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Nozomi Cis-Lunar Phase Orbit Determination

Japan's Institute of Space and Astronautical Science (ISAS) launched Nozomi, its first mission to the planet Mars using the newly developed M-V launch vehicle on July 3, 1998. Scientific objectives of the mission are to study the structure and dynamics of the Martian upper atmosphere and its interaction with the solar wind. Nozomi is a cooperative mission between ISAS and the National Aeronautics and Space Administration (NASA). The NASA contribution includes navigation and tracking services provided by the Jet Propulsion Laboratory (JPL). The spacecraft also serves as an engineering demonstration of basic technology for planetary exploration. One of the new technologies was a unique trajectory, developed by ISAS, which used solar gravitational perturbations at the weak stability boundary as an aid to achieve an Earth-Mars transfer orbit. This trajectory saves approximately 120 m/s of Delta V compared to direct hyperbolic insertion and is considered an enabling technology for the mission. Nozomi was the first spacecraft to employ this trajectory and provided on-orbit validation of the technique. The trajectory was achieved by initially placing the spacecraft in a highly elliptical cis-lunar phasing orbit. Six maneuvers were performed during this period to correct injection errors and target an outbound lunar swingby in September 1998. The gravity assist from the lunar swingby raised apogee to the vicinity of the weak stability boundary. After three more targeting maneuvers, Nozomi performed an inbound lunar swingby followed immediately by a powered Earth swingby in late December 1998. A 420 m/s Trans Mars Insertion (TMI) burn at the final Earth periapsis was intended to place the spacecraft on a heliocentric trajectory leading to Mars orbit insertion in October 1999. Orbit determination for Nozomi is performed in parallel by both ISAS and the Multi-Mission Navigation (MMNAV) group at JPL. This was an advantage for the mission because each group would generate solutions based on data collected from their respective tracking networks. Spacecraft events, such as sequence uplinks and maneuvers, were generally scheduled during passes at the Usuda tracking station in Japan. As a result, maneuver design and reconstruction was derived from MMNAV solutions based on JPL tracking data obtained immediately prior to or following maneuvers. Data was also exchanged between ISAS and MMNAV so orbit determination could be performed on joint data sets in support of critical targeting late in the cis-lunar phase. In this paper, information regarding the MMNAV orbit determination effort for the first six months of the mission is presented. The spacecraft trajectory is characterized first, followed by a discussion of the orbit determination estimation procedure and models. Results from selected orbit solutions are presented and compared against reconstructed trajectories. One area of emphasis in this paper is orbit determination in the vicinity of the weak stability boundary. Precise navigation was necessary to target the second lunar swingby and the powered Earth swingby. Delivery accuracy of 150 m was required for these critical encounters, but a number of factors contributed to the general degradation of orbit determination accuracy. This included the fact that the spacecraft was at apogee, at a range of 1.7 million km and moving at less than I km/sec perpendicular to the line of sight. Nozomi was also close to zero degrees declination where there are known limitations on orbit determination performance. Finally, S-band tracking data was acquired through the Nozomi backup low gain antenna. This antenna is offset from the axis of this spin stabilized spacecraft and superimposed large signatures in the Doppler and range data. These difficulties were overcome by combining long data arcs, spanning several maneuvers, with a high fidelity solar pressure model. The model included a physically accurate representation of the spacecraft structure and a high time resolution orientation model. Observation modeling included the removal of the spin induced Doppler bias, spin signature and per pass correction of range calibration errors applied for data leading up to critical events. As a result, all orbit determination goals were met. A second area of emphasis in this paper is the JPL tracking and orbit determination effort in support of the TMI maneuver. TMI occurred out of contact with ground stations and the JPL Goldstone tracking complex had the first pass following the bum. As a result, MMNAV had the responsibility to make a rapid assessment of the maneuver performance. MMNAV made the determination that a 100 m/s under bum had occurred and promptly informed ISAS via voice lines. ISAS immediately began preparations for a correction maneuver (TMIc), which had to be performed during the next Usuda pass. The near real time assessment by MMNAV provided accurate antenna frequency and pointing updates for the spacecraft acquisition at Usuda and the close coordination between the two agencies enabled the design and successful execution of the TMc maneuver. Propellant consumption during the correction burn dictated that the mission be redesigned. ISAS developed a new plan which adds 3 full solar orbits, two Earth swingbys and one lunar swingby with arrival at Mars in January 2004. The final Mars orbit will still enable the mission to achieve all of its science objectives.

Ryne, Mark↗

Nozomi Cis-Lunar Phase Orbit Determination

Japan's Institute of Space and Astronautical Science (ISAS) launched Nozomi, its first mission to the planet Mars using the newly developed M-V launch vehicle on July 3, 1998.

orbit↗

Nozomi Earth swingby orbit determination

This paper describes the Jet Propulsion Laboratory effort to navigate Nozomi, in conjunction with Japan's Institute of Space and Astronauticaal Science, past two Earth swingbys using differential tracking techniques to successfully place the spacecraft on a trajectory reaching Mars in December 2003.

Nandi, Sumita↗

Mass Spectrometers in Deep Space Missions

Mass spectrometers have been included in the payloads of several deep space missions over the past three decades. Our laboratory has designed and developed mass spectrometers for the Galileo Probe into the atmosphere of Jupiter, the Pioneer Venus Orbiter, the Cassini Orbiter Mission to Saturn, the Cassini/Huygens Probe Mission to Saturn's moon Titan, the Nozomi Mission to Mars, and most recently the CONTOUR comet nucleus flyby mission. Each mission has required attention to miniaturization, autonomous sampling, and consideration of the special hazards and measurement requirements of the target environment. Development ongoing in our laboratory includes further miniaturization, improved performance in the areas of sensitivity and precision for the important isotope measurements, and adaptation for the unusual environments to be encountered in locations such as the surface or subsurface of Europa or Mars. Various aspects of both the technical implementation of these delivered and planned experiments and the science drivers will be described.

Mahaffy, Paul↗

Co-Investigator for the Planet B NMS

This is the final report. The effort under this contract consisted mainly with meetings and discussions with our NASA/GSFC and ISAS partners of the neutral mass spectrometer team of the Nozomi mission. The activities were to serve the purpose to prepare and co-ordinate our activities in preparation for the anticipated data analysis and science interpretation of the data after Mars orbit insertion. Given the unfortunate initial delays this effort included a number of visits to ISAS in Tokyo and participation in co-ordination and science workshops. We participated in a paper describing the instrument, which was published. We also worked on certain theoretical calculations in order to evaluate measurement opportunities for the mass spectrometer at Mars. The major aspect of this effort was a series of calculations on the feasibility of measuring hot atoms in the upper atmosphere. We calculated the densities of hot oxygen and carbon. Although this work established that their abundance is probably below the sensitivity of the mass spectrometer, it was of scientific importance and the results were presented at scientific meetings and published in the open literature.

Nagy, Andrew↗

Using Gravity Assists in the Earth-moon System as a Gateway to the Solar System

For spacecraft departing the Earth - Moon system, lunar flybys can significantly increase the hype rbolic escape energy (C3, in km 2 /sec 2 ) for a modest increase in flight time. Within ~2 months, lunar flybys can produce a C3 of ~2. Over 4 - 6 months, lunar flybys alone can increase the C3 to ~4.5, or they can provide for additional periapsis burns to increase the C3 from ~2 -3 to 10 or more, suitable for planetary missions. A lunar flyby departure can be followed by additional ∆ -V (such as that efficiently provided by a low thrust system, eg. Solar Electric Propulsion (SEP)) to raise the Earth - relative velocity (at a ratio of more than 2:1) before a subsequent Earth flyby, which redirects that velocity to a more di stant target, all within not much more than a year. This paper describes the applicability of lunar flybys for different flight times and propulsi on systems, and illustrates this with instances of past usage and future possibilities. Examples discussed i nclude ISEE - 3, Nozomi, STEREO, 2018 Mars studies (which showed an 8% payload increase), and missions to Near Earth Objects (NEOs). In addition, the options for the achieving the initial lunar flyby are systematically discussed, with a view towards their p ractical use with in a compact launch period. In particular, we show that launches to geosynchronous transfer orbit (GTO) as a secondary payload provide a feasible means of obtaining a lunar flyby for an acceptable cost, even for SEP systems that cannot ea sily deliver large ∆ - Vs at periapsis. Taken together, these results comprise a myriad of options for increasing the mission performance, by the efficient use of lunar flybys within an acceptable extension of the flight time.

lunar fly-bys↗

Using Gravity Assists in the Earth-moon System as a Gateway to the Solar System

For spacecraft departing the Earth - Moon system, lunar flybys can significantly increase the hyperbolic escape energy (C3, in km (exp 2) /sec (exp 2) ) for a modest increase in flight time. Within approx 2 months, lunar flybys can produce a C3 of approx 2. Over 4 - 6 months, lunar flybys alone can increase the C3 to approx 4.5, or they can provide for additional periapsis burns to increase the C3 from approx 2 -3 to 10 or more, suitable for planetary missions. A lunar flyby departure can be followed by additional delta -V (such as that efficiently provided by a low thrust system, eg. Solar Electric Propulsion (SEP)) to raise the Earth - relative velocity (at a ratio of more than 2:1) before a subsequent Earth flyby, which redirects that velocity to a more distant target, all within not more than a year. This paper describes the applicability of lunar flybys for different flight times and propulsion systems, and illustrates this with instances of past usage and future possibilities. Examples discussed include ISEE-3, Nozomi, STEREO, 2018 Mars studies (which showed an 8% payload increase), and missions to Near Earth Objects (NEOs). In addition, the options for the achieving the initial lunar flyby are systematically discussed, with a view towards their practical use within a compact launch period. In particular, we show that launches to geosynchronous transfer orbit (GTO) as a secondary payload provide a feasible means of obtaining a lunar flyby for an acceptable cost, even for SEP systems that cannot easily deliver large delta-Vs at periapsis. Taken together, these results comprise a myriad of options for increasing the mission performance, by the efficient use of lunar flybys within an acceptable extension of the flight time.

Solar Electric Propulsion (SEP)↗

Reconstruction of Cysteine Biosynthesis Using Engineered Cysteine-Free and Methionine-Free Enzymes

Ten of the proteinogenic amino acids can be generated abiotically while the remaining thirteen require biology for their synthesis. Paradoxically, the biosynthesis pathways observed in nature require enzymes that are made with the amino acids they produce. For example, Escherichia coli produces cysteine from serine via two enzymes that contain cysteine. Here, we substituted alternate amino acids for cysteine and also methionine, which is biosynthesized from cysteine, in serine acetyl transferase (CysE) and O-acetylserine sulfhydrylase (CysM). CysE function was rescued by cysteine-and-methionine-free enzymes and CysM function was rescued by cysteine-free enzymes. Structural modeling suggests that methionine stabilizes CysM and is present in the active site of CysM. Cysteine is not conserved among CysE and CysM protein orthologs, suggesting that cysteine is not functionally important for its own synthesis. Engineering biosynthetic enzymes that lack the amino acids being synthesized provides insights into the evolution of amino acid biosynthesis and pathways for bioengineering.

proteinogenic amino acids↗

Reflectivity Around the Gold M-Edges of X-ray Reflector of the Soft X-Ray Telescope Onboard ASTRO-H

The X-ray astronomy satellite ASTRO-H are equipped with two equivalent soft X-ray telescopes (SXT-I and SXT-S) which cover the energy band 0.3-12 keV. The X-ray reflectors of the SXTs are coated with a gold monolayer by means of the replication technique. A series of gold M absorption edges in the 2-4 keV band causes complex structures in the energy response of the SXTs. In the same band, there are astrophysically important emission lines from Si, Ar and S. Since the SXS has unprecedentedly high spectral resolution, we have measured the reflectivity around the gold M-edges in an extremely fine energy pitch at the synchrotron radiation facility KEK PF BL11-B, with the 2 eV pitch in 2100 eV to 4100 eV band that covers the entire series of the absorption edges (M-I through M-V) at grazing incident angles to the reflectors of 0.5, 0.8, 1.0, 1.2, 1.4 degree, and with a finer pitch of 0.25 eV in the 2200 eV to 2350 eV band where the two deepest M-IV and M-V edges are included. In the resultant reflectivity curves, we have clearly identified the fine structures associated with all the M-edges. Using these data, we calculated atomic scattering factor f1 as a function of X-ray energy, with which we have built the mirror response function which can be applied to the Suzaku spectra. As a result, we have found that discrepancy of the spectral model to the Suzaku data of 4U1630-472 (a black hole transient) and the Crab nebula around the M-edges are significantly reduced from those with the official Suzaku response.

ASTRO-H↗

First Peek of ASTRO-H Soft X-Ray Telescope (SXT) In-Orbit Performance

ASTRO-H (Hitomi) is a Japanese X-ray astrophysics satellite just launched in February, 2016, from Tanegashima, Japan by a JAXA's H-IIA launch vehicle. It has two Soft X-ray Telescopes (SXTs), among other instruments, that were developed by the NASA Goddard Space Flight Center in collaboration with ISAS/JAXA and Nagoya University. One is for an X-ray micro-calorimeter instrument (Soft X-ray Spectrometer, SXS) and the other for an X-ray CCD camera (Soft X-ray Imager, SXI), both covering the X-ray energy band up to 15 keV. The two SXTs were fully characterized at the 30-m X-ray beam line at ISAS/JAXA. The combined SXT+SXS system effective area is about 250 and 300 cm(exp 2) at 1 and 6 keV, respectively, although observations were performed with the gate valve at the dewar entrance closed, which blocks most of low energy X-rays and some of high energy ones. The angular resolution for SXS is 1.2 arcmin (Half Power Diameter, HPD). The combined SXT+SXI system effective area is about 370 and 350 cm (exp 2) at 1 and 6 keV, respectively. The angular resolution for SXI is 1.3 arcmin (HPD). The both SXTs have a field of view of about 16 arcmin (FWHM of their vignetting functions).The SXT+SXS field of view is limited to 3 x 3 arcmin by the SXS array size. In-flight data available to the SXT team was limited at the time of this conference and a point-like source data is not available for the SXT+SXS. Although due to lack of attitude information we were unable to reconstruct a point spread function of SXT+SXI, according to RXJ1856.5-3754 data, the SXT seems to be working as expected in terms of imaging capability. As for the overall effective area response for both SXT+SXS and SXT+SXI, consistent spectral model fitting parameters with the previous measurements were obtained for Crab and G21.5-0.9 data. On the other hand, their 2-10 keV fluxes differ by about 20% at this point. Calibration work is still under progress. The SXT is the latest version of the aluminum foil X-ray mirror, which is extremely light-weight and very low cost, yet produces large effective area over a wide energy-band. Its area-mass ratio is the largest, 16 cm(exp 2)/kg, among ASTRO-H, Chandra, and XMM-Newton mirrors. The aluminum foil mirror is a still compelling technology depending on the mission science goal.

X-rays↗

The ASTRO-H SXT Performance to the Large Off-Set Angles

The X-ray astronomy satellite ASTRO-H, which is the 6th Japanese X-ray astronomy satellite and is renamed Hitomi after launch, is designed to observe celestial X-ray objects in a wide energy band from a few hundred eV to 600 keV. The Soft X-ray Telescopes (SXTs) onboard ASTRO-H play a role of collecting and imaging X-rays up to approximately 12 keV. Although the field of view of the SXT is approximately 15' (FWHM), due to the thin-foil-nested Wolter-I type optics adopted in the SXTs, X-rays out of the field of view can reach the focal plane without experiencing a normal double reflection. This component is referred to as 'stray light'. Owing to investigation of the stray light so far, 'secondary reflection' is now identified as the main component of the stray light, which is composed of X-rays reflected only by secondary reflectors. In order to cut the secondary reflections, a 'pre-collimator' is equipped on top of the SXTs. However, we cannot cut all the stray lights with the pre-collimator in some off-axis angle domain. In this study, we measure the brightness of the stray light of the SXTs at some representative off-axis angles by using the ISAS X-ray beam line. ASTRO-H is equipped with two modules of the SXT; one is for the Soft X-ray Spectrometer (SXS), an X-ray calorimeter, and the other is for the Soft X-ray Imager (SXI), an X-ray CCD camera. These SXT modules are called SXT-S and SXT-I, respectively. Of the two detector systems, the SXI has a large field of view, a square with 38' on a side. To cope with this, we have made a mosaic mapping of the stray light at a representative off-axis angle of 30' in the X-ray beam line at the Institute of Space and Astronautical Science. The effective area of the brightest secondary reflection is found of order approximately 0.1% of the on-axis effective area at the energy of 1.49 keV. The other components are not so bright (less than 5 x 10(exp -4) times smaller than the on-axis effective area). On the other hand, we have found that the effective area of the stray light in the SXS field of view (approximately 3' x 3') at large off-axis angles (greater than 15') are approximately 1(exp -4) times smaller than the on-axis effective area (approximately 590 sq cm at 1.49 keV).

X-rays↗

Point Spread Function of ASTRO-H Soft X-Ray Telescope (SXT)

ASTRO-H (Hitomi) satellite equips two Soft X-ray Telescopes (SXTs), one of which (SXT-S) is coupled to Soft-X-ray Spectrometer (SXS) while the other (SXT-I) is coupled to Soft X-ray Imager (SXI). Although SXTs are lightweight of approximately 42 kgmodule1 and have large on-axis effective area (EA) of approximately 450 cm(exp 2) at 4.5 keV module(sub 1) by themselves, their angular resolutions are moderate approximately 1.2 arcmin in half power diameter. The amount of contamination into the SXS FOV (3.05 times 3.05 arcmin(exp 2) from nearby sources was measured in the ground-based calibration at the beamline in Institute of Space and Astronautical Science. The contamination at 4.5 keV were measured with sources distant from the SXS center by one width of the FOV in perpendicular and diagonal directions, that is, 3 and 4.5 arcmin-off, respectively. The average EA of the contamination in the four directions with the 3 and 4.5 arcmin-off were measured to be 2 and 0.6% of the on-axis EA of 412 cm (exp) for the SXS FOV, respectively. The contamination from a source distant by two FOV widths in a diagonal direction, that is, 8.6 arcmin-off was measured to be 0.1% of the on-axis at 4.5 keV. The contamination amounts were also measured at 1.5 keV and 8.0 keV which indicated that the ratio of the contamination EA to that of on-axis hardly depended on the source energy. The off-axis SXT-I images from 4.5 to 27 arcmin were acquired at intervals of -4.5 arcmin for the SXI FOV of 38 times 38 arcmin(exp 2). The image shrinked as the off-axis angle increased. Above 13.5 arcmin of off-angle, a stray appeared around the image center in the off-axis direction. As for the on-axis image, a ring-shaped stray appeared at the edge of SXI of approximately 18 arcmin distant from the image center.

Soft X-ray spectrometer↗

Examining the Angular Resolution of the Astro-H's Soft X-Ray Telescopes

The international x-ray observatory ASTRO-H was renamed Hitomi after launch. It covers a wide energy range from a few hundred eV to 600 keV. It is equipped with two soft x-ray telescopes (SXTs: SXT-I and SXT-S) for imaging the soft x-ray sky up to 12 keV, which focus an image onto the respective focal-plane detectors: CCD camera (SXI) and a calorimeter (SXS). The SXTs are fabricated in a quadrant unit. The angular resolution in half-power diameter (HPD) of each quadrant of the SXTs ranges between 1.1 and 1.4 arc min at 4.51 keV. It was also found that one quadrant has an energy dependence on the HPD. We examine the angular resolution with spot scan measurements. In order to understand the cause of imaging capability deterioration and to reflect it to the future telescope development, we carried out spot scan measurements, in which we illuminate all over the aperture of each quadrant with a square beam 8 mm on a side. Based on the scan results, we made maps of image blurring and a focus position. The former and the latter reflect figure error and positioning error, respectively, of the foils that are within the incident 8 mm x 8 mm beam. As a result, we estimated those errors in a quadrant to be approx. 0.9 to 1.0 and approx. 0.6 to 0.9 arc min, respectively. We found that the larger the positioning error in a quadrant is, the larger its HPD is. The HPD map, which manifests the local image blurring, is very similar from quadrant to quadrant, but the map of the focus position is different from location to location in each telescope. It is also found that the difference in local performance causes energy dependence of the HPD.

Astro-H/Hitomi; soft x-ray telescope; SXT; Wolter ↗

Poisson vs. Gaussian statistics for sparse X-ray data: Application to the soft X-ray spectrometer

Reliable results when fitting X-ray data require proper consideration of the statistics involved. We probe the impact of Gaussian versus Poisson statistics at low count levels using both the standard χ^(2) method and maximum likelihood based on Poisson (C) statistics. The difference is studied and quantified through simulated spectra with known properties. We then test the results through analysis of Mn Kα calibration data taken with the flight spare microcalorimeter for the Hitomi soft X-ray spectrometer. Through comparison with simulations, our results show that the χ^(2) method tends to give overly optimistic estimates of the detector energy resolution, in particular when there are few counts. Given an energy resolution of ∼5 eV and a line with about 100 photons, the line width becomes ∼10% lower in the χ^(2) method than in Poisson statistics. This is a consequence of the uncertainties being dominated by counting statistics, and therefore highlights the need to choose the appropriate fit statistic.

Shinya Yamada↗

Spatial distribution of the X-ray-emitting plasma of U Geminorum in quiescence and outburst

We present our analysis of the Suzaku data of U Geminorum (U Gem) from 2012 both in quiescence and outburst. Unlike SS Cygni (SS Cyg), the hard X-ray flux of U Gem is known to increase at times of optical outburst. A sophisticated spectral model and reliable distance estimate now reveal that this can be attributed to the fact that the mass accretion rate onto the white dwarf (WD) does not exceed the critical rate that causes the optically thin to thick transition of the boundary layer. From comparison of the X-ray and optical light curves, the X-ray outburst peak seems to be retarded by 2.1 ± 0.5 d, although there remains uncertainty in the X-ray peak identification, due to short data coverage. The larger delay than SS Cyg (0.9–1.4 d) also supports the lower accretion rate in U Gem. A fluorescent iron 6.4 keV emission line bears significant information about the geometry of the X-ray-emitting hot plasma and the accretion disk (AD) that reflects the hard X-ray emission. Our reflection simulation has shown that the optically thick AD is truncated at a distance of 1.20–1.25 times the white dwarf radius (RWD) in quiescence, and the accreting matter in the disk turns into the optically thin hard-X-ray-emitting plasma at this radius. In outburst, on the other hand, our spectral analysis favors the picture that the optically thick disk reaches the WD surface, although disk truncation can take place in the region of <1.012 RWD. From the profile of the 6.4 keV line, we have also discovered that the accreting matter is heated up close to the maximum temperature immediately after the matter enters the boundary layer at the disk truncation radius. This is consistent with the fact that the hard X-ray spectra of dwarf novae, in general, can be well represented with the cooling flow model.

Mai Takeo↗

Early Fluid Activity on Ryugu Inferred By Oxygen, Carbon, and 53Mn-53Cr Isotopic Analyses of Carbonates and Magnetite

Samples from asteroid Ryugu returned by the Hayabusa2 mission contain evidence of extensive alteration by aqueous fluids and appear related to the CI chondrites. To understand the sources of the fluid and the timing of chemical reactions occurring during the alteration processes, we investigated the oxygen, carbon, and 53Mn-53Cr systematics of carbonate and magnetite in two Ryugu particles. We find that the fluid was initially between 0−20 °C and enriched in 13C, and 17O and 18O, and subsequently evolved towards lighter carbon and oxygen isotopic compositions as alteration proceeded. Carbonate ages show that this fluid-rock interaction took place within the first ~1.8 million years of solar system history, requiring early accretion either in a planetesimal less than ~20 km in diameter or within a larger body which was disrupted and reassembled.

Astromaterials↗

Early Aqueous Alteration of Ryugu’s Parent Body – Insight from In-situ Isotopic Analyses

The Hayabusa2 mission returned approximately 5.4 g of highly aqueously-altered material resembling the CI (Ivuna-type) chondrites from the C-type asteroid Ryugu. To understand the timing and duration of aqueous alteration on Ryugu’s parent body, we measured the 53Mn-53Cr (t1/2 = 3.7 Myr) ages of dolomite, breunnerite, and Ca-carbonate minerals in Ryugu particles A0037 and C0009 using secondary ion mass spectrometry (SIMS) with the UCLA CAMECA ims-1290 instrument with Hyperion II oxygen plasma source. Using these carbonate formation ages, we estimate the accretion time and size of Ryugu’s parent body to have been within the first 1.8 million years of Solar System history in a planetesimal less than ~20 km in diameter, or within a larger body which was disrupted and reassembled. To further constrain the conditions of aqueous alteration, we measured the δ13C, δ18O, and Δ17O of Ryugu dolomite, Ca-carbonate, and magnetite using the UCLA CAMECA ims-1290. The results of our stable isotopic analyses show that the earliest stages of aqueous alteration occurred at low temperatures (between 0 and 20 °C), that the initial fluid was enriched in the heavy 13C, 17O and 18O isotopes, and that the fluid evolved towards lighter carbon and oxygen isotopic compositions as alteration proceeded.

Astromaterials↗