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VMn is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. V is bonded in a body-centered cubic geometry to eight equivalent Mn atoms. All V–Mn bond lengths are 2.49 Å. Mn is bonded in a body-centered cubic geometry to eight equivalent V atoms.
V3Mn is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. there are two inequivalent V sites. In the first V site, V is bonded in a distorted body-centered cubic geometry to four equivalent V and four equivalent Mn atoms. All V–V bond lengths are 2.54 Å. All V–Mn bond lengths are 2.54 Å. In the second V site, V is bonded in a 8-coordinate geometry to eight equivalent V and six equivalent Mn atoms. All V–Mn bond lengths are 2.93 Å. Mn is bonded in a distorted body-centered cubic geometry to fourteen V atoms.
VMn is beta Np-derived structured and crystallizes in the orthorhombic Cmmm space group. The structure is three-dimensional. V is bonded in a 8-coordinate geometry to four equivalent V and four equivalent Mn atoms. All V–V bond lengths are 2.53 Å. All V–Mn bond lengths are 2.45 Å. Mn is bonded in a 8-coordinate geometry to four equivalent V and four equivalent Mn atoms. All Mn–Mn bond lengths are 2.53 Å.