Production of oxide fibers by co-reduction Final report
Plastic deformation of metal oxides by high temperature extrusion in molybdenum and tungsten
Loewenstein, P.↗
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Characterization study of polycrystalline tin oxide surfaces before and after reduction in CO
Polycrystalline tin oxide surfaces have been examined before and after reduction in 40 Torr of CO at 100 and 175 C using Auger electron spectroscopy (AES), electron spectroscopy for chemical analysis (ESCA), ion scattering spectroscopy (ISS) and electron stimulated desorption (ESD). The changes in the surface composition and chemical states of the surface species generally are subtle for the reductive conditions used. However, significant changes do occur with regard to the amounts and the chemical forms of the hydrogen-containing species remaining after both the 100 and 175 C reductions.
Drawdy, Jean E.↗
Reduction of aircraft gas turbine engine pollutant emissions
To accomplish simultaneous reduction of unburned hydrocarbons, carbon monoxide, and oxides of nitrogen, required major modifications to the combustor. The modification most commonly used was a staged combustion technique. While these designs are more complicated than production combustors, no insurmountable operational difficulties were encountered in either high pressure rig or engine tests which could not be resolved with additional normal development. The emission reduction results indicate that reductions in unburned hydrocarbons were sufficient to satisfy both near and far-termed EPA requirements. Although substantial reductions were observed, the success in achieving the CO and NOx standards was mixed and depended heavily on the engine/engine cycle on which it was employed. Technology for near term CO reduction was satisfactory or marginally satisfactory. Considerable doubt exists if this technology will satisfy all far-term requirements.
Diehl, L. A.↗
General aviation piston-engine exhaust emission reduction
To support the promulgation of aircraft regulations, two airports were examined, Van Nuys and Tamiami. It was determined that the carbon monoxide (CO) emissions from piston-engine aircraft have a significant influence on the CO levels in the ambient air in and around airports, where workers and travelers would be exposed. Emissions standards were set up for control of emissions from aircraft piston engines manufactured after December 31, 1979. The standards selected were based on a technologically feasible and economically reasonable control of carbon monoxide. It was concluded that substantial CO reductions could be realized if the range of typical fuel-air ratios could be narrowed. Thus, improvements in fuel management were determined as reasonable controls.
Kempke, E. E., Jr.↗
Mass Economy Evaluation for Integrated ECLSS and Propulsion Architecture
As missions in Low Earth Orbit (LEO) lengthen and extend to deep space, minimizing resupply needs becomes vital for sustaining crewed operations. Traditional life support systems depend on consumables resupplied from Earth, a method that is increasingly impractical for missions beyond LEO, such as lunar outposts or Mars transit. Long-duration missions require more efficient, autonomous systems that can recycle essential resources, particularly water and oxygen, to minimize the frequency and mass of resupply missions. The Environmental Control and Life Support System (ECLSS) is essential to such missions, with the International Space Station (ISS) serving as a testbed for advanced water recovery and partial oxygen recycling via physico-chemical methods. Yet, ECLSS and propulsion subsystems generally operate independently, despite overlapping requirements and potential areas for synergy. For instance, ECLSS byproducts, water, CO₂, and hydrogen, could be repurposed for propulsion, potentially reducing dedicated propellant mass and increasing overall system efficiency. One promising approach is to develop shared-resource architectures that integrate ECLSS with propulsion systems. This study examines the potential of such integration through the Sabatier CO₂ reduction process, focusing on water management as a key factor in system mass trade-offs. The Sabatier reaction produces water and methane from metabolic CO₂ and electrolytic hydrogen, partially closing the life support loop and providing methane, which could serve as a propellant. This integration could minimize waste, reduce resupply requirements, and enhance mission mass efficiency. A dynamic modeling framework will be used to simulate resource flows over long missions, capturing interactions between life support and propulsion. By comparing integrated versus separate system configurations, the study aims to quantify mass benefits and penalties, informing future habitat designs and trade studies for missions prioritizing autonomy and mass efficiency.
ECLSS↗
Mass Economy Evaluation for Integrated ECLSS and Propulsion Architecture
As missions in low Earth orbit (LEO) lengthen and extend to deep space, minimizing resupply needs becomes vital for sustaining crewed operations. Traditional life support systems depend on consumables resupplied from Earth, a method that is increasingly impractical for missions beyond LEO, such as lunar outposts or Mars transit. Long-duration missions require more efficient, autonomous systems that can recycle essential resources, particularly water and oxygen, to minimize the frequency and mass of resupply missions. The Environmental Control and Life Support System (ECLSS) is essential to such missions, with the International Space Station (ISS) serving as a testbed for advanced water recovery and partial oxygen recycling via physico-chemical methods. Yet, ECLSS and propulsion subsystems generally operate independently, despite overlapping requirements and potential areas for synergy. For instance, ECLSS byproducts, water, CO 2 , and hydrogen, could be repurposed for propulsion, potentially reducing dedicated propellant mass and increasing overall system efficiency. One promising approach is to develop shared-resource architectures that integrate ECLSS with propulsion systems. This study examines the potential of such integration through the Sabatier CO₂ reduction process, focusing on water management as a key factor in system mass trade-offs. The Sabatier reaction produces water and methane from metabolic CO 2 and electrolytic hydrogen, partially closing the life support loop and providing methane, which could serve as a propellant. This integration could minimize waste, reduce resupply requirements, and enhance mission mass efficiency. A dynamic modeling framework will be used to simulate resource flows over long missions, capturing interactions between life support and propulsion. By comparing integrated versus separate system configurations, the study aims to quantify mass benefits and penalties, informing future habitat designs and trade studies for missions prioritizing autonomy and mass efficiency.
ECLSS↗
Oxygen Extraction from Minerals
Oxygen, whether used as part of rocket bipropellant or for astronaut life support, is a key consumable for space exploration and commercialization. In Situ Resource Utilization (ISRU) has been proposed many times as a method for making space exploration more cost effective and sustainable. On planetary and asteroid surfaces the presence of minerals in the regolith that contain oxygen is very common, making them a potential oxygen resource. The majority of research and development for oxygen extraction from minerals has been for lunar regolith although this work would generally be applicable to regolith at other locations in space. This presentation will briefly survey the major methods investigated for oxygen extraction from regolith with a focus on the current status of those methods and possible future development pathways. The major oxygen production methods are (1) extraction from lunar ilmenite (FeTiO3) with either hydrogen or carbon monoxide, (2) carbothermal reduction of iron oxides and silicates with methane, and (3) molten regolith electrolysis (MRE) of silicates. Methods (1) and (2) have also been investigated in a two-step process using CO reduction and carbon deposition followed by carbothermal reduction. All three processes have byproducts that could also be used as resources. Hydrogen or carbon monoxide reduction produce iron metal in small amounts that could potentially be used as construction material. Carbothermal reduction also makes iron metal along with silicon metal and a glass with possible applications. MRE produces iron, silicon, aluminum, titanium, and glass, with higher silicon yields than carbothermal reduction. On Mars and possibly on some moons and asteroids, water is present in the form of mineral hydrates, hydroxyl (-OH) groups on minerals, andor water adsorbed on mineral surfaces. Heating of the minerals can liberate the water which can be electrolyzed to provide a source of oxygen as well. The chemistry of these processes, some key development and demonstration projects, the challenges remaining to be overcome, and possible future directions will be discussed with a goal of increased understanding of these important ISRU technologies and their potential applications to space exploration and settlement.
propellant production↗
Global biomass burning - Atmospheric, climatic, and biospheric implications
The present volume discusses the biomass burning (BMB) studies of the International Global Atmospheric Chemistry project, GEO satellite estimation of Amazonian BMB, remote sensing of BMB in West Africa with NOAA-AVHRR, an orbital view of the great Chinese fire of 1987, BMB's role in tropical rainforest reduction, CO and O3 measurements of BMB in the Amazon, effects of vegetation burning on the atmospheric chemistry of the Venezuelan savanna, an assessment of annually-burned biomass in Africa, and light hydrocarbon emissions from African savanna burnings. Also discussed are BMB in India, trace gas and particulate emissions from BMB in temperate ecosystems, ammonia and nitric acid emissions from wetlands and boreal forest fires, combustion emissions and satellite imagery of BMB, BMB in the perspective of the global carbon cycle, modeling trace-gas emissions from BMB, NO(x) emissions from BMB, and cloud-condensation nuclei from BMB.
Levine, Joel S.↗
Carbon and Hydrogen Isotope Measurements of Alcohols and Organic Acids by Online Pyroprobe-GC-IRMS
The detection of methane in the atmosphere of Mars, combined with evidence showing widespread water-rock interaction during martian history, suggests that the production of methane on Mars may be the result of mineral surface-catalyzed CO2 and or CO reduction during Fisher-Tropsch Type (FTT) reactions. A better understanding of these reaction pathways and corresponding C and H isotope fractionations is critical to deciphering the synthesis of organic compounds produced under abiotic hydrothermal conditions. Described here is a technique for the extraction and analysis of both C and H isotopes from alcohols (C1-C4) and organic acids (C1-C6). This work is meant to provide a "proof of concept" for making meaningful isotope measurements on complex mixtures of solid-phase hydrocarbons and other intermediary products produced during high-temperature and high-pressure synthesis on mineral-catalyzed surfaces. These analyses are conducted entirely "on-line" utilizing a CDS model 5000 Pyroprobe connected to a Thermo Trace GC Ultra that is interfaced with a Thermo MAT 253 isotope ratio mass spectrometer operating in continuous flow mode. Also, this technique is designed to carry a split of the GC-separated product to a DSQ II quadrupole mass spectrometer as a means of making semi-quantitative compositional measurements. Therefore, both chemical and isotopic measurements can be carried out on the same sample.
Socki, Richard A.↗
Kinetic inhibition of CO and N2 reduction in the solar nebula
It is shown that the conversion of CO to methane and of N2 to ammonia in the primitive solar nebula was probably so slow relative to radial mixing rates or nebula evolutionary rates that only small amounts of NH3 and CH4 could have been present. Thus most of the nitrogen was present as N2 and most of the carbon as CO and CO2 throughout the nebula. The consequences of this kinetic effect upon the composition of cometary ices and of the Jovian planets, the melting and outgassing behavior of ice rich planetary satellites, and the abundance of carbon in the terrestrial planets are briefly discussed.
Lewis, J. S.↗
Kinetic inhibition of CO and N2 reduction in circumplanetary nebulae - Implications for satellite composition
In contrast to the solar nebula, the conversion of CO to CH4 and of N2 to NH3 in the circumplanetary nebulae of the Jovian planets is fast enough relative to radial mixing and nebula cooling rates that CO and N2 are minor constituents in the circumplanetary nebulae. Thus, although the Jovian planets may have accreted carbon and nitrogen from the solar nebula mainly in the form of CO and N2, these species were then reprocessed within the circumplanetary nebulae to form mainly CH4 and NH3. Satellites of the Jovian planets which accreted in sufficiently cool parts of their circumplanetary nebula are therefore predicted to retain large amounts of NH3 and CH4 in the form of clathrate hydrates and also very small but chemically important amounts of HCN.
Prinn, R. G.↗
Status of the US Space Station ECLSS and internal TCS
The U.S. Space Station includes many elements and systems. Responsibility for these have been delegated to four NASA centers via a work packaging concept. Marshall Space Flight Center (MSFC) is responsible for work package one (WPOI) which includes the habitation, laboratory modules, the logistic carrier elements, as well as the environmental control and life support system (ECLSS), the internal thermal control system (ITCS), and the internal audio and video systems. Current status of the ECLSS and internal thermal are the subjects of this paper. The ECLSS is composed of six subsystem groups: the temperature humidity control, the atmosphere control and supply, the air revitalization, water reclamation and management, fecal waste management, and the fire detection and suppression subsystems. The internal TCS consists of all WP01 elements of passive and active thermal measures. The ECLSS and ITCS provide services for the permanently orbiting pressurized modules as well as the pressurized and unpressurized logistics carriers. The logistics carriers are used as ground-to-station ferries for both resupply and initial delivery of selected new equipment and later replacement items. Equipment, which cannot be subjected to the rigors of the space environment, will be carried in the pressurized logistic carrier; while an unpressurized carrier is used to resupply other commodities, such as external fluid consumables. The laboratory module houses the equipment for both payloads and subsystem maintenance and repair. The habitation module is dedicated to providing living and sleeping quarters including a galley, sleeping provisions, hygiene facilities, medical services as well as services for exercise and relaxation. The four nodes that join the two modules at their ends also house electronics as well as work stations and outside viewing cupolas. The airlocks, one providing an emergency hyperbaric chamber capability, are also attached. This assembly constitutes the U.S. provided portion of the initial station. Additional international modules and docking provisions for future attached pressurized payload as well as dual logistic module and growth capabilities are also provided. The primary heat rejection mechanism is achieved via a central set of radiators provided by another work package. The interface with the central TCS at the module heat exchangers defines the active control interface boundary of the ITCS with the central TCS. All internal cooling of the permanent orbital elements are provided via internal active fluid loops within the elements utilizing water as the transport media. Cabin and equipment cooling are provided by forced air flow and cold plate heat sinks. A special active cooling loop is provided in the laboratory module to accommodate experiments and other payloads. Coatings and insulation are used in conjunction with the active components to passively limit heat losses/gains. The most challenging ECLSS new technology issues relate to oxygen and water recovery. Closure of the oxygen loop requires the use of new regenerative CO 2 removal and concentration techniques, CO 2 reduction to convert the CO 2 to water with a waste by-product, and the electrolysis of water to produce breathing oxygen for water recovery. For water recovery three separate loops are currently planned. One loop provides potable water by utilizing a combination of recovered condensate and CO 2 reduction water. A second loop purifies hygiene water from waste from the showers, clothes washer, hygiene/hand wash stations and a dishwasher. The third loop provides hygiene water by the reclamation and purification of urine water. This paper outlines the basic services provided by the ECLSS and ITCS and describes the ECLSS functional distribution throughout the pressurized assembly.
R. Humphries↗
Performance characterization of a Bosch CO sub 2 reduction subsystem
The performance of Bosch hardware at the subsystem level (up to five-person capacity) in terms of five operating parameters was investigated. The five parameters were: (1) reactor temperature, (2) recycle loop mass flow rate, (3) recycle loop gas composition (percent hydrogen), (4) recycle loop dew point and (5) catalyst density. Experiments were designed and conducted in which the five operating parameters were varied and Bosch performance recorded. A total of 12 carbon collection cartridges provided over approximately 250 hours of operating time. Generally, one cartridge was used for each parameter that was varied. The Bosch hardware was found to perform reliably and reproducibly. No startup, reaction initiation or carbon containment problems were observed. Optimum performance points/ranges were identified for the five parameters investigated. The performance curves agreed with theoretical projections.
Heppner, D. B.↗
Automotive Stirling engine development program - Overview and status report
The current status of the automotive-Stirling-engine development program being undertaken by DOE and NASA Lewis is reviewed. The program goals and the reference-engine design are explained, and the modifications introduced to improve performance and lower manufacturing costs are discussed and illustrated, including part-power optimization; increased operating temperature (from 720 to 820 C); 45.4-kg weight reduction; elimination of Co and reduction of Cr used; and improved seals, ceramic components, and high-temperature alloys. The test program, some difficulties encountered, and results after 2042 h are summarized.
Nightingale, N. P.↗
Kinetic conversion of CO to CH4 in the Solar System
Some of the most interesting chemistry in the Solar System involves changes in the oxidation state of the simple carbon species. The chemical pathways for the conversion of CH4 to CO and CO2 are for the most part known. The reverse process, the reduction of CO to CH4, is, however, poorly understood. This is surprising in view of the importance of the reduction process in the chemistry of the Solar System. Recently we investigated the chemical kinetics of a hitherto unsuspected reaction. It is argued that the formation of the methoxy radical (CH3O) from H+H2CO may play an essential role in the reduction of CO to CH4. The rate coefficient for this reaction has been estimated using the approximate theory of J. Troe and transition state theory. We will discuss the implications of this reaction for the chemistry of CO on Jupiter, in the solar nebula, for interpreting the laboratory experiments of A. Bar-Nun and A. Shaviv and A. Bar-Nun and S. Chang, and for organic synthesis in the prebiotic terrestrial atmosphere. The possible relation of CO reduction in the solar nebula and polyoxymethylene observed in comet Halley will be discussed.
Yung, Y. L.↗
Photochemical and thermal modeling in the early atmosphere of the earth
The simplest carbon compounds, present in the terrestrial and planetary atmospheres, exhibit a wide range of oxidation states, carbon dioxide and methane being the most oxidized and the most reduced form of carbon, respectively. The question arises as to the origin and the interconversion among the carbon species. The chemical pathways for the conversion of CH4 to CO and CO2 are for the most part known. The reverse process, the reduction of CO to CH4 is however, poorly understood. A new reaction is proposed, H2CO + H + M yields CH3O + M, which might play a fundamental role in the reduction of CO or CH4. An update is presented of nitrile photochemistry on Titan.
Yung, Yuk L.↗
Advanced Turboprop Transport Aircraft Modeling for the Electrified Powertrain Flight Demonstration Project
The objective of this study is to establish models for state of the art, representative regional non-electrified turboprop configurations in the 19 to 50 passenger capability range and assess performance impacts from advanced aircraft technologies. Two of these models will serve as reference baseline configurations for comparison to electrified aircraft propulsion (EAP) demonstrator concepts for the Electrified Powertrain Flight Demonstration (EPFD) project. The other two non-electrified configurations will primarily assess the impacts of advanced technologies on fuel consumption and CO₂ emissions. This paper details an aircraft synthesis and performance analysis approach using the General Aviation Synthesis Program (GASP) which is used to establish baseline performance capabilities, calibrate airplane and engine models using published manufacturer data and conduct technology sensitivity studies. Advanced technologies are selected from the categories of propulsion, aerodynamics, and flight systems. A GASP-Monte Carlo simulation framework for uncertainty propagation is used to obtain performance distributions of the expected fuel burn, weight reduction and CO₂ emissions reductions from advanced aircraft technologies. Significant fuel burn savings from application of aerodynamics and propulsion technologies was observed.
Dahlia D.V. Pham↗
Bakeout procedures for small glass ultrahigh vacuum systems. Reduction of O2 to CO CONVERSION
Bakeout procedures for small glass ultrahigh vacuum systems with small oxygen to carbon monoxide conversion
ULTRAHIGH VACUUM↗