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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Mechanically flexible mid-wave infrared imagers using black phosphorus ink films

The mid-wave infrared (MWIR) spectral range (λ = 3–8 μm) enables important sensing and imaging applications, including non-invasive bioimaging, night vision, and autonomous navigation. Commercial MWIR photodetectors are limited to rigid imagers based on heteroepitaxial materials. There is an emerging need for mechanically flexible MWIR imagers to broaden their functionality and practicality. Recently, photodetectors using van der Waals (vdW) black phosphorus (BP) flakes have demonstrated highly sensitive room-temperature photodetection. Additionally, vdW materials are solution-processable, facilitating scalable processing and flexible device fabrication. In this work, we present flexible MWIR imagers consisting of photodiodes fabricated on thin plastic substrates using BP ink films. We demonstrate mechanically robust responsivity up to 2.5-mm bending radii and after 5000 bending cycles. Leveraging this flexibility, we achieve full-azimuthal imaging, detecting directional light sources with precision. These results establish a scalable approach for large-area, conformable MWIR imaging and pave the way for integration with flexible electronics.

Wijaya, Theodorus Jonathan↗
DOE OSTI2025

Epitaxial PbGeSe thin films and their photoluminescence in the mid-wave infrared

PbSe is a narrow bandgap IV–VI compound semiconductor with application in mid-wave infrared optoelectronics, thermoelectrics, and quantum devices. Alkaline-earth or rare-earth elements such as Sr and Eu can substitute Pb to widen the bandgap of PbSe in heterostructure devices, but they come with challenges such as deteriorating optical and electronic properties, even in dilute concentrations due to their dissimilar atomic nature. We substitute Pb instead with column IV Ge and assess the potential of rocksalt phase PbGeSe as a wider bandgap semiconductor in thin films grown by molecular beam epitaxy on GaAs substrates. Low sticking of GeSe adatoms requires synthesis temperatures below 260 °C to incorporate Ge, but this yields poor structural and compositional uniformity as determined by x-ray diffraction. Consequently, as-grown films in the range Pb0.94Ge0.06Se–Pb0.83Ge0.17Se (6%–17% Ge) show much less bandgap widening in photoluminescence than prior work on bulk crystals using absorption. We observe that post-growth rapid thermal annealing at temperatures of 375–450 °C improves the crystal quality and recovers bandgap widening. Rapid interdiffusion of Ge during annealing, however, remains a challenge in harnessing such PbGeSe materials for compositionally sharp heterostructures. Annealed 17% Ge films emit light at 3–3.1 μm with a minimal shift in wavelength vs temperature. These samples are wider in bandgap than PbSe films by 55 meV at room temperature, and the widening increases to 160 meV at 80 K, thanks to sharply different dependence of bandgap on temperature in PbSe vs PbGeSe.

Xiao, Kelly (ORCID:0000000321000838)↗
NASA NTRS2000

Observations of Leonid Meteors Using a Mid-Wave Infrared Imaging Spectrograph

We report broadband 3-5.5 micrometer detections of two Leonid meteors observed during the 1998 Leonid Multi-Instrument Aircraft Campaign. Each meteor was detected at only one position along their trajectory just prior to the point of maximum light emission. We describe the particular aspects of the Aerospace Corp. Mid-wave Infra-Red Imaging Spectrograph (MIRIS) developed for the observation of short duration transient events that impact its ability to detect Leonid meteors. This instrument had its first deployment during the 1998 Leonid MAC. We infer from our observations that the mid-infrared light curves of two Leonid meteors differed from the visible light curve. At the points of detection, the infrared emission in the MIRIS passband was 25 +/- 4 times that at optical wavelengths for both meteors. In addition, we find an upper limit of 800 K for the solid body temperature of the brighter meteor we observed, at the point in the trajectory where we made our mid-wave infrared detection.

Rossano, G. S.↗
NASA NTRS2008

Comparison of Terra and Aqua MODIS VIS Bands On-Orbit Response

The Moderate Resolution Imaging Spectroradiometer (MODIS) has 36 spectral bands with a total of 490 detectors, covering spectral regions in the visible (VIS), near-infrared (NIR), short-wave infrared (SWIR), mid-wave infrared (MWIR), and long-wave infrared (LWIR). MODIS is a cross-track scanning radiometer which collects data using a rotating scan mirror (both sides) over a wide range of scan angles. The VIS, NIR, and SWIR bands (bands 1-19 and 26) make measurements of daytime surface reflected radiances, thus are referred to as the reflective solar bands (RSB). MODIS was built with a complete set of on-board calibrators, capable of providing radiometric, spatial, and spectral calibration and characterization during its entire mission. The RSB on-orbit calibration is primarily provided using a solar diffuser (SD) and a solar diffuser stability monitor (SDSM). The SD and SDSM calibration system is operated on a regular (weekly to bi-weekly) basis. The spectro-radiometric calibration assembly (SRCA) is another on-hoard calibrator that also provides RSB radiometric calibration support. For this purpose, the SRCA is operated in a radiometric mode on a monthly basis. A complete SRCA radiometric calibration is performed using different lamp configurations, or different radiance levels, to cover the range of RSB gain. Two additional SRCA modes with slightly different configurations are designed and operated for sensor on-orbit spectral and spatial characterization. In addition to its on-hoard calibrators, each MODIS makes monthly lunar observations to monitor RSB radiometric calibration stability. The MODIS lunar observations are made through its space view (SV) port at nearly the same lunar phase angles via spacecraft roll maneuvers. The SD, SRCA, and lunar measurements are made at different scan angles and data samples are collected for all spectral bands and detectors using both sides of the scan minor. Since launch, Terra and Aqua MODIS have operated successfully for more than 8 years and 6 years, respectively. Many SD/SDSM, SRCA, and lunar observations have been made by each instrument and used to derive RSB on-orbit calibration parameters, enabling corrections for sensor response changes and changes of the response versus scan angle (RVS). In general, the RSB calibration parameters are updated regularly into the MODIS Level 1B (LIB) code in support of continuous data processing for all MODIS science data products. This paper provides a brief description of MODIS RSB calibration methodologies and approaches, and summarizes on-orbit changes of their responses (gains), particularly for the VIS spectral bands.

Xiong, Xiaoxiong↗
NASA NTRS2008

Characterization of MODIS VIS/NIR Spectral Band Detector-to-Detector Difference

MODIS has 36 spectral bands with wavelengths in the visible (VIS), near-infrared (NIR), shortwave infrared (SWTR), mid-wave infrared (MWIR), and long-wave infrared (LWIR). It makes observations at three nadir spatial resolutions: 0,25km for bands 1-2 with 40 detectors per band, 0.5km for bands 3-7 with 20 detectors per band, and 1km for bands 8-36 with 10 detectors per band. The VIS, NIR, and S\VIR spectral bands are the reflective solar bands (RSB), which are calibrated on-orbit by a solar diffuser (SD). In addition, MODIS lunar observations are used to track the RSB calibration stability. In this study, we examine detector-to-detector calibration difference for the VIStNIR spectral bands using the SD and lunar observations. The results will be compared with an independent analysis with additional information, such as polarization correction, derived from standard ocean color data products. The current MODIS RSB calibration approach only carries a band-averaged RVS (response versus scan angle) correction. The results from this study suggest that a detector-based RVS correction should be used to improve the L1B data quality, especially for several VIS bands in Terra MODIS due to large changes of the scan mirror's optical properties in recent years.

Xiong, X.↗
NASA NTRS2009

An Overview of MODIS Calibration and Characterization and Lessons Learned

The Moderate Resolution Imaging Spectroradiometer (MODIS) is a key instrument for NASA's EOS missions. Two nearly identical copies have flown on the Terra and Aqua spacecraft for more than 9 years and 6 years since their launch in December 1999 and May 2002, respectively. MODIS observations and associated data products have been widely used by the science community and users worldwide for studies of Earth's system of land, oceans, and atmosphere. MODIS was developed based on the desire of the science community to extend and enhance heritage sensors' data records. It was designed with enhancements made over its heritage sensors in terms of its spectral, spatial, and radiometric characteristics. It is a cross-track scanning radiometer, that uses a two-sided scan mirror, collecting data in 36 spectral bands covering spectral regions of visible (VIS), near-infrared (NIR), short-wave infrared (SWIR), mid-wave infrared (MWIR), and long-wave infrared (LWIR). The VIS, NIR, and SWIR bands (bands 1-19 and 26), which make measurements of daytime surface reflected radiances, are referred to as the reflective solar bands (RSB). The MWIR and LWIR bands (20-25 and 27-36), which measure both the daytime and nighttime scene emissive radiances, are thus referred to as the thermal emissive bands (TEB). In this paper, we provide an overview of MODIS instrument calibration and characterization methodologies, activities, and results from pre-launch to post launch, with emphasis on the lessons learned from its design to on-orbit operation. Currently, both instruments are operated normally and all the on-orbit calibration activities are performed on a regular basis with some at slightly reduced frequencies. The TEB responses have been extremely stable with less than 0.3% change per year. For the RSB, the changes are wavelength and scan angle dependent with the largest changes in the VIS spectral bands. As both Terra and Aqua MODIS continue to operate beyond their prime missions, constant effort is still needed to maintain instrument and calibration and data product quality. This paper shows that the lessons from Terra MODIS design, test, and operation, have greatly benefitted Aqua MODIS. Because of this, Aqua MODIS overall performance is better than Terra MODIS. It is not surprising that lessons from MODIS calibration and characterization, from methodologies to on-orbit implementation, have also provided valuable information for the design and development of future earth observing missions/sensors, such as VHRS on the NPP and NPOESS, ABI on GOES-R, OLI on LDCM, and the reflective solar sensor on CLARREO.

Xiong, Xiaxiong↗
DOE OSTI2025

Uncooled GeSn MWIR Photodetectors Using Fully Relaxed Thin Triple‐Step Buffer

GeSn photodetectors monolithically grown on Ge virtual substrates demonstrate mid-wave infrared (MWIR) detection at room temperature. The lattice mismatch between GeSn and Ge causes dislocations and compressive strain, creating leakage pathways and unwanted indirect band transitions. Designed thin Ge 0.91 Sn 0.09 triple-step buffer layers of ≈175 nm total thickness reduce dislocations and enable full relaxation, showing 100% lattice relaxation and smooth surface roughness of 0.83 nm with shorter auto-correlation length in surface morphology compared to single-step buffers. Ge 1-x Sn x photodetectors (x = 0.09, 0.12, and 0.15) on triple-step buffers with n-i-p configurations achieve lattice strain relaxations of 99%, 88%, and 80%, respectively. Ge 0.91 Sn 0.09 and Ge 0.88 Sn 0.12 show gradual variation in auto-correlation amplitude, while Ge 0.85 Sn 0.15 shows an increase due to lattice mismatch. Shockley–Read–Hall recombination current dominates at low reverse bias due to mismatch-induced dislocations, while band-to-band tunneling current dominates at higher reverse bias due to narrowing bandgap under strong electric fields. Here, the photodetectors show extended spectral response with increasing Sn composition of i-GeSn active layer sandwiched by barriers. Ge 0.88 Sn 0.12 and Ge 0.85 Sn 0.15 exhibit extended wavelength cut-offs of 3.12 and 3.27 µm at room temperature, demonstrating significant potential for silicon-based MWIR applications.

GeSn↗
NASA NTRS2003

Detecting water hazards for autonomous off-road navigation

Detecting water hazards for autonomous, off-road navigation of unmanned ground vehicles is a largely unexplored problem. In this paper, we catalog environmental variables that affect the difficulty of this problem, including day vs. night operation, whether the water reflects sky or other terrain features, the size of the water body, and other factors. We briefly survey sensors that are applicable to detecting water hazards in each of these conditions. We then present analyses and results for water detection for four specific sensor cases: 1) using color image classification to recognize sky reflections in water during the day, 2) using ladar to detect the presence of water bodies and to measure their depth, 3) using short-wave infrared (SWIR) imagery to detect water bodies, as well as snow and ice, and 4) using mid-wave infrared (MWIR) imagery to recognize water bodies at night. For color imagery, we demonstrate solid results with a classifier that runs at nearly video rate on a 433 MHz processor. For ladar, we present a detailed propagation analysis that shows the limits of water body detection and depth estimation as a function of look ahead distance, water depth, and ladar wavelength. For SWIR and MWIR, we present sample imagery from a variety of data collections that illustrate the potential of these sensors. These results demonstrate significant progress on this problem.

McHenry, Mike↗
DOE OSTI2026

From binary to quinary: The rationale and development of GaInAsSbBi for mid- and long-wave infrared sensing applications

Given the added complexity in flux calibration and composition evaluation inherent to quinary alloy growth, what motivates compounding the challenges of III–V-Bi growth with the goal of producing a quinary alloy of GaInAsSbBi for mid- and long-wave infrared sensing applications? Each elemental constituent provides some additional design freedom to achieve the ultimate goal of producing a lattice-matched, bulk random alloy mid-wave infrared III–V material with smooth surface morphology and high optoelectronic quality to enable high performance elevated operating temperatures. Here, this paper reviews the evolution of Bi-containing semiconductor research, focusing on mid- and long-wave infrared materials and highlighting key research findings that motivated the decisions to accept the added complexity in going from binaries like InAs or InSb, to InAsBi, to InAsSbBi, and, finally, to GaInAsSbBi to meet the performance demands of advanced infrared sensing applications.

Webster, Preston T. [Air Force Research Laboratory↗
DOE OSTI2024

Mid-infrared photodetection with 2D metal halide perovskites at ambient temperature

The detection of mid-infrared (MIR) light is technologically important for applications such as night vision, imaging, sensing, and thermal metrology. Traditional MIR photodetectors either require cryogenic cooling or have sophisticated device structures involving complex nanofabrication. Here, we conceive spectrally tunable MIR detection by using two-dimensional metal halide perovskites (2D-MHPs) as the critical building block. Leveraging the ultralow cross-plane thermal conductivity and strong temperature-dependent excitonic resonances of 2D-MHPs, we demonstrate ambient-temperature, all-optical detection of MIR light with sensitivity down to 1 nanowatt per square micrometer, using plastic substrates. Through the adoption of membrane-based structures and a photonic enhancement strategy unique to our all-optical detection modality, we further improved the sensitivity to sub–10 picowatt-per-square-micrometer levels. The detection covers the mid-wave infrared regime from 2 to 4.5 micrometers and extends to the long-wave infrared wavelength at 10.6 micrometers, with wavelength-independent sensitivity response. Our work opens a pathway to alternative types of solution-processable, long-wavelength thermal detectors for molecular sensing, environmental monitoring, and thermal imaging.

Li, Yanyan [Yale University, New Haven, CT (United↗
DOE OSTI2026

Spatiotemporal Thermal Coupling in VO 2 Device Arrays

Correlated oxides such as VO 2 exhibit an electrically driven insulator–metal transition (IMT) that underlies their promise for neuromorphic and memory devices. Yet the IMT is not a uniform bulk process but a spatiotemporal phenomenon in which local heating nucleates filaments, contracts or dissolves them with the electric field, and couples to the environment. In this work, we directly image the VO 2 IMT dynamics by mid-wave infrared, thermography synchronized with electrical transport, resolving device temperature with micrometer spatial and microsecond temporal resolution. At the single-device level, we capture the full cycle of filament nucleation, contraction, and relaxation during current/voltage-driven resistive switching. At the array level, we show that heat propagates across etched gaps with an effective length scale of ∼131 µm, enabling cooperative behaviors among electrically isolated devices. Short-range distanced devices exhibit mutual filament attraction and sequential dissolution, while long-range distanced devices differentiate into distinct roles: drivers that initiate switching, cooperative responders that undergo assisted self-oscillations, and passive reporters that record the thermal field. Furthermore, these results reframe thermal crosstalk, long regarded as parasitic, as an intrinsic coupling channel and design principle for organizing collective switching behaviors, with direct implications for emergent circuit functionality in neuromorphic and unconventional computing architectures.

coupling↗
NASA NTRS1996

Balancing Science Objectives and Operational Constraints: A Mission Planner's Challenge

The Air Force minute sensor technology integration (MSTI-3) satellite's primary mission is to characterize Earth's atmospheric background clutter. MSTI-3 will use three cameras for data collection, a mid-wave infrared imager, a short wave infrared imager, and a visible imaging spectrometer. Mission science objectives call for the collection of over 2 million images within the one year mission life. In addition, operational constraints limit camera usage to four operations of twenty minutes per day, with no more than 10,000 data and calibrating images collected per day. To balance the operational constraints and science objectives, the mission planning team has designed a planning process to e event schedules and sensor operation timelines. Each set of constraints, including spacecraft performance capabilities, the camera filters, the geographical regions, and the spacecraft-Sun-Earth geometries of interest, and remote tracking station deconflictions has been accounted for in this methodology. To aid in this process, the mission planning team is building a series of tools from commercial off-the-shelf software. These include the mission manifest which builds a daily schedule of events, and the MSTI Scene Simulator which helps build geometrically correct scans. These tools provide an efficient, responsive, and highly flexible architecture that maximizes data collection while minimizing mission planning time.

Weldy, Michelle↗
NASA NTRS1996

Vibration Isolation, Suppression, Steering, and Pointing (VISSP)

The design of a six degree of freedom flight vibration isolation suppression and steering (VISS) subsystem for a mid-wave infrared camera on the top of a spacecraft is presented. The development of a long stroke piezoelectric, redundant, compact, low stiffness and power efficient actuator is summarized. A subsystem that could be built and validated for flight within 15 months was investigated. The goals of the VISS are 20 dB vibration isolation above 2 Hz, 15 dB vibration suppression of disturbances at about 60 Hz and 120 Hz, and +/- 0.3 deg steering at 2 Hz and 4 Hz.

Wada, Ben K.↗
NASA NTRS2007

Multiyear On-orbit Calibration and Performance of Terra MODIS Thermal Emissive Bands

Since launch in December 1999, Terra MODIS has been making continuous Earth observations for more than seven years. It has produced a broad range of land, ocean, and atmospheric science data products for improvements in studies of global climate and environmental change. Among its 36 spectral bands, there are 20 reflective solar bands (RSB) and 16 thermal emissive bands (TEB). MODIS thermal emissive bands cover the mid-wave infrared (MWIR) and long-wave infrared (LWIR) spectral regions with wavelengths from 3.7 to 14.4pm. They are calibrated on-orbit using an on-board blackbody (BB) with its temperature measured by a set of thermistors on a scan-by-scan basis. This paper will provide a brief overview of MODIS TEB calibration and characterization methodologies and illustrate on-board BB functions and TEB performance over more than seven years of on-orbit operation and calibration. Discussions will be focused on TEB detector short-term stability and noise characterization, and changes in long-term response (or system gain). Results show that Terra MODIS BB operation has been extremely stable since launch. When operated at its nominal controlled temperature of 290K, the BB temperature variation is typically less than +0.30mK on a scan-by-scan basis and there has been no time-dependent temperature drift. In addition to excellent short-term stability, most TEB detectors continue to meet or exceed their specified noise characterization requirements, thus enabling calibration accuracy and science data product quality to be maintained. Excluding the noisy detectors identified pre-launch and those that occurred post-launch, the changes in TEB responses have been less than 0.7% on an annual basis. The optical leak corrections applied to bands 32-36 have been effective and stable over the entire mission

Xiong, Xiaoxiong↗
NASA NTRS2009

Large Format Multicolor QWIP Focal Plane Arrays

Mid-wave infrared (MWIR) and long-wave infrared (LWIR) multicolor focal plane array (FPA) cameras are essential for many DoD and NASA applications including Earth and planetary remote sensing. In this paper we summarize our recent development of large format multicolor QWIP FPA that cover MWIR and LWIR bands.

infrared detectors↗
NASA NTRS2001

Infrared Sensing Aeroheating Flight Experiement: STS-96 Flight Results

Major elements of an experiment called the Infrared Sensing Aeroheating Flight Experiment are discussed. The primary experiment goal is to provide reentry global temperature images from infrared measurements to define the characteristics of hypersonic boundary-layer transition during flight. Specifically, the experiment is to identify, monitor, and quantify hypersonic boundary layer windward surface transition of the X-33 vehicle during flight. In addition, the flight data will serve as a calibration and validation of current boundary layer transition prediction techniques, provide benchmark laminar, transitional, and fully turbulent global aeroheating data in order to validate existing wind tunnel and computational results, and to advance aeroheating technology. Shuttle Orbiter data from STS-96 used to validate the data acquisition and data reduction to global temperatures, in order to mitigate the experiment risks prior to the maiden flight of the X-33, is discussed. STS-96 reentry mid-wave (3-5 Pm) infrared data were collected at the Ballistic Missile Defense Organization/Innovative Sciences and Technology Experimentation Facility site at NASA-Kennedy Space Center and subsequently mapped into global temperature contours using ground calibrations only. A series of image mapping techniques have been developed in order to compare each frame of infrared data with thermocouple data collected during the flight. Comparisons of the ground calibrated global temperature images with the corresponding thermocouple data are discussed. The differences are shown to be generally less than about 5%, which is comparable to the expected accuracy of both types of aeroheating measurements.

Blanchard, Robert C.↗
DOE OSTI2024

Advanced Instrumentation for Metal Additive Manufacturing

Laser powder bed fusion (LPBF) is the most widely used process for metal additive manufacturing (AM), particularly where complex geometries provide performance advantages unattainable with traditional manufacturing techniques. However, LPBF is highly sensitive to innate variability in both the powder spreading and fusion steps, often leading to defects such as pores that are difficult to detect yet significantly impair component mechanical properties and fatigue life. This thesis presents a range of novel instruments enabling both precise assessment of powder layer characteristics and in-situ thermal metrology of metal AM to advance the quality control of LPBF. First, leveraging a custom X-ray microscope and a radiation-transport model developed through this work, transmission X-ray imaging is used to study spreading of thin metal powder layers. Effective layer depth is directly mapped at a process-relevant size scale, surpassing optical techniques that can only estimate local deposition from layer surface topography. Layer packing density and quality are shown to be influenced by powder flowability and particle size relative to nominal powder layer thickness. Layer quality is additionally connected to the geometry of the spreading implement and its velocity. This technique and its presented findings enable pairing feedstocks with spreading strategies that create layers with consistent packing density and uniformity. Second, a twofold approach is employed to optically interrogate the laser fusion step of LPBF for observing signatures of defect formation. Aperture division multiplexing is conceptualized, providing for simultaneous laser delivery and high-fidelity infrared (IR) process monitoring through a common optic. In-situ microscopy at 50 μm spatial resolution and at mid-wave IR wavelengths is proven readily achievable with the first purpose-built optic of this type. Next, a bespoke imaging spectrometer, along with a temperature-emissivity separation technique, is used to retrieve accurate process temperatures over a 1000 K range. Data from these instruments are correlated to porosity as fine as 4.3 μm in two LPBF test artifacts, as verified using computed tomography (CT), establishing the viability of robust optically-based component qualification.

Penny, Ryan↗
NASA NTRS1993

Evolution of miniature detectors and focal plane arrays for infrared sensors

Sensors that are sensitive in the infrared spectral region have been under continuous development since the WW2 era. A quest for the military advantage of 'seeing in the dark' has pushed thermal imaging technology toward high spatial and temporal resolution for night vision equipment, fire control, search track, and seeker 'homing' guidance sensing devices. Similarly, scientific applications have pushed spectral resolution for chemical analysis, remote sensing of earth resources, and astronomical exploration applications. As a result of these developments, focal plane arrays (FPA) are now available with sufficient sensitivity for both high spatial and narrow bandwidth spectral resolution imaging over large fields of view. Such devices combined with emerging opto-electronic developments in integrated FPA data processing techniques can yield miniature sensors capable of imaging reflected sunlight in the near IR and emitted thermal energy in the Mid-wave (MWIR) and longwave (LWIR) IR spectral regions. Robotic space sensors equipped with advanced versions of these FPA's will provide high resolution 'pictures' of their surroundings, perform remote analysis of solid, liquid, and gas matter, or selectively look for 'signatures' of specific objects. Evolutionary trends and projections of future low power micro detector FPA developments for day/night operation or use in adverse viewing conditions are presented in the following test.

Watts, Louis A.↗