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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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6 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2002

Synthesis and Characterization of the First Liquid Single Source Precursors for the Deposition of Ternary Chalcopyrite (CuInS2) Thin Film Materials

Molecular engineering of ternary single source precursors based on the [{PBu3}2Cu(SR')2In(SR')2] architecture have afforded the first liquid CIS ternary single source precursors (when R = Et, n-Pr), which are suitable for low temperature deposition (< 350 C). Thermogravimetric analyses (TGA) and modulated-differential scanning calorimetry (DSC) confirm their liquid phase and reduced stability. X-ray diffraction studies, energy dispersive analyzer (EDS), and scanning electron microscopy (SEM) support the formation of the single-phase chalcopyrite CuInS2 at low temperatures.

Banger, Kulbinder K.↗
DOE OSTI2020

Materials Data on PrN by Materials Project

PrN is Halite, Rock Salt structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Pr3+ is bonded to six equivalent N3- atoms to form a mixture of edge and corner-sharing PrN6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Pr–N bond lengths are 2.61 Å. N3- is bonded to six equivalent Pr3+ atoms to form a mixture of edge and corner-sharing NPr6 octahedra. The corner-sharing octahedral tilt angles are 0°.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on PrN by Materials Project

PrN crystallizes in the tetragonal P4/nmm space group. The structure is two-dimensional and consists of one PrN sheet oriented in the (0, 0, 1) direction. Pr3+ is bonded to four equivalent N3- atoms to form a mixture of distorted edge and corner-sharing PrN4 trigonal pyramids. All Pr–N bond lengths are 2.42 Å. N3- is bonded to four equivalent Pr3+ atoms to form a mixture of distorted edge and corner-sharing NPr4 trigonal pyramids.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on PrN by Materials Project

PrN is Zincblende, Sphalerite structured and crystallizes in the cubic F-43m space group. The structure is three-dimensional. Pr3+ is bonded to four equivalent N3- atoms to form corner-sharing PrN4 tetrahedra. All Pr–N bond lengths are 2.41 Å. N3- is bonded to four equivalent Pr3+ atoms to form corner-sharing NPr4 tetrahedra.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on PrN by Materials Project

PrN is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Pr3+ is bonded in a body-centered cubic geometry to eight equivalent N3- atoms. All Pr–N bond lengths are 2.74 Å. N3- is bonded in a body-centered cubic geometry to eight equivalent Pr3+ atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on PrN by Materials Project

PrN is Tungsten Carbide structured and crystallizes in the hexagonal P-6m2 space group. The structure is three-dimensional. Pr3+ is bonded to six equivalent N3- atoms to form a mixture of distorted edge, corner, and face-sharing PrN6 pentagonal pyramids. All Pr–N bond lengths are 2.60 Å. N3- is bonded to six equivalent Pr3+ atoms to form a mixture of distorted edge, corner, and face-sharing NPr6 pentagonal pyramids.

36 MATERIALS SCIENCE↗