Materials Data on Na8N3O by Materials Project
Na8N3O is Fluorite-derived structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Na1+ is bonded to three equivalent N2- and one O2- atom to form a mixture of edge and corner-sharing NaN3O tetrahedra. All Na–N bond lengths are 2.53 Å. The Na–O bond length is 2.45 Å. N2- is bonded in a body-centered cubic geometry to eight equivalent Na1+ atoms. O2- is bonded in a body-centered cubic geometry to eight equivalent Na1+ atoms.