Search NASA⌕ Search

SEARCH · Search NASA

Results for “MAGNESIUM 33”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2011

Nuclear Data Sheets for A = 33

The experimental data are evaluated for known nuclides of mass number A=33 (Ne, Na, Mg, Al, Si, P, S, Cl, Ar, K). Detailed evaluated level properties and related information are presented, including adopted values of level and {gamma}-ray energies, decay data (energies, intensities and placement of radiations), and other spectroscopic data. This work supersedes earlier full evaluations of A=33 published by 1990En08 (also 1998En04 update) and 1978En02. Experimental studies for the identification of the {sup 33}Ne and {sup 33}K nuclides have not met with success as yet. Values of S(n) and S(p) from systematics for {sup 33}Ne and {sup 33}K, respectively suggest that these nuclei are likely to be unstable to particle emission. The radioactive decay schemes of {sup 33}Na and {sup 33}Al seem incomplete in view of large Q values and known excitations much below than allowed by the Q values. The {sup 33}S and {sup 33}Cl nuclides remain as the most extensively studied from many different reactions and decays.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2017

Declamped Piezoelectric Coefficients in Patterned 70/30 Lead Magnesium Niobate–Lead Titanate Thin Films

Lateral subdivision of blanket piezoelectric thin films increases the functional properties through both increased domain wall mobility and declamping of the intrinsic response. This work presents the local effects of substrate declamping on the piezoelectric coefficient d 33,f of 300 nm thick, rhombohedral, {001}-oriented lead magnesium niobate–lead titanate thin films at the 70/30 composition (70PMN–30PT). Films grown by chemical solution deposition on platinized Si substrates are patterned into strip structures ranging from 0.75 to 9 µm in width. The longitudinal piezoelectric coefficient, d 33,f , is interrogated as a function of position across the patterned structures by three approaches: finite element modeling, piezoresponse force microscopy, and nanoprobe synchrotron X-ray diffraction. It is found that d 33,f increases from the clamped value of 40–50 to ≈160 pm V -1 at the free sidewall under 200 kV cm -1 excitation. The sidewalls partially declamp the piezoelectric response 500–600 nm into the patterned structure, raising the piezoelectric response at the center of features with lateral dimensions less than 1 µm (3:1 width to thickness aspect ratio). The normalized data from all three methods are in excellent agreement, with quantitative differences providing insight to the field dependence of the piezoelectric coefficient and its declamping behavior.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Friction-based riveting technique for AZ31 magnesium alloy

Rivet materials used in the aerospace and automotive industries are typically alloys of aluminum (Al) or steel. Magnesium (Mg) is an attractive alternative because it is 33% and 75% lighter than Al and steel, respectively. However, a primary barrier for using Mg as rivet material is its poor formability at room temperature, resulting in brittle fracture of the rivet head during cold riveting. Hot riveting is possible but suffers from high cycle time due to the need for pre-heating. A new friction-based riveting technique, Rotating Hammer Riveting (RHR), is reported to fully form AZ31 Mg rivet heads in a mere 0.23 seconds cycle time. Heat and pressure generated through severe plastic deformation during the process was sufficient to form the Mg rivet head without the need for a separate pre-heating operation. Due to dynamic recrystallization, AZ31 Mg grains in the rivet head were significantly refined from about 15 to 2.6 µm during RHR, which favors the formability of Mg rivet by triggering grain boundary sliding and reducing plastic anisotropy of Mg. In addition, RHR joints showed a metallurgical bond between the rivet head and top sheet, which eliminates a significant pathway for corrosion.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Strongly coupled rotational band in Mg 33

The “island of inversion” at N≈20 for the neon, sodium, and magnesium isotopes has long been an area of interest both experimentally and theoretically due to the subtle competition between 0p-0h and np-nh configurations leading to deformed shapes. However, the presence of rotational band structures, which are fingerprints of deformed shapes, have only recently been observed in this region. In this work, we report on a measurement of the low-lying level structure of Mg33 populated by a two-stage projectile fragmentation reaction and studied with the Gamma Ray Energy Tracking In-Beam Nuclear Array (GRETINA). The experimental level energies, ground-state magnetic moment, intrinsic quadrupole moment, and γ-ray intensities show good agreement with the strong-coupling limit of a rotational model.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2016

Insights from a Recent Meeting: Current Status and Future Directions in Magnesium Corrosion Research

The United States Department of Energy Vehicle Technologies Office held a Technical Review Meeting entitled “Current Status and Future Directions in Magnesium Corrosion Research” at Oak Ridge National Laboratory in April 2016. Here current funded Mg corrosion projects presented their latest results, along with invited presentations from academic and industrial researchers in the area of Mg corrosion. This paper overviews select topics from the meeting, with an emphasis on relaying meeting discussion points regarding future needs in understanding and mitigating Mg corrosion, particularly for automotive applications. Topics highlighted include the need for pretreatments and coatings suitable for mass vehicle production of Mg components, particularly for dissimilar metal joints involving Mg, Al, or steel, and corrosion evaluation methods more relevant to automotive components and operating conditions. Finally, from a scientific perspective, the need for better fundamental understanding of Mg dissolution, hydrogen evolution, and film formation behavior was a recurring theme, as was phenomena related to microgalvanic coupling involving second phases and impurities in Mg.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2017

Optical Properties of Non-stoichiometric Amorphous Silicates with Application to Circumstellar Dust Extinction

We determine the optical constants of non-stoichiometric amorphous magnesium-iron silicates and demonstrate that they can well reproduce the observed mid-infrared emission spectra of evolved stars. Stoichiometric and non-stoichiometric amorphous magnesium-iron silicate films are fabricated by pulsed laser deposition. Transmittance and ellipsometry measurements are performed in the wavelength range between 2 and 200 μm and 1.7 and 33 μm, respectively. Optical constants are derived from transmittance and ellipsometric Ψ and Δ spectra by means of oscillator models. These newly obtained optical constants are applied in radiative transfer models for examining reproducibility of the observed spectral features of circumstellar dust shells around supergiants. The spectra of four selected supergiants are dominated by amorphous silicate dust emission in the wavelength range between 9 and 25 μm. To obtain a good fit to the observed spectra, we take into account amorphous corundum and metallic iron particles as additional dust components to the model calculations to rationalize the dust emission at λ<8 μm. For each of the objects, a set of model parameters (dust mass and condensation temperature) is derived by an automated optimization procedure that reproduces the observation well. Consequently, our model spectra using new optical data reveal that the silicate bands at ∼10 and ∼18 μm depend on the magnesium and iron ratio in the silicate system, and that a good fit requires a significant iron content of the amorphous silicate dust component to reproduce the observed peak positions and shape of the silicate bands.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

Light polarization sensitive photodetectors with m- and r-plane homoepitaxial ZnO/ZnMgO quantum wells

Homoepitaxial ZnO/(Zn,Mg)O multiple quantum wells (MQWs) grown with m- and r-plane orientations are used to demonstrate Schottky photodiodes sensitive to the polarization state of light. In both orientations, the spectral photoresponse of the MQW photodiodes shows a sharp excitonic absorption edge at 3.48 eV with a very low Urbach tail, allowing the observation of the absorption from the A, B and C excitonic transitions. The absorption edge energy is shifted by ∼30 and ∼15 meV for the m- and r-plane MQW photodiodes, respectively, in full agreement with the calculated polarization of the A, B, and C excitonic transitions. The best figures of merit are obtained for the m-plane photodiodes, which present a quantum efficiency of ∼11%, and a specific detectivity D* of ∼6.4 × 10{sup 10} cm Hz{sup 1/2}/W. In these photodiodes, the absorption polarization sensitivity contrast between the two orthogonal in-plane axes yields a maximum value of (R{sub ⊥}/R{sub ||}){sub max} ∼ 9.9 with a narrow bandwidth of ∼33 meV.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2013

Lightweight Materials 2012 Annual Progress Report

The FY 2012 Annual Progress Report for Lightweight Materials provides a detailed description of the activities and technical accomplishments which focuses on the development and validation of advanced materials and manufacturing technologies to significantly reduce light and heavy duty vehicle weight without compromising other attributes such as safety, performance, recyclability, and cost.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2012

CLEERS Aftertreatment Modeling and Analysis

DOE FY 2011 Advanced Combustion Technologies Annual Report. CLEERS is a research and development focus project of the Diesel Cross-Cut Team. The overall objective is to promote the development of improved computational tools for simulating realistic full-system performance of lean-burn engines and the associated emissions control systems. Three fundamental research projects are sponsored at PNNL through CLEERS: DPF, SCR, and LNT. Resources are shared between the three efforts in order to actively respond to current industrial needs. In FY 2011, more emphasis was placed on the SCR and LNT activities because of urgent application issues associated with these technologies. Objectives of this project are to lead and contribute to the Cross-Cut Lean Exhaust Emissions Reduction Simulations (CLEERS) activities - (a) Provide project updates to the industry sub-team, solicit feedback, and adjust work scope accordingly; and (b) Lead technical discussions, invite distinguished speakers, and maintain an open dialogue on selective catalytic reduction (SCR), lean-NOx trap (LNT), and diesel particulate filter (DPF) modeling issues. Fiscal Year (FY) 2011 Objectives are to: (1) Develop improved modeling capabilities for SCR and DPFs through fundamental experiments; and (2) Develop a fundamental understanding of SCR and LNT catalysts with primary focus on reaction mechanisms and material characterization. Some accomplishments are: (1) Participated in monthly CLEERS teleconferences and coordinated the calls focused on SCR, LNT and DPF technologies; (2) Updated PNNL's SCR model for the state-of-the-art commercial Cu-zeolite SCR catalyst to extract kinetic parameters and to quantitatively describe the effects of hydrothermal aging; (3) Examined the effects of hydrothermal aging on the physicochemical properties and SCR reactions using the commercial Cu catalyst in collaboration with Oak Ridge National Laboratory (ORNL); (4) Investigated the nature of Cu species and obtained kinetic parameters for small-pore zeolite-based Cu SCR catalyst. (5) Examined the effects of support materials for Ba-based LNT catalysts, and found magnesium aluminate may improve the oxides of nitrogen (NO{sub x}) reduction performance at high temperatures; (6) Investigated soot oxidation mechanisms for relevant oxidants (O{sub 2}, NO{sub 2}) through reactor experiments and transmission electron spectroscopy (TEM) analysis; (7) Seven publications and 21 public presentations (eight invited) during the past FY; and (8) Co-organized sessions on emission control and modeling for the SAE World Congress and the American Society of Mechanical Engineers Internal Combustion Engine Conference.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2024

Effect of relative humidity on the interlayer spacing of phosphate intercalated Mg, Al layered double hydroxide (hydrotalcite‐like) crystals

Abstract The availability of water and the type of interlayer anions present affect the arrangement and interlayer spacing of layered double hydroxide (LDH). A systematic study of the effect of relative humidity (RH) on the basal spacing of phosphate intercalated, magnesium aluminum LDHs (MgAl–PO 4 LDH) was conducted, confirming that MgAl‐PO 4 LDH exhibit distinct interlayer spacing corresponding to separate low‐ and high‐hydration states produced when exposed to low and high humidity conditions. The transition from the low‐ to high‐hydration form begins when RH exceeds 33% and is accompanied by the transition from one to two interlayers of water. An improved understanding of the effect of RH on MgAl–PO 4 LDHs will enable more accurate atomistic modeling and experimental characterization of MgAl–PO 4 LDHs and may lead to improvements in the tunability of MgAl‐PO 4 LDHs for commercial applications such as slow‐release fertilizer.

Reed, Titus↗
DOE OSTI2011

In-beam {gamma}-ray spectroscopy of {sup 35}Mg and {sup 33}Na

Excited states in the very neutron-rich nuclei {sup 35}Mg and {sup 33}Na were populated in the fragmentation of a {sup 38}Si projectile beam on a Be target at 83 MeV/u beam energy. We report on the first observation of {gamma}-ray transitions in {sup 35}Mg, the odd-N neighbor of {sup 34}Mg and {sup 36}Mg, which are known to be part of the 'island of inversion' around N=20. The results are discussed in the framework of large-scale shell-model calculations. For the A=3Z nucleus {sup 33}Na, a new {gamma}-ray transition was observed that is suggested to complete the {gamma}-ray cascade 7/2{sup +}{yields}5/2{sup +}{yields}3/2{sub gs}{sup +} connecting three neutron two-particle-two-hole intruder states that are predicted to form a close-to-ideal K=3/2 rotational band in the strong-coupling limit.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2017

Precision mass measurements of magnesium isotopes and implications for the validity of the isobaric mass multiplet equation

If the mass excess of neutron-deficient nuclei and their neutron-rich mirror partners are both known, it can be shown that deviations of the isobaric mass multiplet equation (IMME) in the form of a cubic term can be probed. Such a cubic term was probed by using the atomic mass of neutron-rich magnesium isotopes measured using the TITAN Penning trap and the recently measured proton-separation energies of 29 Cl and 30 Ar. The atomic mass of 27 Mg was found to be within 1.6σ of the value stated in the Atomic Mass Evaluation. The atomic masses of 28,29 Mg were measured to be both within 1σ, while being 7 and 33 times more precise, respectively. Using the 29 Mg mass excess and previous measurements of 29 Cl, we uncovered a cubic coefficient of d = 28(7)keV, which is the largest known cubic coefficient of the IMME. This departure, however, could also be caused by experimental data with unknown systematic errors. Hence there is a need to confirm the mass excess of 28 S and the one-neutron separation energy of 29 Cl, which have both come from a single measurement. Lastly, our results were compared with ab initio calculations from the valence-space in-medium similarity renormalization group, resulting in a good agreement.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2014

Microstructure stability of ultra-fine grained magnesium alloy AZ31 processed by extrusion and equal-channel angular pressing (EX–ECAP)

Thermal stability of the ultra-fine grained (UFG) microstructure of magnesium AZ31 alloy was investigated. UFG microstructure was achieved by a combined two-step severe plastic deformation process: the extrusion (EX) and subsequent equal-channel angular pressing (ECAP). This combined process leads to refined microstructure and enhanced microhardness. Specimens with UFG microstructure were annealed isochronally at temperatures 150–500 °C for 1 h. The evolution of microstructure, mechanical properties and dislocation density was studied by electron backscatter diffraction (EBSD), microhardness measurements and positron annihilation spectroscopy (PAS). The coarsening of the fine-grained structure at higher temperatures was accompanied by a gradual decrease of the microhardness and decrease of dislocation density. Mechanism of grain growth was studied by general equation for grain growth and Arrhenius equation. Activation energies for grain growth were calculated to be 115, 33 and 164 kJ/mol in temperature ranges of 170–210 °C, 210–400 °C and 400–500 °C (443–483 K, 483–673 K and 673–773 K), respectively. - Highlights: • Microhardness of UFG AZ31 alloy decreases with increasing annealing temperature. • This fact has two reasons: dislocation annihilations and/or grain growth. • The activation energies for grain growth were calculated for all temperature ranges.

36 MATERIALS SCIENCE↗
DOE OSTI2021

In situ monitoring of dislocation, twinning, and detwinning modes in an extruded magnesium alloy under cyclic loading conditions

This work investigates the microscopic deformation mechanisms of an extruded, precipitation-strengthened AZ80 magnesium (Mg) alloy subjected to strain-controlled low-cycle fatigue using in situ neutron diffraction measurements. Results demonstrate that the plastic deformation during cyclic loading is dominated by the alternating {10.2} extension twinning and detwinning mechanisms. The observed deformation mode is strongly texture and precipitate dependent. For the initial texture, the tested material has two major texture components which result in the occurrence of extension twinning during both compression and reverse tension in the first two cycles. The prolonged detwinning process in the following cycles is proposed to relieve the shear stress field of {00.2} grains, leading to the disappearance of twinning. The precipitation strengthening results in an increase of the critical resolved shear stress (CRSS) by similar to 33 MPa for the extension twinning in this AZ80 alloy. Here, the synergistic effects of the initial texture, precipitation strengthening, and load sharing of various grain families and phases contribute to the complicated evolution of dominant deformation mechanisms, among which elevated dislocation activities are believed to be responsible for the relatively poor low-cycle-fatigue lifetime when compared to other Mg alloys.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Assessment of BQ-9000 Biodiesel Properties for 2020 (CRADA CRD-15-593)

Biodiesel producers in the United States and Canada can voluntarily participate in the industry's BQ-9000 quality assurance program. This is the fourth in a series of reports documenting biodiesel quality from participating producers. Participants in the BQ-9000 program were requested to voluntarily provide data to a third-party team. This team anonymized and randomized the data prior to providing to the National Renewable Energy Laboratory (NREL) for analysis and reporting. The critical quality parameters analyzed are: sodium and potassium, calcium and magnesium, phosphorus, flash point and alcohol control, water and sediment, cloud point, acid number, free and total glycerin, monoglycerides, sulfur, oxidation stability, and cold soak filterability test (CSFT). The statistical analysis for these parameters is presented in Table ES-1.

09 BIOMASS FUELS↗