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At least 19 records

Nuclear Data Sheets for A = 54

The 2005 evaluation for A=54 (2006Hu08) has been updated. Detailed experimental nuclear structure data and decay data for all nuclei with mass chain A=54 are presented in this current evaluation. The new data and information are given in following datasets: {sup 54}Ca: {sup 9}Be({sup 76}Ge, X) and Be({sup 55}Sc, p), ({sup 56}Ti, 2p) {sup 54}Sc: {sup 54}Ca β{sup −} decay and {sup 54}Sc IT decay {sup 54}Ti: {sup 54}Sc β{sup −} decay {sup 54}Cr: {sup 54}Mn ε decay, {sup 56}Fe(μ, nupng), and {sup 238}U({sup 64}Ni, Xγ) {sup 54}Mn: {sup 51}V({sup 20}Ne, Xγ), {sup 55}Mn(p, pn), and {sup 56}Fe(μ, nu2ng) {sup 54}Fe: {sup 58}Ni α decay, {sup 9}Be({sup 55}Co, Xγ), {sup 54}Fe(e, e'), {sup 54}Fe(p, p'), and Coulomb Excitation {sup 54}Co: {sup 54}Ni ε decay, {sup 55}Cu εp decay, {sup 28}Si({sup 32}S, αpnγ), {sup 54}Fe(p,n), and {sup 54}Fe({sup 3}He, t) {sup 54}Ni: {sup 54}Ni IT decay, {sup 55}Zn εp decay, {sup 9}Be({sup 55}Ni, Xγ), and {sup 24}Mg({sup 32}S, Xγ) {sup 54}Zn: Ni({sup 58}Ni, X)

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Iron and nickel isotope compositions of presolar silicon carbide grains from supernovae

Here we report the carbon, silicon, iron, and nickel isotope compositions of twenty-five presolar SiC grains of mostly supernova (SN) origin. The iron and nickel isotope compositions were measured with the new Chicago Instrument for Laser Ionization, CHILI, which allows the analysis of all iron and nickel isotopes without the isobaric interferences that plagued previous measurements with the NanoSIMS. Despite terrestrial iron and nickel contamination, significant isotopic anomalies in 54 Fe/ 56 Fe, 57 Fe/ 56 Fe, 60 Ni/ 58 Ni, 61 Ni/ 58 Ni, 62 Ni/ 58 Ni, and 64 Ni/ 58 Ni were detected in nine SN grains (of type X). Combined multi-isotope data of three grains with the largest nickel isotope anomalies (>100% or <-100% in at least one isotope ratio, when expressed as deviation from the solar value) are compared with the predictions of two SN models, one with and one without hydrogen ingestion in the He shell prior to SN explosion. One grain's carbon-silicon-iron-nickel isotope composition is consistent with the prediction of the model without hydrogen ingestion, whereas the other two grains' isotope anomalies could not be reproduced using either SN models. The discrepancies between the measured isotope compositions and model predictions may indicate element fractionation in the SN ejecta prior to or during grain condensation, and reiterate the need for three-dimensional SN models.

79 ASTRONOMY AND ASTROPHYSICS↗

Effective reduction in the nanoparticle sizes of NiO obtained via the pyrolysis of nickel malonate precursor modified using oleylamine surfactant

Nickel oxide nanoparticles were synthesized via thermal decomposition of two precursors, the first, a simple nickel malonate and the second, a nickel malonate modified by oleylamine, a surfactant, both having been synthesized by precipitation. While FTIR, TGA and ToF-SIMS were used to characterize the two precursors and to show the presence of oleylamine in the modified precursor, XRD, SEM, TEM and BET were employed to investigate the structure, the morphology and the specific surface area of the decomposition products obtained after pyrolysis. The results showed that the modification of nickel malonate by oleylamine was effective. The XRD results, which showed a cubic structure for the NiO obtained, suggest with SEM an important particle size reduction (at least 54%) when oleylamine was used to modify the nickel malonate precursor. The SEM images also showed a well-defined spherical nanoparticle morphology in both cases, not affected by the presence of oleylamine. The TEM also confirmed the reduction of particle size and their spherical nature but at the same time showed that, in the presence of oleylamine, there was no agglomeration resulting in a more uniform particle size distribution. The specific surface area of the NiO obtained by the oleylamine-modified precursor was 4.7 times larger than that obtained with the regular precursor. This again confirms the particle size reduction. - Highlights: • Nickel malonate precursor has been synthesized by precipitation method. • This precursor was successfully modified by a surfactant (oleylamine). • NiO was identified as the decomposition products of the previous precursors. • Oleylamine has provoked around 54% of particle size reduction of the NiO.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NEWS BRIEF: Move Over Platinum, We Want Nickel!

NETL has identified ways to convert CO2 that is released into the air into valuable fuels and chemicals. A new catalyst has been developed through the usage of relatively inexpensive nickel.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

On measuring the metallicity of a type ia supernova's progenitor

In Type Ia Supernovae (SNe Ia) the relative abundances of chemical elements are affected by the neutron excess in the composition of the progenitor white dwarf. Since these products leave signatures in the spectra near maximum light, spectral features may be used to constrain the composition of the progenitor. We calculate the nucleosynthetic yields for three SN Ia simulations, assuming single degenerate, Chandrasekhar-mass progenitors, for a wide range of progenitor metallicities, and calculate synthetic light curves and spectra to explore correlations between progenitor metallicity and the strength of spectral features. We use two two-dimensional simulations of the deflagration–detonation–transition scenario with different {sup 56}Ni yields and the W7 simulation to control for differences between explosion models and total yields. While the overall yields of intermediate-mass elements (16 < A ⩽ 40) differ between the three cases, trends in the yields are similar. With increasing metallicity, {sup 28}Si yields remain nearly constant, {sup 40}Ca yields decline, and Ti and {sup 54}Fe yields increase. In the synthetic spectra, we identify two features at 30 days post-explosion that appear to deepen with progenitor metallicity: a Ti feature around 4200 Å and an Fe feature around 5200 Å. In all three simulations, their pseudo equivalent widths show a systematic trend with progenitor metallicity. This suggests that these two features may allow for differentiation among progenitor metallicities of observed SNe Ia and potentially help to reduce the intrinsic Hubble scatter.

79 ASTRONOMY AND ASTROPHYSICS↗

Earth Observing System (EOS) Terra Spacecraft 120 Volt Power Subsystem: Requirements, Development and Implementation

Built by the Lockheed-Martin Corporation, the Earth Observing System (EOS) TERRA spacecraft represents the first orbiting application of a 120 Vdc high voltage spacecraft electrical power system implemented by the National Aeronautics and Space Administration (NASA) Goddard Space Flight Center (GSFC). The EOS TERRA spacecraft's launch provided a major contribution to the NASA Mission to Planet Earth program while incorporating many state of the art electrical power system technologies to achieve its mission goals. The EOS TERRA spacecraft was designed around five state-of-the-art scientific instrument packages designed to monitor key parameters associated with the earth's climate. The development focus of the TERRA electrical power system (EPS) resulted from a need for high power distribution to the EOS TERRA spacecraft subsystems and instruments and minimizing mass and parasitic losses. Also important as a design goal of the EPS was maintaining tight regulation on voltage and achieving low conducted bus noise characteristics. This paper outlines the major requirements for the EPS as well as the resulting hardware implementation approach adopted to meet the demands of the EOS TERRA low earth orbit mission. The selected orbit, based on scientific needs, to achieve the EOS TERRA mission goals is a sun-synchronous circular 98.2degree inclination Low Earth Orbit (LEO) with a near circular average altitude of 705 kilometers. The nominal spacecraft orbit is approximately 99 minutes with an average eclipse period of about 34 minutes. The scientific goal of the selected orbit is to maintain a repeated 10:30 a.m. +/- 15 minute descending equatorial crossing which provides a fairly clear view of the earth's surface and relatively low cloud interference for the instrument observation measurements. The major EOS TERRA EPS design requirements are single fault tolerant, average orbit power delivery of 2, 530 watts with a defined minimum lifetime of five years (EOL). To meet these mission requirements, while minimizing mass and parasitic power losses, the EOS TERRA project relies on 36, 096 high efficiency Gallium Arsenide (GaAs) on Germanium solar cells adhered to a deployable flexible solar array designed to provide over 5,000 watts of power at EOL. To meet the eclipse power demands of the spacecraft, EOS TERRA selected an application of two 54-cell series connected Individual Pressure Vessel (IPV) Nickel-Hydrogen (NiH2) 50 Ampere-Hour batteries. All of the spacecraft observatory electrical power is controlled via the TERRA Power Distribution Unit (PDU) which is designed to provide main bus regulation of 120 Vdc +/- -4% at all load interfaces through the implementation of majority voter control of both the spacecraft's solar array sequential shunt unit (SSU) and the two battery bi-directional charge and discharge regulators. This paper will review the major electrical power system requirement drivers for the EOS TERRA mission as well as some of the challenges encountered during the development, testing, and implementation of the power system. In addition, spacecraft test and early on orbit performance results will also be covered.

Keys, Denney J.↗

Electrodeposition of Low Stress Nickel Phosphorous Alloys for Precision Component Fabrication

Nickel alloys are favored for electroforming precision components. Nickel phosphorous and nickel cobalt phosphorous are studied in this work. A completely new and innovative electrolytic process eliminates the fumes present in electroless processes and is suitable for electroforming nickel phosphorous and nickel cobalt phosphorous alloys to any desirable thickness, using soluble anodes, without stripping of tanks. Solutions show excellent performance for extended throughput. Properties include, cleaner low temperature operation (40 - 45 C), high Faradaic efficiency, low stress, Rockwell C 52 - 54 hardness and as much as 2000 N per square millimeter tensile strength. Performance is compared to nickel and nickel cobalt electroforming.

Engelhaupt, Darell↗

Experimental investigation of neutronic characteristics of the IR-8 reactor to confirm the results of calculations by MCU-PTR code

A comparison of measured and calculated neutronic characteristics (fast neutron flux and fission rate of {sup 235}U) in the core and reflector of the IR-8 reactor is presented. The irradiation devices equipped with neutron activation detectors were prepared. The determination of fast neutron flux was performed using the {sup 54}Fe (n, p) and {sup 58}Ni (n, p) reactions. The {sup 235}U fission rate was measured using uranium dioxide with 10% enrichment in {sup 235}U. The determination of specific activities of detectors was carried out by measuring the intensity of characteristic gamma peaks using the ORTEC gamma spectrometer. Neutron fields in the core and reflector of the IR-8 reactor were calculated using the MCU-PTR code.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Constraints on explosive silicon burning in core-collapse supernovae from measured Ni/Fe ratios

Measurements of explosive nucleosynthesis yields in core-collapse supernovae provide tests for explosion models. We investigate constraints on explosive conditions derivable from measured amounts of nickel and iron after radioactive decays using nucleosynthesis networks with parameterized thermodynamic trajectories. The Ni/Fe ratio is for most regimes dominated by the production ratio of {sup 58}Ni/({sup 54}Fe + {sup 56}Ni), which tends to grow with higher neutron excess and with higher entropy. For SN 2012ec, a supernova (SN) that produced a Ni/Fe ratio of 3.4 ± 1.2 times solar, we find that burning of a fuel with neutron excess η≈6×10{sup −3} is required. Unless the progenitor metallicity is over five times solar, the only layer in the progenitor with such a neutron excess is the silicon shell. SNe producing large amounts of stable nickel thus suggest that this deep-lying layer can be, at least partially, ejected in the explosion. We find that common spherically symmetric models of M{sub ZAMS}≲13 M{sub ⊙} stars exploding with a delay time of less than one second (M{sub cut}<1.5 M{sub ⊙}) are able to achieve such silicon-shell ejection. SNe that produce solar or subsolar Ni/Fe ratios, such as SN 1987A, must instead have burnt and ejected only oxygen-shell material, which allows a lower limit to the mass cut to be set. Finally, we find that the extreme Ni/Fe value of 60–75 times solar derived for the Crab cannot be reproduced by any realistic entropy burning outside the iron core, and neutrino-neutronization obtained in electron capture models remains the only viable explanation.

79 ASTRONOMY AND ASTROPHYSICS↗

Metal hypersensitivity in the context of connective tissue disease – An opportunity for practice prevention

Highlights: • Metal implants are association with metal hypersensitivity reactions of the skin. • American Contact Dermatitis Society endorses nickel allergy testing. • Metal dental appliances may trigger cutaneous reactions. • Alternative include stainless steel, fiber composite, plastic, and resin-coated. • Alternatives may improve symptoms of fibromyalgia and connective tissue disease. Metal hypersensitivity reactions (MHR) are not associated with metal containing orthodontic implants unless there is a positive history of dermatitis from a high nickel-release item (piercing post, earring, watch). We wish to present this letter to highlight evidence surrounding orthodontic-related nickel hypersensitivity and to bring to the readers attention current American Contact Dermatitis Society (ACDS) guidelines that endorse the importance of addressing metal hypersensitivity reactions in the setting of implantable dental devices.

54 ENVIRONMENTAL SCIENCES↗

Effect of a Large Population of Seeded Alumina Inclusions on Crack Initiation and Small Crack Fatigue Crack Growth in Udimet 720 Nickel-Base Disk Superalloy

Crack initiation, crack coalescence and small crack growth behavior were monitored for over 400 seeded inclusions during interrupted low cycle fatigue testing conducted on the P/M Udimet 720 nickel disk alloy at 650°C. Two types of seeded alumina inclusions with average sizes of 54 μm and 122 μm were used in the study performed at varying loading conditions resulting in LCF lives ranging from 2,000 cycles to over 1,000,000 cycles. The fatigue behavior was sub-categorized into four groups. Visual maps detailing inclusion size/cycle history were developed. The effect of surface residual stresses on the fatigue life was also investigated.

Superalloys↗

High Resistance of Resting Eggs of Cladoceran Moina macrocopa to the Effect of Heavy Metals

The research aimed to determine critical concentrations of heavy metals at which survival of resting eggs of the cladoceran Moina macrocopa is negatively affected. Resting eggs’ viability was not affected over a 30-days exposure towards copper, cadmium, zinc or nickel at concentrations up to 60–70 g/L. When resting eggs were exposed to sediment contaminated with heavy metals for 8 months, the hatching success was affected at 30 g copper/kg. Thus, resting eggs of Cladocera can tolerate heavy metals at concentrations that far exceed lethal concentrations of heavy metals to active life stage and exceed low or moderate levels of environmental pollution. Follow up investigation of life table parameters of hatchlings from resting eggs exposed to heavy metals demonstrated that neither lifespan nor fecundity of hatchlings differ from control animals. These results demonstrate that zooplankton may rapidly recover from resting egg bank once aquatic habitat becomes unpolluted.

54 ENVIRONMENTAL SCIENCES↗

Process for generating hydrogen from heavy oil or hydrocarbons

The present invention provides a steam reforming process for heavy oil or hydrocarbons using a circulating fluidized bed reactor, the process having a reforming step and a regeneration step, wherein the reforming step and the regeneration step comprise a bubbling fluidized reactor containing a fluidizable nickel-containing reforming catalyst and produce hydrogen as a product of the reforming bed. The API gravity of the feedstock may be between −11 and 54, preferably between −11 and 20. The present invention also provides a fluidized bed hydrocarbon steam reforming process using a regenerable catalyst to produce hydrogen, wherein a circulating bed reactor is operated in an alternating manner, switching between two steps: reforming and regeneration; using a mixture of a fluidizable solid and a fluidizable nickel-containing reforming catalyst; producing hydrogen as a product of the reforming step with a minimum hydrogen content of 25 volume percent, preferably at least 60 volume % and more preferably at least 70 volume percent on a dry weight basis.

Srinivas, Girish↗

Effects of carbon and silicon nanotubes and carbon nanofibers on marine microalgae Heterosigma akashiwo

Highlights: • Carbon and silicon nanotubes did not inhibit algal growth up to 10 mg/l. • Carbon nanofibers did not inhibit algal growth at 100 mg/l. • Cell death of marine alga Heterosigma akashiwo was associated with mechanical damage. • Nickel impurities in carbon nanofibers caused irregular shape formation. The effect of carbon and silicon nanotubes (CNTs and SiNTs) and carbon nanofibers (CNFs) to microscopic marine algae Heterosigma akashiwo was studied, using algal growth inhibition for 3 days (acute effect) and 7 days (chronic effect) as toxicity endpoints. The criterion of the toxic effect was the statistically significant reduction of the number of algal cells in the exposed samples compared to the control. Samples did not demonstrate toxic effects at doses 1 mg/l and 10 mg/l. CNTs and SiNTs samples at 100 mg/l exhibited both acute and chronic toxic effects. We assume that the main cause of cell death in these samples was related to the mechanical damage of cell integrity. CNFs at concentrations of 100 mg/l did not inhibit algal growth, but cells with irregular shapes were observed, which were not observed after exposure to CNTs and SiNTs. Nickel impurities present in CNFs samples are presumably the main cause of observed cell deformations.

54 ENVIRONMENTAL SCIENCES↗

E-cigarettes as a source of toxic and potentially carcinogenic metals

Background and aims: The popularity of electronic cigarette devices is growing worldwide. The health impact of e-cigarette use, however, remains unclear. E-cigarettes are marketed as a safer alternative to cigarettes. The aim of this research was the characterization and quantification of toxic metal concentrations in five, nationally popular brands of cig-a-like e-cigarettes. Methods: We analyzed the cartomizer liquid in 10 cartomizer refills for each of five brands by Inductively Coupled Plasma Mass Spectrometry (ICP-MS). Results: All of the tested metals (cadmium, chromium, lead, manganese and nickel) were found in the e-liquids analyzed. Across all analyzed brands, mean (SD) concentrations ranged from 4.89 (0.893) to 1970 (1540) μg/L for lead, 53.9 (6.95) to 2110 (5220) μg/L for chromium and 58.7 (22.4) to 22,600 (24,400) μg/L for nickel. Manganese concentrations ranged from 28.7 (9.79) to 6910.2 (12,200) μg/L. We found marked variability in nickel and chromium concentration within and between brands, which may come from heating elements. Conclusion: Additional research is needed to evaluate whether e-cigarettes represent a relevant exposure pathway for toxic metals in users. - Highlights: • Certain brands of cig-a-like e-cigarettes contain high levels of nickel and chromium. • Cig-a-likes contain low levels of cadmium, compared to tobacco cigarettes. • Nickel and chromium in the e-liquid of cig-a-likes may come from nichrome heating coils.

54 ENVIRONMENTAL SCIENCES↗

Isotope anomalies in the FE-group elements in meteorites and connections to nucleosynthesis in AGB stars

We study the effects of neutron captures in AGB stars on “Fe-group” elements, with an emphasis on Cr, Fe, and Ni. These elements show anomalies in {sup 54}Cr, {sup 58}Fe, and {sup 64}Ni in solar system materials, which are commonly attributed to supernovae (SNe). However, as large fractions of the interstellar medium (ISM) were reprocessed in AGB stars, these elements were reprocessed, too. We calculate the effects of such reprocessing on Cr, Fe, and Ni through 1.5 M{sub ⊙} and 3 M{sub ⊙} AGB models, adopting solar and 1/3 solar metallicities. All cases produce excesses of {sup 54}Cr, {sup 58}Fe, and {sup 64}Ni, while the other isotopes are little altered; hence, the observations may be explained by AGB processing. The results are robust and not dependent on the detailed initial isotopic composition. Consequences for other “Fe group” elements are then explored. They include {sup 50}Ti excesses and some production of {sup 46,47,49}Ti. In many circumstellar condensates, Ti quantitatively reflects these effects of AGB neutron captures. Scatter in the data results from small variations (granularity) in the isotopic composition of the local ISM. For Si, the main effects are instead due to variations in the local ISM from different SN sources. The problem of Ca is discussed, particularly with regard to {sup 48}Ca. The measured data are usually represented assuming terrestrial values for {sup 42}Ca/{sup 44}Ca. Materials processed in AGB stars or sources with variable initial {sup 42}Ca/{sup 44}Ca ratios can give apparent {sup 48}Ca excesses/deficiencies, attributed to SNe. The broader issue of galactic chemical evolution is also discussed in view of the isotopic granularity in the ISM.

79 ASTRONOMY AND ASTROPHYSICS↗

Consistent Controls on Trace Metal Micronutrient Speciation in Wetland Soils and Stream Sediments

Trace metal are essential for microbially-mediated biogeochemical processes occurring in anoxic wetland soils and stream bed sediments, but low availability of these elements may inhibit anaerobic element cycling and transformations. Solid-phase speciation is likely a critical control on trace metal availability but has seen limited study in anoxic systems having concentrations similar to geological background levels, where metal limitations may be most prevalent. We have investigated trace metal concentrations and solid-phase speciation in three freshwater subsurface aquatic systems: marsh wetland soils, riparian wetland soils, and the sediments of a streambed. These systems displayed low solid-phase trace metal concentrations, generally at or below geological background levels, which generally followed the trend Zn > Cu ≈ Ni > Co and showed no correlation with major element compositions. All soils and sediments were dominated by quartz but varied in clay mineralogy as well as the organic matter, total sulfur, and total iron contents. X-ray absorption near-edge structure (XANES) spectroscopy shows that sulfur speciation in both wetlands is dominated by organic sulfur. Elemental sulfur and iron sulfides together made up <25% of the sulfur in the wetland soils, but the distribution between inorganic and organic forms was reversed in the stream sediments. Ferrous and ferric iron in clay minerals were common species identified by both XANES and extended X-ray absorption fine structure (EXAFS) spectroscopies at all sites. Iron(III) oxides were substantial components in all but the marsh wetland soils. Quantitative analysis of copper, nickel, and zinc XANES spectra revealed similar metal speciation across all sites. Copper speciation was dominated by sulfides, adsorbed species, and minor amounts of copper bound to organic matter; no metallic copper was detected. Nickel speciation also varied little and was dominated by nickel in clay mineral octahedral sheets and nickel sulfide, with adsorbed species also present. Zinc speciation was slightly more varied, with the marsh wetland soils and stream bed sediments containing adsorbed species, zinc associated with clay mineral structures, and zinc bound to reduced sulfur groups on organic matter, whereas the riparian wetland soils lacked clay-associated zinc but contained zinc sulfide. Trace metals bound to reduced sulfur occurred at every site, with a greater sulfur-bound fraction for copper. The fractional abundance of sulfur-bound species showed no relationship with soil or sediment total sulfur content, which varied by two orders of magnitude. More broadly, the observations in this study suggest that trace metal speciation in freshwater wetland soils and stream sediments is consistently dominated by a small set of recurring components which are distinct for each metal. Furthermore, this may represent a general geochemical phenomenon in anoxic soils and sediments containing trace metals at background concentrations (as low as 3 µg g -1 ) that was not predicted from systems that are contaminated with or naturally-enriched in copper, nickel, or zinc.

54 ENVIRONMENTAL SCIENCES↗

Global Electrification of Vehicles and Intertwined Material Supply Chains of Cobalt, Copper and Nickel

Electric vehicles (EVs) will be an important part of a low-carbon economy. Future EV adoption depends on overcoming multiple barriers, including charging infrastructure, sufficient electricity generation, and the availability of battery raw materials at acceptable costs, including cobalt, copper and nickel – which typically are co-produced. Various EV projections have been made, along with associated requirements for battery raw materials (demand). There have been separate assessments of the availability of raw materials (supply). However, integrated assessments of supply and demand and their interaction over time are lacking to support decision-making. Using a dynamic market model that reflects the co-produced nature of cobalt, copper and nickel production as well as recycling, we estimate global output of these three metals under different EV growth scenarios from 2020 to 2040. In this work, results suggest that starting in 2025, replacement demand for battery raw materials becomes important. Thus, estimates for future material demand that consider only demands from new EVs are incomplete and misleading. EV deployment and associated increased demand for raw materials will have a greater impact on prices for cobalt than nickel and, in turn, for nickel than copper. High EV deployment scenarios will be difficult to achieve without larger supplies of copper, nickel and cobalt than forthcoming under the conditions modeled here, which anticipates a six-year time lag between a demand increase and the expansion of metal-production capacity. Shortening battery lifetimes and improving collection and recycling rates increase secondary supply, but the extent to which these factors support additional EV deployment is mixed.

54 ENVIRONMENTAL SCIENCES↗