Assessing Short‐Term Impacts of Management Practices on N 2 O Emissions From Diverse Mediterranean Agricultural Ecosystems Using a Biogeochemical Model
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Jia Deng↗
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Mineral-Catalysed Formation of Marine NO and N 2 O on the Anoxic Early Earth
Microbial denitrification converts fixed nitrogen species into gases in extant oceans. However, it is unclear how such transformations occurred within the early nitrogen cycle of the Archean. Here 5we present experimental anoxic surface-catalyzed reduction of nitrite and nitrate via green rust and magnetite combined with diffusion and photochemical modeling. We find that in a Fe 2+ -rich marine environment, Fe minerals could have catalyzed abiotic denitrification reactions leading to the formation of nitric oxide (NO) and nitrous oxide (N 2 O). Nitrate did not exhibit reactivity in the presence of either mineral or aqueous Fe2+, however, both minerals induced rapid nitrite reduction 10to NO and N 2 O. While N 2 O escaped into the atmosphere (63% of nitrite-nitrogen, with green rust as catalyst), NO remained associated with precipitates (7%) serving as a potential shuttle to the benthic ocean.The modeling suggests that marine N 2 O emissions would have sustained 0.8-6 ppb of atmospheric N 2 O without a protective ozone layer. Our findings add detail to the as yet incompletely documented Archean nitrogen cycle, implying a globally distributed process driven 15by chemical kinetics similar to those of modern enzymatically mediated conversions.
Steffen Buessecker↗
Absorption and photoionization cross sections of o sub 2 and n sub 2 at intense solar emission lines.
Photoionization and absorption cross sections measured for nitrogen and oxygen at wavelengths below 1100 angstroms
NITROGEN↗
Simultaneous HCN and H sub 2 O laser emission in mixtures containing H, C, N, and O.
Simultaneous HCN and HOH laser emission in pulsed discharge through mixture containing H, C, N and O
Haak, F. A.↗
Fluorescent excitation of Fe 2, Mn 2, Ti 2, N 1 lines by V 4, N 5, O 6: Emission lines in the spectra of symbiotic stars and Seyfert galaxies
Analysis of the published IUE and ground based high resolution spectra of symbiotic stars, particularly RR Tel, shows that the dominant excitation mechanism of Fe II, Mn II, Ti II, and N I lines is the selective fluorescent excitation of some levels by the strong C IV, N V, and O VI emission lines. The same mechanism should work for the excitation of Fe II lines in the spectra of Seyfert galaxies and Q60's whose emission spectra are quite similar to those of symbiotic stars. The similarities and differences between the fluroescent excitation mechanism reported herein and the Bowen's mechanism is analyzed.
Gilra, D. P.↗
A comparison of the C III, O V, F VI, and Ne VII Delta n = 0 (2-2) line emissions from a laboratory plasma with theoretical predictions and astrophysical observations
Spectra of the Delta n = 0 (2-2) transitions of Be I-like ions, C III, O V, F VI, and Ne VII emitted from the TEXT tokamak, were measured with photometrically calibrated instrumentation and compared to the predictions of several models which differ in their treatment of electron impact excitation, using either the distorted wave or R-matrix approach. It was found that the ions from C III to Ne VII were located near the edge of the plasma, at densities between 10 to the 12th and 13th/cu cm. The experimental line ratios were compared with several sets of computations. Agreement is obtained between the experimental data and computations by using the R-matrix technique. This leads to the conclusion that the effect resonances must be included in collision strength calculations, particularly at low nuclear charge. The results show that the line ratios studied may be used with confidence as electron density diagnostics for laboratory or astrophysical plasmas.
Finkenthal, M.↗
An investigation of the solar cycle response of odd-nitrogen in the thermosphere
This annual report covers the first year of funding for the study of the solar cycle variations of odd-nitrogen (N((sup 2)D), N((sup 4)S), NO) in the Earth's thermosphere. The study uses the extensive data base generated by the Atmosphere Explorer (AE) satellites, and the Solar Mesosphere Explorer Satellite. The AE data are being used, for the first time, to define the solar variability effect on the odd-nitrogen species through analysis of the emissions at 520 nano-m from N((sup 2)D) and the emission from O(+)((sup 2)P). Additional AE neutral and ion density data are used to help define and quantify the physical processes controlling the variations. The results from the airglow study will be used in the next two years of this study to explain the solar cycle changes in NO measured by the Solar Mesosphere Explorer.
Rusch, David W.↗
Harmonizing Food Systems Emissions Accounting for More Effective Climate Action
Food systems—encompassing activities in food production, land-use change, supply chains and waste management—contribute significantly to climate change. Recent estimates indicate that food systems produce over 30% of annual anthropogenic greenhouse gas (GHG) emissions (about 20% of CO 2 , 50% of CH 4 , and 75% of N 2 O), with the Intergovernmental Panel on Climate Change (IPCC) estimating a notably broad range of 23%–42% of global GHG emissions. This paper synthesizes current research on the contributions of food systems to climate change, highlights challenges in quantifying their impact and proposes a harmonized accounting framework for more effective climate action. We recommend that an expert committee aligned with the IPCC develop guidance for food systems emissions accounting in four key areas, including: (1) defining system boundaries and nomenclature; (2) developing protocols to allocate broader sectoral emissions to food systems; (3) prioritizing critical areas for research into activity data and emissions factors; and (4) developing a balanced framework for evaluating the impact of mitigation interventions in light of other food systems imperatives. The committee should be integrated into two key international policy processes—the United Nations Framework Convention on Climate Change and the United Nations Food Systems Summit—to support coordinated action towards global net-zero goals. Guidance from the committee could significantly improve the ability of governments, companies, and researchers to estimate, report, monitor and ultimately reduce the climate impacts of food systems.
GHG accounting↗
Source of O mode radio emissions from the dayside of Uranus
During the inbound trajectory toward Uranus, the Planetary Radio Astronomy instrument on Voyager 2 observed narrow-band smooth (n-smooth) emission at frequencies centered near 60 kHz and O-mode emission (the dayside source) in a frequency range narrowly confined around 160 kHz. Assuming empirical models of the plasma density for the dayside magnetosphere of Uranus, and using cold plasma theory together with observational constraints, ray-tracing calculations are performed to determine the source location of the O-mode emission. The dayside source appears to originate along magnetic field lines with a footprint near the north magnetic pole. Sources of nightside high-frequency broadband smooth (b-smooth) emission observed by Voyager after encounter are believed to exist near the conjugate footprint of these same field lines. This would indicate that the particle population supplying the free energy source has energies at least as high as a few keV.
Menietti, J. D.↗
RADIATIVE ENERGY TRANSFER ON ENTRY INTO MARS AND VENUSQUARTERLY REPORT NO. 4
The emissivity of carbon dioxide in the 2.7 4 µ region has been measured at temperatures from 2000°K to 3500°K, for optical densities less than 5 atm-cm. The high temperatures were obtained by passing a shock wave through the test gas. A total gas pressure of one atm was maintained by varying the carbon dioxide concentration in an inert gas. Emissivities obtained from absorption and emission measurements are in agreement. results are compared to an approximate method for calculating emissivity, The which considers the molecular population concentrated in a single band whose center is temperature dependent. A comparison with previous results suggests that this single band model will overestimate the peak and underestimate the width of the observed values. The observed and calculated emissivities are in agreement if the intensities of the (n 1 +1,n 2 , n 3 + 1 → n 1 , n 2 , n 3 ) and (n 1 ,n 2 +2, n 3 + 1 → n 1 , n 2 , n 3 ) transitions are assumed proportional to (n 1 +1) (n 3 +1) and (n 2 +1)(n 3 +1)/2. The use of this single band model which was originally intended to provide a rough prediction of emissivity, indicates that the use of the appropriate terms of the electric dipole expansion is satisfactory for the (n 1 +1,n 2 , n 3 + 1 → n 1 , n 2 , n 3 ) transition, but is not for (n 1 ,n 2 +2, n 3 + 1 → n 1 , n 2 , n 3 ) transition.
radiative heat transfer↗
Narrow circumstellar emission lines in SN 1987A
Low and high dispersion short wavelength prime (SWP) spectra of SN 1987A show that the supernova's progenitor was in a post red giant branch stage of evolution at the time of its demise in February 1987. The development of narrow high temperature emission lines of N 5, N 4, N 3, C 3, He 2 and O 3 were followed since May 1987. Observations through April 1990 are presented. The lines are interpreted as arising in a low density gas surrounding the supernova which was photoionized by the extreme UV pulse at shock breakout. In this picture, their temporal evolution is determined primarily by light travel time effects and recombination. Comparison of models of circumstellar environment with the International Ultraviolet Explorer (IUE) observations are discussed.
Sonneborn, George↗
Inland Water Greenhouse Gas Budgets for RECCAP2: 2. Regionalization and Homogenization of Estimates
Inland waters are important emitters of the greenhouse gasses (GHGs) carbon dioxide (CO 2 ), methane (CH 4 ), and nitrous oxide (N 2 O) to the atmosphere. In the framework of the 2 nd phase of the REgional Carbon Cycle Assessment and Processes (RECCAP-2) initiative, we synthesize existing estimates of GHG emissions from streams, rivers, lakes and reservoirs, and homogenize them with regard to underlying global maps of water surface area distribution and the effects of seasonal ice cover. We then produce regionalized estimates of GHG emissions over 10 extensive land regions. According to our synthesis, inland water GHG emissions have a global warming potential of an equivalent emission of 13.5 (9.9-20.1) and 8.3 (5.7-12.7) Pg CO 2 -eq. yr -1 at a 20 and 100 year horizon (GWP 20 and GWP 100 ), respectively. Contributions of CO 2 dominate GWP100, with rivers being the largest emitter. For GWP 20 , lakes and rivers are equally important emitters, and the warming potential of CH4 is more important than that of CO2. Contributions from N 2 O are about two orders of magnitude lower. Normalized to the area of RECCAP-2 regions, S-America and SE-Asia show the highest emission rates, dominated by riverine CO 2 emissions.
Ronny Lauerwald↗
Impact of low-temperature plasmas on Deinococcus radiodurans and biomolecules
The effects of cold plasma on Deinococcus radiodurans, plasmid DNA, and model proteins were assessed using microbiological, spectrometric, and biochemical techniques. In low power O(2) plasma (approximately 25 W, approximately 45 mTorr, 90 min), D. radiodurans, a radiation-resistant bacterium, showed a 99.999% reduction in bioburden. In higher power O(2) plasma (100 W and 500 mTorr), the reduction rate increased about 10-fold and observation by atomic force microscopy showed significant damage to the cell. Damage to cellular lipids, proteins, and chromosome was indicated by losses of infrared spectroscopic peaks at 2930, 1651, 1538, and 1245 cm(-1), respectively. In vitro experiments show that O(2) plasmas induce DNA strand scissions and cross-linking as well as reduction of enzyme activity. The observed degradation and removal of biomolecules was power-dependent. Exposures to 200 W at 500 mTorr removed biomolecules to below detection limits in 60 s. Emission spectroscopy indicated that D. radiodurans cells were volatilized into CO(2), CO, N(2), and H(2)O, confirming that these plasmas were removing complex biological matter from surfaces. A CO(2) plasma was not as effective as the O(2) plasma, indicating the importance of plasma composition and the dominant role of chemical degradation. Together, these findings have implications for NASA planetary protection schemes and for the contamination of Mars.
Evaluation Studies↗
Low redshift Lyman alpha absorption lines and the dark matter halos of disk galaxies
Recent observations using the Hubble Space Telescope of the z = 0.156 QSO 3C 273 have discovered a surprisingly large number of Ly-alpha absorption lines. In particular, Morris et al. found 9 certain and 7 possible Ly-alpha lines with equivalent widths above 25 mA. This is much larger (by a factor of 5-10) than the number expected from extrapolation of the high-redshift behavior of the Ly-alpha forest. Within the context of pressure-confined models for the Ly-alpha clouds, this behavior can be understood if the ionizing background declines sharply between z is approximately 2 and z is approximately 0. However, this requires that the ionizing photon flux drop as rapidly as the QSO volume emissivity; moreover, the absorbers must have a space density n(sub O) is approximately 2.6(N/10)h/((D/100 kpc)(sup 2)) Mpc(sup -3) where D is the present-day diameter of the absorbers. It is somewhat surprising that such necessarily fragile objects could have survived in such numbers to the present day. It is shown that it is plausible that the atomic hydrogen extents of spiral and irregular galaxies are large enough to produce the observed number of Ly-alpha absorption lines toward 3C 273, and that the neutral column densities and doppler b-values expected under these conditions fall in the range found by Morris et al. (1991).
Maloney, Philip↗
Elemental Abundances in NGC 3516
We present Reflection Grating Spectrometer data from an XMM-Newton observation of the Seyfert 1 galaxy NGC 3516, taken while the continuum source was in an extremely low flux state. This observation offers a rare opportunity for a detailed study of emission from a Seyfert 1 galaxy as these are usually dominated by high nuclear continuum levels and heavy absorption. The spectrum shows numerous narrow emission lines (FWHM approximately less than 1300 kilometers per second) in the 0.3 - 2 keV range, including the H-like lines of C, N, and O and the He-like lines of N, O and Ne. The emission-line ratios and the narrow width of the radiative recombination continuum of CVI indicate that the gas is photoionized and of fairly low temperature (kT approximately less than 0.01 keV). The availability of emission lines from different elements for two iso-electronic sequences allows us to constrain the element abundances. These data show that the N lines are far stronger than would be expected from gas of solar abundances. Based on our photoionization models we find that nitrogen is overabundant in the central regions of the galaxy, compared to carbon, oxygen and neon by at least a factor of 2.5. We suggest that this is the result of secondary production of nitrogen in intermediate mass stars, and indicative of the history of star formation in NGC 3516.
Turner, T. J.↗
The Evolution of Disks and Winds in Dwarf Nova Outbursts - FUSE
This project was a project to study the FUV spectra of two proto-typical dwarf novae, U Gem and SS Cygni, through an outburst cycle. The luminosity of the boundary layer in the two systems, as evidenced by earlier EUVE observations, is different in the two systems. Our intensive study of the two systems was intended to (1) probe the ionization and kinematic structure of the wind as a function of system brightness, (2) isolate the contributions of the disk to the FUV spectra, and (3) examine physical conditions and abundances of material just being accreted onto the disk from the secondary. The U Gem and SS Cyg observations took place in March and October 2000, respectively. The data obtained with FUSE was of excellent quality. Analysis of the both observations is now essentially complete, although some modeling of the SS Cyg spectra is ongoing, as we complete an ApJ manuscript on this object. Our main results for U Gem are as follows: The plateau spectra have continuum shapes and fluxes that are approximated by steady state accretion disk model spectra with an accretion rate 7x10(exp 9) Msolar/yr. The spectra also show numerous absorption lines of H I, He II, and 2-5 times ionized transitions of C, N, O, P, S, and Si. There are no emission features in the spectra, with the possible exception of a weak feature on the red wing of the 0 VI doublet. The absorption lines are narrow (FWHM approx. 50 km/s), too narrow to arise from the disk photosphere, and at low velocities (less than or equal to 700 km/s). The S VI and O VI doublets are optically thick. The absorption lines in the plateau spectra show orbital variability: in spectra obtained at orbital phases between 0.53 and 0.79, low-ionization absorption lines appear and the central depths of the preexisting lines increase. The increase in line absorption occurs at the same orbital phases as previously observed EUV and X-ray light-curve dips. If the absorbing material is in (near-) Keplerian rotation around the disk, it must be located at large disk radii. The final observation occurred when U Gem was about 2 mag from optical quiescence. The spectra are dominated by emission from an approx. 43,000 K, metal-enriched white dwarf (WD). The inferred radius of the WD is 4.95x10(exp 8) cm, close to that observed in quiescence. Allowing for a hot heated region on the surface of the WD improves the fit to the spectrum at short (less than 960 A) wavelengths. Our main results for SS Cyg are as follows: The first two of four observations of SS Cyg show disk dominated spectra with accretion rates of order 10(exp -8) Msolar/yr. Except for narrow interstellar features (atomic and molecular H), the lines are all broad consistent with a disk or wind origin. The O VI line in the spectra is mostly of wind origin as detailed modeling with our Monte Carlo code (developed in part using funds from this project) show. The continua from spectra in observations 3 and 4, observed during the decline phase, are not well fit with steady-state disks, and show considerable resemblance to quiescent spectra obtained with HUT. The most probable interpretation for the emission features seen in the spectrum in the last two observations is that they arise from a photo-illuminated choronosphere above the disk, rather than a wind.
Long, Knox↗
Analysis of EUV limb brightening observations from ATM. II - Influence of spicules
A comparison of limb brightening measurements with theoretical limb brightening curves calculated for simple atmospheric models indicates that a significant fraction of the EUV emission from lines formed in the transition layer comes from spicules. We find that spicules contribute about 20% of the total quiet sun intensity for lines of the C II, C III, N III, and O VI ions. The uncertainty in the magnitude of the percentage is about a factor of 2. The EUV-emission scale heights above the limb are consistent with the assumption that the variation with height of the number of EUV-emitting spicules is the same as for H-alpha-emitting spicules. Optical depths derived for the C II 1335 A and C III 977 A lines yield estimates for the pressure in the transition layer that are in good agreement with pressures derived under the assumption that the transition layer is in pressure equilibrium with the chromosphere and corona.
Withbroe, G. L.↗
Atmospheric Formaldehyde Trend and Its Source Attributions in the Recent Decades
Formaldehyde (CH 2 O) is one of the most important reactive trace gases in the atmosphere with an important role in tropospheric chemistry and in the control of surface air quality. Sources of CH 2 O includes direct emissions and in situ production from the oxidation of volatile organic compounds (VOCs). In this study, we investigate spatial-temporal variations in atmospheric CH 2 O and how changes in CH 2 O couple with tropospheric ozone variability during the past two decades using recently available retrievals from the Ozone Monitoring Instrument (OMI) aboard NASA’s Aura satellite and the RefD1 simulation from the NASA Goddard Earth Observing System Chemistry Climate Model (GEOSCCM). Our initial analysis provides evidence of significant increases in atmospheric CH 2 O concentrations over several of the world’s major anthropogenic regions, including China, India, and the Middle East, and several biomass burning regions, including South America, southern Africa, boreal regions and Indonesia. We furthermore will identify regional source contributions to CH 2 O trends, including anthropogenic VOCs emissions, biogenic isoprene emissions and open fires. In particular, we will focus on anthropogenic emission regions to examine the role of changing anthropogenic VOC emissions on CH 2 O abundance.
Atmospheric Formaldehyde↗