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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2011

Unknown Input and Sensor Fault Estimation Using Sliding-Mode Observers

Sliding-mode observers are used to construct unknown input estimators. Then, these unknown input estimators are combined with sensor fault estimation schemes into one architecture that employs two sliding-mode observers for simultaneously estimating the plant’s actuator faults (part of the unknown input) and detecting sensor faults. Closed form expressions are presented for the estimates of unknown inputs and sensor faults. A benchmark example of a controlled inverted pendulum system from the literature is utilized in the simulation study. The study shows that the observers analyzed in this paper generate good estimates of the unknown input and sensor faults signals in noisy environments for nonlinear plants.

Kalsi, Karanjit↗
DOE OSTI2017

Information Content Analysis for Selection of Optimal JWST Observing Modes for Transiting Exoplanet Atmospheres

The James Webb Space Telescope ( JWST ) is nearing its launch date of 2018, and is expected to revolutionize our knowledge of exoplanet atmospheres. In order to specifically identify which observing modes will be most useful for characterizing a diverse range of exoplanetary atmospheres, we use an information content (IC) based approach commonly used in the studies of solar system atmospheres. We develop a system based upon these IC methods to trace the instrumental and atmospheric model phase space in order to identify which observing modes are best suited for particular classes of planets, focusing on transmission spectra. Specifically, the atmospheric parameter space we cover is T = 600–1800 K, C/O = 0.55–1, [M/H] = 1–100 × Solar for an R = 1.39 R{sub J}, M = 0.59 M{sub J} planet orbiting a WASP-62-like star. We also explore the influence of a simplified opaque gray cloud on the IC. We find that obtaining broader wavelength coverage over multiple modes is preferred over higher precision in a single mode given the same amount of observing time. Regardless of the planet temperature and composition, the best modes for constraining terminator temperatures, C/O ratios, and metallicity are NIRISS SOSS+NIRSpec G395. If the target’s host star is dim enough such that the NIRSpec prism is applicable, then it can be used instead of NIRISS SOSS+NIRSpec G395. Lastly, observations that use more than two modes should be carefully analyzed because sometimes the addition of a third mode results in no gain of information. In these cases, higher precision in the original two modes is favorable.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Kepler-93b: A terrestrial world measured to within 120 km, and a test case for a new Spitzer observing mode

We present the characterization of the Kepler-93 exoplanetary system, based on three years of photometry gathered by the Kepler spacecraft. The duration and cadence of the Kepler observations, in tandem with the brightness of the star, enable unusually precise constraints on both the planet and its host. We conduct an asteroseismic analysis of the Kepler photometry and conclude that the star has an average density of 1.652 ± 0.006 g cm{sup –3}. Its mass of 0.911 ± 0.033 M{sub ☉} renders it one of the lowest-mass subjects of asteroseismic study. An analysis of the transit signature produced by the planet Kepler-93b, which appears with a period of 4.72673978 ± 9.7 × 10{sup –7} days, returns a consistent but less precise measurement of the stellar density, 1.72{sub −0.28}{sup +0.02} g cm{sup –3}. The agreement of these two values lends credence to the planetary interpretation of the transit signal. The achromatic transit depth, as compared between Kepler and the Spitzer Space Telescope, supports the same conclusion. We observed seven transits of Kepler-93b with Spitzer, three of which we conducted in a new observing mode. The pointing strategy we employed to gather this subset of observations halved our uncertainty on the transit radius ratio R{sub P} /R{sub *}. We find, after folding together the stellar radius measurement of 0.919 ± 0.011 R{sub ☉} with the transit depth, a best-fit value for the planetary radius of 1.481 ± 0.019 R{sub ⊕}. The uncertainty of 120 km on our measurement of the planet's size currently renders it one of the most precisely measured planetary radii outside of the solar system. Together with the radius, the planetary mass of 3.8 ± 1.5 M{sub ⊕} corresponds to a rocky density of 6.3 ± 2.6 g cm{sup –3}. After applying a prior on the plausible maximum densities of similarly sized worlds between 1 and 1.5 R{sub ⊕}, we find that Kepler-93b possesses an average density within this group.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2010

Preferential selection of isomer binding from chiral mixtures: alternate binding modes observed for the E and Z isomers of a series of 5-substituted 2,4-diaminofuro[2,3-d]pyrimidines as ternary complexes with NADPH and human dihydrofolate reductase

The structures of six chirally mixed E/Z-isomers of 5-substituted 2,4-diaminofuro[2,3-d]pyrimidines reveals only one isomer is bound in the active site of human DHFR. The configuration of all but one C9-analogue is observed as the E-isomer. The crystal structures of six human dihydrofolate reductase (hDHFR) ternary complexes with NADPH and a series of mixed E/Z isomers of 5-substituted 5-[2-(2-methoxyphenyl)-prop-1-en-1-yl]furo[2,3-d]pyrimidine-2,4-diamines substituted at the C9 position with propyl, isopropyl, cyclopropyl, butyl, isobutyl and sec-butyl (E2–E7, Z3) were determined and the results were compared with the resolved E and Z isomers of the C9-methyl parent compound. The configuration of all of the inhibitors, save one, was observed as the E isomer, in which the binding of the furopyrimidine ring is flipped such that the 4-amino group binds in the 4-oxo site of folate. The Z3 isomer of the C9-isopropyl analog has the normal 2,4-diaminopyrimidine ring binding geometry, with the furo oxygen near Glu30 and the 4-amino group interacting near the cofactor nicotinamide ring. Electron-density maps for these structures revealed the binding of only one isomer to hDHFR, despite the fact that chiral mixtures (E:Z ratios of 2:1, 3:1 and 3:2) of the inhibitors were incubated with hDHFR prior to crystallization. Superposition of the hDHFR complexes with E2 and Z3 shows that the 2′-methoxyphenyl ring of E2 is perpendicular to that of Z3. The most potent inhibitor in this series is the isopropyl analog Z3 and the least potent is the isobutyl analog E6, consistent with data that show that the Z isomer makes the most favorable interactions with the active-site residues. The isobutyl moiety of E6 is observed in two orientations and the resultant steric crowding of the E6 analog is consistent with its weaker activity. The alternative binding modes observed for the furopyrimidine ring in these E/Z isomers suggest that new templates can be designed to probe these binding regions of the DHFR active site.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

Using Monte Carlo ray tracing simulations to model the quantum harmonic oscillator modes observed in uranium nitride

Recently an extended series of equally spaced vibrational modes was observed in uranium nitride (UN) by performing neutron spectroscopy measurements using the ARCS and SEQUOIA time-of- flight chopper spectrometers [A.A. Aczel et al, Nature Communications 3, 1124 (2012)]. These modes are well described by 3D isotropic quantum harmonic oscillator (QHO) behavior of the nitrogen atoms, but there are additional contributions to the scattering that complicate the measured response. In an effort to better characterize the observed neutron scattering spectrum of UN, we have performed Monte Carlo ray tracing simulations of the ARCS and SEQUOIA experiments with various sample kernels, accounting for the nitrogen QHO scattering, contributions that arise from the acoustic portion of the partial phonon density of states (PDOS), and multiple scattering. These simulations demonstrate that the U and N motions can be treated independently, and show that multiple scattering contributes an approximate Q-independent background to the spectrum at the oscillator mode positions. Temperature dependent studies of the lowest few oscillator modes have also been made with SEQUOIA, and our simulations indicate that the T-dependence of the scattering from these modes is strongly influenced by the uranium lattice.

Lin, J. Y. Y.↗
DOE OSTI2021

Commissioning the H i Observing Mode of the Beam Former for the Cryogenically Cooled Focal L-band Array for the GBT (FLAG)

We present the results of commissioning observations for a new digital beam-forming back end for the Focal plane L-band Array for the Robert C. Byrd Green Bank Telescope (FLAG), a cryogenically cooled Phased Array Feed (PAF) with the lowest measured T {sub sys}/η of any PAF outfitted on a radio telescope to date. We describe the custom software used to apply beam-forming weights to the raw element covariances to create research-quality spectral-line images for the new fine-channel mode, study the stability of the beam weights over time, characterize FLAG’s sensitivity over a frequency range of 150 MHz, and compare the measured noise properties and observed distribution of neutral hydrogen emission from several extragalactic and Galactic sources with data obtained with the current single-pixel L-band receiver. These commissioning runs establish FLAG as the preeminent PAF receiver currently available for spectral-line observations on the world’s major radio telescopes.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2019

The impact of neglecting ice phase on cloud optical depth retrievals from AERONET cloud mode observations

Clouds present many challenges to climate modelling. To develop and verify the parameterisations needed to allow climate models to represent cloud structure and processes, there is a need for high-quality observations of cloud optical depth from locations around the world.Retrievals of cloud optical depth are obtainable from radiances measured by Aerosol Robotic Network (AERONET) radiometers in “cloud mode” using a two-wavelength retrieval method. However, the method is unable to detect cloud phase, and hence assumes that all of the cloud in a profile is liquid.This assumption has the potential to introduce errors into long-term statistics of retrieved optical depth for clouds that also contain ice.Using a set of idealised cloud profiles we find that, for optical depths above 20, the fractional error in retrieved optical depth is a linear function of the fraction of the optical depth that is due to the presence ofice cloud (“ice fraction”). Clouds that are entirely ice have positive errors with magnitudes of the order of 55 % to 70 %. We derive a simple linear equation that can be used as a correction at AERONET sites where ice fraction can be independently estimated. Using this linear equation, we estimate the magnitude of the error for a set of cloud profiles from five sites of the Atmospheric Radiation Measurement programme. The dataset contains separate retrievals of ice and liquid retrievals; hence ice fraction can be estimated. The magnitude of the error at each location was related to the relative frequencies of occurrence in thick frontal cloud at the mid-latitude sites and of deep convection at the tropical sites – that is, of deep cloud containing both ice and liquid particles. The long-term mean optical depth error at the five locations spans the range 2–4, which we show to be small enough to allow calculation of top-of-atmosphere flux to within 10 % and surface flux to about 15 %.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Lightning Characteristics Associated With Storm Modes Observed During RELAMPAGO

Global satellite studies show a maximum in deep convection and lightning downstream of the Andes in subtropical South America. The Remote sensing of Electrification, Lightning, And Mesoscale/microscale Processes with Adaptive Ground Observations (RELAMPAGO) field campaign was designed to investigate the physical processes that contribute to the rapid development of deep convection and mesoscale convective systems (MCSs) in Argentina. A lightning mapping array (LMA) was deployed to Argentina as part of RELAMPAGO to collect lightning observations from extreme storms in the region. This study combines lightning data from the LMA and the Geostationary Lightning Mapper onboard GOES-16 with 1-km gridded radar data to examine the electrical characteristics of a variety of convective storms throughout their life cycle observed during RELAMPAGO. Results from the full campaign show 48% of flashes are associated with deep convection that occurs along the eastern edge of the Sierras de Córdoba (SDC) overnight. These flashes are 65 km 2 smaller on average compared to stratiform flashes, which occur most frequently 50–100 km east of the SDC in the early morning hours, consistent with the upscale growth of MCSs off the terrain. Analysis of the 13–14 December MCS shows that sharp increases in flash rates correspond to deep and wide convective cores that have high graupel and hail mass, 35-dBZ volume, and ice water path. This work validates previous satellite studies of lightning in the region, but also provides higher spatial and temporal resolution information across the convective life cycle that has not been available in previous studies.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Asynchronous quadratic control for constrained hidden markov jump linear systems with incomplete MTPM and MOCPM

Abstract This paper investigates the quadratic optimal control problem for constrained Markov jump linear systems with incomplete mode transition probability matrix (MTPM). Considering original system mode is not accessible, observed mode is utilized for asynchronous controller design where mode observation conditional probability matrix (MOCPM), which characterizes the emission between original modes and observed modes is assumed to be partially known. An LMI optimization problem is formulated for such constrained hidden Markov jump linear systems with incomplete MTPM and MOCPM. Based on this, a feasible state-feedback controller can be designed with the application of free-connection weighting matrix method. The desired controller, dependent on observed mode, is an asynchronous one which can minimize the upper bound of quadratic cost and satisfy restrictions on system states and control variables. Furthermore, clustering observation where observed modes recast into several clusters, is explored for simplifying the computational complexity. Numerical examples are provided to illustrate the validity.

Zhu, Jin↗
DOE OSTI2018

Lattice dynamics and phase transition in CrI 3 single crystals

Here, the vibrational properties of CrI 3 single crystals were investigated using Raman spectroscopy and were analyzed with respect to the changes of the crystal structure. All but one mode are observed for both the low-temperature R¯3 and the high-temperature C2/m phase. For all observed modes the energies and symmetries are in good agreement with DFT calculations. The symmetry of a single layer was identified as p¯31/m . In contrast to previous studies we observe the transition from the R¯3 to the C2/m phase at 180 K and find no evidence for coexistence of both phases over a wide temperature range.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

High-pressure behavior of a linear chain alkane, tricosane

Exploring the behavior of hydrocarbon under pressure is important for understanding its role in planetary sciences and also for exploring novel organic chemistry. In this study, we explored the high-pressure behavior of a linear-chain hydrocarbon, tricosane (C 23 H 48 ), using Raman spectroscopy. We compressed tricosane up to 23 GPa and did not find any evidence for pressure-induced amorphization within the conditions explored in this study. Upon compression, we observe new modes in the low energy region 100–300 cm -1 . In order to understand the appearance of these new modes at high pressures, we used complementary ab initio calculations and explored the effect of chain configurations (linear and bent) on the predicted Raman spectra. We find that these new modes observed at higher pressures are better explained by bent configuration of tricosane chains. Thus, based on high-pressure Raman spectra, it is very likely that a linear chain of tricosane is bent under pressure, i.e., it undergoes a pressure-induced trans-gauche transformation. Furthermore, it is likely that such bent regions (i.e., kinks) will act as sites along which large chain hydrocarbons could dissociate into smaller chain lengths at extreme conditions relevant to the interiors of Jovian planets.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2013

DESIGN AND MEASUREMENT OF THE STOKES POLARIMETER FOR THE COSMO K-CORONAGRAPH

We present the Stokes polarimeter for the new Coronal Solar Magnetism Observatory K-coronagraph. The polarimeter can be used in two modes. In observation mode, it is sensitive to linear polarization only and operates as a ''Stokes definition'' polarimeter. In the ideal case, such a modulator isolates a particular Stokes parameter in each modulation state. For calibrations, the polarimeter can diagnose the full Stokes vector. We present here the design process of the polarimeter, analyze its tolerances with a Monte Carlo method, develop a way to align the individual elements, and measure and evaluate its performance in both modes.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2019

Lattice dynamics and phase transitions in Fe 3 - x GeTe 2

We present Raman spectroscopy measurements of the van der Waals bonded ferromagnet Fe 3-x GeTe 2 , together with lattice dynamics. Four out of eight Raman active modes are observed and assigned, in agreement with numerical calculations. The energies and linewidths of the observed modes display an unconventional temperature dependence at about 150 and 220 K, followed by the nonmonotonic evolution of the Raman continuum. Whereas the former can be related to the magnetic phase transition, the origin of the latter anomaly remains an open question.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗