Search NASA⌕ Search

SEARCH · Search NASA

Results for “Mn3N2”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

3 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on Mn3N2 by Materials Project

Mn3N2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. there are two inequivalent Mn2+ sites. In the first Mn2+ site, Mn2+ is bonded to five equivalent N3- atoms to form a mixture of corner and edge-sharing MnN5 square pyramids. There are four shorter (2.03 Å) and one longer (2.06 Å) Mn–N bond lengths. In the second Mn2+ site, Mn2+ is bonded in a linear geometry to two equivalent N3- atoms. Both Mn–N bond lengths are 1.93 Å. N3- is bonded to six Mn2+ atoms to form a mixture of corner and edge-sharing NMn6 octahedra. The corner-sharing octahedra tilt angles range from 0–6°.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Mn3N2 by Materials Project

Mn3N2 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. there are two inequivalent Mn2+ sites. In the first Mn2+ site, Mn2+ is bonded in a distorted trigonal non-coplanar geometry to four equivalent N3- atoms. There are three shorter (1.84 Å) and one longer (2.48 Å) Mn–N bond lengths. In the second Mn2+ site, Mn2+ is bonded to six equivalent N3- atoms to form edge-sharing MnN6 octahedra. There are two shorter (2.25 Å) and four longer (2.28 Å) Mn–N bond lengths. N3- is bonded in a 3-coordinate geometry to seven Mn2+ atoms.

36 MATERIALS SCIENCE↗