Materials Data on Mg3NF3 by Materials Project
Mg3NF3 crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Mg2+ is bonded to two equivalent N3- and four equivalent F1- atoms to form a mixture of edge and corner-sharing MgN2F4 octahedra. The corner-sharing octahedral tilt angles are 0°. Both Mg–N bond lengths are 2.13 Å. All Mg–F bond lengths are 2.13 Å. N3- is bonded to six equivalent Mg2+ atoms to form corner-sharing NMg6 octahedra. The corner-sharing octahedral tilt angles are 0°. F1- is bonded in a square co-planar geometry to four equivalent Mg2+ atoms.
36 MATERIALS SCIENCE↗