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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1955

Analysis of turbulent heat transfer, mass transfer, and friction in smooth tubes at high Prandtl and Schmidt numbers

The expression for eddy diffusivity from a previous analysis was modified in order to account for the effect of kinematic viscosity on the turbulence in the region close to a wall. By using the modified expression, good agreement was obtained between predicted and experimental results for heat and mass transfer at Prandtl and Schmidt numbers between 0.5 and 3000. The effects of length-to-diameter ratio and of variable viscosity were also investigated for a wide range of Prandtl numbers.

Deissler, Robert G↗
NASA NTRS1999

Prediction of Heat and Mass Transfer in a Rotating Ribbed Coolant Passage With a 180 Degree Turn

Numerical results are presented for flow in a rotating internal passage with a 180 degree turn and ribbed walls. Reynolds numbers ranging from 5200 to 7900, and Rotation numbers of 0.0 and 0.24 were considered. The straight sections of the channel have a square cross section, with square ribs spaced one hydraulic diameter (D) apart on two opposite sides. The ribs have a height of 0.1D and are not staggered from one side to the other. The full three dimensional Reynolds Averaged Navier-Stokes equations are solved combined with the Wilcox k-omega turbulence model. By solving an additional equation for mass transfer, it is possible to isolate the effect of buoyancy in the presence of rotation. That is, heat transfer induced buoyancy effects can be eliminated as in naphthalene sublimation experiments. Heat transfer, mass transfer and flow field results are presented with favorable agreement with available experimental data. It is shown that numerically predicting the reattachment between ribs is essential to achieving an accurate prediction of heat/mass transfer. For the low Reynolds numbers considered, the standard turbulence model did not produce reattachment between ribs. By modifying the wall boundary condition on omega, the turbulent specific dissipation rate, much better agreement with the flow structure and heat/ mass transfer was achieved. It is beyond the scope of the present work to make a general recommendation on the omega wall boundary condition. However, the present results suggest that the omega boundary condition should take into account the proximity to abrupt changes in geometry.

Rigby, David L.↗
NASA NTRS1990

Interfacial mass transfer to a cylinder endwall during spin-up/spin-down

The local rate of mass transfer to the bottom endwall of a large aspect ratio cylinder was measured during spin-up/spin-down. The local mass transfer rate was a strong function radial position along the endwall. At the center during spin-up from rest, the maximum enhancement in mass transfer occurred after the Ekman time scale and before the viscous time scale. At the center during spin-down to rest, a stagnation vortex formed, causing the mass transfer rate to decay and then increase back to the original value of the order of the viscous time scale. Away from the center a much more complicated pattern was observed, but spin-up and spin-down were similar. Two peaks in mass transfer rate occurred for an Ekman number over 0.0074. Alternating spin-up and spin-down with a short period caused the center of the endwall to experience a nearly sinusoidal variation in mass transfer with the frequency equal to the forcing frequency. Near the edge the frequency was twice the forcing frequency.

Larrousse, Mark F.↗
NASA NTRS1982

Spanwise mass transfer variations on a cylinder in 'nominally' uniform crossflow

Mass transfer experiments on a circular cylinder in a 'nominally' uniform crossflow are described. Experiments were conducted at the tunnel's turbulence level and with a woven-wire turbulence screen. In both cases spanwise and circumferential mass transfer measurements were made. Without the turbulence screen, the results were found to be spanwise independent and agreed quite well with both theory and the result of others. In addition to the mass transfer measurements, spanwise traverse measurements of the mean velocity and turbulence quantities in the incident flow were made and showed that the screen produced a small-amplitude spanwise periodic perturbation in the incident flow. Although this perturbation was only one quarter of a percent in the mean velocity and buried in the stream's turbulence, disproportionately large spanwise variations of 15 percent were found in the mass transfer rate.

Mayle, R. E.↗
NASA NTRS1987

Dynamical mass transfer in cataclysmic binaries

When a binary comes into contact and mass transfer begins, orbital angular momentum is stored in the accretion disk until the disk couples tidally to the binary system. Taam and McDermott (1987) have suggested that this leads to unstable dynamical mass transfer in many cataclysmic variables in which mass transfer would otherwise be stable, and that it explains the gap between 2 and 3 h in the orbital period distribution of these systems. Here the consequences of this hypothesis for the evolution of cataclysmic binaries are explored. It is found that systems coming into contact longward of the period gap undergo one or more episodes of dynamical mass transfer.

Melia, Fulvio↗
NASA NTRS1988

Transient natural convection heat and mass transfer in crystal growth

A numerical analysis of transient combined heat and mass transfer across a rectangular cavity is performed by a numerical method based on the SIMPLE algorithm. The physical parameters are selected to represent a range of possible crystal growth in solutions. Numerical results are compared with available experimental data to confirm the accuracy of the results. Good qualitative agreements are obtained for the average mass transfer rate across the cavity. Also, qualitative agreements are observed for the global development of thermal and solute fields. It is found that the thermal and solute fields become highly oscillatory when the thermal and solute Grashof numbers are large. Oscillations are probably caused by a number of different instability mechanisms. By reducing the gravity some of these instabilities were made to disappear at the lower Grashof numbers. Transient temperature and solute distribution near the crystal growing surface are highly non-uniform at the higher Grashof numbers. These non-uniformities are less severe in the reduced gravity environments but still exist. The effects of convection on the rate of average mass transfer are more than one order of magnitude higher than those of conduction in the range of Grashof numbers studied. Dependency of mass transfer rate on the Grashof number indicates that the convection effects many not be negligible even in the microgravity environments for the range of parameters investigated.

Han, Samuel S.↗
NASA NTRS1986

Thermophoretically augmented mass transfer rates to solid walls across laminar boundary layers

Predictions of mass transfer (heavy vapor and small particle deposition) rates to solid walls, including the effects of thermal (Soret) diffusion ('thermophoresis' for small particles), are made by numerically solving the two-dimensional self-similar forced convection laminar boundary-layer equations with variable properties, covering the particle size range from vapor molecules up to the size threshold for inertial (dynamical nonequilibrium) effects. The effect of thermophoresis is predicted to be particularly important for submicron particle deposition on highly cooled solid surfaces, with corresponding enhancement factors at atmospheric conditions being over a thousand-fold at T(w)/T(e) equal to about 0.6. As a consequence of this mass transfer mechanism, the particle size dependence of the mass transfer coefficient to a cooled wall will be much weaker than for the corresponding case of isothermal capture by Brownian-convective diffusion.

Gokoglu, S. A.↗
NASA NTRS1987

Numerical calculations of mass transfer flow in semi-detached binary systems

The details of the mass transfer flow near the inner Lagrangian point in a semidetached binary system are numerically calculated. A polytropic equation of state with n = 3/2 is used. The dependence of the mass transfer rate on the degree to which the star overfills its Roche lobe is calculated, and good agreement with previous analytic estimates is found. The variation of mass transfer rate which occurs if the binary system has a small eccentricity is calculated and is used to cast doubt on the model for superhumps in dwarf novae proposed by Papaloizou and Pringle (1979).

Edwards, D. A.↗
NASA NTRS1986

Turbulent heat and mass transfers across a thermally stratified air-water interface

Rates of heat and mass transfer across an air-water interface were measured in a wind-wave research facility, under various wind and thermal stability conditions (unless otherwise noted, mass refers to water vapor). Heat fluxes were obtained from both the eddy correlation and the profile method, under unstable, neutral, and stable conditions. Mass fluxes were obtained only under unstable stratification from the profile and global method. Under unstable conditions the turbulent Prandtl and Schmidt numbers remain fairly constant and equal to 0.74, whereas the rate of mass transfer varies linearly with bulk Richardson number. Under stable conditions the turbulent Prandtl number rises steadily to a value of 1.4 for a bulk Richardson number of about 0.016. Results of heat and mass transfer, expressed in the form of bulk aerodynamic coefficients with friction velocity as a parameter, are also compared with field data.

Papadimitrakis, Y. A.↗
NASA NTRS1986

Prediction and rational correlation of thermophoretically reduced particle mass transfer to hot surfaces across laminar or turbulent forced-convection gas boundary layers

A formulation previously developed to predict and correlate the thermophoretically-augmented submicron particle mass transfer rate to cold surfaces is found to account for the thermophoretically reduced particle mass transfer rate to overheated surfaces such that thermophoresis brings about a 10-decade reduction below the convective mass transfer rate expected by pure Brownian diffusion and convection alone. Thermophoretic blowing is shown to produce effects on particle concentration boundary-layer (BL) structure and wall mass transfer rates similar to those produced by real blowing through a porous wall. The applicability of the correlations to developing BL-situations is demonstrated by a numerical example relevant to wet-steam technology.

Gokoglu, Suleyman A.↗
DOE OSTI2024

Revealing the role of redox reaction selectivity and mass transfer in current–voltage predictions for ensembles of photocatalysts

Photocatalysts are conceptually simple reaction units where nanoscale semiconductors integrated with catalysts drive a pair of redox reactions on illumination. However, the proximity of reaction sites performing cathodic and anodic reactions poses dire challenges to realize large light-to-fuel conversion efficiencies. In this study, a powerful, yet straightforward, equivalent-circuit detail-balance modeling framework is developed and applied to evaluate the performance of photocatalytic systems featuring multiple light absorbers. Specifically, low bandgap iridium-doped strontium titanate is modeled as a Z-scheme photocatalyst to achieve desirable hydrogen evolution and iron-based redox shuttle oxidation reactions. Our model has unique capabilities to simulate competing redox reactions and address mass-transfer limitations. In a significant departure from state-of-the-art circuit models, our study develops tools to perform load-line analyses by incorporating a net electrochemical load curve that includes both desired and competing redox reactions. Consequently, reaction selectivity is predicted from equivalent circuit models for photocatalytic and photoelectrochemical systems. Our investigation into ensembles comprised of multiple, semi-transparent light absorbers reveals their potential to outperform a single, optically thick light absorber, particularly when operated under mass-transfer-limited conditions. However, this outcome hinges on minimizing mass-transfer rates of select redox species to prevent undesired reactions of hydrogen oxidation and/or redox shuttle reduction. Our findings demonstrate that reaction selectivity can be achieved by tuning asymmetry in redox species mass-transfer even with perfectly symmetric electrocatalytic charge-transfer coefficients. The influences of various kinetic, mass-transfer, and thermodynamic parameters are explored to offer crucial insights for synthesis of the next-generation of photocatalysts and selective coatings, and reactor designs.

25 ENERGY STORAGE↗