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At least 19 records

Comparing the magnetic resonant coupling radiofrequency stimulation to the traditional approaches: Ex-vivo tissue voltage measurement and electromagnetic simulation analysis

Recently, the design concept of magnetic resonant coupling has been adapted to electromagnetic therapy applications such as non-invasive radiofrequency (RF) stimulation. This technique can significantly increase the electric field radiated from the magnetic coil at the stimulation target, and hence enhancing the current flowing through the nerve, thus enabling stimulation. In this paper, the developed magnetic resonant coupling (MRC) stimulation, magnetic stimulation (MS) and transcutaneous electrical nerve stimulation (TENS) are compared. The differences between the MRC RF stimulation and other techniques are presented in terms of the operating mechanism, ex-vivo tissue voltage measurement and electromagnetic simulation analysis. The ev-vivo tissue voltage measurement experiment is performed on the compared devices based on measuring the voltage induced by electromagnetic induction at the tissue. The focusing effect, E field and voltage induced across the tissue, and the attenuation due to the increase of separation between the coil and the target are analyzed. The electromagnetic stimulation will also be performed to obtain the electric field and magnetic field distribution around the biological medium. The electric field intensity is proportional to the induced current and the magnetic field is corresponding to the electromagnetic induction across the biological medium. The comparison between the MRC RF stimulator and the MS and TENS devices revealed that the MRC RF stimulator has several advantages over the others for the applications of inducing current in the biological medium for stimulation purposes.

60 APPLIED LIFE SCIENCES↗

Optical Bound States in the Continuum Enabled by Magnetic Resonances Coupled to a Mirror

Dielectric metasurfaces made of high refractive index and low optical loss materials have emerged as promising platforms to achieve high-quality factor modes enabling strong light–matter interaction. Bound states in the continuum have shown potential to demonstrate narrow spectral resonances but often require asymmetric geometry and typically feature strong polarization dependence, complicating fabrication and limiting practical applications. Here, we introduce a novel approach for designing high-quality bound states in the continuum using magnetic dipole resonances coupled to a mirror. The resulting metasurface has simple geometric parameters requiring no broken symmetry. To demonstrate the unique features of our photonic platform we show a record-breaking third harmonic generation efficiency from the metasurface benefiting from the strongly enhanced electric field at high-quality resonances. Our approach mitigates the shortcomings of previous platforms with simple geometry enabling facile and large-area fabrication of metasurfaces paving the way for applications in optical sensing, detection, quantum photonics, and nonlinear devices.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

General expressions and physical origin of the coupling coefficient of arbitrary tuned coupled electromagnetic resonators

The theory and operation of various devices and systems, such as wireless power transfer via magnetic resonant coupling, magneto-inductive wave devices, magnetic resonance spectroscopy probes, and metamaterials can rely on coupled tuned resonators. The coupling strength is usually expressed in terms of the coupling coefficient κ, which can have electrical κ{sub E} and/or magnetic κ{sub M} components. In the current article, general expressions of κ are derived. The relation between the complex Poynting equation in its microscopic form and κ is made and discussed in detail. It is shown that κ can be expressed in terms of the interaction energy between the resonators' modes. It thus provides a general form that combines the magnetic and electric components of κ. The expressions make it possible to estimate the frequencies and fields of the coupled modes for arbitrarily oriented and spaced resonators. Thus, enabling the calculation of system specific parameters such as the transfer efficiency of wireless power transfer systems, resonator efficiency for electron spin resonance probes, and dispersion relations of magneto-inductive and stereo-metamaterials structures.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Methods and systems for J-coupled nuclear magnetic resonance

A nuclear magnetic resonance (NMR) system is configured to detect combinatorial signatures stemming from homonuclear and heteronuclear J-couplings. The system comprises a pre-polarization system, a detector, and NMR electronics, wherein the detector includes an NMR magnet with a magnetic field of strength between 300 mT and 10 μT.

Williams, Robert F.↗

Applicability of Wireless Power Transfer for Monitoring Technology of Radioactive Waste Geological Disposal - 16156

To assure the engineered barrier of a high-level radioactive waste repository functions correctly, long-term monitoring inside the backfilled deposition holes and tunnels is planned. Cables are used to power monitoring equipment and send signals however complete isolation will not be possible. Previously developed monitoring systems send information wirelessly and used batteries. Due to the limited battery life, these systems cannot be used for long-term monitoring. In this paper a wireless power transfer method based on magnetic resonant coupling is presented. The necessary transmitter and receiver coils have been developed. The performance of the individual coils has been tested. The performance of the system of transmitter and receiver with both air and bentonite as medium was tested. The results showed that the system with bentonite performed similarly well as the system with air. Wireless power transfer based on magnetic resonant coupling is therefore a feasible method for high-level radioactive waste repository monitoring applications which could in principle work for a period of 100 year or longer. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Wireless Power Transfer

Wireless Power Transfer is an innovative approach using magnetic resonance coupling of air core transformers designed for today's growing plug-in electric vehicle market. This technology can provide a convenient, safe and flexible means to charge electric vehicles under stationary and dynamic conditions. Plug-in Electric Vehicles (PEV) are burdened by the need for cable and plug charger, galvanic isolation of the on-board electronics, bulk and cost of this charger and the large energy storage system (ESS) packs needed. With a system where you have to physically plug in there are a number of occasions where the owner could very well forget to charge the vehicle. For stationary applications (like charging of a PHEV at home), ORNL's innovative wireless power transfer technology adds a convenience factor compared to actually plugging in which will mean that the vehicle will have a full charge every morning. Electric vehicle charging must be safe, compact and efficient in order to be convenient for customers. By reconfiguring the transformer and altering the resonance frequency, energy is transferred to the battery with lower energy losses and with fewer demands on the primary circuit by the rest of the transformer system. The ORNL discovery shows that sufficient power for the battery can be transferred from the primary to secondary circuits without significant energy losses if the operating frequency is set at 50% to 95% of the resonance frequency of the circuit. The electrical power is then transmitted to the chargeable battery, which is electrically coupled to the secondary circuit through the air core transformer. Some advantages include: Reduced energy losses during transfer of energy to the battery; A charge potential that is relatively unaffected by up to 25% misalignment of vehicle; and Other receiving components draw less power from the primary circuit. These advantages allow wireless power technology applications to expand at the workplace and beyond as the demand for EV rises. For vehicles that operate over a fixed route such as busses and shuttle vehicles, Wireless Power Transfer (WPT) means that a smaller battery pack can be used. In the traditional system, the battery pack is designed to accommodate the needs of the entire route or shift. With WPT the battery can be downsized because it can be charged when the vehicle stops on its route (a rental car shuttle bus, for example, can charge when it waits in the terminal and again when it waits at the rental car place. Thus the battery only needs enough charge to get to the next stop. This decrease in battery size means significant cost savings to electrify the vehicle. This technology enables efficient "opportunity charging stations" for predefined routes and planned stops reducing down time. Charging can occur in minutes. This improvement also eliminates the harmful emissions that occur in garages while buses are at idle during charging. In larger cities, dynamic charging offers an even greater impact utilizing existing infrastructure. As vehicles travel along busy freeways and interstate systems, wireless charging can occur while the vehicle is in motion. With this technology a vehicle essentially has unlimited electric range while using a relatively small battery pack. In-motion charging stations use vehicle sensors to alert the driver. Traveling at normal speeds, sensors establish in-motion charging. WPT transmit pads sequentially energize to the negotiated power level based on vehicle speed and its requested charging energy. Lower power when vehicle speed is slow and much higher power for faster moving vehicles. Vehicle to Infrastructure communications (V2I) coordinates WPT charging level according to on-board battery pack state-of-charge. V2I activates the roadway transmit pads placing them in standby mode and negotiates charging fee based on prevailing grid rate and vehicle energy demand. Dynamic charging would allow electricity to supply a very large fraction of the energy for the transportation sector and reduce greatly petroleum consumption. Previously worrisome traffic delays now provide longer periods of charge while passing over in-motion chargers. Inclement weather such as rain and snow do not affect the charging capability. At ORNL, we are working to develop the robust nature of wireless power technology to provide a convenient, safe and flexible means to charge electric vehicles under stationary and dynamic conditions.

33 ADVANCED PROPULSION SYSTEMS↗

Electromagnetically induced transparency with large delay-bandwidth product induced by magnetic resonance near field coupling to electric resonance

In this paper, we numerically and experimentally demonstrate electromagnetically induced transparency (EIT)-like spectral response with magnetic resonance near field coupling to electric resonance. Six split-ring resonators and a cut wire are chosen as the bright and dark resonator, respectively. An EIT-like transmission peak located between two dips can be observed with incident magnetic field excitation. A large delay bandwidth product (0.39) is obtained, which has potential application in quantum optics and communications. The experimental results are in good agreement with simulated results.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Primary-Side Power Flow Control of Wireless Power Transfer for Electric Vehicle Charging

Various noncontacting methods of plug-in electric vehicle charging are either under development or now deployed as aftermarket options in the light-duty automotive market. Wireless power transfer (WPT) is now the accepted term for wireless charging and is used synonymously for inductive power transfer and magnetic resonance coupling. WPT technology is in its infancy; standardization is lacking, especially on interoperability, center frequency selection, magnetic fringe field suppression, and the methods employed for power flow regulation. This paper proposes a new analysis concept for power flow in WPT in which the primary provides frequency selection and the tuned secondary, with its resemblance to a power transmission network having a reactive power voltage control, is analyzed as a transmission network. Analysis is supported with experimental data taken from Oak Ridge National Laboratory s WPT apparatus. Lastly, this paper also provides an experimental evidence for frequency selection, fringe field assessment, and the need for low-latency communications in the feedback path.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Relativistic nuclear magnetic resonance J-coupling with ultrasoft pseudopotentials and the zeroth-order regular approximation

We present a method for the first-principles calculation of nuclear magnetic resonance (NMR) J-coupling in extended systems using state-of-the-art ultrasoft pseudopotentials and including scalar-relativistic effects. The use of ultrasoft pseudopotentials is allowed by extending the projector augmented wave (PAW) method of Joyce et al. [J. Chem. Phys. 127, 204107 (2007)]. We benchmark it against existing local-orbital quantum chemical calculations and experiments for small molecules containing light elements, with good agreement. Scalar-relativistic effects are included at the zeroth-order regular approximation level of theory and benchmarked against existing local-orbital quantum chemical calculations and experiments for a number of small molecules containing the heavy row six elements W, Pt, Hg, Tl, and Pb, with good agreement. Finally, {sup 1}J(P-Ag) and {sup 2}J(P-Ag-P) couplings are calculated in some larger molecular crystals and compared against solid-state NMR experiments. Some remarks are also made as to improving the numerical stability of dipole perturbations using PAW.

97 MATHEMATICS AND COMPUTING↗

Quantum transport in coupled resonators enclosed synthetic magnetic flux

Quantum transport properties are instrumental to understanding quantum coherent transport processes. Potential applications of quantum transport are widespread, in areas ranging from quantum information science to quantum engineering, and not restricted to quantum state transfer, control and manipulation. Here, we study light transport in a ring array of coupled resonators enclosed synthetic magnetic flux. The ring configuration, with an arbitrary number of resonators embedded, forms a two-arm Aharonov–Bohm interferometer. The influence of magnetic flux on light transport is investigated. Tuning the magnetic flux can lead to resonant transmission, while half-integer magnetic flux quantum leads to completely destructive interference and transmission zeros in an interferometer with two equal arms. -- Highlights: •The light transport is investigated through ring array of coupled resonators enclosed synthetic magnetic field. •Aharonov–Bohm ring interferometer of arbitrary configuration is investigated. •The half-integer magnetic flux quantum leads to destructive interference and transmission zeros for two-arm at equal length. •Complete transmission is available via tuning synthetic magnetic flux.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Bi-directional magnetic resonance based wireless power transfer for electronic devices

In order to power or charge electronic devices wirelessly, a bi-directional wireless power transfer method has been proposed and experimentally investigated. In the proposed design, two receiving coils are used on both sides of a transmitting coil along its central axis to receive the power wirelessly from the generated magnetic fields through strongly coupled magnetic resonance. It has been observed experimentally that the maximum power transfer occurs at the operating resonant frequency for optimum electric load connected across the receiving coils on both side. The optimum wireless power transfer efficiency is 88% for the bi-directional power transfer technique compared 84% in the one side receiver system. By adopting the developed bi-directional power transfer method, two electronic devices can be powered up or charged simultaneously instead of a single device through usual one side receiver system without affecting the optimum power transfer efficiency.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Carbon Defect Characterization of Nitrogen-Doped Reduced Graphene Oxide Electrocatalysts for the Two-Electron Oxygen Reduction Reaction

Numerous modified-carbon catalysts have been developed for the direct synthesis of hydrogen peroxide through electrochemical oxygen reduction. Yet, given the complex structure of most porous carbons and the poor oxygen reduction reaction (ORR) selectivity typically observed when they are used as catalysts, it is still unclear which carbon defects are responsible for the high two-electron ORR activity typically observed in these materials. Here, we study electrocatalytic peroxide formation activity of nitrogen-doped reduced graphene oxide ( N -rGO) materials to relate carbon defects to electrocatalytic activity. To achieve this, we selected two N -rGO electrodes that selectively produce peroxide at all potentials studied (0.70–0.10 V vs RHE) under alkaline conditions. Oxygen reduction studies, combined with material characterization, especially solid-state 13 carbon nuclear magnetic resonance coupled with magic angle spinning and cross-polarization, demonstrate that epoxy or ether groups in the N -rGO catalyst are likely associated with the active sites that form peroxide at the lowest overpotential in alkaline media.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Three-dimensional infrared metamaterial with asymmetric transmission

A novel three-dimensional (3D) metallic metamaterial structure with asymmetric transmission for linear polarization is demonstrated in the infrared spectral region. The structure was fabricated by direct laser writing and selective electroless silver coating, a straightforward, novel technique producing mechanically and chemically stable 3D photonic structures. The structure unit cell is composed of a pair of conductively coupled magnetic resonators, and the asymmetric transmission response results from interplay of electric and magnetic responses; this equips the structure with almost total opaqueness along one propagation direction versus satisfying transparency along the opposite one. It also offers easily adjustable impedance, 90° one-way pure optical activity and backward propagation possibility, resulting thus in unique capabilities in polarization control and isolation applications. We show also that scaling down the structure can make it capable of exhibiting its asymmetric transmission and its polarization capabilities in the optical region.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Spin-orbit quantum impurity in a topological magnet

Quantum states induced by single-atomic impurities are at the frontier of physics and material science. While such states have been reported in high-temperature superconductors and dilute magnetic semiconductors, they are unexplored in topological magnets which can feature spin-orbit tunability. Here we use spin-polarized scanning tunneling microscopy/spectroscopy (STM/S) to study the engineered quantum impurity in a topological magnet Co 3 Sn 2 S 2 . We find that each substituted In impurity introduces a striking localized bound state. Our systematic magnetization-polarized probe reveals that this bound state is spin-down polarized, in lock with a negative orbital magnetization. Moreover, the magnetic bound states of neighboring impurities interact to form quantized orbitals, exhibiting an intriguing spin-orbit splitting, analogous to the splitting of the topological fermion line. Our work collectively demonstrates the strong spin-orbit effect of the single-atomic impurity at the quantum level, suggesting that a nonmagnetic impurity can introduce spin-orbit coupled magnetic resonance in topological magnets.

36 MATERIALS SCIENCE↗

Noise performance of magneto-inductive cables

Magneto-inductive (MI) waveguides are metamaterial structures based on periodic arrangements of inductively coupled resonant magnetic elements. They are of interest for power transfer, communications and sensing, and can be realised in a flexible cable format. Signal-to-noise ratio is extremely important in applications involving signals. Here, we present the first experimental measurements of the noise performance of metamaterial cables. We focus on an application involving radiofrequency signal transmission in internal magnetic resonance imaging (MRI), where the subdivision of the metamaterial cable provides intrinsic patient safety. We consider MI cables suitable for use at 300 MHz during {sup 1}H MRI at 7 T, and find noise figures of 2.3–2.8 dB/m, together with losses of 3.0–3.9 dB/m, in good agreement with model calculations. These values are high compared to conventional cables, but become acceptable when (as here) the environment precludes the use of continuous conductors. To understand this behaviour, we present arguments for the fundamental performance limitations of these cables.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Frequency stabilization of spin-torque-driven oscillations by coupling with a magnetic nonlinear resonator

The fundamental function of any oscillator is to produce a waveform with a stable frequency. Here, we show a method of frequency stabilization for spin-torque nano-oscillators (STNOs) that relies on coupling with an adjacent nanomagnet through the magnetic dipole–dipole interaction. It is numerically demonstrated that highly stable oscillations occur as a result of mutual feedback between an STNO and a nanomagnet. The nanomagnet acts as a nonlinear resonator for the STNO. This method is based on the nonlinear behavior of the resonator and can be considered as a magnetic analogue of an optimization scheme in nanoelectromechanical systems. The oscillation frequency is most stabilized when the nanomagnet is driven at a special feedback point at which the feedback noise between the STNO and resonator is completely eliminated.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Single-Step Conversion of Ethanol to n-Butene over Ag-ZrO2/SiO2 Catalysts

Ethanol is a promising platform molecule for production of a variety of fuels and chemicals. Of particular interest is producing middle distillate fuels (i.e., jet and diesel blendstock) from renewable ethanol feedstock. State-of-the-art alcohol-to-jet technology requires multiple process steps based on catalytic dehydration of ethanol to form ethylene, followed by sometimes a multi-step oligomerization, and then hydrotreatment and distillation. Here we report on a new catalytic route in which ethanol is directly converted to n-butene (1- and 2-butene mixtures) over Ag-ZrO2/SBA-16, thus offering the potential for a reduction in the number of required processing steps versus conventional alcohol-to-jet technology. This catalyst system provides the balanced metal and Lewis acid sites required to selectively facilitate a cascading sequence of reactions that includes dehydrogenation, aldol condensation, Meerwein–Ponndorf–Verley reduction, dehydration, and hydrogenation. High conversion and selectivity toward either n-butene or 1,3-butadiene is achieved by tuning the hydrogen feed partial pressure and other process/catalyst parameters. With sufficient hydrogen partial pressure 1,3-butadiene is completely and selectively hydrogenated to form n-butene. The reaction mechanism was elucidated through operando-nuclear magnetic resonance investigations coupled with reactivity measurements. Combined experimental-computational investigation reveals how changes in silver and zirconium composition and the silver oxidation state affects reactivity under controlled hydrogen partial pressures and after prolonged run times. Finally, catalyst effectiveness also was demonstrated when using wet ethanol feed, thus highlighting process flexibility in terms of feedstock purity requirements. This work was financially supported by the U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Bioenergy Technologies Office, and was performed at the Pacific Northwest National Laboratory (PNNL) under Contract No. DE-AC05-76RL01830 and the National Renewable Energy Laboratory under Contract No. DE-AC36- 08GO28308. Part of the work conducted by S. A. Akhade was performed under the auspices of the U.S. DOE at Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344. This work was partly supported through the PNNL-WSU Distinguished Graduate Research Program for ADW. NMR and XPS experiments were performed using EMSL (grid.436923.9), a DOE Office of Science User Facility sponsored by the Office of Biological and Environmental Research

Dagle, Vanessa↗

Ferromagnetic resonance of exchange-coupled perpendicularly magnetized bilayers

Strong ferromagnetic interlayer exchange couplings J in perpendicularly magnetized systems are becoming increasingly desirable for applications. We study whether ferromagnetic interlayer exchange couplings can be measured by a combination of broadband ferromagnetic resonance methods and magnetometry hysteresis loops. For this, we model the switching and the eigenexcitations in bilayer systems comprising a soft layer coupled to a thicker harder layer that possesses higher perpendicular magnetic anisotropy. For large J > 0, the switching fields are essentially independent of J but the frequency of the optical eigenmode of the bilayer and the linewidth of the acoustical and optical eigenmode are directly sensitive to the coupling. We derive a corpus of compact analytical expressions to analyze these frequencies, their linewidth and discuss the meaning thereof. We illustrate this corpus on a system mimicking the fixed layers of a magnetic tunnel junction meant for spin torque applications.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗