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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Electrical Interrogation of Thickness‐Dependent Multiferroic Phase Transitions in the 2D Antiferromagnetic Semiconductor NiI 2

Abstract 2D magnetic materials hold promise for quantum and spintronic applications. 2D antiferromagnetic materials are of particular interest due to their relative insensitivity to external magnetic fields and higher switching speeds compared to 2D ferromagnets. However, their lack of macroscopic magnetization impedes detection and control of antiferromagnetic order, thus motivating magneto‐electrical measurements for these purposes. Additionally, many 2D magnetic materials are ambient‐reactive and electrically insulating or highly resistive below their magnetic ordering temperatures, which imposes severe constraints on electronic device fabrication and characterization. Herein, these issues are overcome via a fabrication protocol that achieves electrically conductive devices from the ambient‐reactive 2D antiferromagnetic semiconductor NiI 2 . The resulting gate‐tunable transistors show band‐like electronic transport below the antiferromagnetic and multiferroic transition temperatures of NiI 2 , revealing a Hall mobility of 15 cm 2 V −1 s −1 at 1.7 K. These devices also allow direct electrical probing of the thickness‐dependent multiferroic phase transition temperature of NiI 2 from 59 K (bulk) to 28 K (monolayer).

2D magnets↗
DOE OSTI2025

Shear–Mediated Stabilization of Spin Spiral Order in Multiferroic NiI 2

Type-II multiferroicity from non-collinear spin order is recently explored in the van der Waals material NiI 2 . Despite the importance for improper ferroelectricity, the microscopic mechanism of the helimagnetic order remains poorly understood. Here, the magneto-structural phases of NiI 2 are investigated using resonant magnetic X-ray scattering (RXS) and X-ray diffraction. Two competing magnetic phases are identified. Below 60 K, an incommensurate magnetic reflection (q ≈ [0.143,0,1.49] reciprocal lattice units) is observed which exhibits finite circular dichroism in RXS, signaling the inversion symmetry-breaking helimagnetic ground state. At elevated temperature, in the non-polar phase (60 K < T < 75 K), a distinct q ≈ [0.087,0.087,1.5] magnetic order is observed, attributed to a collinear incommensurate (CI) state. The first-order CI-helix transition is concomitant with a structural transition characterized by a significant interlayer shear, which drives the helimagnetic ground state as evidenced by a mean-field Heisenberg model including interlayer exchange and its coupling to the structural distortion. Furthermore, these findings identify interlayer magneto-structural coupling as the key driver behind multiferroicity in NiI 2 .

36 MATERIALS SCIENCE↗
DOE OSTI2024

Photocurrent Spectroscopy of Dark Magnetic Excitons in 2D Multiferroic NiI 2

Abstract Two‐dimensional (2D) antiferromagnetic (AFM) semiconductors are promising components of opto‐spintronic devices due to terahertz operation frequencies and minimal interactions with stray fields. However, the lack of net magnetization significantly limits the number of experimental techniques available to study the relationship between magnetic order and semiconducting properties. Here, they demonstrate conditions under which photocurrent spectroscopy can be employed to study many‐body magnetic excitons in the 2D AFM semiconductor NiI 2 . The use of photocurrent spectroscopy enables the detection of optically dark magnetic excitons down to bilayer thickness, revealing a high degree of linear polarization that is coupled to the underlying helical AFM order of NiI 2 . In addition to probing the coupling between magnetic order and dark excitons, this work provides strong evidence for the multiferroicity of NiI 2 down to bilayer thickness, thus demonstrating the utility of photocurrent spectroscopy for revealing subtle opto‐spintronic phenomena in the atomically thin limit.

Lebedev, Dmitry↗
DOE OSTI2024

Effects of pressure on the electronic and magnetic properties of bulk NiI 2

Transition metal dihalides have recently garnered interest in the context of two-dimensional van der Waals magnets as their underlying geometrically frustrated triangular lattice leads to interesting competing exchange interactions. In particular, NiI 2 is a magnetic semiconductor that has been long known for its exotic helimagnetism in the bulk. Recent experiments have shown that the helimagnetic state survives down to the monolayer limit with a layer-dependent magnetic transition temperature that suggests a relevant role of the interlayer coupling. Here, we explore the effects of hydrostatic pressure as a means to enhance this interlayer exchange and ultimately tune the electronic and magnetic response of NiI 2 . We study first the evolution of the structural parameters as a function of external pressure using first-principles calculations combined with x-ray diffraction measurements. We then examine the evolution of the electronic structure and magnetic exchange interactions via first-principles calculations and Monte Carlo simulations. Further, we find that the leading interlayer coupling is an antiferromagnetic second-nearest-neighbor interaction that increases monotonically with pressure. The ratio between isotropic third- and first-nearest-neighbor intralayer exchanges, which controls the magnetic frustration and determines the magnetic propagation vector q of the helimagnetic ground state, is also enhanced by pressure. As a consequence, our Monte Carlo simulations show a monotonic increase in the magnetic transition temperature, indicating that pressure is an effective means to tune the magnetic response of NiI 2 .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

Materials Data on NiI by Materials Project

NiI is Wurtzite structured and crystallizes in the hexagonal P6_3mc space group. The structure is three-dimensional. Ni1+ is bonded to four equivalent I1- atoms to form corner-sharing NiI4 tetrahedra. There are one shorter (2.51 Å) and three longer (2.52 Å) Ni–I bond lengths. I1- is bonded to four equivalent Ni1+ atoms to form corner-sharing INi4 tetrahedra.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Evidence for a single-layer van der Waals multiferroic

Here we searched for signatures of type-II multiferroic order in ultrathin van der Waals materials, to determine if such a state, comprising coexisting electrical polarization and spin order with strong magnetoelectric effects, could persist down to a single-atomic layer. We reported the first observation of such a state in triangular lattice material NiI 2 . This system has a layered structure and built-in magnetic frustration that promotes a complex magnetic ground state with proper-screw spin helices. The spin helix pattern breaks inversion symmetry and induces electrical polarization via magnetoelectric coupling. We use circular dichroic Raman measurements to directly probe the magneto-chiral ground state and its electromagnon modes originating from dynamic magnetoelectric coupling. Using birefringence and second-harmonic generation measurements, we detect a highly anisotropic electronic state simultaneously breaking three-fold rotational and inversion symmetry. The evolution of the optical signatures as a function of temperature and layer number surprisingly revealed a multiferroic state that persists down to the ultrathin limit of monolayer NiI 2 . These observations establish NiI 2 and transition metal dihalides as a new platform for studying emergent multiferroic phenomena, chiral magnetic textures and ferroelectricity in the 2D limit.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

Upper boundaries of active galactic nucleus regions in optical diagnostic diagrams

The distribution of galaxies in optical diagnostic diagrams can provide information about their physical parameters when compared with ionization models under proper assumptions. By using a sample of central emitting regions from the Mapping Nearby Galaxies at Apache Point Observatory survey (MaNGA), we find evidence of the existence of upper boundaries for narrow-line regions (NLRs) of active galactic nuclei (AGNs) in optical Baldwin, Phillips & Terlevich (BPT) diagrams, especially in diagrams involving [Sii]λλ6716, 6731/Hα. Photoionization models can reproduce the boundaries well, as a consequence of the decrease of [Sii]λλ6716, 6731/Hα and [Oiii]λ5007/Hβ ratios at very high metallicity. Whilst the exact location of the upper boundary in the [Sii] BPT diagram depends only weakly on the electron density of the ionized cloud and the secondary nitrogen prescription, its dependence on the shapes of the input spectral energy distributions (SEDs) is much stronger. This allows us to constrain the power-law index of the AGN SED between 1 Ryd and ~100 Ryd to be less than or equal to -1.40 ± 0.05. The coverage of photoionization models in the [Nii] BPT diagram has a stronger dependence on the electron density and the secondary nitrogen prescription. With the density constrained by the [Sii] doublet ratio and the input SED constrained by the [Sii] BPT diagram, we find that the extent of the data in the [Nii] BPT diagram favours those prescriptions with high N/O ratios. Furthermore, although shock-ionized clouds can produce line ratios similar to those from photoionization, the resulting shapes of the upper boundaries, if they exist, would likely be different from those of photoionizing origin.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

The flux ratio of the [N II] λ λ 6548, 6583 Å lines in sample of Active Galactic Nuclei Type 2

In spectra of the Active Galactic Nuclei (AGNs), the [N II]λλ 6548, 6583 Å lines are commonly fitted using the fixed intensity ratio of these two lines (R [NII] = I 6583 /I 6548 ). However, the used values for fixed intensity ratio are slightly different through literature. There are several theoretical calculations of the transition probabilities which can be used for the line ratio estimation, but there are no experimental measurements of this ratio, since the [N II] lines are extremely weak in laboratory plasma. Therefore, the intensity ratio of [N II] lines can be measured only in the spectra of astrophysical objects. However, precise and systematic measurements have not be done so far, because of difficulties in measurement of the [N II] ratio in various spectra (overlapping with Hα, weak intensity of [N II], influence of the continuum noise and outflow contribution, etc.). Here we present the measurements of the flux ratio of the [N II] λλ 6548, 6583 Å emission lines for a sample of 250 Type 2 AGNs spectra taken form Sloan Digital Sky Survey (SDSS) data base. Further, the spectra are chosen to have high signal-to-noise ratio and to [N II] and Hα lines do not overlap. The obtained mean flux ratio from measurements is 3.049 ± 0.021. Our result is in agreement with theoretical result obtained by taking into account the relativistic corrections to the magnetic dipole operator.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Computational Optimization of Room Temperature Usable Capacity for Hydrogen Storage in MFU-4-Type Metal–Organic Frameworks via Pairwise Metal Substitutions

The efficient storage of hydrogen is a critical challenge in the quest for sustainable energy solutions. Current adsorbent-based methods achieve satisfactory storage densities predominantly under cryogenic temperatures and/or high pressures, which imposes problems with cost-efficient and safe implementation of this technology. Materials that can bind hydrogen gas reversibly at ambient temperatures and more moderate pressures could play a pivotal role in enabling hydrogen-powered technologies. In this study, we use reliable computational modeling to investigate two synthetically feasible paths for tuning the enthalpy of H2 binding in MFU-4-type metal–organic frameworks (MOFs), aiming to maximize usable capacity. This study examines MIM4 IICl3(bta)6 (bta– = benzotriazolate) Kuratowski-type clusters as a model for strong binding sites in MFU-4l frameworks. We systematically evaluate the impact of separately tuning the central MII metal ion (which plays a structural role) and the peripheral MI metal ion (which binds the substrate) on the energetics of H2 binding. Our computational study reveals that H2 binding at an MI site mostly follows the trend AgI < CuI < NiI < CoI < AuI while a larger central MII site generally weakens the H2 binding at a MI site. Importantly, we have identified three new combinations of MI and MII to achieve high fractional usable capacities of the total H2 adsorbed under a pressure swing from 5 to 100 bar at room temperature. Additionally, we examine the nature of the binding interaction between the peripheral metal atom and the hydrogen molecule. While charge transfer predominantly induces this interaction, for several atom combinations, a change in the polarization (associated with variations in the ionic radius of the MI binding atom) is another important factor for adjusting the strength of the interaction. We suggest that the proposed compositions of Kuratowski-type clusters are highly desirable synthetic targets for future laboratory study.

Tkachenko, Nikolay V↗
DOE OSTI2021

Enantioselective C–H Amination Catalyzed by Nickel Iminyl Complexes Supported by Anionic Bisoxazoline (BOX) Ligands

The trityl-substituted bisoxazoline ( TrH BOX) was prepared as a chiral analogue to a previously reported nickel dipyrrin system capable of ring-closing amination catalysis. Ligand metalation with divalent NiI 2 (py) 4 followed by potassium graphite reduction afforded the monovalent (TrH BOX)Ni(py) (4). Slow addition of 1.4 equiv of a benzene solution of 1-adamantylazide to 4 generated the tetrazido ( TrH BOX)Ni(κ 2 -N 4 Ad 2 ) (5) and terminal iminyl adduct ( TrH BOX)Ni(NAd) (6). Investigation of 6 via single-crystal X-ray crystallography, NMR and EPR spectroscopies, and computations revealed a Ni(II)-iminyl radical formulation, similar to its dipyrrinato congener. Complex 4 exhibits enantioselective intramolecular C–H bond amination to afford N-heterocyclic products from 4-aryl-2-methyl-2-azidopentanes. Catalytic C–H amination occurs under mild conditions (5 mol % catalyst, 60 °C) and provides pyrrolidine products in decent yield (29%–87%) with moderate ee (up to 73%). Substrates with a 3,5-dialkyl substitution on the 4-aryl position maximized the observed enantioselectivity. Kinetic studies to probe the reaction mechanism were conducted using 1H and 19F NMR spectroscopies. A small, intermolecular kinetic isotope effect (1.35 ± 0.03) suggests an H-atom abstraction step with an asymmetric transition state while the reaction rate is measured to be first order in catalyst and zeroth order in substrate concentrations. Enantiospecific deuterium labeling studies show that the enantioselectivity is dictated by both the H-atom abstraction and radical recombination steps due to the comparable rate between radical rotation and C–N bond formation. Furthermore, the competing elements of the two-step reaction where H-removal from the pro-R configuration is preferred while the preferential radical capture occurs with the Si face of the carboradical likely lead to the diminished ee observed, as corroborated by theoretical calculations. Furthermore, based on these enantio-determining steps, catalytic enantioselective synthesis of 2,5-bis-tertiary pyrrolidines is demonstrated with good yield (50–78%) and moderate ee (up to 79%).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Time-of-flight detection of terahertz phonon-polariton

A polariton is a fundamental quasiparticle that arises from strong light-matter interaction and as such has attracted wide scientific and practical interest. When light is strongly coupled to the crystal lattice, it gives rise to phonon-polaritons (PPs), which have been proven useful in the dynamical manipulation of quantum materials and the advancement of terahertz technologies. Yet, current detection and characterization methods of polaritons are still limited. Traditional techniques such as Raman or transient grating either rely on fine-tuning of external parameters or complex phase extraction techniques. To overcome these inherent limitations, we propose and demonstrate a technique based on a time-of-flight measurement of PPs. We resonantly launch broadband PPs with intense terahertz fields and measure the time-of-flight of each spectral component with time-resolved second harmonic generation. The time-of-flight information, combined with the PP attenuation, enables us to resolve the real and imaginary parts of the PP dispersion relation. We demonstrate this technique in the van der Waals magnets NiI 2 and MnPS 3 and reveal a hidden magnon-phonon interaction. We believe that this approach will unlock new opportunities for studying polaritons across diverse material systems and enhance our understanding of strong light-matter interaction.

condensed-matter physics↗
DOE OSTI2025

Electrical switching of a p-wave magnet

Magnetic states with zero magnetization but non-relativistic spin splitting are outstanding candidates for the next generation of spintronic devices. Their electronvolt (eV)-scale spin splitting, ultrafast spin dynamics and nearly vanishing stray fields make them particularly promising for several applications. A variety of such magnetic states with non-trivial spin textures have been identified recently, including even-parity d-wave, g-wave or i-wave altermagnets and odd-parity p-wave magnets. Achieving voltage-based control of the non-uniform spin polarization of these magnetic states is of great interest for realizing energy-efficient and compact devices for information storage and processing. Spin-spiral type II multiferroics are optimal candidates for such voltage-based control, as they exhibit an inversion-symmetry-breaking magnetic order that directly induces ferroelectric polarization, allowing for symmetry-protected cross-control between spin chirality and polar order. Here we combine photocurrent measurements, first-principles calculations and group-theory analysis to provide direct evidence that the spin polarization of the spin-spiral type II multiferroic NiI 2 exhibits odd-parity character connected to the spiral chirality. The symmetry-protected coupling between chirality and polar order enables electrical control of a primarily non-relativistic spin polarization. Our findings represent an observation of p-wave magnetism in a spin-spiral type II multiferroic, which may lead to the development of voltage-based switching of non-relativistic spin polarization in compensated magnets.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2023

A complete spectroscopic catalogue of local galaxies in the northern spring sky: Gas properties and nuclear activity in different environments

With the aim of providing the complete demography of galaxies in the local Universe, including their nuclear properties, we present SPRING, a complete census of local galaxies limited to the spring quarter of the northern sky (10h < RA < 16h; 0° < Dec < 65°). The SPRING catalogue is a flux- and volume-limited sample (r < 17.7 mag, cz < 10 000 km s -1 ) of 30 597 galaxies, including the Virgo, Coma, and A1367 clusters. Images and spectra were individually examined to clear the sample from unwanted entries. To inspect possible secular and environmental dependencies of the various nuclear excitation properties (star-forming versus active nuclei), we performed a multi-dimensional analysis by dividing the total sample according to: (i) their position in the (NUV - i) versus M star diagram, (ii) the local galaxy density, (iii) the stellar mass, (iv) the halo mass of the group to which galaxies belong, and (v) the neutral hydrogen content. We present a new calibration of the optical diameter-based H I-deficiency parameter H I def , employing a reference sample of isolated galaxies extracted from SPRING. At intermediate distances between Virgo and Coma, we identify a ring-like structure of galaxies constituted by three large filaments, each with a length of approximately 20h -1 Mpc, mostly composed of blue-cloud galaxies with stellar masses M star ≲ 10 10 M ⊙ . The fraction of H I-deficient galaxies within the filament (~30%) suggests that filaments are a transitioning environment between lower- and higher-overdensity environments in terms of H I content, as we find a clear progression from field galaxies to the filament and cluster galaxies for an increasing H I def parameter. We classify the nuclear spectra according to the four-line Baldwin-Phillips-Terlevich (BPT) and the two-line EWHα versus [NII]/Hα (WHAN) diagnostic diagrams, and investigate the variation in the fraction of active nuclei hosts with stellar mass, as well as their colours and environments. We observe that the fraction of low-ionisation nuclear emitting regions (LINERs) is a steep function of stellar mass, for example, it is consistent with zero up to M star ≲ 10 9.5 M ⊙ and becomes ~40% for M star ≳ 101 0.5 M ⊙ , whereas, for M star ≲ 10 9 - 9.5 M ⊙ , almost the entire spectroscopic sample is constituted of galaxies with star-forming nuclei. We investigate whether the nuclear-excitation fractions depend predominantly on the stellar mass or, conversely, on the galaxy environment. In general, we observe that the mass dependence of the fraction of Seyfert nuclei is not very sensitive to the galaxy environment, whereas the fraction of star-forming nuclei is a steeper function of stellar mass in lower-density environments and in blue-cloud galaxies. We find that the fraction of LINERs depends on galaxy colour and, for M star ≳ 10 9.5 - 10 M ⊙ , increases in galaxies belonging to the green valley.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Discovery of the luminous X-ray ignition eRASSt J234402.9-352640: I. Tidal disruption event or a rapid increase in accretion in an active galactic nucleus?

In November 2020, a new, bright object, eRASSt J234402.9-352640, was discovered in the second all-sky survey of SRG/eROSITA. The object brightened by a factor of at least 150 in 0.2–2.0 keV flux compared to an upper limit found six months previous, reaching an observed peak of 1.76 -0.24 +0.03 × 10 -11 erg cm -2 s -1 . The X-ray ignition is associated with a galaxy at z = 0.10, making the peak luminosity log 10 (L 0.2-2 keV /[erg s -1 ]) = 44.7 ± 0.1. Around the time of the rise in X-ray flux, the nucleus of the galaxy brightened by approximately 3 mag. in optical photometry, after correcting for the host contribution. We present X-ray follow-up data from Swift, XMM-Newton, and NICER, which reveal a very soft spectrum as well as strong 0.2–2.0 keV flux variability on multiple timescales. Optical spectra taken in the weeks after the ignition event show a blue continuum with broad, asymmetric Balmer emission lines, and high-ionisation ([OIII]λλ4959,5007) and low-ionisation ([NII]λ6585, [SII]λλ6716,6731) narrow emission lines. Following the peak in the optical light curve, the X-ray, UV, and optical photometry all show a rapid decline. The X-ray light curve shows a decrease in luminosity of ~0.45 over 33 days and the UV shows a drop of ~0.35 over the same period. eRASSt J234402.9-352640 also shows a brightening in the mid-infrared, likely powered by a dust echo of the luminous ignition. We find no evidence in Fermi-LAT γ-ray data for jet-like emission. The event displays characteristics of a tidal disruption event (TDE) as well as of an active galactic nucleus (AGN), complicating the classification of this transient. Based on the softness of the X-ray spectrum, the presence of high-ionisation optical emission lines, and the likely infrared echo, we find that a TDE within a turned-off AGN best matches our observations.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Mechanical, electronic, optical, piezoelectric and ferroic properties of strained graphene and other strained monolayers and multilayers: an update

Abstract This is an update of a previous review (Naumis et al 2017 Rep. Prog. Phys. 80 096501). Experimental and theoretical advances for straining graphene and other metallic, insulating, ferroelectric, ferroelastic, ferromagnetic and multiferroic 2D materials were considered. We surveyed (i) methods to induce valley and sublattice polarisation ( P ) in graphene, (ii) time-dependent strain and its impact on graphene’s electronic properties, (iii) the role of local and global strain on superconductivity and other highly correlated and/or topological phases of graphene, (iv) inducing polarisation P on hexagonal boron nitride monolayers via strain, (v) modifying the optoelectronic properties of transition metal dichalcogenide monolayers through strain, (vi) ferroic 2D materials with intrinsic elastic ( σ ), electric ( P ) and magnetic ( M ) polarisation under strain, as well as incipient 2D multiferroics and (vii) moiré bilayers exhibiting flat electronic bands and exotic quantum phase diagrams, and other bilayer or few-layer systems exhibiting ferroic orders tunable by rotations and shear strain. The update features the experimental realisations of a tunable two-dimensional Quantum Spin Hall effect in germanene, of elemental 2D ferroelectric bismuth, and 2D multiferroic NiI 2 . The document was structured for a discussion of effects taking place in monolayers first, followed by discussions concerning bilayers and few-layers, and it represents an up-to-date overview of exciting and newest developments on the fast-paced field of 2D materials.

Physics↗
DOE OSTI2020

Resilient U.S. Land Ports of Entry

The continued operation of Land Ports of Entry (LPOE), managed by the Customs and Border Protection (CBP) and General Services Administration% is vital to the U.S. economy and security. Border faculties are included in the Department of Homeland Security (DHS) Government Facilities Sector2, one of the 16 critical infrastructures "whose assets, systems, and networks, whether physical or virtual, are considered so vital to the United States that their incapacitation or destruction would have a debilitating effect on security, national economic security, national public health or safety, or any combination thereof.'" Specifically, disruptions to the flow of border crossing traffic, in the form of closures or increased border crossing wait times, impact the economy and security of all countries involved. This paper describes a process for analyzing and improving the resilience of U.S. Land Ports of Entry. For LPOE, the team believes that energy resilience is the primary objective due to the complete reliance on the e-manifest system and the increasing use of Multi-Energy Portals (MEPs). Emanifests are part of CPB's Automated Commercial Environment (ACE). They document several key pieces of information about cargo vehicles wishing to cross the border into the United States and are submitted before arriving at the port. Vehicles can be flagged for more invasive inspection based on the content of the e-manifest. MEPs are a non-intrusive inspection (NII) technology used to scan the contents of the cargo. Together MEPs and ACE serve an important role in aiding CBP with their mission to protect "the public from dangerous people and materials", and "enabling legitimate trade and travel.'" To analyze resilience of a port, the team would need to understand the port's current energy usage, which systems depend on energy and what backup systems exist, and any emergency operation plans that dictate how systems are operated in the event of a power outage. The team would also need to determine the design basis threats (DBTs) for the LPOE which could include natural disasters, manmade events, and accidents. The magnitudes of the DBTs are calculated and are then translated to expected impacts on the infrastructure and systems at the port. With this information gathered, existing LPOE models developed here at Sandia National Laboratories could be extended to support decisions about resilience. Current models are implemented in FlexSim, a 3rd party discrete event simulator. FlexSim provides 3-D visuals of physical layout that can reveal valuable insights, allows input to be variable (e.g. time it takes to interact with the CBP officer at primary inspection can vary) so that a whole range of possibilities can be captured in the results, and can be used to collect user-defined output metrics. Current LPOE models focus on cargo vehicle traffic, and process changes caused by the installation of new drive-through MEPs. Extending them to address resilience questions would require the addition of key pieces of information learned during the resilience analysis including critical systems, failure rates, and process changes for when failures occur. The primary output metric for current models is border crossing wait time. Additional metrics would also be added to the model to gain a more complete understanding of impacts related to resilience, for example, MEP scan rate. Once complete, the model could be used to analyze the effectiveness of mitigation strategies representing some future state.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2026

A New Record Census of Dwarf AGN and a Bimodal $M_{\rm BH}$-$M_{\star}$ Scaling Relation with DESI DR1

Using the first spectroscopic data release from the Dark Energy Spectroscopic Instrument (DESI DR1), we search for AGN signatures in 1,678,787 low-redshift ($0.001 \le z \le 0.45$) line-emitting galaxies. Based on the [NII]-BPT emission-line ratio diagnostic, we identify AGN in 314,245/1,211,573 (25.9%) high-mass ($\log (M_{\star}/M_{\odot}) > 9.5$) and 9648/467,214 (2.1%) dwarf ($\log (M_{\star}/M_{\odot}) \le 9.5$) galaxies. Among these AGN, 17,949 are broad-line candidates (BL-AGN) with broad H$α$ emission, enabling black hole (BH) mass estimates using single-epoch virial methods. We find that the AGN fraction in line-emitting galaxies increases monotonically with stellar mass, rising from $\sim$1.4% at the low-mass end to $\sim$93.3% at the high-mass end. Using the large BL-AGN sample, we extend the $M_{\rm BH} - M_{\star}$ scaling relation down to $\log (M_{\star}/M_{\odot}) \approx 7.8$ and $\log (M_{\rm BH}/M_{\odot}) \approx 4.4$. In the context of high-redshift overmassive BHs, our results suggest that galaxies and their central BHs may follow two distinct evolutionary pathways across cosmic time. With this paper, we release the EmFit value-added catalog, containing emission-line flux and width measurements for $\sim$7.4 million galaxies, the largest catalog with emission-line decomposition into narrow, broad, and outflow components to date. This work significantly expands upon the early DESI results and provides a statistical sample for probing the galaxy$-$BH connection in the low-mass galaxy regime.

Pucha, Ragadeepika [Utah U.; Arizona U., Astron. D↗
DOE OSTI2023

Changing temperature profiles and the risk of dengue outbreaks

As temperatures change worldwide, the pattern and competency of disease vectors will change, altering the global distribution of both the burden of infectious disease and the risk of the emergence of those diseases into new regions. To evaluate the risk of potential summer dengue outbreaks triggered by infected travelers under various climate scenarios, we develop an SEIR-type model, run numerical simulations, and conduct sensitivity analyses under a range of temperature profiles. Our model extends existing theoretical frameworks for studying dengue dynamics by introducing temperature dependence of two key parameters: the mosquito extrinsic incubation period and the lifespan of mosquitoes, which empirical data suggests are both highly temperature dependent. We find that changing temperature significantly alters dengue risk in an inverted U-shape, with temperatures in the range 27-31°C producing the highest risk. As temperatures increase beyond 31°C, the determinants of dengue risk begin to shift from mosquito biting rate and carrying capacity to the duration of the human infectious period, suggesting that changing temperatures not only alter dengue risk but also the potential efficacy of control measures. To illustrate the role of spatial and temporal temperature heterogeneity, we select five US cities where the primary dengue vector, the mosquito Aedes aegypti , has been observed, and which have had dengue cases in the past: Los Angeles, Houston, Miami, Brownsville, and Phoenix. Our analysis suggests that an increase of 3°C leads to an approximate doubling of the risk of dengue in Los Angeles and Houston, but a reduction of risk in Miami, Brownsville, and Phoenix due to extreme heat.

54 ENVIRONMENTAL SCIENCES↗