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Results for “Mid-infrared spectroscopy”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Mid-infrared Spectroscopy of Planetary Nebulae

The application of infrared spectral lines observed in part of the broadened spectral range (18 to 36 microns) to planetary nebula studies is discussed. Infrared spectral lines in the mid-infrared supply information about planetary nebulae which both supplement and complement optical results. Their utility lies mainly in the insensitivity of the line intensities to temperature variations or uncertainties, in contrast to the behavior of optical emission. This in turn leads to more accurate ionic abundances than presently available from optical lines. Although densities from optical line ratios are not very sensitive to temperature, the lines are weighted toward regions of higher temperatures. A comparison with infrared densities from the same ions therefore provide clues to the density and/or temperature variations within nebulae. Temperatures from OIV and NeV ions show a part of high-excitation nebulae previously inaccessible. They verify the picture of physical processes in the HeIII zone.

Shure, M. A.↗
NASA NTRS1992

Mid-infrared spectroscopy of Pahala ash palagonite and implications for remote sensing studies of Mars

The mid-IR (7-20 micron range) spectral properties of Pahala ash palagonite and the effect of thin dustings of the palagonite on reflectance characteristics of quartzite and basalt were investigated. Unlike the reflectance of quartzite and basalt, the reflectance of the palagonite is flat and low (1-2 percent). It was found that a dusting of 1-20 micron palagonite particles and 20-250 micron particle clumps, covering 50 percent of the quartzite of the basalt host reduced the quartizite mid-IR reflectance by about 50 percent. The reflectance of the underlying rock was found to be linearly related to the exposed surface area even for extremely small amounts of palagonite (2-100 micron thickness, averaging 5 microns), indicating that mid-IR remote sensing of rocks on Mars will be practical only for dust-free areas.

Crisp, Joy↗
NASA NTRS1993

Study of tellurium precipitates in CdTe crystals

The effect of tellurium precipitates was studied in medium resistivity (10 exp 3-10 exp 6 ohm cm) undoped and Cl-doped CdTe using differential scanning calorimetry (DSC) and mid-infrared spectroscopy and the results were correlated with near-infrared microscopy photographs. When present in a significant quantity (about 0.25 wt pct), we show that Te precipitates are detectable using DSC measurements. In the mid-infrared, the contribution of the absorption by free-carriers is negligible, and therefore, the effect of the Te precipitates in these crystals can be considered uncoupled from the effects of Cd vacancies.

Jayatirtha, H. N.↗
NASA NTRS1993

Non-invasive optical detection of glucose in cell culture nutrient medium

The objective of the proposed research was to begin the development of a non-invasive optical sensor for measuring glucose concentration in the output medium of cell cultures grown in a unique NASA bioreactor referred to as an integrated rotating-wall vessel (IRWV). The input, a bovine serum based nutrient media, has a known glucose concentration. The cells within the bioreactor digest a portion of the glucose. Thus, the non-invasive optical sensor is needed to monitor the decrease in glucose due to cellular consumption since the critical parameters for sustained cellular productivity are glucose and pH. Previous glucose sensing techniques have used chemical reactions to quantify the glucose concentration. Chemical reactions, however, cannot provide for continuous, real time, non-invasive measurement as is required in this application. Our effort while in the fellowship program was focused on the design, optical setup, and testing of one bench top prototype non-invasive optical sensor using a mid-infrared absorption spectroscopy technique. Glucose has a fundamental vibrational absorption peak in the mid-infrared wavelength range at 9.6 micron. Preliminary absorption data using a CO2 laser were collected at this wavelength for water based glucose solutions at different concentrations and one bovine serum based nutrient medium (GTSF) with added glucose. The results showed near linear absorption responses for the glucose-in-water data with resolutions as high at 108 mg/dl and as low as 10 mg/dl. The nutrient medium had a resolution of 291 mg/dl. The variability of the results was due mainly to thermal and polarization drifts of the laser while the decrease in sensitivity to glucose in the nutrient medium was expected due to the increase in the number of confounders present in the nutrient medium. A multispectral approach needs to be used to compensate for these confounders. The CO2 laser used for these studies was wavelength tunable (9.2 to 10.8 micrometers), however, it was to unstable across wavelengths to test the multispectral approach. From this research, further NASA support was obtained to continue the work throughout the year in which a more stable light source will be used at smaller, near-infrared, wavelengths. It is anticipated that a more compact, non-invasive, optical glucose sensor will be realized which can be used with a bioreactor on future space shuttle missions. It is also anticipated that a multispectral optical sensor may be used to determine the concentration of other molecules needed within the NASA bioreactor, such as fructose and galactose.

Cote, Gerald L.↗
NASA NTRS1991

Recent star formation in the interacting galaxy system NGC 520

New optical spectroscopy, near-infrared spectroscopy, and mid-infrared imaging of the interacting system NGC 520 are presented. The data show that the heavily obscured primary nucleus has a current star-forming rate about 35 times the typical rate for a late-type galaxy nucleus, which may account for most of the large far-infrared luminosity of NGC 520. The secondary nucleus has little current star formation but has recently undergone a mild starburst. Optical colors and absorption line equivalent widths suggest that the extranuclear regions in both galaxies have experienced enhanced star formation roughly at the same time as the secondary nucleus, though at a lesser intensity. The extent of the extranuclear burst is large; at least half of the projected surface area of the two disks took part to varying degrees in the episode. Determining the exact age and strength of the recent star-formation episode in NGC 520 is uncertain. The best estimate for the initiation time of about few x 10 exp 8 yrs ago is consistent with the system-wide starburst being caused by the galaxy collision.

Stanford, S. A.↗
NASA NTRS1992

The moon - Mid-infrared (7.5- to 11.4-microns) spectroscopy of selected regions

Scaled spectral emissivity spectra have been obtained from five locations on the illuminated lunar surface and are interpreted in terms of differences in their mineralogic composition. The emission maximum, which typically falls near 8.0 microns for lunar rocks and fines, is observed to be shifted from 7.9 microns for noritic Copernicus crater walls to 8.1 microns for the olivine-rich central peak. Two mare locations show the emission maximum centered at 8.0 microns, consistent with laboratory emission measurements of basalts. An emissivity minimum at 10.5 microns in the spectrum from central peak 2 is attributed to the presence of olivine. Minima centered at 8.75 microns in the crater wall spectra resemble minima in laboratory spectra from pyroxene. A broad minimum centered at 8.5 microns in the Kepler ejecta spectrum and a sharp drop in emissivity at wavelengths longer than 11 microns in spectra from both mare locations suggest plagioclase.

Sprague, A. L.↗
NASA NTRS1987

Method and apparatus for enhancing laser absorption sensitivity

A simple optomechanical method and apparatus is described for substantially reducing the amplitude of unwanted multiple interference fringes which often limit the sensitivities of tunable laser absorption spectrometers. An exterior cavity is defined by partially transmissible surfaces such as a laser exit plate, a detector input, etc. That cavity is spoiled by placing an oscillating plate in the laser beam. For tunable diode laser spectroscopy in the mid-infrared region, a Brewster-plate spoiler allows the harmonic detection of absorptances of less than 10 to the -5 in a single laser scan. Improved operation is achieved without subtraction techniques, without complex laser frequency modulation, and without distortion of the molecular lineshape signal. The technique is applicable to tunable lasers operating from UV to IR wavelengths and in spectrometers which employ either short or long pathlengths, including the use of retroreflectors or multipass cells.

Webster, Christopher R.↗
NASA NTRS1980

Water ice polymorphs and their significance on planetary surfaces

Impacts into an icy surface could produce significant amounts of high pressure forms of water ice. Due to the relatively low ambient surface temperatures on satellites in the outer solar system and the modest temperature rises accompanying the impact pressures required for water ice metamorphism, high-pressure polymorphs will be created by and may remain after large cratering events. If so, those high-pressure ices should be ubiquitous. Low-pressure cubic ice may be abundant as well. Impacts into an icy regolith may both produce high-pressure polymorphs from ice I and destroy high-pressure polymorphs already present. The result will be an (unknown) equilibrium concentration of high pressure polymorphs in the regolith. Polymorphs may be detectable and mappable by reflection spectroscopy at vacuum ultraviolet and mid-infrared wavelengths.

Gaffney, E. S.↗
NASA NTRS1992

Grain Spectroscopy

Our fundamental knowledge of interstellar grain composition has grown substantially during the past two decades thanks to significant advances in two areas: astronomical infrared spectroscopy and laboratory astrophysics. The opening of the mid-infrared, the spectral range from 4000-400 cm(sup -1) (2.5-25 microns), to spectroscopic study has been critical to this progress because spectroscopy in this region reveals more about a materials molecular composition and structure than any other physical property. Infrared spectra which are diagnostic of interstellar grain composition fall into two categories: absorption spectra of the dense and diffuse interstellar media, and emission spectra from UV-Vis rich dusty regions. The former will be presented in some detail, with the latter only very briefly mentioned. This paper summarized what we have learned from these spectra and presents 'doorway' references into the literature. Detailed reviews of many aspects of interstellar dust are given.

Allamandola, L. J.↗
NASA NTRS1993

Mid- and far-infrared spectroscopy of ices - Optical constants and integrated absorbances

Laboratory spectra through the mid-infrared (4000 to 500/cm (2.5-20 microns) have been used to calculate the optical constants (n and k) and integrated absorption coefficients (A) for a variety of pure and mixed molecular ices of relevance to astrophysics. The ices studied were H2O, CH3OH, CO2, OCS, CH4, CO2 + CH4, CO2 + OCS, CO + CH4, CO + OCS, O2 + CH4, O2 + OCS, N2 + CH4, N2 + OCS, H2O + CH4, H2O + OCS, and H2O + CH3OH + CO + NH3. In addition, the measurements have been extended through the far-infrared (500 to 50/cm (20-200 microns) for the H2O, CH3OH, and H2O + CH3OH + CO + NH3 ices.

Hudgins, D. M.↗
NASA NTRS1992

Tunable Electro-optic modulators for lidar systems and atmospheric applications

In global sensing applications using different types of lidars, the spectral range and fine frequency coverages are often limited because of the finite tunabilities of molecular lasers and the number of molecular species that are available. To overcome the above obstacle, we have proposed new broadband frequency tunable electro-optic (EO) modulators that can cover a wide range from the mid-infrared to the visible as lidar sources in atmospheric sensing applications such as high resolution atmospheric molecular spectroscopy, Differential Absorption Lidar (DIAL), and laser radar imaging. The configuration of the proposed new tunable EO modulators includes an electro-optic active crystal element surrounded by a ferrite tuning element which is placed inside a microwave waveguide. The tuning is provided by an external magnetic field, which is either longitudinal or transverse, and the modulator can be either single sideband type or a double sideband type depending on the application required for the spectral purity of the modulator output.

Eng, R. S.↗
NASA NTRS1983

Guidance and control of MIR TDL radiation via flexible hollow metallic rectangular pipes and fibers for possible LHS and other optical system compaction and integration

Flexible hollow metallic rectangular pipes and infrared fibers are proposed as alternate media for collection, guidance and manipulation of mid-infrared tunable diode laser (TDL) radiation. Certain features of such media are found to be useful for control of TDL far field patterns, polarization and possibly intensity fluctuations. Such improvement in dimension compatibility may eventually lead to laser heterodyne spectroscopy (LHS) and optical communication system compaction and integration. Infrared optical fiber and the compound parabolic coupling of light into a hollow pipe waveguide are discussed as well as the design of the waveguide.

Yu, C.↗
NASA NTRS1990

Thermal emission spectroscopy of the middle atmosphere

The general objective of this research is to obtain, via remote sensing, simultaneous measurements of the vertical distributions of stratospheric temperature, ozone, and trace constituents that participate in the catalytic destruction of ozone (NO(sub y): NO, NO2, NO3, HNO3, ClONO2, N2O5, HNO4; Cl(sub x): HOCl), and the source gases for the catalytic cycles (H2O, CH4, N2O, CF2Cl2, CFCl3, CCl4, CH3Cl, CHF2Cl, etc.). Data are collected during a complete diurnal cycle in order to test our present understanding of ozone chemistry and its associate catalytic cycles. The instrumentation employed is an emission-mode, balloon-borne, liquid-nitrogen-cooled Michelson interferometer-spectrometer (SIRIS), covering the mid-infrared range with a spectral resolution of 0.020 cm(exp -1). Cryogenic cooling combined with the use of extrinsic silicon photoconductor detectors allows the detection of weak emission features of stratospheric gaseous species. Vertical distributions of these species are inferred from scans of the thermal emission of the limb in a sequence of elevation angles. The fourth SIRIS balloon flight was carried out from Palestine, Texas on September 15-16, 1986 with 9 hours of nighttime data (40 km). High quality data with spectral resolution 0.022 cm(exp -1), were obtained for numerous limb sequences. Fifteen stratospheric species have been identified to date from this flight: five species from the NO(sub y) family (HNO3, NO2, NO, ClONO2, N2O5), plus CO2, O3, H2O, N2O, CH4, CCl3F, CCl2F2, CHF2Cl, CF4, and CCl4. The nighttime values of N2O5, ClONO2, and total odd nitrogen have been measured for the first time, and compared to model results. Analysis of the diurnal variation of N2O5 within the 1984 and 1986 data sets, and of the 1984 ClONO2 measurements, were presented in the literature. The demonstrated ability of SIRIS to measure all the major NO(sub y) species, and therefore to determine the partitioning of the nitrogen family over a continuous diurnal cycle, is a powerful tool in the verification and improvement of photochemical modeling.

Kunde, V. G.↗
NASA NTRS1988

Mid-infrared solid-state lasers and laser materials

An account is given of NASA-Langley's objectives for the development of advanced lasers and laser materials systems applicable to remote sensing in the mid-IR range. Prominent among current concerns are fiber-optic spectroscopy, eye-safe solid-state lasers for both Doppler sensing and mid-IR wavelength-generation laser pumping, and nonlinear optics generating tunable mid-IR radiation. Ho:YAG lasers are noted to exhibit intrinsic advantages for the desired applications, and are pumpable by GaAlAs laser diodes with a quantum efficiency approaching 2.

Barnes, Norman P.↗
NASA NTRS1991

Infrared reflectance spectra (2.2-15 microns) of plagioclase feldspars

Laboratory results show that (1) the Christiansen frequency (CF) feature in mid-infrared reflectance spectra of powders can be used to accurately distinguish plagioclase composition, and (2) the wavelength position of the CF is not affected by vitrification of the plagioclase. Although the CF position does not distinguish glass from crystalline forms of plagioclase, other features (combination-tone, overtone, restrahlen bands) in the mid-IR spectra of plagioclase can be used for that purpose. These results have important implications for application of thermal emission spectroscopy to mapping the surface composition of regolith-covered planetary bodies like the moon, Mars, and asteroids.

Nash, Douglas B.↗
NASA NTRS1990

Infrared spectroscopic remote sensing from the Cassini orbiter

An infrared spectroscopy instrument for infrared remote sensing from the Cassini orbiter is being breadboarded in the laboratory. The Composite Infrared Spectrometer (CIRS) consists of a pair of Fourier Transform Spectrometers (FTS) which together cover the range from 10 - 1400/cm with a spectral resolution up to 0.5/cm. The far-infrared FTS is a polarizing interferometer covering the 10 - 300/cm range. The mid-infrared FTS is a conventional Michelson FTS covering 200 - 1400/cm in three spectral channels. CIRS will retrieve information on the atmospheres of Titan and Saturn with good vertical resolution, from deep in their tropospheres to high in their stratospheres, and into the upper few centimeters of the regoliths of icy objects. The science objectives and design of CIRS are discussed.

Kunde, V.↗
NASA NTRS1991

Infrared reflectance spectra (4-12 microns) of typical lunar samples

A laboratory study of the mid-infrared spectral reflectance properties of typical Apollo lunar rock and soil samples was conducted using a modern interferometric spectrometer. The results show that characteristic spectral features exist in the 4-12 micrometer range that are diagnostic of rock composition and mineralogy, especially for the plagioclase-rich rocks and soils. This is the first phase of a comprehensive infrared reflectance study under way to better understand the use of infrared emission spectroscopy for mapping the surface composition of the moon and other silicate bodies.

Nash, Douglas B.↗