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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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Two Circuits for Directing and Controlling Ballistic Fluxons

Reversible logic schemes using flux solitons (fluxons) on long Josephson junctions (LJJs) have recently been proposed. The attraction of the fluxon is that it propagates ballistically along an LJJ until it encounters a change in the character of the LJJ, often a designed circuit element. Logic gates involve fluxons interacting with circuit elements and with other fluxons. However, testing of ballistic fluxon circuits requires other circuits outside the logic family to direct and control fluxon motion. Here we discuss two such non-reversible fluxon control circuits. First, the polarity filter gate is a simple non-reversible gate that allows one polarity of fluxon to pass, while reflecting the other polarity. In the off state both polarities reflect. Second, the polarity separator generalizes on the polarity filter concept and allows separation of the two fluxon polarities into different LJJs. We discuss simulations of these structures and possible applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Quantum Foundations of Classical Reversible Computing

The reversible computation paradigm aims to provide a new foundation for general classical digital computing that is capable of circumventing the thermodynamic limits to the energy efficiency of the conventional, non-reversible digital paradigm. However, to date, the essential rationale for, and analysis of, classical reversible computing (RC) has not yet been expressed in terms that leverage the modern formal methods of non-equilibrium quantum thermodynamics (NEQT). In this paper, we begin developing an NEQT-based foundation for the physics of reversible computing. We use the framework of Gorini-Kossakowski-Sudarshan-Lindblad dynamics (a.k.a. Lindbladians) with multiple asymptotic states, incorporating recent results from resource theory, full counting statistics and stochastic thermodynamics. Important conclusions include that, as expected: (1) Landauer’s Principle indeed sets a strict lower bound on entropy generation in traditional non-reversible architectures for deterministic computing machines when we account for the loss of correlations; and (2) implementations of the alternative reversible computation paradigm can potentially avoid such losses, and thereby circumvent the Landauer limit, potentially allowing the efficiency of future digital computing technologies to continue improving indefinitely. We also outline a research plan for identifying the fundamental minimum energy dissipation of reversible computing machines as a function of speed.

97 MATHEMATICS AND COMPUTING↗

Atomistic Mechanisms of the Crystallographic Orientation‐Dependent Cu 1.8 S Conductive Channel Formation in Cu 2 S‐Based Memristors

Achieving multiple types of resistive switching in a single material with controlled ionic motion is a key challenge in neuromorphic computing, traditionally addressed by combining materials with distinct switching behaviors. Here, Cu 2-x S is identified as a promising candidate to overcome this limitation due to its hierarchical phase transitions. Using in situ biasing experiments, reversible and non-reversible phase transitions (and resistive switching) are demonstrated in γ-Cu 2 S by controlling the compliance current. The formation of parallel high-digenite Cu 1.8 S channels, orientated along the γ-Cu 2 S [201] crystallographic direction, drives the nonvolatile resistive switching. These channels emerge via an intermediate δ-Cu 2 S phase and are stabilized at room temperature by residual strains, alongside β-Cu 2 S phase. In conclusion, the work clarifies the complex, electrically triggered phase transformations in γ-Cu 2 S, and highlights the potential of Cu 2-x S as a versatile material for neuromorphic computing.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Incorporating Electrochemical Halide Oxidation into Drift-Diffusion Models to Explain Performance Losses in Perovskite Solar Cells under Prolonged Reverse Bias

Partial shading of a solar module can induce a set of cells within the module to operate under reverse bias. Studies have shown that metal halide perovskite solar cells with a wide variety of compositions and contacts exhibit interesting behavior in reverse bias that includes both reversible performance loss and non-reversible degradation. In this paper, an advanced drift-diffusion approach incorporating an electrochemical term to explain the short-circuit, open circuit and fill factor losses that are experimentally measured after prolonged reverse bias is used. It is shown that holes can tunnel into the perovskite due to sharp band bending near the contact, accumulate within the bulk of the perovskite absorber, and trigger the oxidation of halides to form neutral halogens. The density of neutral halogens is much higher in reverse bias because there are hardly any electrons available to reduce the iodine. The resulting halogens act as bulk recombination centers. While the interstitial halogen density does decay when the cell is operated in forward bias, permanent degradation can occur if the iodine diffuses out of the perovskite layer. Finally, the ways in which changing parameters such as the mobile ion density or the series resistance at the contact can influence device performance and stability are discussed.

degradation↗

Recyclability of reversible polymer networks over a Dozen reprocessing cycles

Reversible polymer networks capable of reversible reactions along their backbone provide a promising strategy for addressing waste management challenges associated with conventional thermoset products. However, reversible polymer networks cannot be recycled infinitely. Unavoidable side reactions eventually cause significant degradation of mechanical properties or loss of recyclability. This study aims to answer a simple yet critical question on reversible polymer network systems: how many reprocessing cycles can be achieved before profound mechanical degradation or a loss of recyclability? The recyclability of Diels–Alder (DA) network samples was evaluated by repeating consistent reprocessing cycles until they were no longer reprocessable. To enhance their recyclability, the chemical structure of the maleimide precursor was tailored to mitigating side reactions by maleimide homopolymerization. Remarkably, by employing a maleimide precursor with alkyl substitutions on its phenyl group, the DA network system attained 12 reprocessing cycles using injection molding at 160 °C without significant degradation of mechanical properties. However, the 13th reprocessing cycle did not succeed. Rheological analysis revealed the accumulation of non-reversible bonds within the network structure during repeated reprocessing, despite fairly consistent mechanical properties under operating conditions. This study demonstrates that the rational design of the maleimide precursor is an effective means to enhance the reprocessability of DA networks.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Debonding-on-demand reversible adhesives via heat or light with competitive adhesion strength to conventional epoxy adhesives

Stimuli responsive debonding-on-demand (DoD) reversible adhesives are of great interest for the circular economy. However, the reversible adhesives developed so far often lack competitive adhesion strength in a bonding state. In this work, reversible epoxy adhesives based on Diels–Alder (DA) chemistry were developed and exhibited a competitive adhesion strength (e.g., 12 – 16 MPa of a lap shear strength) to commercial non-reversible epoxy adhesives. The reversible epoxy formulation showed superior thermal stability up to 110°C, and transition to a debonding state in the order of 0.1 MPa at 140°C, consequently, an on/off-type debonding behavior. The transition to a debonding state was attributed to crosslinking density control (e.g., decrease by 33% – 49%) through the reversible DA chemistry and the proximity to the glass transition. Next, for debonding by light stimulus, photothermal refractory plasmonic titanium nitride (TiN) nanoparticles were incorporated in the reversible epoxy, which can generate the required heat for debonding upon exposure to visible light. Photothermal debonding allows for precise debonding at target areas and tunable adhesion strength by controlling the exposure area and light intensity. The DA adhesive formulations containing 0.5 wt.% TiN nanoparticles presented a debonding state with zero adhesion under light exposure with intensity of 1670 mW/cm 2 (inducing 140°C). Even after three cycles of reattachment, the DA adhesive formulations retained 96% of the pristine sample’s adhesion strength measured at 110°C. Therefore, the DA adhesives are attractive candidates as reversible DoD systems applicable in higher temperatures.

42 ENGINEERING↗

Global linear and nonlinear gyrokinetic simulations of tearing modes

Abstract To better understand multi-scale interactions between global tearing modes and microturbulence in the Madison Symmetric Torus (MST) reversed-field pinch (RFP), the global gyrokinetic code Gene is modified to describe global tearing mode instability via a shifted Maxwellian (SM) distribution consistent with experimental equilibria. The implementation of the SM is tested and benchmarked by comparisons with different codes and models. Good agreement is obtained in code-code and code-theory comparisons. Linear stability of tearing modes of a non-reversed MST discharge is studied. A collisionality scan is performed to the lowest order unstable modes ( n = 5, n = 6) and shown to behave consistently with theoretical scaling. The nonlinear evolution is simulated, and saturation is found to arise from mode coupling and transfer of energy from the most unstable tearing mode to small-scale stable modes mediated by the m = 2 tearing mode. The work described herein lays the foundation for nonlinear simulation and analysis of the interaction of tearing modes and gyroradius-scale instabilities in RFP plasmas.

Physics↗

XCT System for Harvesting In-Current Hydrokinetic Energy from Low-Velocity Sites

The Project demonstrated the functionality of a cross cutting (XCT) type turbine in laboratory and open water testing. The fundamental design approach of locating small axial rotors near the ends of driving spars, which pull the rotors through the water at a multiple of the free-stream velocity eliminates the need (and thus the cost) for a gearbox and torque resisting structures. This configuration, however, introduces the complexity of transmitting electricity across a rotating interface. Even so, cost models indicate that depending on the anchoring and mooring system, LCOE less than $0.10/kWh should be possible in high capacity-factor sites with non-reversing currents.

13 HYDRO ENERGY↗

Experimental Study of Instabilities in Hydrogen-Air Fueled Rotating Detonation Combustion Presentation

Conventional gas turbine engines rely on an idealized constant pressure combustion process that in reality produces a pressure decrease as a result of viscous and other non-reversible losses. An alternative approach is rotating detonation combustion (RDC) which is a form of pressure gain combustion in which one or more detonation waves propagate an annular channel resulting in an increase in pressure across, subsequently providing greater work availability compared to deflagration ultimately leading to opportunities for greater thermodynamic efficiency when used in gas turbine engines that conventionally relies on constant. Modern gas turbine engines often rely on pre-mixed reactants to limit NOx emissions, although this may result in greater susceptibility to instabilities such as flashback and thermoacoustic oscillation, particularly for applications that utilize hydrogen as the fuel. Research in RDC has focused on non-premixed reactants thus limiting the occurrence of flashback, and high frequency detonation wave propagation (kHz) may interfere with the occurrence of thermoacoustic oscillations. Thermal NOx emissions are controlled through rapid combustion and sudden expansion of the working fluid. Although RDC may not be susceptible to instabilities encountered in conventional state of the art gas turbine engine combustion, there may be other mechanisms occurring that support instabilities that could be detrimental to performance.

Weber, Justin↗

Models of an early lunar dynamo

The hypothesis that a dynamo once existed in the moon, and hence was the source of lunar paleomagnetism, is tested using a model for the global thermoremanent magnetization of spherical lithospheres. Various models of an ancient lunar dipole field are used which incorporate intensity variations and reversals, and which are consistent with lunar sample paleointensities. It is found that non-reversing lunar dynamos which have simple exponential decay histories beginning at 4.6 b.y. ago are inconsistent with this limit, unless the moon has been thoroughly demagnetized to a depth of tens of kilometers by impacts or other processes. An early lunar dynamo cannot be excluded by global scalar measurements unless the permanent lunar dipole moment is shown to be significantly less than 10 to the 13th power G/cu cm by future spacecraft measurements, which may be technologically impossible; vector measurements of lunar magnetic anomalies over the whole moon offer a possibility of determining the source of the field which magnetized the lunar crust.

Srnka, L. J.↗

Honeycomb Core Permeability Under Mechanical Loads

A method for characterizing the air permeability of sandwich core materials as a function of applied shear stress was developed. The core material for the test specimens was either Hexcel HRP-3/16-8.0 and or DuPont Korex-1/8-4.5 and was nominally one-half inch thick and six inches square. The facesheets where made of Hercules' AS4/8552 graphite/epoxy (Gr/Ep) composites and were nominally 0.059-in. thick. Cytec's Metalbond 1515-3M epoxy film adhesive was used for co-curing the facesheets to the core. The permeability of the specimens during both static (tension) and dynamic (reversed and non-reversed) shear loads were measured. The permeability was measured as the rate of air flow through the core from a circular 1-in2 area of the core exposed to an air pressure of 10.0 psig. In both the static and dynamic testing, the Korex core experienced sudden increases in core permeability corresponding to a core catastrophic failure, while the URP core experienced a gradual increase in the permeability prior to core failure. The Korex core failed at lower loads than the HRP core both in the transverse and ribbon directions.

Glass, David E.↗

The Effect of Solution Thermal History on Chicken Egg White Lysozyme Nucleation

Proteins are highly flexible molecules and often exhibit defined conformational changes in response to changes in the ambient temperature. Chicken egg white lysozyme has been previously shown to undergo an apparent structural change when warmed above the tetragonal/orthorhombic phase transition temperature. This is reflected by a change in the habit of the tetragonal and orthorhombic crystals so formed. In this study, we show that possible conformational changes induced by heating are stable and apparently non-reversible by simple cooling. Exposure of protein solutions to temperatures above the phase change transition temperature, before combining with precipitant solution to begin crystallization, reduces final crystal numbers. Protein that is briefly warmed to 37 C, then cooled shows no sign of reversal to the unheated nucleation behavior even after storage for four weeks at 4 C. The change in nucleation behavior of tetragonal lysozyme crystals, attributed to a structural shift, occurs faster the greater the exposure to temperature above the equi-solubility point for the two phases. Heating for 2 hours at 48 C reduces crystal numbers by 20 fold in comparison to the same solution heated for the same time at 30 C. Thermal treatment of solutions is therefore a possible tool to reduce crystal numbers and increase crystal size. The effects of a protein's previous thermal history are now shown to be a potentially critical factor in subsequent macromolecule crystal nucleation and growth studies.

Burke, Michael W.↗

Human vertical eye movement responses to earth horizontal pitch

The vertical eye movements in humans produced in response to head-over-heels constant velocity pitch rotation about a horizontal axis resemble those from other species. At 60 degrees/s these are persistent and tend to have non-reversing slow components that are compensatory to the direction of rotation. In most, but not all subjects, the slow component velocity was well characterized by a rapid build-up followed by an exponential decay to a non-zero baseline. Super-imposed was a cyclic or modulation component whose frequency corresponded to the time for one revolution and whose maximum amplitude occurred during a specific head orientation. All response components (exponential decay, baseline and modulation) were larger during pitch backward compared to pitch forward runs. Decay time constants were shorter during the backward runs, thus, unlike left to right yaw axis rotation, pitch responses display significant asymmetries between paired forward and backward runs.

NASA Program Space Physiology and Countermeasures↗

Can Machine Learning Reveal Precursors of Reversals of the Geomagnetic Axial Dipole Field?

It is well known that the axial dipole part of Earth’s magnetic field reverses polarity, so that the magnetic North Pole becomes the South Pole and vice versa. The timing of reversals is well documented for the past 160 Myr, but the conditions that lead to a reversal are still not well understood. It is not known if there are reliable ‘precursors’ of reversals (events that indicate that a reversal is upcoming) or what they might be. We investigate if machine learning (ML) techniques can reliably identify precursors of reversals based on time-series of the axial magnetic dipole field. The basic idea is to train a classifier using segments of time-series of the axial magnetic dipole. This training step requires modification of standard ML techniques to account for the fact that we are interested in rare events—a reversal is unusual, while a non-reversing field is the norm. Without our tweak, the ML classifiers lead to useless predictions. Perhaps even more importantly, the usable observational record is limited to 0–2 Ma and contains only five reversals, necessitating that we determine if the data are even sufficient to reliably train and validate an ML algorithm. To answer these questions we use several ML classifiers (linear/non-linear support vector machines and long short-term memory networks), invoke a hierarchy of numerical models (from simplified models to 3-D geodynamo simulations), and two palaeomagnetic reconstructions (PADM2M and Sint-2000). The performance of the ML classifiers varies across the models and the observational record and we provide evidence that this is not an artefact of the numerics, but rather reflects how ‘predictable’ a model or observational record is. Studying models of Earth’s magnetic field via ML classifiers thus can help with identifying shortcomings or advantages of the various models. For Earth’s magnetic field, we conclude that the ability of ML to identify precursors of reversals is limited, largely due to the small amount and low frequency resolution of data, which makes training and subsequent validation nearly impossible. Put simply: the ML techniques we tried are not currently capable of reliably identifying an axial dipole moment (ADM) precursor for geomagnetic reversals. This does not necessarily imply that such a precursor does not exist, and improvements in temporal resolution and length of ADM records may well offer better prospects in the future.

Kyle Gwirtz↗

Fluorescent compositions

A fluorescent composition includes at least one of a fluorescent sensor compound and organic reporter molecules encapsulated in a microsphere structure. When encapsulated, the fluorescent sensor compound and the organic reporter molecules are distributed in a liquid organic matrix. When non-encapsulated, the remaining one of the fluorescent sensor compound and the organic reporter molecules reside in the matrix. In response to a force applied to the composition sufficient to break at least a portion of the microsphere structure, the fluorescent sensor compound and the organic reporter molecules are transformed into a non-reversible fluorescent state exhibiting a quantum yield greater than 0.2. The fluorescent state is objectively visually verifiable without physically contacting the composition.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Fluorescent compositions

An article that includes a fluorescent composition having at least one of a fluorescent sensor compound and organic reporter molecules encapsulated in a microsphere structure. When encapsulated, the fluorescent sensor compound and the organic reporter molecules are distributed in a liquid organic matrix. When non-encapsulated, the remaining one of the fluorescent sensor compound and the organic reporter molecules reside in the matrix. In response to a force applied to the composition sufficient to break at least a portion of the microsphere structure, the fluorescent sensor compound and the organic reporter molecules are transformed into a non-reversible fluorescent state exhibiting a quantum yield greater than 0.2. The fluorescent state is objectively visually verifiable without physically contacting the composition.

Smartt, Heidi A.↗

Fluorescent compositions

An article that includes a fluorescent composition having at least one of a fluorescent sensor compound and organic reporter molecules encapsulated in a microsphere structure. When encapsulated, the fluorescent sensor compound and the organic reporter molecules are distributed in a liquid organic matrix. When non-encapsulated, the remaining one of the fluorescent sensor compound and the organic reporter molecules reside in the matrix. In response to a force applied to the composition sufficient to break at least a portion of the microsphere structure, the fluorescent sensor compound and the organic reporter molecules are transformed into a non-reversible fluorescent state exhibiting a quantum yield greater than 0.2. The fluorescent state is objectively visually verifiable without physically contacting the composition.

Smartt, Heidi A.↗

Accelerating multicanonical sampling with irreversibility

Flat-histogram Monte Carlo simulations are well-established, robust methods to perform random walks in a physical observable or parameter space, making them suitable for finding ground states or studying phase transitions in complex systems in statistical physics. However, their efficiency can be limited by the time to attain the desired flat distribution, which is generally unknown prior to the simulations. In particular, they might suffer from slowing down towards the end of a simulation due to the diffusive nature of random walks. In this work we apply irreversibility to the multicanonical Monte Carlo method via the lifting approach to alleviate this behavior. We achieve a 2–4 times speedup in ground-state search for a two-dimensional (2D) Ising model, and up to an order of magnitude of speedup for finding the ground-state energy in an Edwards–Anderson spin glass, compared to traditional multicanonical sampling. In conclusion, the round-trip times between ground states show a narrower distribution and are significantly shorter compared to the reversible counterpart, suggesting that a lower convergence time with a smaller time variance is feasible.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗