Materials Data on MnV2O10 by Materials Project
V2MnO10 crystallizes in the monoclinic Cc space group. The structure is three-dimensional. there are two inequivalent V sites. In the first V site, V is bonded in a 5-coordinate geometry to five O atoms. There are a spread of V–O bond distances ranging from 1.68–2.03 Å. In the second V site, V is bonded in a 5-coordinate geometry to five O atoms. There are a spread of V–O bond distances ranging from 1.68–2.03 Å. Mn is bonded in a distorted octahedral geometry to six O atoms. There are a spread of Mn–O bond distances ranging from 2.03–2.70 Å. There are ten inequivalent O sites. In the first O site, O is bonded in a distorted bent 120 degrees geometry to one V and one Mn atom. In the second O site, O is bonded in a single-bond geometry to one O atom. The O–O bond length is 1.24 Å. In the third O site, O is bonded in a distorted bent 150 degrees geometry to one V and one Mn atom. In the fourth O site, O is bonded in a bent 120 degrees geometry to one Mn and one O atom. The O–O bond length is 1.23 Å. In the fifth O site, O is bonded in a bent 150 degrees geometry to one V and one Mn atom. In the sixth O site, O is bonded in a trigonal non-coplanar geometry to three V atoms. In the seventh O site, O is bonded in a single-bond geometry to one O atom. In the eighth O site, O is bonded in a bent 120 degrees geometry to one Mn and one O atom. In the ninth O site, O is bonded in a trigonal non-coplanar geometry to three V atoms. In the tenth O site, O is bonded in a bent 150 degrees geometry to one V and one Mn atom.