the RML computer. Some of this report is also generated by RML data storage and handling routines.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Advanced Test Reactor Loop Activity Report: Gamma-Ray Emitting Radionuclides Concentrations and Decontamination Factors of ATR Loop Liquid Samples for ATR Cycle 175B-1

The gamma-ray emitting radionuclide concentration and decontamination factor results from gamma-ray spectrometry measurements of ATR loop liquid samples by the Radiation Measurements Laboratory (RML) are contained in this report for ATR Cycle 175B-1 from August 4, 2025 to October 6, 2025.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Gamma-Ray Emitting Radionuclides Concentrations and Decontamination Factors of ATR Loop Liquid Samples Cycle 173A Revision 0

This report contains the gamma-ray emitting radionuclides concentration and decontamination factor results from gamma-ray spectrometry measurements of ATR loop liquid samples by the Radiation Measurements Laboratory (RML) for ATR Cycle 173A running May 3, 2024, to July 6, 2024. This report consists of five subsections, one for each loop. Each subsection contains the results for each sampling of the loop along with the date and time of sampling, spectral data identifications, sample type, and reactor power (MW). The results are reported in units of disintegrations per minute per milliliter of sample. The results are obtained with the gamma-ray spectral data analysis routines of the RML computer. Some of this report is also generated by RML data storage and handling routines.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Complete resolution across the neodymium/samarium isotopic envelope with a liquid sampling‐atmospheric pressure glow discharge — Orbitrap mass spectrometer

Rationale Nd and Sm isotope ratios play an important role in geological dating and as nuclear forensic signatures; however, the overlap of the respective 144, 148, 150 Nd/Sm isobars requires prior separations to be performed before analysis on typical MS platforms. The work presented here overcomes these isobaric interferences using ultrahigh‐mass resolution to alleviate interference without prior chemical separations. Methods A liquid sampling‐atmospheric pressure glow discharge ion source was coupled to a standard, QExactive Focus Orbitrap mass spectrometer, providing a mass resolution of ~80 k. A Spectroswiss FTMS booster X2 data acquisition package was used to collect extended transients, providing much higher mass resolution; ~230 k and ~600 k are employed here for Nd and Sm isotopes. Results While the standard Orbitrap resolution is far greater than typical “atomic” MS platforms, it was insufficient to alleviate all isobars. The use of a resolution of ~230 k resulted in baseline separation across the entire isotopic envelope for both Nd and Sm. Isotope ratios obtained from Nd:Sm mixtures using high‐resolution were equivalent to those found for individual‐element solutions, while isotope ratios obtained at a resolution of ~80 k (standard for the OEM data system) showed large deviations. Conclusions Use of ultrahigh‐resolution is an attractive alternative to extensive chemical separations to alleviate severe isobaric interferences. Sufficient mass resolution greatly reduces/eliminates the need for sample manipulations (separations) before analysis while reducing costs and total analysis times.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗