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Nuclear Data Sheets for A = 129

The experimental nuclear spectroscopic data for known nuclides of mass number 129 (Ag, Cd, In, Sn, Sb, Te, I, Xe, Cs, Ba, La, Ce, Pr, Nd, Pm, Sm) have been evaluated and presented together with adopted properties for levels and γ rays. This evaluation represents a revision of the previous one 18 years ago by Y. Tendow (1996Te01). Extensive new data have become available for many nuclides in the intervening years, although, no data are available for excited states in {sup 129}Pm and {sup 129}Sm, and for {sup 129}Ag and {sup 129}Cd, only limited information is available for the g.s. and isomers. The decay schemes of {sup 129}Ag, {sup 129}Pm and {sup 129}Sm are unknown, and those for {sup 129}Cd, {sup 129}In, {sup 129}Ce, {sup 129}Pr and {sup 129}Nd are incomplete. Many γ rays and extended level schemes have been reported for the ground state and isomer decays of {sup 129}Ba to {sup 129}Cs, yet the adopted set of intensities in this evaluation originate from a brief paper in an annual laboratory report. There remain several unplaced gamma rays, coupled with ambiguity about division of intensities amongst the two activities of {sup 129}Ba with nearly the same half-lives. Isomerism is expected in {sup 129}Pr, but there is no confirmed identification. Low-lying level structure in {sup 129}Nd, including identification of a possible third long-lived isomer in this nuclide, remains uncertain. The spin-parity assignments of (5/2+) for the ground state and (7/2−) for an isomer at 107.6 keV in {sup 129}Ce are assigned based on strong support from systematics and band configurations, yet this result is in contradiction with the quadrupole interaction hyperfine structure measurement which favors 9/2− over 7/2− for the isomer, consequently 7/2+ for the ground state. Direct measurements of spins of ground state and isomer of {sup 129}Ce are needed to settle this issue. Confirmed spins and parities of the ground state and isomer of {sup 129}La are also lacking. Assignments in this work are mainly based on systematics of h{sub 11/2} decoupled structures. A direct measurement of ground state spin of {sup 129}La will also be desirable. Recommended data presented in this work supersede those in previous NDS evaluations of A=129 nuclides published by 1996Te01, 1983Ha46 and 1972Ho55.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Decay studies of {sup 145,147}Er, {sup 146}Ho and {sup 129}Nd

Based on a He-jet apparatus coupled with a tape transport system, Very neutron-deficient isotopes {sup 145,147}Er, {sup 146}Ho, and {sup 129}Nd were identified by p-{gamma}(X) or {gamma}-{gamma}(X) coincidence measurements, and their radioactive decay properties were studied.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Upgrade of the Resonance Ionization Mass Spectrometer for Precise Identification of Failed Fuel in a Fast Reactor

Isotopic analysis of krypton (Kr) and xenon (Xe) by resonance ionization mass spectrometry (RIMS) is an effective tool for identification of failed fuel in fast reactors to achieve their safety operation and high plant availability. Reliability of the failed fuel detection and location (FFDL) system depends on the precise determination of {sup 78}Kr/{sup 80}Kr, {sup 82}Kr/{sup 80}Kr and {sup 126}Xe/{sup 129}Xe isotopic ratios, which is mainly hampered by statistical errors for detection of the corresponding isotopes except {sup 82}Kr generated in large amounts during operation of fast reactors. In this paper, we report on improvements of the laser optical system of our spectrometer to increase the resonance ionization efficiency of Kr and Xe atoms, focusing on (i) utilization of the uniform YAG laser beam to improve the wavelength conversion efficiency of sum frequency generation and (ii) reflection of the ultraviolet light by a concave mirror to increase the photon density. The results indicate that our upgraded resonance ionization mass spectrometer has enough performance for isotopic analysis of Kr and Xe required in the Monju FFDL system.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

NdHO, a novel oxyhydride

A new metal oxyhydride; neodymium oxyhydride, NdHO, has been synthesized from a reactant mixture of metal hydride (CaH{sub 2} or NdH{sub 3}) and neodymium oxide (Nd{sub 2}O{sub 3}). The unit cell dimensions decrease smoothly in the series from LaHO, CeHO, PrHO to NdHO, in line with the lanthanide contraction. The crystal structure of NdHO is described on the basis of Rietveld refinement on neutron powder diffraction data: Space group: P4/nmm (no. 129, D{sub 4h}{sup 7}). Axis lengths: a=7.8480(5) A, c=5.5601(8) A. Volume: V=342.46(6) A{sup 3}. The tetragonal structure is derived from the fluorite structure, showing complete ordering of hydride and oxide ions over the anion sublatttice. The formation of NdHO was further substantiated by Raman spectroscopy. - Graphical Abstract: View of the NdHO structure. Highlights: > CaH{sub 2} or NdH{sub 3} react with Nd{sub 2}O{sub 3} in reducing atmospheres forming a new oxyhydride, NdHO. > NdHO crystalises in tetragonal space group P4/nmm with axes a=b=7.8480(5) A and c=5.5601(8) A. > The structure is similar to the fluorite structure with complete ordering of hydride and oxide ions. > Unit cell dimensions decrease smoothly in the series from LaHO, CeHO, PrHO to NdHO. > The formation of NdHO is substantiated by Raman spectroscopy.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Structure and magnetic properties of the REAuBi{sub 2} (RE=La–Nd, Sm) phases

We present the crystal structures and basic magnetic properties of the REAuBi{sub 2} (RE=La–Nd, Sm) compounds. This isostructural family crystallizes in the tetragonal P4/nmm (no. 129) HfCuSi{sub 2}-type, as determined by single crystal X-ray diffraction. Three distinct substructures are present: an RE layer, a tetrahedral AuBi layer, and a Bi square net layer. Electronic structure calculations indicate that these compounds display bands which cross the Fermi level, derived from both the Bi square net and the covalent AuBi layer. The small size of LaAuBi{sub 2} crystals precluded detailed physical property measurements, whereas large single crystals could be grown for all other phases investigated here. Single crystal measurements of CeAuBi{sub 2}, PrAuBi{sub 2}, and NdAuBi{sub 2} show overall antiferromagnetic ordering and decreasing magnetic anisotropy with decreasing rare earth size. SmAuBi{sub 2} also shows signatures of magnetic ordering. - Graphical abstract: The crystal structures and basic electronic and magnetic properties of the five REAuBi{sub 2} (RE=La–Nd, Sm) phases are presented. These tetragonal structures have alternating layers of AuBi{sub 4} tetrahedra and a Bi square net balanced by RE cations. Measurements performed on single crystals show strong magnetic anisotropy for CeAuBi{sub 2} and PrAuBi{sub 2} and weak anisotropy for NdAuBi{sub 2}. SmAuBi{sub 2} is weakly magnetic. - Highlights: • We present the structures and basic properties of single crystals of the new, tetragonal REAuBi{sub 2} (RE=La–Nd, Sm) phases. • CeAuBi{sub 2}, PrAuBi{sub 2}, NdAuBi{sub 2}, and SmAuBi{sub 2} order magnetically. • CeAuBi{sub 2} and PrAuBi{sub 2} display magnetic anisotropy. • CeAuBi{sub 2} appears analogous to CeAuSb{sub 2} and may be worthy of further study as a potential system for quantum criticality.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗