SEARCH · Search NASA
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Ionization cross sections in collisions between excited nitrogen molecules and argon atoms, oxygen molecules, and nitric oxide molecules
Ionization of nitrogen and oxygen molecules by nitrogen and oxygen molecules
Quantum mechanical study of molecules - prediction of ground, ionized, and excited states of unknown nitrogen fluoride molecule
Measurement of ionization cross sections for nitrogen and oxygen molecules on impact with other nitrogen and oxygen molecules
Cross sections for ionization in collisions between excited nitrogen molecules and carbon monoxide and nitrogen ground state molecules
Ionization of nitrogen and oxygen molecules by beams - electron impact ionization and charge transfer neutralization
Quantum mechanical study of transition probabilities, Einstein A coefficients, and oscillator strengths of band systems of diatomic molecules
Arc-heated, supersonic, argon molecular beam measurements of molecular collision cross section energies
Octopole moments for methane and carbon tetrafluoride derived from second virial coefficients temperature dependence, using spherical shell potential model
Monte Carlo analysis of free and near free molecular flow through circular tubes for mass, momentum and energy transfer
Over 600 measured heat-transfer coefficients in the transition from slip to free-molecule flow have been correlated by using the Nusselt number Nu as a function of the Knudsen Kn and Reynolds Re (or Mach M) numbers. The experimental range for these heat-transfer data from transverse cylinders in air corresponds to the following dimensionless groups: M, 0.10 to 0.90; Re, 0.03 to 11.5; Kn, 0.10 to 5.0. The total air temperature T(sub t) was maintained constant at 80 F, but wire temperature was Varied from 150 to 580 F. At Kn=0.10, Nu extrapolates smoothly into slip-flow empirical curves that show Nu as a function of Re and M or Kn. The correlation gradually changes from the square root of Re(sub t) dependence characteristic of continuum flow to first-power Re dependence as Kn increases (decreasing Re). At the experimental limit Kn ft 5.0, the Nu data correlate with a mean fractional error of 413 percent by the prediction of free-molecule-flow theory. In comparing experimental results with theory, an accommodation coefficient of 0.57+/-0.07 was inferred from the heat-transfer data, which were obtained with etched tungsten wire in air. The wire recovery temperature T(sub e) was measured and compared with existing data and theory in terms of a ratio eta(equivalent to T(sub e)/T(sub t). The results can be divided into three groups by Kn criteria: For Kn less than 2.01, eta is independent of Kn, and eta decreases from 1.0 to 0.97 as M increases from 0 to 0.90; for 2.0 less than Kn less than 5.0, eta is a function of both Kn and M in this transition region to fully developed free-molecule flow; and for Kn greater than 5.0, eta predicted by free-molecule-flow theory is observed and increases from 1.0 to 1.08 as M increases from 0 to 0.90, again independent of Kn. Therefore, these T(sub e) data provide a guide to the boundary of fully developed free-molecule flow, which is.inferred from this research to exist for Kn greater than 5.0. This boundary criterion is substantiated by other published data on T(sub e) at supersonic speeds.
The search for organic matter on Mars has rapidly evolved in the past decade with simple aromatic, S-heterocycles, and aliphatic organic molecules detected in Gale crater. We report the in situ detection of >20 organic molecules from clay-bearing sandstones in the ~3.5-billion-year-old Knockfarrill Hill member of Glen Torridon, Gale crater, by the Sample Analysis at Mars instrument suite onboard the Curiosity rover. These molecules were liberated by the onboard tetramethylammonium hydroxide wet chemistry experiment. Diverse thermochemolysis products, including benzothiophene, methyl benzoate, and single and dicyclic aromatic molecules were released and detected by evolved gas analysis and gas chromatography-mass spectrometry. Results indicate the experiment successfully released molecules preserved in ancient macromolecular or free organic matter within Martian bedrock despite ~3.5 billion years of diagenesis and radiation exposure.
Potential-energy curves for nitrogen atom (N-N) interactions corresponding to the X (1)Sigma(sup +, sub g), A (3)Sigma(sup +, sub u), (5)Sigma(sup +, sub g), (7)Sigma(sup +, sub u), B (3) Pi(sub g), C (3)(Pi(su u)and a (1)Pi(sub g) states of the nitrogen molecule N2 as well as curves for the atom-molecules (N-N2) and molecule-molecule (N2-N2) interactions have been calculated. All calculations have been based as nearly as possible on experimental data, including spectroscopically determined vibrational energy levels, scattering cross sections of atomic beams in gases, and measured vibrational relaxation times. In cases where experimental data were not available, approximate quantum-mechanical calculations have been made. Results obtained by these various methods are remarkably consistent with one another and are believed to have good accuracy.
The environments experienced by vehicles upon entry into planetary atmospheres generally result in severe aerothermodynamic loading. These flows are characterized by the formation of strong shock waves, behind which high temperatures and non-equilibrium environments are generated, and the accurate prediction of internal energy relaxation and chemical kinetics becomes important. This manuscript focuses on the internal relaxation of the rotational energy of polyatomic molecules. Previous work has described the implementation of a discrete rotational energy model for diatomic molecules (linear rotators). Later, Gimelshein et. al extended this model to include polyatomic molecular internal energies. However, they did not include details on how to generate the particles at equilibrium conditions and centrifugal distortion was not included in their model. The purpose of the present study is to extend the afore-mentioned models to the treatment of discrete rotational energy in polyatomic molecules with the addition of centrifugal distortion. An overview of the background theory needed for the implementation of the model will be given followed by the model itself and verification of the model. For example, sampled versus Boltzmann distributions are compared in Figure 1 for CH3 (oblate rotator – two quantum numbers) and examples of thermal relaxation behavior for linear and non-linear rotators are presented in Figure 2. In addition, comparisons of thermophysical properties will be presented, as well as examples of adiabatic relaxation and application to hypersonic flow.
Ionization of nitrogen molecules by nitrogen molecules
This paper, following a brief introduction, is divided into five parts. Part I outlines the theory of the molecular orbital method for the ground, ionized and excited states of molecules. Part II gives a brief summary of the interaction integrals and their tabulation. Part III outlines an automatic program designed for the computation of various states of molecules. Part IV gives examples of the study of ground, ionized and excited states of CO, BH and N2 where the program of automatic computation and molecular integrals have been utilized. Part V enlists some special problems of Molecular Quantum Mechanics are being tackled at New York University.
Perturbation theory of heteronuclear diatomic molecules based on isoelectronic homonuclear molecules applied to carbon monoxide and nitrogen
Formulas are derived that express the contributions of the electric quadrupole-quadrupole and dipole-octupole forces, respectively, to the dispersion energy of two unexcited molecules possessing axial symmetry. The formulas are valid in situations where the optical dispersion curve of each molecule is adequately characterized by a pair of resonance frequencies.