Towards robust and scalable dispatch modeling of long-duration energy storage
Not Available
Guerra, Omar J.↗
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Cyclic moisture reactivation of calcium sorbents for long duration thermochemical energy storage
The transition to a flexible and reliable energy infrastructure, using electro-thermal energy generation technologies such as geothermal, concentrated solar power, and nuclear, usually demands simultaneous advancement of thermal energy storage (TES) to support on-demand electricity generation and industrial applications while mitigating the inherent intermittency of renewable energy sources and power outages from direct energy generation. Among TES technologies, thermochemical energy storage (TCES) based on calcium looping emerges as a compelling high-power energy storage candidate due to its high reaction enthalpy, compatibility with elevated operating temperatures, and abundance of low-cost materials. However, the long-term durability of calcium-based sorbents for TCES is hindered by surface sintering and particle aggregation, leading to performance degradation over repeated thermal cycles. This study explores a moisture hydration-based strategy to regenerate a degraded calcium sorbent and mitigate performance degradation for long duration TCES. The addition of moisture transforms calcium oxide into calcium hydroxide and produces intercalation water layers, associated with a regenerated surface area and reduced calcium oxide crystallite size. Both these effects are beneficial in restoring the sorbents' reactivity for carbonization. Additionally, an optimized hydration-assisted reactivation protocol balances the recovered energy storage capacity with heating penalty required for moisture removal from hydrated samples, resulting in an enhanced energy storage capacity up to 176% compared to benchmark sorbents that undergo cycling without reactivation after 60 cycles. In conclusion, these results highlight the potential of hydration-assisted reactivation to enhance the long-term performance of TCES, providing an effective pathway to advancing electro-thermal storage technologies.
36 MATERIALS SCIENCE↗
Multielectrode Array Sensors to Enable Long-Duration Corrosion Monitoring and Control of Concentrating Solar Power Systems
Molten mixtures of MgCl2-KCl-NaCl are promising heat transfer fluid (HTF) candidates for the next generation of concentrating solar power systems (Gen3 CSP), because of their low cost, high decomposition temperature, and favorable heat transfer characteristics. However, if the chemistry of the salts is not properly controlled, molten chlorides can cause corrosion of high-temperature metal alloys, such as Inconel (R), in CSP systems. Here we demonstrate a corrosion monitoring system that can be used to monitor the health of the structural alloys over long durations. The monitoring system includes a multielectrode array voltammetry sensor that measures the redox potential of molten MgCl2-KCl-NaCl mixture as well as the presence of corrosion products and impurities. The sensors have been successfully operated in static molten salt environments for long durations, and are capable of detecting corrosion products, such as Cr2+ and Fe2+, quantitatively at low concentrations (i.e., approximately 100 ppm) with less than 4% error.
Concentrated solar power↗
Exploring the Future Energy Value of Long-Duration Energy Storage
Long-duration energy storage is commonly viewed as a key technology for providing flexibility to the grid and broader energy systems over a multidecadal time frame. However, prior work has typically used present-day grid infrastructures to characterize the relationship between the duration and arbitrage value of storage in electricity markets. This study leverages established National Renewable Energy Laboratory grid planning and operations tools, analysis, and data to execute a price-taker model of an energy storage system for several 8760 h price series representative of current and future contiguous United States grid infrastructures with varying shares of variable renewable energy (VRE). We find that the total value of energy storage typically increases with VRE shares, but any increase in the relative value of longer storage durations over time depends on the region and grid mix. Some regions see incremental value increasing notably, up to 20–40 h in 2050, while others do not. The negative effect of lower roundtrip efficiency on value is also found to be scenario-dependent, with the energy value in higher VRE scenarios being less sensitive to roundtrip efficiency and more supportive of longer storage durations. Long-duration storage value and deployment potential are a function of evolving electricity sector infrastructure, markets, and policy, making it critical to consistently revisit potential long-duration storage contributions to the grid.
14 SOLAR ENERGY↗
Modeling electrical particle thermal energy storage systems for long-duration, grid-electricity storage applications
Not Available
Gifford, Jeffrey (ORCID:0000000259090325)↗
Effect of modeled time horizon on quantifying the need for long-duration storage
Long-Duration Energy Storage (LDES) has gained interest due to its key role in attaining a decarbonized, low-cost, and stable grid driven by variable renewable electricity (VRE). Currently, there is a wide range of LDES technologies being developed to provide electricity with 8+ hours of consecutive discharge. However, current capacity expansion models used in long-term planning processes rarely consider low cost LDES as a candidate technology. If they do, the storage balancing horizon (SBH) of the model usually only considers non-consecutive 1-day periods that do not capture the potential of LDES to shift energy across multiple days or even seasons. Addressing these limitations in existing models, this work explores the ways in which the optimal energy storage changes when increasing the number of consecutive days in the SBH and how these changes will impact planners who are determining the future roles of energy storage. Our analysis uses SWITCH, an open-source capacity expansion model with a high spatial resolution for the entire Western Electricity Coordinating Council (WECC) in a zero-carbon scenario in 2050. We find that the number of consecutive days in the SBH changes both the total selected power and energy capacity of LDES when storage energy and power capacity overnight costs are $\$$13 USD/kWh (or less) and $113 USD/kW, respectively. We also find that the amount of required energy in storage to drive a future VRE-driven WECC grid ranges from 2.5 TWh to 16.0 TWh depending on the length of the SBH. The optimal storage duration (energy to power ratio) we obtain ranges from 10 h to 620 h among all the scenarios. Furthermore, depending on the storage cost assumption, we observe different charge/discharge patterns when varying the length of the SBH. Given our results, we anticipate that as more LDES technologies become commercially available, it will be critical to increase the length of the SBH to fully capture the benefits of LDES assets in long-term planning processes of high VRE-driven grids.
42 ENGINEERING↗
Dispatching Long Duration Storage on High PV Systems
Long duration storage is expected to become increasingly important as shares of variable renewable energy increase. This presentation details some of the challenges of representing long duration storage, the importance of accurately modeling its dispatch, and a few methods for improving dispatch models.
dispatch↗
Storage Futures Study: The Challenge of Defining Long-Duration Energy Storage
This document explores the definition of "long duration" as applied to energy storage. Given the growing use of this term, a uniform definition could aid in communication and consistency among various stakeholders. There is large and growing use of the ARPA-E definition of greater than 10 hours. However, the term "long-duration energy storage" is often used as shorthand for storage with sufficient duration to provide firm capacity and support grid resource adequacy. The actual duration needed for this application varies significantly from as little as a few hours to potentially multiple days. This leads to the unsatisfying conclusion that there cannot be a simple, uniform, and static definition of long duration storage that captures its ability to provide firm capacity and also aids consistent communication.
24 POWER TRANSMISSION AND DISTRIBUTION↗
Shorting at Long Duration: Impact of Extended Discharge Capacity on Battery Solid Electrolytes
Long-duration energy storage (LDES) is critical to a stable, resilient, and decarbonized electric grid. While batteries are emerging as important LDES devices, extended, high-power discharges necessary for cost-competitive LDES present new materials challenges. Here, focusing on a new generation of low-temperature molten sodium batteries, we explore here unique phenomena related to long-duration discharge through a well-known solid electrolyte, NaSICON. Specifically, molten sodium symmetric cells at 110°C were cycled at 0.1 A cm -2 for 1-23 h discharges. Longer discharges led to unstable overpotentials, reduced resistances, and decreased electrolyte strength, caused by massive sodium penetration not observed in shorter duration discharges. Scanning electron microscopy informed mechanisms of sodium penetration and even “healing” during shorter-duration cycling. Importantly, these findings show that traditional, low-capacity, shorter-duration tests may not sufficiently inform fundamental materials phenomena that will impact LDES battery performance. This case highlights the importance that candidate LDES batteries be tested under pertinent long-duration conditions.
25 ENERGY STORAGE↗
Origin of deactivation of aqueous Na–CO 2 battery and mitigation for long-duration energy storage
Here, the development of long-duration energy storage technology is crucial to facilitate the efficient utilization of renewable energy sources while mitigating carbon dioxide production. In this study, we investigate the deactivation and reactivation mechanisms of the aqueous Na–CO 2 battery during extended cycling. We have designed the cathode to include non-precious intermetallic catalysts. As the cell undergoes repeated cycles, the voltage polarization during discharge progressively rises, eventually leading to the cell's deactivation and formation of decomposition products clogging the electrode surface. Results obtained from comprehensive characterization techniques, including conductive atomic force microscopy (cAFM), Raman spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, and inductively coupled plasma-mass spectrometry provide insight into the decomposition products. We also showcase an electrochemical approach for regeneration of these aqueous cells. Our findings, along with the insights we have gained, provide a path toward creating long-duration systems with self-healing properties.
25 ENERGY STORAGE↗
Benefit Analysis of Long-Duration Energy Storage in Power Systems with High Renewable Energy Shares
The integration of high shares of variable renewable energy raises challenges for the reliability and cost-effectiveness of power systems. The value of long-duration energy storage, which helps address variability in renewable energy supply across days and seasons, is poised to grow significantly as power systems shift to larger shares of variable generation such as wind and solar. This study explores the system-level services and associated benefits of long-duration energy storage on the 2050 Western Interconnection (WI). The operation of the future WI system with 85% renewable penetration is simulated using a two-stage production cost model. The impact of long duration energy storage on systemwide operations is examined for the 2050 WI system, using a range of round-trip efficiencies corresponding to four different energy storage technologies. The analysis projects the energy storage dispatch profile, system-wide production cost savings (from both diurnal and seasonal operation), and impacts on generation mix, and change in renewable generation curtailment.
25 ENERGY STORAGE↗
A Comprehensive Comparison of Methods for Evaluating Dispatch of Long-Duration Energy Storage in Power Systems Models
Long-duration energy storage (LDES) could play a pivotal role in the transformation of electricity grids with high shares of variable renewable energy (VRE) such as solar and wind. However, the weather-dependent nature of VRE introduces challenges for grid balancing and stability, which LDES - along with short-duration energy storage (SDES) - can help address. However, modeling LDES in production cost models (PCMs) is particularly challenging due to the need for high temporal resolution over extended optimization windows while preserving chronology, which ensures the alignment of energy storage operations with VRE generation over multi-day periods. This report compares traditional dispatch methods with advanced LDES dispatch strategies, such as the extended horizon approach, across different PCM platforms and examines tradeoffs and scalability. The comparison reveals that the traditional 1-day optimization horizon within the PCM leads to inefficient utilization of LDES. In contrast, extending the optimization horizon as much as possible significantly reduces curtailment and improves storage dispatch, especially in renewable-dense systems. There is also promise in using state-of-charge or end volume targets set by an external model, however this requires an additional modeling set and generally increases computational burden. This paper presents a comparison of these various methods in a number of power systems, showing algorithms initially in small test systems and scaling up to large, country-wide simulations. Overall, the research presents the trade-offs of various computational methods and illustrates how LDES may play an essential role in power systems of the future.
14 SOLAR ENERGY↗
System and component development for long-duration energy storage using particle thermal energy storage
Energy storage, at various scales, will be required to maintain reliable power supply from variable renewable resources, and improve grid resilience. Long-duration energy storage (10-100 h) can substitute baseload coal power generation and increase levels of renewable power supply. Thermal energy storage (TES) has siting flexibility and the ability to store a large capacity of energy, and thus it has the potential to meet the needs of long-duration energy storage. Here, a novel TES system was developed by using solid particles as storage media and charging/discharging electricity from renewable power connected via the electric grid. The particle TES uses low-cost silica sand at 30-40$/Ton that is stable at high temperatures of >1,000 degrees C. Thus, the particle TES system has an overall low storage cost and high thermal-power efficiency. Key components of the system were conceptually designed and modeled for their performance. Conversion of electricity to thermal energy using electric heating can achieve a >98% charging efficiency, and the conversion of thermal energy back to electricity uses an air-Brayton combined power cycle with >52% thermal-to-electricity efficiency at >1,170 degrees C to achieve a >50% roundtrip efficiency after subtracting estimated plant parasitic losses. Laboratory-scale prototypes were fabricated and tested to verify their design approaches and operations relevant to product-scale components.
25 ENERGY STORAGE↗
Using time reversal with long duration broadband noise signals to achieve high amplitude and a desired spectrum at a target location
Time Reversal (TR) is a signal processing technique that can be used to focus acoustic waves to a specific location in space, with most applications aiming to create an impulsive focus. Here, this study instead aims to focus long-duration noise signals using TR. This paper seeks to generate higher amplitude noise at a desired location over an existing method of broadcasting equalized noise. Additionally, this paper explores various characteristics associated with focusing long duration noise using TR. The dependence of the focal amplitude on the duration of the focused signal is explored as well as the implications of using multiple sources when focusing noise. The focal amplitude decreases with longer duration and then levels off when the duration exceeds a few seconds. Coherent addition of focused noise is observed if all loudspeakers have coherent noise signals convolved with their reversed impulse responses. Lastly, focusing noise with a desired spectrum is explored.
42 ENGINEERING↗
Economic Long-Duration Electricity Storage by Using Low-Cost Thermal Energy Storage and High-Efficiency Power Cycle (ENDURING)
The project involved considerable industry participation including General Electric (GE, power cycle analysis), Babcock & Wilcox (B&W), Allied Mineral Products (insulation materials), and Worley-Advisian (system integration). They provided insights on their products or services for component and system designs. The project successfully achieved the project goals of demonstrating technology feasibility for long duration energy storage with a technology path towards 5c/kWh levelized cost of storage. The project has generated four patent applications (one awarded patent and three under review), three published journal papers, a draft book chapter, and five manuscripts under preparation, with several conference papers and numerous presentations including invited talks. An intellectual properties (IP) option agreement has been signed with an U.S. manufacturer, with interests from energy developers. Four related projects with $5.5 million DOE funding support more developments for long duration energy storage and broad industry decarbonization.
25 ENERGY STORAGE↗
Individual and Collective Strategies to Limit the Impacts of Large Power Outages of Long Duration
As modern society becomes ever more dependent on the availability of electric power, the costs that could arise from individual and social vulnerability to large outages of long duration (LLD-outages) increases. During such an outage, even a small amount of power would be very valuable. Here, this article compares individual and collective strategies for providing limited amounts of electric power to residential customers in a hypothetical New England community during a large electric power outage of long duration. We develop estimates of the emergency load required for survival and assess the cost of strategies to address outages that last 5, 10, and 20 days in either winter or summer. We find that the cost of collective solutions could be as much as 10 to 40 times less than individual solutions (less than $2 per month per home). However, collective solutions would require community-wide coordination, and if local distribution system lines are destroyed, only individual back-up systems could provide contingency power until those lines are repaired. Costs might be reduced if more robust distributed generation were employed that could be operated continuously with the ability to sell power back to the grid. Our cost-effectiveness analysis only assesses what could be done, developing estimates of preparedness cost. A decision about what should be done would require additional input from a range of stakeholders as well as some form of analytical deliberative process.
24 POWER TRANSMISSION AND DISTRIBUTION↗
The value of long-duration energy storage under various grid conditions in a zero-emissions future
Long-duration energy storage (LDES) is a key resource in enabling zero-emissions electricity grids but its role within different types of grids is not well understood. Using the Switch capacity expansion model, we model a zero-emissions Western Interconnect with high geographical resolution to understand the value of LDES under 39 scenarios with different generation mixes, transmission expansion, storage costs, and storage mandates. We find that a) LDES is particularly valuable in majority wind-powered regions and regions with diminishing hydropower generation, b) seasonal operation of storage becomes cost-effective if storage capital costs fall below US$\$$5 kWh −1 , and c) mandating the installation of enough LDES to enable year-long storage cycles would reduce electricity prices during times of high demand by over 70%. Given the asset and resource diversity of the Western Interconnect, our results can provide grid planners in many regions with guidance on how LDES impacts and is impacted by energy storage mandates, investments in LDES research and development, and generation mix and transmission expansion decisions.
25 ENERGY STORAGE↗
Nine Canyon Long-Duration Energy Storage: A Feasibility Study
The Nine Canyon Long Duration Energy Storage (LDES) Feasibility Study explores the technical and economic viability of deploying advanced energy storage technologies at Energy Northwest's (EN) Nine Canyon (9C) Wind Project site in Benton County, Washington. Supported by the Washington State Department of Commerce and the U.S. Department of Energy’s Office of Electricity under its LDES Voucher Program, the study represents a collaborative effort between EN, Pacific Northwest National Laboratory (PNNL), and ARES North America. At the core of this effort is the development of a generalized techno-economic modeling framework and evaluation tool designed to assess the value proposition of LDES projects across a variety of contexts. The modeling tool is technology-agnostic and accommodates user-defined parameters such as rated power, energy duration, round-trip efficiency, capital and operational costs, and dispatch constraints. It also integrates economic inputs, including market prices, energy revenue structures, and financing parameters to evaluate performance through key metrics. The tool provides utilities with a transparent, adaptable platform to support decision-making, investment prioritization, and portfolio planning for various storage technologies. To guide scenario design and interpretation, the study first surveyed the LDES technology landscape, including lithium-ion batteries, flow batteries, non-hydro gravity storage, and thermo-mechanical systems, comparing cost trajectories, technical performance, safety and hazards, materials sourcing and recyclability, and spatial/siting considerations. This literature-grounded review highlights technology trade-offs and reinforces the need to align technology choice with site characteristics, use cases, and project objectives. A companion chapter examines ownership structures (EN ownership, third-party ownership, shared models) and offtake options (energy marketing, capacity/energy PPAs, time-of-use PPAs, block-delivery PPAs, and tolling), where PPAs (power purchase agreements) represent contractual arrangements for buying and selling electricity. The chapter also highlights implications for risk allocation, capital access, operational control, and revenue certainty. The study also evaluates supervisory control and data acquisition (SCADA) and transmission interconnection pathways, options include upgrading the existing SCADA or deploying a dedicated LDES controller, with attention to protection schemes, data telemetry, cybersecurity, and regulatory coordination with BPA. In addition, an ARES-specific geotechnical and hydrology assessment presented in the appendix screens multiple corridors for slope stability, bearing capacity, cut-and-fill magnitude, and stormwater behavior.
25 ENERGY STORAGE↗