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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Compatibility Studies of Hydrogen Peroxide and a New Hypergolic Fuel Blend

Several preliminary materials compatibility studies have been conducted to determine the practicality of a new hypergolic fuel system. Hypergolic fuel ignites spontaneously as the oxidizer decomposes and releases energy in the presence of the fuel. The bipropellant system tested consists of high-test hydrogen peroxide (HTP) and a liquid fuel blend consisting of a hydrocarbon fuel, an ignition enhancer and a transition metal catalyst. In order for further testing of the new fuel blend to take place, some basic materials compatibility and HTP decomposition studies must be accomplished. The thermal decomposition rate of HTP was tested using gas evolution and isothermal microcalorimetry (IMC). Materials were analyzed for compatibility with hydrogen peroxide including a study of the affect welding has on stainless steel elemental composition and its relation to HTP decomposition. Compatibility studies of valve materials in the fuel blend were performed to determine the corrosion resistance of the materials.

Baldridge, Jennifer↗

Technology assessment of portable energy RDT and P

Results are presented of a workshop conducted to assess portable energy technology. The results were evaluated and areas for future research were considered. Several research categories were studied: increasing presently available fuel supplies, developing new fuel sources, utilization of new transportation fuels, improving conservation practices, and equitable distribution of fuel supplies. Several research projects were proposed, and work statements were constructed for those considered suitable.

Vanston, J. H., Jr.↗

Nanotechnology Investigated for Future Gelled and Metallized Gelled Fuels

The objective of this research is to create combustion data for gelled and metallized gelled fuels using unique nanometer-sized gellant particles and/or nanometer-sized aluminum particles. Researchers at the NASA Glenn Research Center are formulating the fuels for both gas turbine and pulsed detonation engines. We intend to demonstrate metallized gelled fuel ignition characteristics for pulse detonation engines with JP/aluminum fuel and for gas turbine engines with gelled JP, propane, and methane fuel. The fuels to be created are revolutionary as they will deliver the highest theoretically maximum performance of gelled and metallized gelled fuels. Past combustion work has used micrometer-sized particles, which have limited the combustion performance of gelled and metallized gelled fuels. The new fuel used nanometer-sized aluminum oxide particles, which reduce the losses due to mismatch in the gas and solid phases in the exhaust. Gelled fuels provide higher density, added safety, reduced fuel slosh, reduced leakage, and increased exhaust velocity. Altogether, these benefits reduce the overall size and mass of the vehicle, increasing its flexibility.

Palaszewski, Bryan A.↗

Low cost, lightweight fuel cell elements

New fuel cell elements for use in liquid feed fuel cells are provided. The elements including biplates and endplates are low in cost, light in weight, and allow high efficiency operation. Electrically conductive elements are also a part of the fuel cell elements.

Kindler, Andrew↗

Fuel quality processing study, volume 1

A fuel quality processing study to provide a data base for an intelligent tradeoff between advanced turbine technology and liquid fuel quality, and also, to guide the development of specifications of future synthetic fuels anticipated for use in the time period 1985 to 2000 is given. Four technical performance tests are discussed: on-site pretreating, existing refineries to upgrade fuels, new refineries to upgrade fuels, and data evaluation. The base case refinery is a modern Midwest refinery processing 200,000 BPD of a 60/40 domestic/import petroleum crude mix. The synthetic crudes used for upgrading to marketable products and turbine fuel are shale oil and coal liquids. Of these syncrudes, 50,000 BPD are processed in the existing petroleum refinery, requiring additional process units and reducing petroleum feed, and in a new refinery designed for processing each syncrude to produce gasoline, distillate fuels, resid fuels, and turbine fuel, JPGs and coke. An extensive collection of synfuel properties and upgrading data was prepared for the application of a linear program model to investigate the most economical production slate meeting petroleum product specifications and turbine fuels of various quality grades. Technical and economic projections were developed for 36 scenarios, based on 4 different crude feeds to either modified existing or new refineries operated in 2 different modes to produce 7 differing grades of turbine fuels. A required product selling price of turbine fuel for each processing route was calculated. Procedures and projected economics were developed for on-site treatment of turbine fuel to meet limitations of impurities and emission of pollutants.

Ohara, J. B.↗

New applications for phosphoric acid fuel cells

New applications for phosphoric acid fuel cells were identified and evaluated. Candidates considered included all possibilities except grid connected electric utility applications, on site total energy systems, industrial cogeneration, opportunistic use of waste hydrogen, space and military applications, and applications smaller than 10 kW. Applications identified were screened, with the most promising subjected to technical and economic evaluation using a fuel cell and conventional power system data base developed in the study. The most promising applications appear to be the underground mine locomotive and the railroad locomotive. Also interesting are power for robotic submersibles and Arctic villages. The mine locomotive is particularly attractive since it is expected that the fuel cell could command a very high price and still be competitive with the conventionally used battery system. The railroad locomotive's attractiveness results from the (smaller) premium price which the fuel cell could command over the conventional diesel electric system based on its superior fuel efficiency, and on the large size of this market and the accompanying opportunities for manufacturing economy.

Stickles, R. P.↗

Characterization of a New Hypergolic Fuel Candidate

2-(Dimethylamino)ethylazide was identified by Darren Thompson of the US Army Aviation Missile Command (AMCOM) as a promising candidate to replace hydrazine derivatives in certain hypergolic fuel applications, and as a monopropellant using a heated catalyst bed. The preparation of the material has been scaled up to the pilot plant level, and evaluations of its relevant properties have indicated that it may have broader application than was originally foreseen. Physical, chemical, and hazardous properties are reported in this paper.

Manzara, Tony↗

Characterization of a New Hypergolic Fuel Candidate

2-(Dimethylamino)ethylazide was identified by Darren Thompson of the US Army Aviation Missile Command (AMCOM) as a promising candidate to replace hydrazine derivatives in certain hypergolic fuel applications, and as a monopropellant using a heated catalyst bed. The preparation of the material has been scaled up to the pilot plant level, and evaluations of its relevant properties have indicated that it may have broader application than was originally foreseen. Physical, chemical, and hazards properties are reported in this paper

Manzara, Tony↗

Evaluation of conventional power systems

The technical, economic, and environmental characteristics of (thermal, nonsolar) electric power plants are reviewed. The fuel cycle, from extraction of new fuel to final waste management, is included. Emphasis is placed on the fossil fuel and nuclear technologies.

Smith, K. R.↗

Fuel cell elements with improved water handling capacity

New fuel cell components for use in liquid feed fuel cell systems are provided. The components include biplates and endplates, having a hydrophilic surface and allow high efficiency operation. Conductive elements and a wicking device also form a part of the fuel cell components of the invention.

Kindler, Andrew↗

Fuel Cell/Electrochemical Cell Voltage Monitor

A concept has been developed for a new fuel cell individual-cell-voltage monitor that can be directly connected to a multi-cell fuel cell stack for direct substack power provisioning. It can also provide voltage isolation for applications in high-voltage fuel cell stacks. The technology consists of basic modules, each with an 8- to 16-cell input electrical measurement connection port. For each basic module, a power input connection would be provided for direct connection to a sub-stack of fuel cells in series within the larger stack. This power connection would allow for module power to be available in the range of 9-15 volts DC. The relatively low voltage differences that the module would encounter from the input electrical measurement connection port, coupled with the fact that the module's operating power is supplied by the same substack voltage input (and so will be at similar voltage), provides for elimination of high-commonmode voltage issues within each module. Within each module, there would be options for analog-to-digital conversion and data transfer schemes. Each module would also include a data-output/communication port. Each of these ports would be required to be either non-electrical (e.g., optically isolated) or electrically isolated. This is necessary to account for the fact that the plurality of modules attached to the stack will normally be at a range of voltages approaching the full range of the fuel cell stack operating voltages. A communications/ data bus could interface with the several basic modules. Options have been identified for command inputs from the spacecraft vehicle controller, and for output-status/data feeds to the vehicle.

Vasquez, Arturo↗

Global Energy and Aviation Concerns

Renewable energy sources are usually diffuse and require large facilities. Biofuels work better, are more economical to produce for ground transportation, but sharply increase competition for food croplands. Noble laureate Richard Smalley (deceased-2005) conceptual 20 TWe power generation covers hundreds x hundreds of miles. Combined with Fuller s superconducting power grid system would enable renewable planetary energy. A solar-wind project in Australia will have a 7km diameter collector interfacing with a 1 km tower to extract 200 MW from wind turbines mounted at the base. GE Energy s 3.5MW Wind Turbine is large and placing this in perspective, it is as if one were rotating a Boeing 747-200; the blade diameter is that large. Wind turbines are rapidly gaining popularity in Europe and photovoltaic (PV) is expected to also expand rapidly. It becomes clear that we need (and still have time) to develop new sources of energy. Hf 178 bombarded by X-rays produces Gamma-rays for heating. The reaction stops when the X-rays stop; the half life is about 30 years and seems manageable vs 30 000 years. Water splitting needs to be perused as do ultra fast ultra intense laser applications in terms of fusion and new materials developments including new ways to strip and re-bind hydrogen into fuels. New methods and tools for development are being found in quantum mechanical applications to macro-systems and need to be developed into a set of new tool boxes for development of these new energy sources.

Hendricks, Robert C.↗

Multiphysics Modeling of a Single Channel in a Nuclear Thermal Propulsion Grooved Ring Fuel Element

In the past, fuel rods have been used in nuclear propulsion applications. A new fuel element concept that reduces weight and increases efficiency uses a stack of grooved discs. Each fuel element is a flat disc with a hole on the interior and grooves across the top. Many grooved ring fuel elements for use in nuclear thermal propulsion systems have been modeled, and a single flow channel for each design has been analyzed. For increased efficiency, a fuel element with a higher surface-area-to-volume ratio is ideal. When grooves are shallower, i.e., they have a lower surface area, the results show that the exit temperature is higher. By coupling the physics of turbulence with those of heat transfer, the effects on the cooler gas flowing through the grooves of the thermally excited solid can be predicted. Parametric studies were done to show how a pressure drop across the axial length of the channels will affect the exit temperatures of the gas. Geometric optimization was done to show the behaviors that result from the manipulation of various parameters. Temperature profiles of the solid and gas showed that more structural optimization is needed to produce the desired results. Keywords: Nuclear Thermal Propulsion, Fuel Element, Heat Transfer, Computational Fluid Dynamics, Coupled Physics Computations, Finite Element Analysis

Kim, Tony↗

Commercialization of a Direct Methanol Fuel Cell System

This paper describes a major breakthrough in energy technology developed at the Jet Propulsion Laboratory that can be used in a wide variety of portable, remote, and transportation applications without polluting the environment. The status, performance, and design considerations of the JPL non-polluting, direct methanol, fuel cell system for consumer equipment and transportation applications are reported herein. This new fuel cell technology utilizes the direct oxidation of a 3 percent aqueous liquid methanol solution as the fuel and air (O&sub2;) as the oxidant. The only products are CO&sub2; and water. Therefore, because recharging can be accomplished by refueling with methanol, vehicles can enjoy unlimited range and extended use compared to battery operated devices requiring recharging time and power accessibility.

fuel↗

Mars Ascent Vehicle Hybrid Propulsion Development

Hybrid propulsion is being investigated as a propulsion method for a possible Mars Ascent Vehicle (MAV) application. MAV is part of a proposed larger Mars Sample Return (MSR) campaign plan to bring samples from Mars to earth for examination. The Mars Ascent Vehicle would launch Mars surface samples found and packaged by the Mars 2020 mission to orbit around Mars. This version of hybrid propulsion is based on a wax based solid fuel, called SP7A, and a Mixed Oxides of Nitrogen oxidizer, MON-25. SP7 is a new fuel formulation developed by Space Propulsion Group and was modified for this application to be resistant to Mars temperature extremes and modified again to lower the regression rate to become SP7A. MON-25 was chosen for its low freezing temperature. Due to cost constraints, MON-3 was the oxidizer used during testing through 2018. In 2019, full scale hybrid testing with MON-25 commenced in Mojave, CA by Whittinghill Aerospace. One flight motor will be subjected to thermal cycling in a vacuum and later fired in a vacuum to demonstrate the proposed Liquid Injection Thrust Vector Control system performance at White Sands Test Facility (WSTF). In addition, there will be MON-25 characterization work done at Purdue University and WSTF. Additional testing of subscale and full scale motors will be conducted with MON-3 with fuel grain stress, fuel grain support and case design test objectives by Space Propulsion Group Inc. of Butte, MT. This paper documents some of the testing, issues and accomplishments with the MAV hybrid propulsion option that is being considered (along with a two-stage solid propulsion option).

Story, G. T.↗

System Modeling and Diagnostics for Liquefying-Fuel Hybrid Rockets

A Hybrid Combustion Facility (HCF) was recently built at NASA Ames Research Center to study the combustion properties of a new fuel formulation that burns approximately three times faster than conventional hybrid fuels. Researchers at Ames working in the area of Integrated Vehicle Health Management recognized a good opportunity to apply IVHM techniques to a candidate technology for next generation launch systems. Five tools were selected to examine various IVHM techniques for the HCF. Three of the tools, TEAMS (Testability Engineering and Maintenance System), L2 (Livingstone2), and RODON, are model-based reasoning (or diagnostic) systems. Two other tools in this study, ICS (Interval Constraint Simulator) and IMS (Inductive Monitoring System) do not attempt to isolate the cause of the failure but may be used for fault detection. Models of varying scope and completeness were created, both qualitative and quantitative. In each of the models, the structure and behavior of the physical system are captured. In the qualitative models, the temporal aspects of the system behavior and the abstraction of sensor data are handled outside of the model and require the development of additional code. In the quantitative model, less extensive processing code is also necessary. Examples of fault diagnoses are given.

Poll, Scott↗

Three-Dimensional Measurements of Fuel Distribution in High-Pressure, High- Temperature, Next-Generation Aviation Gas Turbine Combustors

In our world-class, optically accessible combustion facility at the NASA Lewis Research Center, we have developed the unique capability of making three-dimensional fuel distribution measurements of aviation gas turbine fuel injectors at actual operating conditions. These measurements are made in situ at the actual operating temperatures and pressures using the JP-grade fuels of candidate next-generation advanced aircraft engines for the High Speed Research (HSR) and Advanced Subsonics Technology (AST) programs. The inlet temperature and pressure ranges used thus far are 300 to 1100 F and 80 to 250 psia. With these data, we can obtain the injector spray angles, the fuel mass distributions of liquid and vapor, the degree of fuel vaporization, and the degree to which fuel has been consumed. The data have been used to diagnose the performance of injectors designed both in-house and by major U.S. engine manufacturers and to design new fuel injectors with overall engine performance goals of increased efficiency and reduced environmental impact. Mie scattering is used to visualize the liquid fuel, and laser-induced fluorescence is used to visualize both liquid and fuel vapor.

Hicks, Yolanda R.↗

Combustor technology for future small gas turbine aircraft

To enhance fuel efficiency, future advanced small gas turbine engines will utilize engine cycles calling for overall engine pressure ratios, leading to higher combustor inlet pressures and temperatures. Further, the temperature rise through the combustor and the corresponding exit temperature are also expected to increase. This report describes future combustor technology needs for small gas turbine engines. New fuel injectors with large turndown ratios which produce uniform circumferential and radial temperature patterns will be required. Uniform burning will be of greater importance because hot gas temperatures will approach turbine material limits. The higher combustion temperatures and increased radiation at high pressures will put a greater heat load on the combustor liners. At the same time, less cooling air will be available as more of the air will be used for combustion. Thus, improved cooling concepts and/or materials requiring little or no direct cooling will be required. Although presently there are no requirements for emissions levels from small gas turbine engines, regulation is anticipated in the near future. This will require the development of low emission combustors. In particular, nitrogen oxides will increase substantially if new technologies limiting their formation are not evolved and implemented. For example, staged combustion employing lean, premixed/prevaporized, lean direct injection, or rich burn-quick quench-lean burn concepts could replace conventional single stage combustors. Due to combustor size considerations, staged combustion is more easily accommodated in large engines. The inclusion of staged combustion in small engines will pose greater combustor design challenges.

Lyons, Valerie J.↗