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At least 19 records

Overview of Wendelstein 7-X high-performance operation

The Wendelstein 7-X (W7-X) stellarator has completed two consecutive experimental campaigns OP 2.2 (Sep.-Dec. 2024) and OP 2.3 (Feb.-May 2025) under a new operational strategy enabling more than one year of uninterrupted device availability. This approach, supported by exceptionally high subsystem reliability, allowed sustained high-efficiency plasma operations with up to 80–100 discharges per day across a broad range of magnetic configurations. Several key technical upgrades-most notably the first operation of a 1.5 MW class steady-state gyrotron, a new steady-state pellet injector, and advanced real-time feedback control systems significantly enhanced heating, fueling, and plasma control capabilities. Together, these improvements enabled major advances in long-pulse performance, high-β operation, and confinement optimization. Long-pulse discharges achieved 1.8 GJ of injected energy under fully detached divertor conditions, while reduced-field scenarios facilitated record volume-averaged β values approaching 3%. High-performance plasmas with centrally peaked density profiles, created via neutral beam injection (NBI) or sustained pellet fueling, demonstrated strongly reduced turbulent transport and stellarator-record fusion triple products. Complementary studies of power exhaust and divertor heat loads revealed the role of scrape-off-layer drift physics in shaping strike-line patterns under attached conditions. Together, the results from OP 2.2 and OP 2.3 significantly expand the operational space of W7-X and strengthen its role as a leading platform for steady-state stellarator research and reactor-relevant plasma scenarios.

Wendelstein 7-X

Routes to high-performance operation in Wendelstein 7-X: turbulence suppression with shaping of the density profile

Steep density gradients generally lead to improved plasma performance in the neoclassically optimized stellarator W7-X. This is evident in the global energy confinement time as well as in the ion temperature and can be explained by a strong reduction of the ion temperature gradient turbulence. Such conditions can experimentally be realized by several methods: injection of cryogenic hydrogen pellets, appropriate combination of neutral beam and electron cyclotron resonance heating (ECRH) and, in some cases, with low power of ECRH after preconditioning of the first wall. The duration of the improved phases is determined by the ability to sustain the steep density gradient, by technical limitations of the involved systems and, eventually, by the plasma stability. This paper gives an overview of relevant experimental results and presents example discharges where the improved confinement conditions could be extended to multiple seconds: up to 4 s using neutral beam injection and from 14 to 40 s with steady state pellet injection. In these plasmas the turbulent thermal diffusivity is reduced by a factor of 3 to 4 in a broad radial range, which allows high ion temperatures of up to 3 keV at the densities of about 1.5 • 10 20 m −3 .

high performance plasma

Improving operational performance using machine learning analysis of Radiation Portal Monitor measurements

Radiation Portal Monitors (RPMs) have been installed worldwide to scan vehicles and cargo for the presence of radiological and nuclear materials. In field operations, the sensitivity of these systems is typically limited by the relatively high rates of nuisance alarms that usually must be followed up with secondary inspections. We have developed a machine-learning based alarm analysis system that has been deployed at numerous locations in the U.S. and internationally. Our Enhanced Radiological Nuclear Inspection and Evaluation (ERNIE) analysis software and its derivatives have demonstrated increased sensitivity to radiological and nuclear material of concern while reducing nuisance alarms by as much as an order of magnitude.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND

Impact of U-10Mo HALEU fuel element tolerances on the Massachusetts Institute of Technology reactor safety and operational performance – Thermal hydraulics

The U.S. is coordinating efforts for the conversion of six U.S. High Performance Research Reactors (USHPRR) including one critical facility from highly enriched uranium (HEU) to low-enriched uranium (LEU). In order to continue the mission of these reactors, including the Massachusetts of Institute of Technology Reactor (MITR), and achieve similar performance, high-assay low-enriched uranium (HALEU) with a high-density metallic alloy of uranium with 10 wt% molybdenum (U-10Mo) is being evaluated. The impact of the fabrication specification and tolerances was assessed following the preliminary design of the MITR LEU fuel elements using the U-10Mo monolithic alloy. This research focuses on the analysis of fabrication specification impact on thermal hydraulics (TH) characteristic of the MITR LEU core as a function of the variation of the relevant fuel specification parameters (e.g., coolant channel gap thickness, fuel plate thickness, etc.). The analyses are performed based on an all-fresh LEU fuel conversion plan identified in a preliminary safety analysis report submitted to the Nuclear Regulatory Commission. The reactor power margin to the onset of nucleate boiling (ONB) is assessed under the limiting safety system settings (LSSS), where a scram occurs, to ensure there is sufficient margin to the reactor safety limit, which is defined by the onset of flow instability that occurs after the ONB. The best estimate plus uncertainty approach is employed to analyze this TH characteristic, which yields realistic results while maintaining adequate conservatism, utilizing a statistical uncertainty propagation method with the STAT7 code. The TH characteristic is analyzed as a function of the variability of the specification parameters resulting from the fabrication process. The main findings of this study show that the MITR core can meet the TH safety and operational requirements at the all-LEU initial core startup (cycle 1), selected transition cycles (most reactive cycle and most limiting cycle: cycle 3 and 5, respectively) and equilibrium (cycle 14) cores under all limiting fabrication parameter combinations considered. In addition, the analyses show that the dependency of the core power margin to ONB on those specification parameters that have the most direct impact on TH performance is non-linear but monotonically decreasing within the specification tolerances. The third order polynomial fit curves are reported in detail for selected limiting cases and can serve as a powerful tool for future MITR fuel management in cases such as when HALEU supply is established that may allow additional cycle length or other operational benefits.

Conversion

Impact of U-10Mo HALEU Fuel Element Tolerances on the Massachusetts Institute of Technology Reactor safety and operational performance – Neutronics

The U.S. is coordinating efforts for the conversion of six U.S. high performance research reactors (USHPRR), including one critical assembly from highly enriched uranium (HEU) to low-enriched uranium (LEU). In order to continue the mission of these reactors, including the Massachusetts Institute of Technology Reactor (MITR), and achieve similar performance, high assay low-enriched uranium (HALEU) with a high-density metallic alloy of uranium with 10 wt% molybdenum (U-10Mo) is being considered. Following the preliminary design of the proposed MITR LEU fuel elements using the U-10Mo monolithic alloy, the impact of the fabrication specification was assessed. This work focuses on the analysis of select neutronics characteristics of the MITR LEU core as a function of the variation of the relevant fuel specification parameters (e.g., U-10Mo composition, fuel plate thickness, etc.). A separate article submitted to this journal addresses the impact on the thermal hydraulic performance. The analyses in these works are performed based on an all-LEU conversion management plan identified in previous work, in which only the proposed elements are utilized for achieving the conversion of MITR. The variations of two main neutronics characteristics are assessed as a function of the variability of the specification parameters resulting from the fabrication process: the MITR LEU core reactivity and the fuel cycle length. The main findings of this work show that the MITR core can meet the operational requirements during the LEU transition plan under the limiting fabrication parameter combinations considered. In addition, the analyses show that the dependency of the core neutronics characteristics on the specification parameters is highly linear within the specification tolerances. The rates of variation are reported in detail for each parameter and can serve as a powerful tool for future MITR fuel management in cases such as when HALEU supply is established that may allow additional cycle length or other operational benefits.

Conversion

Operational and Performance Monitoring of East Tennessee Technology Park Ponds—2025 Results

Performance and operational monitoring are regulatory requirements associated with a non–time-critical removal action for three surface water bodies at the East Tennessee Technology Park (ETTP) in Oak Ridge, Tennessee (Figure 1): the K-1007-P1 Pond, the K-901-A Pond, and the K-720 Slough. This progress report summarizes the monitoring activities and results from FY 2025. The goal of ecological enhancement of the K-1007-P1 and K-901-A Ponds is to reduce risk from polychlorinated biphenyl (PCB) contamination in fish to humans and wildlife. Lowering PCB concentrations in the water column and in the food that fish eat is expected to decrease PCB bioaccumulation in fish. Performance monitoring of the K-1007-P1 Pond focuses on annual PCB trends in water, clams, and fish. PCBs in fish also are sampled annually at the K-720 Slough. Operational monitoring ensures that ecological enhancement measures—including water quality, plant community, fish community, and wildlife actions—have been implemented as intended. Monitoring provides the information necessary to determine whether modifications are needed to attain the design end state (i.e., a heavily vegetated, clearwater pond dominated by sunfish with significantly diminished or at least downwardly trending PCB levels in fish). In FY 2025, fish removal efforts and vegetation planting primarily focused on the K-901-A Pond. These actions were implemented to help push the systems toward the desired end state. Descriptions of the various monitoring activities and preliminary 2025 results are provided in the following sections. An update on fish and plant management actions in FY 2025 is also included in this report. A summary of the more detailed information in this report will be presented as required in the upcoming Remediation Effectiveness Report.

54 ENVIRONMENTAL SCIENCES

Operation and performance of the ATLAS tile calorimeter in LHC Run 2

The ATLAS tile calorimeter (TileCal) is the hadronic sampling calorimeter covering the central region of the ATLAS detector at the Large Hadron Collider (LHC). This paper gives an overview of the calorimeter’s operation and performance during the years 2015–2018 (Run 2). In this period, ATLAS collected proton–proton collision data at a centre-of-mass energy of 13 TeV and the TileCal was 99.65% efficient for data-taking. The signal reconstruction, the calibration procedures, and the detector operational status are presented. The performance of two ATLAS trigger systems making use of TileCal information, the minimum-bias trigger scintillators and the tile muon trigger, is discussed. Studies of radiation effects allow the degradation of the output signals at the end of the LHC and HL-LHC operations to be estimated. Finally, the TileCal response to isolated muons, hadrons and jets from proton–proton collisions is presented. The energy and time calibration methods performed excellently, resulting in good stability and uniformity of the calorimeter response during Run 2. The setting of the energy scale was performed with an uncertainty of 2%. The results demonstrate that the performance is in accordance with specifications defined in the Technical Design Report.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS

Rancor Integrated Procedure System (RIPS): A Computer-Based Procedure Platform for Advanced Reactor Research

The Rancor Microworld Simulator is a simplified, pressurized water, small modular reactor simulator that includes a multi-unit plant model server, an advanced digital human-machine control interface, and the Rancor Integrated Procedure System (RIPS). Rancor provides a research and development tool that can be used for collecting operator performance data and for prototyping concepts of operations (ConOps) for advanced reactor development. RIPS is meant as a research tool and includes many unique features: (1) RIPS has a robust procedure authoring system. (2) RIPS has the capability to run any of the three IEEE-Std-1786 computer-based procedure types. (3) RIPS can be configured to take on the look and feel of different vendors’ computer-based procedure systems for the purpose of developing and evaluating different ConOps for plant upgrades or new builds. (4) RIPS includes the capability for logging operator procedure use, including integrating procedure logs with Rancor simulator logs, thereby allowing automated data collection of operator scenario runs. (5) RIPS integrates with the Human Unimodel for Nuclear Technology to Enhance Reliability (HUNTER), a dynamic human reliability analysis environment that creates a digital human twin or virtual operator to mimic reactor operator performance. (6) RIPS includes support for automation of plant monitoring and control functions. While RIPS is explicitly built into Rancor, it may also be used with full-scope training simulators. This functionality allows RIPS to be used for existing plants and advanced reactors under development.

99 - GENERAL AND MISCELLANEOUS

Operation and performance of the CMS silicon strip tracker with proton-proton collisions at the CERN LHC

Salient aspects of the commissioning, calibration, and performance of the CMS silicon strip tracker are discussed, drawing on experience during operation with proton-proton collisions delivered by the CERN LHC. The data were obtained with a variety of luminosities. The operating temperature of the strip tracker was changed several times during this period and results are shown as a function of temperature in several cases. Details of the system performance are presented, including occupancy, signal-to-noise ratio, Lorentz angle, and single-hit spatial resolution. Saturation effects in the APV25 readout chip preamplifier observed during early Run 2 are presented, showing the effect on various observables and the subsequent remedy. Studies of radiation effects on the strip tracker are presented both for the optical readout links and the silicon sensors. The observed effects are compared to simulation, where available, and they generally agree well with expectations.

47 OTHER INSTRUMENTATION

Performance Evaluation of an Additively Manufactured ultra-High Operating Temperature SiC Solar-Thermal Air Receiver (HOTSSTAR) Test Module

Increasing operating temperatures of solar receivers is paramount to the efficiency of concentrated solar thermal and solar power systems. GE Aerospace Research in collaboration with Heliogen Inc and Sandia National Laboratories (SNL) is engaged in the development of ultra-High Operating Temperature SiC-matrix Solar Thermal Air Receiver (HOTSSTAR) enabled by additive manufacturing. HOTSSTAR goal is to demonstrate SiC receiver with air exit temperatures up to 1100oC. We discuss fabrication and on-sun test results of a prototype 50kWth test module. The receiver architecture is based on a radial airflow design and consists of a series of radial SiC receiver sectors organized around central absorber. These components were fabricated using binder-jet printed SiC followed by melt-infiltration reaction bonding process. To enhance the thermo-mechanical reliability of SiC test articles in thermal gradient/ shock environment of the application, the components were laminated with GE’s MI SiC CMC. A dedicated test facility was constructed at SNL Solar Tower to evaluate the operational performance of HOTSSTAR module under solar fluxes >200 W/cm2. We report on our final 50kW test module fabrication, integration at the test facility at Sandia, and discuss on-sun test results. We compare the performance of HOTSSTAR module relative to our model predictions.

14 SOLAR ENERGY

Advanced Fuels Campaign Time-at-Temperature Irradiation Campaign and Post-Irradiation Examination Plan

With increasing per capita energy consumption and rapidly growing energy consumption predicted for data centers, the US faces challenges in meeting projected energy demands. The current administration is attempting to accelerate the deployment of new nuclear construction by providing significant investments in advanced nuclear and by modernizing regulatory approaches for the licensing new reactors. However, enabling extended power uprates (EPUs) for the current nuclear reactor fleet would provide a shorter-term solution to better calibrate near-term energy generation capacity to the ever-growing energy demands of the modern era. One pathway to achieve power uprates is to increase the operational window by reassessing fuel safety limits around anticipated transients. Existing light-water reactors (LWRs) utilize a targeted operational window with well-defined operational efficiencies, yet this window is also often bound by conservative safety limits that result in suboptimal operational performance. For example, the operation of the existing fleet is highly constrained by safeguards to operation related to anticipated operational occurrences (AOOs), which are moderate-frequency transients expected with a frequency greater than 0.01 per reactor-year. These AOOs include temperature excursions where the critical heat flux for the system is exceeded, resulting in a departure from nucleate boiling (DNB) at the cladding surface. This DNB event is a thermohydraulic condition that, with current conservative fuel safety limits, results in the fuel rods being classified as “failed,” meaning that the cladding may not be returned to service.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS

Advanced Fuels Campaign Time-at-Temperature Irradiation Campaign and Post-Irradiation Examination Plan

With increasing per capita energy consumption and rapidly growing energy consumption predicted for data centers, the US faces challenges in meeting projected energy demands. The current administration is attempting to accelerate the deployment of new nuclear construction by providing significant investments in advanced nuclear and by modernizing regulatory approaches for the licensing new reactors. However, enabling extended power uprates (EPUs) for the current nuclear reactor fleet would provide a shorter-term solution to better calibrate near-term energy generation capacity to the ever-growing energy demands of the modern era. One pathway to achieve power uprates is to increase the operational window by reassessing fuel safety limits around anticipated transients. Existing light-water reactors (LWRs) utilize a targeted operational window with well-defined operational efficiencies, yet this window is also often bound by conservative safety limits that result in suboptimal operational performance. For example, the operation of the existing fleet is highly constrained by safeguards to operation related to anticipated operational occurrences (AOOs), which are moderate-frequency transients expected with a frequency greater than 0.01 per reactor-year. These AOOs include temperature excursions where the critical heat flux for the system is exceeded, resulting in a departure from nucleate boiling (DNB) at the cladding surface. This DNB event is a thermohydraulic condition that, with current conservative fuel safety limits, results in the fuel rods being classified as “failed,” meaning that the cladding may not be returned to service.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS

Developing the hybrid scenario in DIII-D and KSTAR for W-compatible long-pulse operation

Long-pulse, high-performance operation with tungsten plasma-facing components is a crucial challenge for achieving steady-state (SS) goals in ITER and future fusion devices. This paper presents a joint international effort between the DIII-D and KSTAR tokamaks aimed at demonstrating the compatibility of the high q 95 ~ 6 hybrid scenario with a tungsten divertor and superconducting coils. A DIII-D hybrid scenario recipe is successfully tailored to KSTAR’s operational constraints, which facilitates cross-device studies. The results show successful 30 s long-pulse operation in KSTAR at a normalized beta (β N = 2.4) with a benign m/n = 4/3 mode and effective mitigation of tungsten accumulation. Despite this success, the KSTAR scenario exhibits a greater than 25% reduction in thermal confinement compared to the DIII-D reference. To investigate this discrepancy, we performed a predictive TGYRO validation study, which suggests that the difference is likely caused by a weaker temperature pedestal in the KSTAR discharge due to a higher and narrower density pedestal. In addition, such lower thermal confinement leads to higher impurity accumulation, possibly due to a change in neoclassical transport with increased inward pinch, which further degrades global confinement. We also report that stationary, long-pulse operation with sustained thermal confinement requires consistent fueling and wall conditioning. These findings highlight the importance of optimized fueling and real-time wall conditioning in achieving a high temperature pedestal and strong global confinement during stable long-pulse operation. We propose potential approaches toward fully SS, long-pulse operation, including real-time wall conditioning using an impurity dropper in KSTAR and future tokamaks.

DIII-D

Investigating the impact of a multi-module operation environment on the task performance time of human operators – An explanatory study

The worldwide demand for Small Modular Reactors (SMRs) has surged in recent years due to their enhanced safety and versatility in supporting diverse industrial sectors. A unique feature of SMR operation is that a single human operator is responsible for managing multiple modules. Therefore, securing a sufficient amount of human performance data pertaining to this new environment is essential for the safe operation of SMRs. In this explanatory study, a series of experiments were conducted using the NuScale simulator, a representative SMR design, with student operators. A total of 12 student operators were assigned two types of off-normal events and asked to cope with them using paper-based procedures. Subsequently, their task performance times were compared with those of student operators responsible for a single unit based on the Task Complexity (TACOM) measure. Results indicate that the performance of student operators under the experimental conditions of this study degraded by a factor of 2 to 3, depending on the characteristics of the off-normal events.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS

Evaluation of HVAC & refrigeration system fault behaviors and impacts: A systematic review

Achieving the goals of green buildings critically depends on the fault-free operation of heating, ventilation and air conditioning and refrigeration (HVAC&R) systems. However, faults frequently occur in these systems, causing a range of negative consequences, including increased energy consumption, diminished operational performance, compromised indoor environmental quality, higher operational costs, and shortened system lifespan. The evaluation of fault behaviors and impacts plays a critical role in revealing fault characteristics and consequently supports many research areas, including the design of the high-performance equipment, development of fault detection and diagnostics (FDD) and robust control approaches, as well as the enhancement of maintenance decision-making activities. This paper systematically reviews 112 research publications that reported the analysis and evaluation of fault behaviors and impacts in HVAC&R systems over the past thirty years. Here, we designed a review approach to address five crucial research questions, namely: 1) the objectives of analysis and evaluation of fault behaviors and impacts, 2) data sources, 3) equipment/system types and fault types, 4) evaluation methods including evaluation measures and associated metrics, and 5) challenges and future directions in the research on evaluating of fault behaviors and impacts. In-depth discussions on these questions help bridge the gap between the evaluation of fault behaviors and impacts and their practical applications, such as the development of high-performance systems, fault models, FDD methods, and maintenance decision-making tools within the HVAC&R FDD domain.

Chen, Yimin [Oak Ridge National Laboratory (ORNL),

Coupled Induction Machine and HVAC Models for Simulating HVAC Performance Considering Grid Dynamics in Buildings

This paper presents the development of novel models that integrate induction machines with HVAC equipment, such as pumps, heat pumps, and chillers, to analyze the impact of electrical parameters on the operational performance of thermo-fluid systems. The proposed model employs a coupling technique that captures the dynamic interactions between induction machines and HVAC systems. By integrating electrical, thermal, and mechanical dynamics, the models provide a comprehensive framework for simulating real-world scenarios, including interactions with the electrical grid. This achievement was made possible through the development of a Computationally Efficient and Accurate Induction Machine (CEAIM) model. Implemented using the equation-based Modelica language, the CEAIM model has been validated against experimental results, manufacturer data sheets, and various operating conditions. Its performance has been compared with existing induction machine models in the Modelica Standard Library (MSL), demonstrating superior accuracy and computational efficiency. The CEAIM model predicts torque, speed, and power consumption with a coefficient of determination (R 2 ) ranging from 0.98 to 1 and a coefficient of variation of root mean square error (CVRMSE) between 0.27% and 6.67%. Additionally, CEAIM scales more efficiently than conventional MSL models, with a slower computational growth rate in large-scale simulations. After thorough validation of the CEAIM model, it was coupled with HVAC equipment as this approach provides a detailed multi-dimensional view of capturing electrical transients and mechanical performance. To support this, a case study was conducted to showcase its capabilities.

24 POWER TRANSMISSION AND DISTRIBUTION

Permanent magnets for ELM suppression in tokamaks: feasibility and operational compatibility

Permanent magnets can provide static magnetic fields without power supplies or feed lines, offering a simpler alternative to conventional electromagnets in tokamaks. This work examines permanent magnet arrays (PMAs) for edge localized mode (ELM) control in double-null (DN) configurations, where traditional RMP coils exhibit limited effectiveness. Linear plasma response calculations using IPEC assess high-field-side (HFS) permanent magnet placement, benchmarking performance against DIII-D low-field-side (LFS) internal coils (I-coils) while evaluating engineering constraints. Modeling results demonstrate that HFS permanent magnet configurations generate HFS plasma response amplitudes more than 5 times larger than conventional I-coil systems. While other resonant response metrics show comparable or reduced response relative to I-coils, the combination of conventional RMP systems and permanent magnets is expected to provide enhanced performance. Operational impact assessments of persistent magnetic fields, including sideband field effects and startup/ramp-up compatibility, reveal acceptable performance within established operational boundaries. This analysis establishes PMAs as a technically viable approach for DN ELM control with reductions in system complexity, motivating further experimental validation on existing tokamak facilities.

3D magnetic perturbation

Findings from Large Bench-Scale Testing of Denitration Electrolyzers for the EDCGe Project

This report highlights the key findings and outcomes relevant to the processability of waste supernatant at Hanford using a denitration electrolyzer. The Electrosynthesis Company issued a Phase 1 report to the Savannah River National Laboratory (SRNL), summarizing the evaluation of large bench-scale denitration electrolyzers to support the electrochemical denitration and caustic generation (EDCGe) project. The Electrosynthesis Company’s report (attached as Appendix A) provides insights into the initial steps required to implement an electrolyzer system at Hanford. Phase 1 experiments focused on validating the denitration electrolyzer’s performance, operating parameters, and reaction products. The robustness of the electrochemical denitration process was demonstrated by two electrolyzer flow cell systems (a 100 cm 2 ElectroCell MP and a 150 cm 2 NESI NS01 cell), both of which achieved significant nitrate and nitrite removal (>50%) with a current efficiency of ~95% for both systems. Higher current densities (500 mA cm –2 ) improved nitrate and nitrite removal rates compared to lower current densities (333 mA cm –2 ), while maintaining a current efficiency of ~94%. The NS01 cell achieved a nitrate species removal rate of ~0.41 mol h –1 at 5 kA m –2 (equiv. to 500 mA cm –2 ). The primary reaction product was ammonia (NH 3 ), constituting 78.3–91.6% of the products (excluding OH – formation). NH 3 was predominantly retained in the catholyte liquid phase rather than being off-gassed. Additionally, the NS01 cell reported an NH 3 generation rate of ~0.36 mol h –1 at 5 kA m –2 . Other gas formation included ~7% N 2 , ~7% H 2 , and trace amounts of N 2 O. The estimated power requirement (extrapolated from the 0.015 m 2 cell data) for a full-scale denitration electrolyzer is approximated to be ~1.6 MW (DC-only) to treat 50% of nitrate and nitrite in a waste stream and generates ~2.1 kmol h –1 of NH 3 with an initial concentration of 4 M NO 3 – /NO 2 – at 300 gal h –1 . Simulated waste containing aluminate, carbonate, oxalate, and halogens exhibited no adverse effects on denitration performance. A preliminary experiment comparing alkaline anolyte (5 M NaOH) with a nickel based anode to acidic media (2 M H 2 SO 4 ) with a DSA-O 2 anode showed a lower operating voltage and generated less H 2 than the acid media. Maintaining a stable 5 M OH – concentration in the anolyte through periodic additions of caustic did not significantly impact denitration performance. This operational mode will be required for long-term experiments. All the experiments demonstrated that electrochemical denitration is a promising approach for treating nitrate and nitrite in simulated waste streams, achieving significant conversion and robustness across varying experimental conditions and electrochemical cell configurations. Lastly, the ability to generate a nearly pure NH 3 stream may prove advantageous for processing at other locations within the Hanford site.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W