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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Outdoor urban nanomaterials: The emergence of a new, integrated, and critical field of study

Engineered nanomaterials (ENMs) are currently widely incorporated in the outdoor urban environmental fabric and numerous new applications and products containing ENMs are expected in the future. As has been shown repeatedly, products containing ENMs have the potential, at some point in their lifetime, to release ENMs into their surrounding environment. However, the expanding body in environmental nanomaterial research has not yet shifted toward ENMs in the context of the complex outdoor urban environment. This is especially surprising because the world's human populations are on a steady march toward more and more urbanization and technological development, accompanied with increased applications for ENMs in the outdoor urban environment. Our objective for this paper is therefore to review, assess, and provide new information in this emerging field. We provide an overview of nanomaterials (NMs, encompassing both ENMs and incidental nanomaterials, INMs) that are likely to be released in the urban environment from outdoor sources by discussing 1) the applications of ENMs that may lead to release of ENMs in urban areas, 2) the recently published data on the release of ENMs from novel nano-enabled applications in the outdoor urban environment, 3) the available literature on the occurrence of INMs in the atmosphere and within/on dust particles, and 4) the potential pathways and fate of NMs in the outdoor urban environment. This review is then followed by three case studies demonstrating the importance of NMs in the outdoor urban environment. The first and second case studies illustrate the occurrence of NMs in urban dust and stormwater ponds, respectively, whereas the third case study discusses the lessons learned from the release of NMs (e.g. Pt, ph and Rh) from automotive vehicle catalytic convertors. This article ends with a discussion of the research priorities needed to advance this emerging field of “outdoor urban nanomaterials” and to assess the potential risks of NMs in the context of urban environments.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2017

The laboratory environmental algae pond simulator (LEAPS) photobioreactor: Validation using outdoor pond cultures of Chlorella sorokiniana and Nannochloropsis salina

A bench-scale photobioreactor system, the Laboratory Environmental Algae Pond Simulator (LEAPS), was designed and constructed to simulate outdoor pond cultivation for a wide range of geographical locations and seasons. The LEAPS consists of six well-mixed glass column photobioreactors submerged in a temperature controlled waterbath (-2 °C to >60 °C) and illuminated from above by a programmable multicolor LED lighting system (0 to 2,500 µmol/m 2 -sec). Measured incident light intensities and water temperatures deviated from the respective light and temperature setpoints on average only 2.3% and 0.9%, demonstrating accurate simulation of light and temperature conditions measured in outdoor ponds. In order to determine whether microalgae strains cultured in the LEAPS exhibit the same linear phase biomass productivity as in outdoor ponds, Chlorella sorokiniana and Nannochloropsis salina were cultured in the LEAPS bioreactors using light and temperature scripts measured previously in the respective outdoor pond studies. For Chlorella sorokiniana, the summer season biomass productivity in the LEAPS was 6.6% and 11.3% lower than in the respective outdoor ponds in Rimrock, Arizona, and Delhi, California; however, these differences were not statistically significant. For Nannochloropsis salina, the winter season biomass productivity in the LEAPS was 9.2% higher than in the respective outdoor ponds in Tucson, Arizona, a difference shown to be not statistically significant. Potential reasons for the positive or negative divergence in LEAPS performance, relative to outdoor ponds, are discussed. To demonstrate the utility of the LEAPS in predicting productivity, two other strains – Scenedesmus obliquus and Stichococcus minor – were evaluated using the summer season script for Rimrock, Arizona. For both strains, the productivity was around 11.6 g/m 2 -day at 25 cm culture depth. In conclusion, the LEAPS is an accurate pond simulator and thus offers a reliable, fast, and cost-effective way to screen microalgae strains and operating conditions for high biomass productivity and co-product yields.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2013

Outdoor Performance of a Thin-Film Gallium-Arsenide Photovoltaic Module

We deployed a 855 cm2 thin-film, single-junction gallium arsenide (GaAs) photovoltaic (PV) module outdoors. Due to its fundamentally different cell technology compared to silicon (Si), the module responds differently to outdoor conditions. On average during the test, the GaAs module produced more power when its temperature was higher. We show that its maximum-power temperature coefficient, while actually negative, is several times smaller in magnitude than that of a Si module used for comparison. The positive correlation of power with temperature in GaAs is due to temperature-correlated changes in the incident spectrum. We show that a simple correction based on precipitable water vapor (PWV) brings the photocurrent temperature coefficient into agreement with that measured by other methods and predicted by theory. The low operating temperature and small temperature coefficient of GaAs give it an energy production advantage in warm weather.

14 SOLAR ENERGY↗
DOE OSTI2014

Spectroradiometric monitoring for open outdoor culturing of algae and cyanobacteria

We assess the measurement of hyperspectral reflectance for the outdoor monitoring of green algae and cyanobacteria cultures with a multi-channel, fiber-coupled spectroradiometer. Reflectance data acquired over a four-week period are interpreted via numerical inversion of a reflectance model, in which the above-water reflectance is expressed as a quadratic function of the single backscattering albedo, dependent on the absorption and backscatter coefficients. The absorption coefficient is treated as the sum of component spectra consisting of the cultured species (green algae or cyanobacteria), dissolved organic matter, and water (including the temperature dependence of the water absorption spectrum). The backscatter coefficient is approximated as the scaled Hilbert transform of the culture absorption spectrum with a wavelength-independent vertical offset. Additional terms in the reflectance model account for the pigment fluorescence features and the water surface reflection of sunlight and skylight. For both the green algae and cyanobacteria, the wavelength-independent vertical offset of the backscatter coefficient is found to scale linearly with daily dry weight measurements, providing the capability for a non-sampling measurement of biomass in outdoor ponds. Other fitting parameters in the reflectance model are compared to auxiliary measurements and physics-based calculations. The magnitudes of the sunlight and skylight water-surface contributions derived from the reflectance model compare favorably with Fresnel reflectance calculations, while the reflectance-derived quantum efficiency of Chl-a fluorescence is found to be in agreement with literature values. To conlclude, the water temperature derived from the reflectance model exhibits excellent agreement with thermocouple measurements during the morning hours and highlights significantly elevated temperatures in the afternoon hours.

47 OTHER INSTRUMENTATION↗
DOE OSTI2019

GaAs/silicon PVMirror tandem photovoltaic mini‐module with 29.6% efficiency with respect to the outdoor global irradiance

Abstract Balance‐of‐system costs now dominate the installed cost of photovoltaic systems, causing the annually averaged module efficiency to become a primary system cost driver. The resulting continued push towards higher module efficiencies, coupled with the dominance of single‐axis tracking in the utility‐scale PV market, may create an opportunity for a low‐concentration tandem module technology. Here, we demonstrate such a tandem, using the “PVMirror” concept, on the mini‐module scale. The tandem couples a (concentrating) silicon PVMirror having an aperture area of 156.25 cm 2 with a gallium arsenide receiver to achieve 29.6% efficiency with respect to the outdoor global irradiance. Unlike most concentrating technologies, the silicon PVMirror collects some of the diffuse light, but the tandem would nevertheless achieve 31% efficiency in the absence of diffuse light, as in a laboratory measurement. The same tandem technology can be implemented with a wide‐bandgap thin‐film PVMirror and silicon receiver—a potentially cost‐competitive combination—when efficient wide‐bandgap cells have been developed.

Yu, Zhengshan J.↗
DOE OSTI2019

Timing is everything: diel metabolic and physiological changes in the diatom Cyclotella cryptica grown in simulated outdoor conditions

Microalgal cultures grown on a light-dark cycle experience diel patterns in metabolic and physiological processes, including cell cycle synchronization, but the implications for productivity in terms of biomass and commerciallyappealing molecules are not commonly appreciated. Despite a long history of diel response studies, only recently have photobioreactor technology advances enabled the use of sinusoidal light and temperature to more accurately mimic outdoor conditions. The present study investigates cell cycle progression and dynamic changes in biomass, triacylglycerol (TAG), and photosynthetic pigments on a 24-hour scale in the diatom Cyclotella cryptica grown using a sinusoidal light and temperature regime. Cell division synchronized to occur predominantly in the middle of the light period and biomass started to increase several hours earlier, as the cells prepared to divide. TAG levels increased during the day and decreased at night, with a mid-day dip corresponding to the time when lipid needs for cell divisionassociated membrane biosynthesis would be high. For the first time, photosynthetic pigment dynamics data, obtained with higher temporal resolution than previously reported for microalgae, was overlaid with cell cycle progression, indicating that while some photosynthetic pigments respond primarily to light, others are influenced by the cell cycle. Another novel observation was that the abundance of most photosynthetic pigments also fluctuated substantially on a rapid time scale during dawn, dusk, and the beginning of the dark period. Additionally, the results indicate that in a synchronized culture, potential product yields change substantially throughout the day. This may inform harvest timing to significantly increase yield.

microalgae, biofuels, Cell Lipids↗
DOE OSTI2016

International Outdoor Experiments and Models for Outdoor Radiological Dispersal Devices

With the advent of nuclear reactors and the technology to produce radioactive materials in large quantities, concern arose about the use of radioactivity as a poison in warfare, and hence, consideration was given to defensive measures (Smyth 1945). Approximately forty years later, the interest in the environmental- and health effects caused by a deliberate dispersal was renewed, but this time, from the perspective of a malevolent act of radiological terrorism in an urban area. For many years there has been international collaboration in scientific research to understand the range of effects that might result from a device that could be constructed by a sub-national group. In this paper, scientists from government laboratories in Australia, Canada, the United Kingdom, and the United States collectively have conducted a myriad of experiments to understand and detail the phenomenology of an explosive radiological dispersal device.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗