Microwave spectroscopy
Microwave spectroscopy - electric field effects in nuclear magnetic resonance of fluids, expansion of velocity surfaces in spherical harmonics, and electron cross relaxation in dilute ruby
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Microwave spectroscopy - electric field effects in nuclear magnetic resonance of fluids, expansion of velocity surfaces in spherical harmonics, and electron cross relaxation in dilute ruby
Microwave spectroscopy used to identify unambiguously contaminant trace gases in mixture and indicate amount of each
Microwave spectroscopy used to identify unambiguously contaminant trace gases in mixture and indicate amount of each
Radio frequency and microwave spectroscopy of magnetized plasmas
Two intense microwave spectra lines exist in the martian atmosphere that allow unique sounding capabilities: water vapor at 183 GHz and the (2-1) rotational line of CO at 230 GHz. Microwave spectra line sounding is a well-developed technique for the Earth's atmosphere for sounding from above from spacecraft and airplanes, and from below from fixed surface sites. Two simple instruments for temperature sounding on Mars (the CO line) and water vapor measurements are described. The surface sounder proposed for the MESUR sites is designed to study the boundary layer water vapor distribution and the temperature/pressure profiles with vertical resolution of 0.25 km up to 1 km with reduced resolution above approaching a scale height. The water channel will be sensitive to a few tenths of a micrometer of water and the temperature profile will be retrieved to an accuracy between 1 and 2 K. The latter is routinely done on the Earth using oxygen lines near 60 GHz. The measurements are done with a single-channel heterodyne receiver looking into a 10-cm mirror that is canned through a range of elevation angles plus a target load. The frequency of the receiver is sweep across the water and CO lines generating the two spectra at about 1-hr intervals throughout the mission. The mass and power for the proposed instrument are 2 kg and 5-8 W continuously. The measurements are completely immune to the atmospheric dust and ice particle loads. It was felt that these measurements are the ultimate ones to properly study the martian boundary layer from the surface to a few kilometers. Sounding from above requires an orbiting spacecraft with multichannel microwave spectrometers such as the instrument proposed for MO by a subset of the authors, a putative MESUR orbiter, and a proposed Discovery mission called MOES. Such an instrument can be built with less than 10 kg and use less than 15 W. The obvious advantage of this approach is that the entire atmosphere can be sounded for temperature and water vapor in a few hours with somewhat better than a scale height resolution. If a bigger mirror is used (greater than 30 cm) limb sounding geometry can be employed and half scale height resolution achieved to altitudes up to at least 60 km. Again, the measurements are immune to dust and ice loads. Water vapor sensitivity of 0.1 micrometer can be achieved (even with a nadir instrument) and temperature profiles retrieved to an accuracy of better than 2 K from the surface to about 60 km. Winds can be measured from the doppler shifts of CO lines in the limb sounding mode.
Qualitative analysis of gas mixtures by microwave spectroscopy
Dual resonant cavity absorption cell using double resonance microwave spectroscopy modulation technique
Water vapor mixing ratio in lower atmosphere of Venus, using microwave spectroscopy
Microwave and infrared measurements are reported for the van der Waals complex ArCH3CCH and its isotopomers. The structure is T-shaped with equilibrium center-of-mass separation of 3.73 A and an angle of 82 deg between the molecule symmetry axis and the van der Waals bond. The infrared and microwave spectra are complex due to the effects of a slightly hindered internal rotor. Analysis of the spectral data shows that the dipole moment is almost parallel to the dimer b axis. A modified vibration/rotation Hamiltonian that includes an internal rotor potential is used to show that the barrier to internal rotation is near 10.8/cm.
Description of an experimental dual resonant cavity absorption cell for observing microwave spectroscopic double-resonance effects. The device is composed of two Fabry-Perot interferometers excited by independent microwave sources and mounted at right angles in a suitable vacuum enclosure. The pumping transition is modulated by one source and the modulation induced on the rf absorption in the orthogonal cavity is detected.
Gyroresonance opacity renders the solar corona optically thick at frequencies which are low integral multiples of the local gyrofrequency. This causes the microwave spectrum of sunspots to be sensitive to the strength of coronal magnetic fields. The concept is illustrated by high spectral resolution observations of a sunspot acquired with the Owens Valley frequency-agile interferometer. The observed spectrum is compared to the results of three-dimensional atmospheric model calculations in which the sunspot field is represented by the potential field of a dipole located beneath the photosphere. The comparison enables the depth, orientation and magnetic moment of the dipole that best fits the observations to be determined. Since such observations require that the microwave emission be resolved spectrally, not spatially, the technique may be applicable to the study of stellar coronal fields.
The potential implications of observations which combine both high spatial and high spectral resolution are considered. In particular, interest is on the ability to measure the magnetic field at the base of the corona on a point by point basis, as in a true magnetograph. Model calculations are presented of the microwave brightness temperature spectrum along specific lines of sight near a sunspot.
In studies of solar active regions and bursts, the ability to obtain spatially resolved radio spectra (brightness temperature spectra) opens a whole new range of possibilities for study of the solar corona. For active regions, two-dimensional maps of brightness temperature over a wide range of frequencies allows one to determine temperature, column density, and magnetic field strength over the entire region in a straightforward, unambiguous way. For flares, the time-dependent electron energy distribution, number of accelerated electrons, and magnetic field strength and direction can be found. In practice, obtaining complete radio images at a large number of frequencies is a significant technical challenge, especially while keeping costs down. Our instrument at Owens Valley Radio Observatory provided the starting point for a modest attempt at meeting this goal. We proposed to build three additional, very low-cost 2-m antennas which, when combined with our existing two 27-m dishes, expands the array to 5 elements. This modest increase in number of solar dedicated antennas, from 2 to 5, increases our maximum number of physical baselines from 1 to 10 and allows the instrument to do true imaging of solar microwave sources, both bursts and active regions. Combined with the technique of frequency synthesis, the new array has up to 450 effective baselines, giving imaging capability that approaches that of a sub-arrayed VLA. The prototype antenna design was finalized and the antenna was put into operation in Nov. 1989.
Electronic contribution to 9 GHz ultrasonic attenuation studied in thin tin films at low temperatures
Brightness temperature spectra of Venus computed to determine amount of water vapor in lower atmosphere
Io's corona and extended atmosphere, i.e., the plasma torus and neutral Na and K clouds, were the subject of intensive ground-based studies. E. Lellouch et al. not only detected but also fully resolved the profiles of two pure rotational lines of SO2. The lines were found in emission showing that early theoretical predictions for a thermally inverted atmospheric structure were correct.
Latitudinal distributions of upper stratospheric ClO measured by MAS during the three ATLAS missions are presented for northern hemisphere (NH) spring equinox in 1992, southern hemisphere (SH) early fall in 1993, and NH fall in 1994. The MAS ClO results are shown along with correlative MLS observations. The results of both instruments consistently show the same latitudinal features. The ClO maximum in the NH spring occurs at mid latitudes, whereas the latitudinal ClO maximum in both the NH and SH fall occurs at high latitudes. The volume mixing ratio maxima were significantly higher in the fall (0.7-0.8 ppbv) than in spring (0.5-0.6 ppbv). Qualitatively, these results are consistent with calculations of several 2-D models.