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NASA NTRS2012

Photoacoustic Optical Properties at UV, VIS, and near IR Wavelengths for Laboratory Generated and Winter Time Ambient Urban Aerosols

We present the laboratory and ambient photoacoustic (PA) measurement of aerosol light absorption coefficients at ultraviolet wavelength (i.e., 355 nm) and compare with measurements at 405, 532, 870, and 1047 nm. Simultaneous measurements of aerosol light scattering coefficients were achieved by the integrating reciprocal nephelometer within the PA's acoustic resonator. Absorption and scattering measurements were carried out for various laboratory generated aerosols, including salt, incense, and kerosene soot to evaluate the instrument calibration and gain insight on the spectral dependence of aerosol light absorption and scattering. Ambient measurements were obtained in Reno, Nevada, between 18 December 2009 and 18 January 2010. The measurement period included days with and without strong ground level temperature inversions, corresponding to highly polluted (freshly emitted aerosols) and relatively clean (aged aerosols) conditions. Particulate matter (PM) concentrations were measured and analyzed with other tracers of traffic emissions. The temperature inversion episodes caused very high concentration of PM (sub 2.5) and PM( sub 10) (particulate matter with aerodynamic diameters less than 2.5 micrometers and 10 micrometers, respectively) and gaseous pollutants: carbon monoxide (CO), nitric oxide (NO), and nitrogen dioxide (NO2). The diurnal change of absorption and scattering coefficients during the polluted (inversion) days increased approximately by a factor of two for all wavelengths compared to the clean days. The spectral variation in aerosol absorption coefficients indicated a significant amount of absorbing aerosol from traffic emissions and residential wood burning. The analysis of single scattering albedo (SSA), Angstrom exponent of absorption (AEA), and Angstrom exponent of scattering (AES) for clean and polluted days provides evidences that the aerosol aging and coating process is suppressed by strong temperature inversion under cloudy conditions. In general, measured UV absorption coefficients were found to be much larger for biomass burning aerosol than for typical ambient aerosols.

absorptivity↗

NASA NTRS1990

An efficient and accurate technique to compute the absorption, emission, and transmission of radiation by the Martian atmosphere

CO2 comprises 95 pct. of the composition of the Martian atmosphere. However, the Martian atmosphere also has a high aerosol content. Dust particles vary from less than 0.2 to greater than 3.0. CO2 is an active absorber and emitter in near IR and IR wavelengths; the near IR absorption bands of CO2 provide significant heating of the atmosphere, and the 15 micron band provides rapid cooling. Including both CO2 and aerosol radiative transfer simultaneously in a model is difficult. Aerosol radiative transfer requires a multiple scattering code, while CO2 radiative transfer must deal with complex wavelength structure. As an alternative to the pure atmosphere treatment in most models which causes inaccuracies, a treatment was developed called the exponential sum or k distribution approximation. The chief advantage of the exponential sum approach is that the integration over k space of f(k) can be computed more quickly than the integration of k sub upsilon over frequency. The exponential sum approach is superior to the photon path distribution and emissivity techniques for dusty conditions. This study was the first application of the exponential sum approach to Martian conditions.

Lindner, Bernhard Lee↗

NASA NTRS2006

The Effects of Space Weathering at UV Wavelengths: S-Class Asteroids

We present evidence that space weathering manifests itself at near-UV wavelengths as a bluing of the spectrum, in contrast with the spectral reddening that has been seen at visible-near-IR wavelengths. Furthermore, the effects of space weathering at UV wavelengths tend to appear with less weathering than do the longer wavelength effects, suggesting that the UV wavelength range is a more sensitive indicator of weathering, and thus age. We report results from analysis of existing near-UV (approx.220-350 nm) measurements of S-type asteroids from the International Ultraviolet Explorer and the Hubble Space Telescope and comparisons with laboratory measurements of meteorites to support this hypothesis. Composite spectra of S asteroids are produced by combining UV spacecraft data with ground-based longer wavelength data. At visible-near-IR wavelengths, S-type asteroids are generally spectrally redder (and darker) than ordinary chondrite meteorites, whereas the opposite is generally true at near-UV wavelengths. Similarly, laboratory measurements of lunar samples show that lunar soils (presumably more weathered) are spectrally redder at longer wavelengths, and spectrally bluer at near-UV wavelengths, than less weathered crushed lunar rocks. The UV spectral bluing may be a result of the addition of nanophase iron to the regolith through the weathering process. The UV bluing is most prominent in the 300-400 nm range, where the strong UV absorption edge is degraded with weathering.

Moon↗

NASA NTRS2001

Power enhanced frequency conversion system

A frequency conversion system includes at least one source providing a first near-IR wavelength output including a gain medium for providing high power amplification, such as double clad fiber amplifier, a double clad fiber laser or a semiconductor tapered amplifier to enhance the power output level of the near-IR wavelength output. The NFM device may be a difference frequency mixing (DFM) device or an optical parametric oscillation (OPO) device. Pump powers are gain enhanced by the addition of a rare earth amplifier or oscillator, or a Ra-man/Brillouin amplifier or oscillator between the high power source and the NFM device.

Sanders, Steven↗

NASA NTRS2012

NPP VIIRS and Aqua MODIS RSB Comparison Using Observations from Simultaneous Nadir Overpasses (SNO)

Suomi NPP (National Polar-orbiting Partnership) satellite (http://npp.gsfc.nasa.gov/viirs.html) began to daily collect global data following its successful launch on October 28, 2011. The Visible Infrared Imaging Radiometer Suite (VIIRS) is a key NPP sensor. Similar to the design of the OLS, SeaWiFS and MODIS instruments, VIIRS has on-board calibration components including a solar diffuser (SD) and a solar diffuser stability monitor (SDSM) for the reflective solar bands (RSB), a V-groove blackbody for the thermal emissive bands (TEB), and a space view (SV) port for background subtraction. Immediately after the VIIRS nadir door s opening on November 21, 2011, anomalously large degradation in the SD response was identified in the near-IR wavelength region, which was unexpected as decreases in the SD reflectance usually occur gradually in the blue (~0.4 m) wavelength region based on past experience. In this study, we use a well-calibrated Aqua MODIS as reference to track and evaluate VIIRS RSB stability and performance. Reflectances observed by both sensors from simultaneous nadir overpasses (SNO) are used to determine VIIRS to MODIS reflectance ratios for their spectral matching bands. Results of this study provide an immediate post-launch assessment, independent validation of the anomalous degradation observed in SD measurements at near-IR wavelengths and initial analysis of calibration stability and consistency.

Xiong, X.↗

NASA NTRS2001

Frequency conversion system

Laser diode pumped mid-IR wavelength sources include at least one high power, near-IR wavelength, injection and/or sources wherein one or both of such sources may be tunable providing a pump wave output beam to a quasi-phase matched (QPM) nonlinear frequency mixing (NFM) device. The NFM device may be a difference frequency mixing (DFM) device or an optical parametric oscillation (OPO) device. Wavelength tuning of at least one of the sources advantageously provides the ability for optimizing pump or injection wavelengths to match the QPM properties of the NFM device enabling a broad range of mid-IR wavelength selectivity. Also, pump powers are gain enhanced by the addition of a rare earth amplifier or oscillator, or a Raman/Brillouin amplifier or oscillator between the high power source and the NFM device. Further, polarization conversion using Raman or Brillouin wavelength shifting is provided to optimize frequency conversion efficiency in the NFM device.

Sanders, Steven↗

NASA NTRS1999

High power pumped mid-IR wavelength systems using nonlinear frequency mixing (NFM) devices

Laser diode pumped mid-IR wavelength systems include at least one high power, near-IR wavelength, injection and/or sources wherein one or both of such sources may be tunable providing a pump wave output beam to a quasi-phase matched (QPM) nonlinear frequency mixing (NFM) device. The NFM device may be a difference frequency mixing (DFM) device or an optical parametric oscillation (OPO) device. Wavelength tuning of at least one of the sources advantageously provides the ability for optimizing pump or injection wavelengths to match the QPM properties of the NFM device enabling a broad range of mid-IR wavelength selectivity. Also, pump powers are gain enhanced by the addition of a rare earth amplifier or oscillator, or a Raman/Brillouin amplifier or oscillator between the high power source and the NFM device. Further, polarization conversion using Raman or Brillouin wavelength shifting is provided to optimize frequency conversion efficiency in the NFM device.

Sanders, Steven↗

NASA NTRS2001

High power pumped MID-IR wavelength devices using nonlinear frequency mixing (NFM)

Sanders, Steven↗

NASA NTRS2005

Iapetus and Phoebe as Measured by the Cassini UVIS

The bizarre appearance of Iapetus has long intrigued researchers of this Saturnian moon. The leading hemisphere is very dark and reddish in color at visible-near-IR wavelengths. In contrast, the trailing hemisphere is relatively bright and its near-IR spectrum is dominated by water ice. The severe hemispherical brightness dichotomy has been explained by both endogenic and exogenic models. The primary endogenic model involves eruption of dark material onto the leading hemisphere from the interior of Iapetus. Exogenic models include exposure of dark underlying material by micrometeorite bombardment, contamination of Iapetus leading hemisphere by Titan tholin material, and the coating of the leading hemisphere by Phoebe dust. It has been shown that the dark material on Iapetus leading hemisphere is redder in color at visible wavelengths than Phoebe, which is spectrally gray at visible wavelengths. An additional exogenic model involves the coating of both Iapetus leading hemisphere and Hyperion with material from small retrograde satellites, which are reddish in color at visible wavelengths. We present the first FUV spectra of Iapetus and Phoebe to investigate whether the UV wavelength range can contribute to solving the puzzle of Iapetus.

Hendrix, A. R.↗

NASA NTRS1986

Polarization photometer to measure bidirectional reflectance factor R(55 deg, 0 deg, 55 deg, 180 deg) of leaves

A polarization photometer has been developed for rapidly determining the bidirectional, polarized, and diffuse light-scattering properties of individual leavs illuminated and measured 'in vivo' at an angle of 55 deg (approximately Brewster's angle) in six wavelength bands in the visible and near-IR wavelength regions. The optical performance and data quality of the system are evaluated to estimate the magnitude of the variation in the data attributable to the instrument system and to measurement procedures. The potential to discriminate between three species of oak is demonstrated using data acquired by the polarization photometer. The instrument is being used to increase understanding of the radiation transfer process in plant canopies and specifically to determine how agronomic information of the physical and chemical processes in leaves, plants, and plant canopies is expressed in these light-scattering properties.

Vanderbilt, V. C.↗

NASA NTRS1983

Limb darkening of meteorites and asteroids

The limb darkening at small phase angles of several materials believed to be analogs of those found on the surfaces of asteroids and other related objects such as Phobos and Deimos is investigated. The materials include three carbonaceous chondrites, one ordinary chondrite, and a steel powder. The wavelength dependence of the limb darkening at visible and near-IR wavelengths is examined. The effects of surface roughness on limb-darkening parameters, and hence on measured geometric albedos, are estimated, and the implications for spherical and ellipsoidal asteroids are discussed.

French, L. M.↗

NASA NTRS2020

The Hubble Space Telescope's Near-UV and Optical Transmission Spectrum of Earth as an Exoplanet

We observed the 2019 January total lunar eclipse with the Hubble Space Telescope’s STIS spectrograph to obtain the first near-UV (1700–3200 Å) observation of Earth as a transiting exoplanet. The observatories and instruments that will be able to perform transmission spectroscopy of exo-Earths are beginning to be planned, and characterizing the transmission spectrum of Earth is vital to ensuring that key spectral features (e.g., ozone, or O3) are appropriately captured in mission concept studies. O3 is photochemically produced from O2, a product of the dominant metabolism on Earth today, and it will be sought in future observations as critical evidence for life on exoplanets. Ground-based observations of lunar eclipses have provided the Earth’s transmission spectrum at optical and near-IR wavelengths, but the strongest O3 signatures are in the near-UV. We describe the observations and methods used to extract a transmission spectrum from Hubble lunar eclipse spectra, and identify spectral features of O3 and Rayleigh scattering in the 3000–5500 Å region in Earth’s transmission spectrum by comparing to Earth models that include refraction effects in the terrestrial atmosphere during a lunar eclipse. Our near-UV spectra are featureless, a consequence of missing the narrow time span during the eclipse when near-UV sunlight is not completely attenuated through Earth’s atmosphere due to extremely strong O3 absorption and when sunlight is transmitted to the lunar surface at altitudes where it passes through the O3 layer rather than above it.

Allison Youngblood↗

NASA NTRS2000

Empirical Constraints on the Cosmic Infrared Background Using Near-Infrared DIRBE Data

Empirical models for emission from stars and the ISM are subtracted from the zodiacal-light-subtracted DIRBE 3.5 pm emission. Because the models are contaminated by unknown levels of the CM at other near-IR wavelength, the residual is not simply the 3.5 Jim Cosmic IR Background, but a linear combination of the background levels at several wavelengths. In spite of this, the residual can be used to place limits on the near-IR CIB intensity if its spectral shape is assumed. Additionally, the residual level is shown to be more nearly isotropic than previous estimates over a much larger fraction of the sky. An excellent correlation of near-IR and far-IR ISM emission provides evidence of the high accuracy of the brighter stellar emission model. The possibility that any residual emission is zodiacal in nature is discussed.

Arendt, Richard G.↗

NASA NTRS2000

The Dust Content and Opacity of Actively Star-Forming Galaxies

We present far-infrared (FIR) photometry at 150 and 205 micron(s) of eight low-redshift starburst galaxies obtained with the Infrared Space Observatory (ISO) ISOPHOT. Five of the eight galaxies are detected in both wave bands, and these data are used, in conjunction with IRAS archival photometry, to model the dust emission at lambda approximately greater than 40 microns. The FIR spectral energy distributions (SEDs) are best fitted by a combination of two modified Planck functions, with T approx. 40 - 55 K (warm dust) and T approx. 20-23 K (cool dust) and with a dust emissivity index epsilon = 2. The cool dust can be a major contributor to the FIR emission of starburst galaxies, representing up to 60% of the total flux. This component is heated not only by the general interstellar radiation field, but also by the starburst itself. The cool dust mass is up to approx. 150 times larger than the warm dust mass, bringing the gas-to-dust ratios of the starbursts in our sample close to Milky Way values, once resealed for the appropriate metallicity. The ratio between the total dust FIR emission in the range 1-1000 microns and the IRAS FIR emission in the range 40 - 120 microns is approx. 1.75, with small variations from galaxy to galaxy. This ratio is about 40% larger than previously inferred from data at millimeter wavelengths. Although the galaxies in our sample are generally classified as "UV bright," for four of them the UV energy emerging shortward of 0.2 microns is less than 15% of the FIR energy. On average, about 30% of the bolometric flux is coming out in the UV-to-near-IR wavelength range; the rest is emitted in the FIR. Energy balance calculations show that the FIR emission predicted by the dust reddening of the UV-to-near-IR stellar emission is within a factor of approx. 2 of the observed value in individual galaxies and within 20% when averaged over a large sample. If our sample of local starbursts is representative of high-redshift (z approx. greater than 1), UV - bright star-forming galaxies, these galaxies' FIR emission will be generally undetected in submillimeter surveys, unless: (1) their bolometric luminosity is comparable to or larger than that of ultraluminous FIR galaxies and (2) their FIR SED contains a cool dust component.

Calzetti, Daniela↗

NASA NTRS2002

Remote sensing of planetary properties and biosignatures on extrasolar terrestrial planets

The major goals of NASA's Terrestrial Planet Finder (TPF) and the European Space Agency's Darwin missions are to detect terrestrial-sized extrasolar planets directly and to seek spectroscopic evidence of habitable conditions and life. Here we recommend wavelength ranges and spectral features for these missions. We assess known spectroscopic molecular band features of Earth, Venus, and Mars in the context of putative extrasolar analogs. The preferred wavelength ranges are 7-25 microns in the mid-IR and 0.5 to approximately 1.1 microns in the visible to near-IR. Detection of O2 or its photolytic product O3 merits highest priority. Liquid H2O is not a bioindicator, but it is considered essential to life. Substantial CO2 indicates an atmosphere and oxidation state typical of a terrestrial planet. Abundant CH4 might require a biological source, yet abundant CH4 also can arise from a crust and upper mantle more reduced than that of Earth. The range of characteristics of extrasolar rocky planets might far exceed that of the Solar System. Planetary size and mass are very important indicators of habitability and can be estimated in the mid-IR and potentially also in the visible to near-IR. Additional spectroscopic features merit study, for example, features created by other biosignature compounds in the atmosphere or on the surface and features due to Rayleigh scattering. In summary, we find that both the mid-IR and the visible to near-IR wavelength ranges offer valuable information regarding biosignatures and planetary properties; therefore both merit serious scientific consideration for TPF and Darwin.

Planets↗

NASA NTRS1992

Identification of a far-red reflectance response to ectomycorrhizae in slash pine

Spectral reflectances were measured for the canopies of Pinus elliottii seedlings that were inoculated versus noninoculated with the ectomycorrhizal fungus Pisolithus tinctorius. Reflectances of the less vigorous, noninoculated seedlings increased substantially at visible and near-IR wavelengths compared to the more vigorous, inoculated seedlings. An algorithm was developed to indicate the spectral regions in which reflectance was most sensitive to ectomycorrhizae. The reflectance curve of the more vigorous seedlings was used as a standard of comparison. The spectral regions defined by this algorithm are denoted as regions of maximum reflectance sensitivity. Far-red and near-IR photography filtered to the region of maximum sensitivity (700 nm) were used to enable visualization of a 'blue shift' reflectance response to decreased vigor in the noninoculated seedlings in response to these differences of mycorrhizal development.

Cibula, W. G.↗

NASA NTRS1981

Sunlight absorption by aerosols in Jupiter's upper atmosphere

The amount of sunlight deposited in the Jovian upper atmosphere is estimated from reflectivity measurements at 2400 A by the Voyager 2 Photopolarimeter experiment and at visible and near-IR wavelengths observed by Pioneer 10 and ground-based instruments. Zero to about one percent of the incident energy is absorbed at altitudes above the 100 mbar level in models with mean values for haze optical depth and single scattering albedo. Several percent of the incident energy could be absorbed, if limiting values are used, and if an additional absorbing layer is incorporated below the high altitude haze in Pioneer models. Maximum absorption occurs at the edge of the polar regions near + or - 65 deg latitude. Most of the absorbed energy is derived from visible and near-IR radiation rather than UV radiation.

West, R. A.↗

NASA NTRS1993

Remote sensing of the earth's surface with an airborne polarized laser

Attention is given to the Airborne Laser Polarization Sensor (ALPS), which makes multispectral radiometric and polarization measurements of the earth's surface using a polarized laser light source. Results from data flights taken over boreal forests in Maine at two wavelengths (1060 and 532 nm) using an Nd:YAG laser source show distinct depolarization signatures for three broadleaf and five coniferous tree species. A statistically significant increase in depolarization is found to correlate with increasing leaf surface roughness for the broadleaf species in the near-IR. The ALPS system 3 employs 12 photomultiplier tube detectors configurable to measure desired parameters such as the total backscatter and the polarization state, including the azimuthal angle and ellipticity, at different UV to near-IR wavelengths simultaneously.

Kalshoven, James E.↗