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At least 19 records

Mercury - Internal structure and thermal evolution

Mercury's thermal evolution and internal structure are modeled based on the planet's gross physical properties (which imply a high metallic iron content) and predictions for its chemistry made from the Lewis-Cameron model of condensation of the primitive solar nebula (which implies that Mercury may be composed only of those materials that condensed at temperatures near that of metallic iron condensation in the cooling nebula). Various heat sources, initial temperatures, and thermal conductivities are considered for a homogeneous model and a differentiated two-layer model. Density distributions are calculated from the mean density and estimates of the present-day temperature. The moment of inertia and the hydrostatic value of the second degree harmonic coefficient of Mercury's gravity field are found for the differentiated and undifferentiated models. These results should be useful for preliminary interpretation of the Mariner 10 measurements of Mercury's gravitational field.

Siegfried, R. W., II↗

Using Remotely Sensed Observations of Ancient Mare Deposits on the Moon as Possible Analogs to the Intercrater Plains on Mercury

Two commonly held models for the formation of the mercurian intercrater plains are: a global volcanic resurfacing event or basin-ejecta material. Although Mariner 10 images have provided morphologic and limited compositional information of the intercrater plains, the origin of these materials remains ambiguous. We examine whether Mariner 10 image at 355 (UV (ultraviolet)) and 575 nm (orange) can be used to distinguish between these models. Here we use Clementine image data (415 and 750 nm) for ancient lunar mare deposits to evaluate this suggestion. The inventorying of 'hidden' volcanic deposits is important to mercurian studies because they provide evidence of ancient volcanism, which yields clues to the thermal evolution of the planet. The greater abundance of intercrater plains on Mercury, relative to the intercrater plains observed within the lunar highlands, suggests that the resurfacing was comparably more intense. Mercury may represent an intermediate member of planet resurfacing; with the extremes being the Moon (approximately 17% resurfacing) and Venus (global resurfacing). Additional information is contained in the original extended abstract.

Gillis, J. J.↗

Constraints on the Origin of Mercury’s Large Core from Core-Mantle Differentiation Models

Mercury’s core is notoriously large when compared to other planets of our solar system. The origin of this large core is still uncertain. Available data on the surface composition and internal structure of Mercury from the past MESSENGER mission and future data collected by BepiColombo will continue to provide clues to Mercury’s formation. Here, we present results combining experimental data on elemental distribution between core and mantle with spacecraft data, to estimate bulk Mercury composition. We applied this strategy to major elements (Fe, Si, Mg, Al and O), as well as minor elements (Cr and Ti), and compared derived compositions to chondritic data and the chemical compositions of the other terrestrial planets. Our results show that Mercury has a chemical composition significantly different from all known materials of the solar system. In addition, numerous scenarios were proposed to explain Mercury’s structure, including “chaotic models” such as giant impacts and “orderly models” such as aerodynamic sorting. Here, we tested whether Mercury’s composition can be explained by mantle stripping by impacts. We will show how such a scenario reconciles several features of Mercury’s geochemistry with chondritic data. We will also discuss the outlook of additional constraints from supplementary data potentially collected by BepiColombo.

Mercury↗

Potassium permanganate for mercury vapor environmental control

Potassium permanganate (KMnO4) was evaluated for application in removing mercury vapor from exhaust air systems. The KMnO4 may be used in water solution with a liquid spray scrubber system or as a solid adsorber bed material when impregnated onto a zeolite. Air samples contaminated with as much as 112 mg/cu m of mercury were scrubbed to 0.06mg/cum with the KMnO4-impregnated zeolite (molecular sieve material). The water spray solution of permanganate was also found to be as effective as the impregnated zeolite. The KMnO4-impregnated zeolite was applied as a solid adsorber material to (1) a hardware decontamination system, (2) a model incinerator, and (3) a high vacuum chamber for ion engine testing with mercury as the propellant. A liquid scrubber system was also applied in an incinerator system. Based on the results of these experiments, it is concluded that the use of KMnO4 can be an effective method for controlling noxious mercury vapor.

Kuivinen, D. E.↗

Oxygen Depletion on the Surface of Mercury: Evidence of Silicon Smelting?

The MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft collected data that provided important insights into the structure, chemical makeup, and compositional diversity of Mercury. The X-Ray Spectrometer (XRS) and Gamma-Ray Spectrometer (GRS) onboard MESSENGER provided the first detailed chemical analyses of Mercury's surface. Among the many discoveries included several surprising characteristics about the surface of Mercury, including elevated S abundances (up to 4 percent by weight), low Fe abundances (less than 4 percent by weight), and relatively low O abundances (O/Si ratio of 1.40 plus or minus 0.03). The surface chemistry as determined by MESSENGER has been used to identify up to nine distinct geochemical terranes on Mercury. Numerous modeling and experimental efforts have been undertaken to infer the mineralogy and petrology of mercurian lavas and surface materials. However, all of these efforts have presumed valence states for each of the elements according to the following: Si4+, Ti4+, Al3+, Cr2+, Fe2+, Mn2+, Mg2+, Ca2+, Na+, K+, S2-, Cl-. Based on these valence assignments, cations are charged balanced with the anions O2-, S2-, and Cl- and the compositions are recast in terms of oxides, sulfides, and chlorides. Based on these assumptions, the geochemical terranes that have been identified on Mercury yield O/Si wt. ratios ranging from 1.61 to 1.84, which is substantially higher than the preliminary O/Si ratio of 1.40 plus or minus 0.03 determined by the MESSENGER GRS]. We have re-evaluated the O/Si ratio using the entire MESSENGER dataset to reassess its implications for the geochemistry of Mercury.

McCubbin, F. M.↗

Ion thruster plume effects on spacecraft surfaces

A charge-exchange plasma, generated by an ion thruster, is capable of flowing upstream from the ion thruster and therefore represents a source of contamination to a spacecraft. An analytical model of the charge-exchange plasma density around a spacecraft is used to estimate the contamination which various spacecraft materials may be exposed to. Measurements of plasma density around an ion thruster are compared to this model. Results of experimental studies regarding the effects on various spacecraft materials' properties due to exposure to expected mercury contamination levels are presented.

Carruth, M. R., Jr.↗

Ion thruster plume effects on spacecraft surfaces

A charge-exchange plasma, generated by an ion thruster, is capable of flowing upstream from the ion thruster and therefore represents a source of contamination to a spacecraft. An analytical model of the charge-exchange plasma density around a spacecraft was used to estimate the contamination which various spacecraft materials may be exposed to. Measurements of plasma density around an ion thruster were compared to this model. Results of experimental studied regarding the effects on various spacecraft materials' properties due to exposure to expected mercury contamination levels are presented.

Carruth, M. R., Jr.↗

A model for predicting the wearout lifetime of the LeRC/Hughes 30-cm mercury ion thruster

An investigation of parameters that affect the erosion rates of 30-cm-diameter mercury-ion-thruster components is described. A sputter-erosion model is formulated in terms of the design, operational, and material characteristics of the thruster. The erosion model is applied to the screen electrode, which is assumed to be the life-limiting component of the 30-cm thruster, resulting in a model of wearout lifetime. Results of short-term erosion-rate tests are presented that illustrate the dependence of component wear rates on variables such as discharge voltage, accelerator-grid open-area fraction, ion energy, electrode material, and the partial pressure of facility residual gases such as nitrogen. Test results are compared with wearout rates predicted by the sputter-erosion model.

Beattie, J. R.↗

Experimental Behavior of Sulfur Under Primitive Planetary Differentiation Processes, the Sulfide Formations in Enstatite Meteorites and Implications for Mercury.

Enstatite meteorites are the most reduced naturally-occuring materials of the solar system. The cubic monosulfide series with the general formula (Mg,Mn,Ca,Fe)S are common phases in these meteorite groups. The importance of such minerals, their formation, composition and textural relationships for understanding the genesis of enstatite chondrites (EC) and aubrites, has long been recognized (e.g. [1]). However, the mechanisms of formation of these sulfides is still not well constrained certainly because of possible multiple ways to produce them. We propose to simulate different models of formation in order to check their mineralogical, chemical and textural relevancies. The solubility of sulfur in silicate melts is of primary interest for planetary mantles, particularly for the Earth and Mercury. Indeed, these two planets could have formed, at least partly, from EC materials (e.g. [2, 3, 4]). The sulfur content in silicate melts depends on the melt composition but also on pressure (P), temperature (T) and oxygen fugacity fO2. Unfortunately, there is no model of general validity in a wide range of P-T-fO2-composition which describes precisely the evolution of sulfur content in silicate melts, even if the main trends are now known. The second goal of this study is to constrain the sulfur content in silicate melts under reducing conditions and different temperatures.

Malavergne, V.↗

Cathode effects on thrust subsystem performance predictability.

Development of a model of mercury vapor electron bombardment thrustor hollow cathode operation. The proposed model predicts that the primary electron emission mechanism is thermionic when sufficient low work function material is present, that the cathode is heated by power extracted from the plasma to a temperature sufficient to emit the current demanded by the external circuit; that for a given total arc current, attempts to reduce cathode temperature by changes in the external thermal coupling will affect only the amount of power extracted from the plasma; and that depletion of low work function material in the cathode results in higher cathode temperature.

Goldstein, R.↗

On the Effect of IMF Turning on Ion Dynamics at Mercury

We investigate the effect of a rotation of the Interplanetary Magnetic Field (IMF) on the transport of magnetospheric ion populations at Mercury. We focus on ions of planetary origin and investigate their large-scale circulation using three-dimensional single-particle simulations. We show that a nonzero Bx component of the IMF leads to a pronounced asymmetry in the overall circulation pattern . In particular, we demonstrate that the centrifugal acceleration due to curvature of the E x B drift paths is more pronounced in one hemisphere than the other, leading to filling of the magnetospheric lobes and plasma sheet with more or less energetic material depending upon the hemisphere of origin. Using a time-varying electric and magnetic field model, we investigate the response of ions to rapid (a few tens of seconds) re-orientation of the IMF. We show that, for ions with gyroperiods comparable to the field variation time scale, the inductive electric field should lead to significant nonadiabatic energization, up to several hundreds of eVs or a few keVs. It thus appears that IMP turning at Mercury should lead to localized loading of the magnetosphere with energetic material of planetary origin (e.g., Na+).

Delcourt, D. C.↗

Observations on Cavitation Damage in a Flowing System

Cavitation damage to specimens of stainless steel, carbon steel, aluminum, and plexiglas, placed in a cavitating venturi using water and mercury as test fluids is mostly in the form of irregularly shaped pits which do not change with additional exposure to the cavitating field within the limited durations utilized. The rate of damage is very high initially, decreases for a relatively short period of time, then increases again up to the maximum test durations of 150 hours with water and 270 hours with mercury. Observation of damage effects by several independent techniques, using a variety of specimen materials, with two different fluids under various fluid dynamic conditions, leads to a suggested correlating model in terms of the cavitation bubble density and energy and specimen material strength.

VENTURI TUBE↗

Process modelling for materials preparation experiments

The development is examined of mathematical tools and measurement of transport properties necessary for high fidelity modeling of crystal growth from the melt and solution, in particular for the Bridgman-Stockbarger growth of mercury cadmium telluride (MCT) and the solution growth of triglycine sulphate (TGS). The tasks include development of a spectral code for moving boundary problems, kinematic viscosity measurements on liquid MCT at temperatures close to the melting point, and diffusivity measurements on concentrated and supersaturated TGS solutions. A detailed description is given of the work performed for these tasks, together with a summary of the resulting publications and presentations.

Rosenberger, Franz↗

Properties of the solar nebula and the origin of the moon.

The basic geochemical model of the structure of the moon proposed by Anderson, in which the moon is formed by differentiation of the calcium, aluminium, and titanium-rich inclusions in the Allende meteorite, is accepted, and the conditions for formation of this moon within the solar nebula models of Cameron and Pine are discussed. The basic material condenses while iron remains in the gaseous phase, which places the formation of the moon slightly inside the orbit of Mercury. Some condensed metallic iron is likely to enter the moon in this position, and since the moon is assembled at a very high temperature, it is likely to have been fully molten, so that the iron can remove the iridium from the silicate material and carry it down to form a small core. Interactions between the moon and Mercury lead to the present rather eccentric Mercury orbit and to a much more eccentric orbit for the moon, reaching past the orbit of the earth, establishing conditions which are necessary for capture of the moon by the earth.

Cameron, A. G. W.↗

Design, fabrication and testing of porous tungsten vaporizers for mercury ion thrusters

The dispersions in the characteristics, performance and reliability of vaporizers for early model 30-cm thrusters were investigated. The purpose of the paper is to explore the findings and to discuss the approaches that were taken to reduce the observed dispersion and present the results of a program which validated those approaches. The information that is presented includes porous tungsten materials specifications, a discussion of assembly procedures, and a description of a test program which screens both material and fabrication processes. There are five appendices providing additional detail in the areas of vaporizer contamination, nitrogen flow testing, bubble testing, porosimeter testing, and mercury purity. Four neutralizers, seven cathodes and five main vaporizers were successfully fabricated, tested, and operated on thrusters. Performance data from those devices is presented and indicates extremely repeatable results from using the design and fabrication procedures.

Zavesky, R.↗

Theory of global thermoremanent magnetization of planetary lithospheres in dipole fields of internal origin

A model is presented for the global thermoremanent magnetization of spherical lithospheres which cool in the presence of central dipole fields. Reversals and intensity variations of the field are incorporated in this model, which is applicable to bodies whose interiors have remained above the Curie point throughout their evolution. The model demonstrates that even considering Runcorn's (1975) magnetostatics theorems for spherical shells, a nonzero magnetic permeability and a finite cooling rate in the lithosphere permit the acquisition of a sizable global remanent dipole moment, which would be detectable by external measurements after the magnetizing field has disappeared. Preliminary application of this model to Mercury, Venus, and Mars suggests that only the combination of a nonreversing ancient source field with a surface value near 1 Oe plus a sizable concentration (about 1% by volume) of ferromagnetic material in their crusts could produce remanent planetary dipole fields as large as those measured by spacecraft. On the other hand, if ancient reversing dynamos existed in these planets, it is unlikely that large planetary-scale fields like those observed at Mercury could be due to remanence in their crusts, irrespective of their composition.

Srnka, L. J.↗

Process modelling for materials preparation experiments

The main goals of the research consist of the development of mathematical tools and measurement of transport properties necessary for high fidelity modeling of crystal growth from the melt and solution, in particular for the Bridgman-Stockbarger growth of mercury cadmium telluride (MCT) and the solution growth of triglycine sulphate (TGS). Of the tasks described in detail in the original proposal, two remain to be worked on: development of a spectral code for moving boundary problems, and diffusivity measurements on concentrated and supersaturated TGS solutions. During this eighth half-year period, good progress was made on these tasks.

Rosenberger, Franz↗

Advanced electric propulsion and space plasma contactor research

A series of experiments performed on an 8 cm dia. ring cusp magnetic field ion thruster are described. The results show the effects of anode and cathode position and size, ring cusp axial location and discharge chamber length on plasma ion energy cost and extracted ion fraction. Thruster performance is shown to be improved substantially when optimum values of these parameters are used. Investigations into the basic plasma phenomena associated with the process of plasma contacting are described. The results show the process of electron collection from a background plasma to a hollow cathode plasma contactor exhibits a higher impedance than the process of electron emission from the hollow cathode. The importance of having cold ions present to facilitate the plasma contacting process is shown. Results of experiments into the behavior of hollow cathodes operating at high interelectrode pressures (up to approx. 100 Torr) on nitrogen and ammonia are presented. They suggest that diffuse emission from the insert of a hollow cathode can be sustained at high interelectrode pressures if the cathode is made of non-conducting material and the cathode internal pressure is reduced by evacuating the cathode interior. A theoretical model of discharge chamber operation developed for inert gas thrusters is extended so it can be used to evaluste the performance of mercury ion thrusters. Predictions of the model are compared to experimental results obtained on two 30 cm dia. thrusters.

Wilbur, P. J.↗