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Materials Data on OsO4 by Materials Project

OsO4 is Silicon tetrafluoride-like structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two OsO4 clusters. Os8+ is bonded in a tetrahedral geometry to four O2- atoms. All Os–O bond lengths are 1.72 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Os8+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one Os8+ atom.

36 MATERIALS SCIENCE↗

Materials Data on OsO2 by Materials Project

OsO2 is Hydrophilite structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Os4+ is bonded to six equivalent O2- atoms to form a mixture of corner and edge-sharing OsO6 octahedra. The corner-sharing octahedral tilt angles are 53°. There is two shorter (1.97 Å) and four longer (2.02 Å) Os–O bond length. O2- is bonded in a trigonal planar geometry to three equivalent Os4+ atoms.

36 MATERIALS SCIENCE↗

Materials Data on OsO2 by Materials Project

OsO2 crystallizes in the cubic Pa-3 space group. The structure is three-dimensional. Os4+ is bonded to six equivalent O2- atoms to form corner-sharing OsO6 octahedra. The corner-sharing octahedral tilt angles are 60°. All Os–O bond lengths are 2.02 Å. O2- is bonded in a trigonal planar geometry to three equivalent Os4+ atoms.

36 MATERIALS SCIENCE↗

Materials Data on Os3O by Materials Project

OsOs2O is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of four osmium molecules and one Os2O framework. In the Os2O framework, Os+0.67+ is bonded to four equivalent O2- atoms to form a mixture of corner and edge-sharing OsO4 tetrahedra. All Os–O bond lengths are 2.58 Å. O2- is bonded in a body-centered cubic geometry to eight equivalent Os+0.67+ atoms.

36 MATERIALS SCIENCE↗