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At least 19 records

Efficient Measurement of Length Distribution of 1D Nanoparticles in Solution via Optical Polarimetry

The efficient measurement of the length distribution of nanotubes, nanowires, and other one-dimensional (1D) nanoparticles in solution is important to enable their incorporation into materials and devices and to optimize their processing for properties of interest, such as thermal/electrical conductivity or mechanical strength, in suspensions and composites. We report an electric-field (E-field)-assisted optical-polarimetry technique to measure the length distribution of ensembles of high-aspect-ratio particles in dilute suspension. The degree of alignment of polarizable 1D particles suspended in a fluid under Brownian motion explicitly depends on the E-field strength and the particle length. We show that it is possible to extract the length distribution of 1D nanoparticles suspended in an insulating fluid by applying a range of E-fields and using optical polarimetry to measure the corresponding alignment order parameter. Notably, the method is relatively insensitive to the diameter of the 1D particles, which can be poorly known or vary within a sample. The technique is validated with silver nanowires and carbon nanotubes of known lengths, as well as polymer-depletion-length-separated single-wall carbon nanotube samples with length distributions independently measured with analytical ultracentrifugation. Finally, we demonstrate the ability of the optical-polarimetry technique to quantify changes in the length distribution of ultranarrow, sub-nanometer-diameter single-wall carbon nanotubes under different types and durations of ultrasonication. Within its range of applicability (polarizable 1D nanoparticles in the 0.5 to 15 μm length range, constrained by the voltage stability of the media and the suspended particles), the E-field-assisted optical-polarimetry method is a particularly efficient and accurate method to measure the length distribution of nanowires and nanotubes in suspension.

1D nanoparticles↗

Optical polarimetry: Instrumentation and applications; Proceedings of the Seminar, San Diego, Calif., August 23, 24, 1977

Instrumentation used in optical polarimetry is discussed with reference to high-resolution spectropolarimetry, an orbiter cloud photopolarimeter, X-ray polarimeters, and the design of a self-nulling ellipsometer. Consideration is given to surface and thin-film ellipsometry noting studies of electrochemical surface layers, surface anisotropy, polish layers on infrared window materials, and anodic films. Papers on biological, chemical, and physical polarimetry are presented including birefringence in biological materials, vibrational optical activity, and the optical determination of the thermodynamic phase diagram of a metamagnet. Remote sensing is discussed in terms of polarization imagery, the optical polarimetry of particulate surfaces, and techniques and applications of elliptical polarimetry in astronomy and atmospheric studies.

Azzam, R. M. A.↗

Observation of a Goldstone mode in the broken helix by time-resolved optical polarimetry

Magnets with isotropic easy-plane symmetry host Goldstone modes that can be leveraged for efficient spin transport. Here, we present a time-resolved optical polarimetry technique that allows us to detect and characterize such low-frequency modes, and use it to observe the Goldstone mode in the multi-Q broken helix phase of EuIn2As2. The strength of our technique comes from the ability to distinguish between nematic and magnetization dynamics in order to yield information about the mode structure, in addition to its frequency. We find that the nearly uniform spin precession characteristic of a Goldstone mode is realized only when a small magnetic field is used to unpin the broken helix from local strain generated during crystal growth. In this regime, the mode frequency scales linearly with the applied field due to the ground state C2z symmetry of the broken helix. Our work shows how optical polarimetry can be used to study the Goldstone modes of complex magnets.

Liebman-Peláez, A↗

Optical polarimetry and thermal imaging of the disc around Beta Pictoris

The dust disk around the main-sequence A5 star Beta Pic is characterized on the basis of recently obtained data. Optical polarimetry indicates that the disk has polarization of about 15 percent and polarization vectors normal to the scattering plane, indicating that the features observed are indeed a dust disk made visible by scattering. Thermal images of the central 13-arcsec-diameter region, obtained at 10 and 20 microns by Telesco et al. (1988) using the NASA Marshall 20-pixel bolometer array, suggest that the dust grains in the disk have a mean diameter of 1 micron or smaller. Also discussed are (1) unsuccessful searches for other nearby stars with disks and (2) the potential value of Hubble Space Telescope images for understanding the structure of Beta Pic.

Wolstencroft, R. D.↗

Quantitative Nonlinear Optical Polarimetry with High Spatial Resolution

Nonlinear optical microscopy such as in the optical second-harmonic generation (SHG) modality has become a popular tool today for probing materials in the physical and biological sciences. While imaging and spectroscopy are widely used in the microscopy mode, nonlinear polarimetry, which can shed light on materials’ symmetry and microstructure, is relatively underdeveloped. This is partly because quantitative analytical modeling of the optical SHG response for anisotropic crystals and films largely assumes low-numerical aperture (NA) focusing of light, where the plane-wave approximation is sufficient. Tight focusing provides unique benefits in revealing out-of-plane polarization responses, which cannot be detected by near-plane-wave illumination at normal incidence. Here, we outline a method for quantitatively analyzing SHG polarimetry measurements obtained under high-NA focusing within a microscope geometry. Experiments and simulations of a variety of standard samples, from single crystals to thin films, are in good agreement, including measured and simulated spatial SHG maps of ferroelectric domains. A solution to the inverse problem is demonstrated, where the spatial distribution of an SHG tensor with unknown tensor coefficient magnitudes is determined by experimentally measured polarimetry. The ability to extract the out-of-plane component of the nonlinear polarization in normal incidence is demonstrated, which can be valuable for high-resolution polarimetry of 2D materials, thin films, heterostructures, and uniaxial crystals with a strong out-of-plane response.

36 MATERIALS SCIENCE↗

Optical polarimetry of PKS 2155 - 304 and constraints on accretion disk models for BL Lacertae objects

Optical broad-band polarimetry and photometry of the BL Lacertae object PKS 2155 - 304 during late 1990 are presented. Variability in both flux and linear polarization was moderate during this period. The optical polarization ranged from 2 to 7 percent while photometric variations were within 0.2 mag (V = 13.2-13.4). Accurate multicolor measurements were made to study any wavelength dependence of the polarization with an eye to using these data to test the model of Wandel and Urry (1991) which proposes that the UV to soft X-ray continuum of this object arises from an accretion disk. Wavelength-dependent polarization (WDP) is observed in PKS 2155 - 304. However, the polarization is always seen to decrease with wavelength when WDP is observed. This is opposite to the expected sense of WDP if the UV continuum is dominated by an accretion disk.

Smith, Paul S.↗

Optical polarimetry and photometry of X-ray selected BL Lacertae objects

We present the data from 3 years of monitoring the optical polarization and apparent brightness of 37 X-ray-selected BL Lacertae objects. The monitored objects include a complete sample drawn from the Einstein Extended Medium Sensitivity Survey. We confirm the BL Lac identifications for 15 of these 22 objects. We include descriptions of the objects and samples in our monitoring program and of the existing complete samples of BL Lac objects, highly polarized quasars, optically violent variable quasars, and blazars.

Jannuzi, Buell T.↗

Multicolor optical polarimetry of reddened stars in the small Magellanic cloud

First results of an on-going program to determine the wavelength dependence of the interstellar optical polarization of reddened stars in the Small Magellanic Cloud (SMC) are presented. IUE observations of reddened stars in the SMC (Bouchet et al. 1985) generally show marked differences in the extinction law as compared to both the Galaxy and the Large Megallanic Cloud. The aim here is to determine the wavelength dependence of the optical linear polarization in the direction of several such stars in the SMC in order to further constrain the dust composition and size distribution in that galaxy.

Magalhaes, Antonio M.↗

Optical polarimetry of asteroids and laboratory samples

Interpretations of astronomical polarization data for more than 100 minor planets are summarized with reference to laboratory data for lunar, meteoritic, and terrestrial samples. All observed asteroids, including objects only a few kilometers in diameter, have microscopically intricate surfaces. Detailed comparisons between laboratory measurements of basaltic achondrites and telescopic results for Vesta show that its surface is particulate with a broad range of particle sizes, including a component of fine (1-5 micron) dust. The surface soils have not, however, undergone marked optical alterations as is the case for the lunar fines. For albedos greater than about 0.06, the albedo and hence the diameter can be determined with some reliability from the slope of the ascending branch of the polarization-phase curve. Many minor planets have surfaces that are remarkably uniform in albedo and texture on a hemispheric scale. A notable exception is 4 Vesta, which shows about ten percent albedo variegation between hemispheres.

Dollfus, A.↗

Optical polarimetry of Comet West 1976 VI

Four narrowband filters covering the 440-850 nm wavelengths were used to measure the polarization of the continuum of Comet West 1976 VI. Postperihelion observations indicated wavelength-independent linear polarization in all of the three measurements made, in agreement with other polarization measurements of the comet from the visible to the near-infrared but in contrast with the general tendency in comets toward polarization increase with wavelength. No circular polarization was detected, and it is suggested by (1) the magnitude of polarization as a function of scattering angle, (2) wavelength independence, and (3) infrared and optical photometric properties, that dirty silicates with radii approaching 5 microns may be responsible for the phenomena observed.

Michalsky, J. J.↗

Optical polarimetry of particulate surfaces

Reflection polarimetry is a remote-sensing tool sensitive to the refractive index and microtexture of solid surfaces. Mechanisms producing linear polarization within a rough, porous, or particulate surface are discussed, and laboratory techniques for precise measurements are described in some detail. Polarimetry of atmosphereless solar-system bodies provides valuable indications of albedo for objects too small and distant for direct diameter determinations, and reveals that even quite small asteroids and satellites have particulate surfaces

Zellner, B.↗

New results from optical polarimetry of Saturn's rings

Linear polarimetry of Saturn's rings, obtained through the period of the 1979 opposition, is presented. The polarisation clearly correlates in direction with the plane containing the Sun, planet and Earth, but not the ring plane. The results are consistent with local scattering on the surface of individual ring bodies, covered with frost

Johnson, P. E.↗

Surface texture of Vesta from optical polarimetry

Polarimetric, photometric, and reflective spectroscopic properties of asteroid 4 Vesta are simulated in the laboratory by a preparation of eucrite Bereba consisting of a broad mixture of particle sizes (mainly greater than 50-micron) mixed and partially coated with particles of size 10 microns and less. Coarse grains are necessary for producing the same albedo and a very fine dust coating is necessary for producing the same polarization inversion angle as observed for Vesta. There are less small grains and fine dust in this sample than in lunar soils. Photometrically, if coating a sphere, this sample shows a constant brightness on the sunward half of the observed hemisphere, the brightness being given on the other half by the Minnaert reciprocity principle. With such a photometric behavior, the global geometric albedo and the sub-earth point geometric albedo differ by no more than 5%. The microscopic phase coefficient is 0.021 magnitude per degree for the sample; the larger value, 0.025, observed telescopically for Vesta, indicates that large-scale roughness is present on this asteroid.

Le Bertre, T.↗

X-Ray Absorbed, Broad-Lined, Red AGN and the Cosmic X-ray Background

This award represents the second phase of an X-ray study of QSOs that are heavily obscured in the optical/near-IR. An earlier survey revealed that these active galactic nuclei (AGN) are also typically strongly absorbed at high photon energies, but the enhanced sensitivity of XMM-Newton provided for the first time the opportunity to measure the spectral indices of individual sources and to test the possibility that obscured AGN are responsible for a substantial portion of the cosmic X-ray background (CXRB). The new observations confirm and greatly extend the earlier results. Substantial intervening absorbing material is detected for 3 of the sources, and 2 additional targets show hard power-law continua. In addition, soft X-ray excesses are detected in 3 of sources, indicating the presence of extended regions of ionized gas. This component is-particularly well-defined in the Type 1 source 2MASS2344+1221, allowing analysis and modeling at a level of detail unusual for such distant sources. An important finding that parallels conclusions from optical polarimetry is the lack of dependence of absorption on optical spectral class (Type 1 or 2). The combination of strong polarization and X-ray absorption in sources that show strong, broad emission lines indicates either a very small (nuclear) absorber or a favored viewing angle which allows the X-ray source to be covered but the surrounding broad emission-line region to be largely exposed. The observed spectral also indicate that obscured AGN of both Type 1 and 2 contribute significantly to the CXRB at higher X-ray energies.

Schmidt, Gary D.↗

Intensive optical monitoring of the BL Lacertae object PKS 2155-304

Ground-based optical polarimetry and photometry of the BL Lac object PKS 2155-304 conducted just before and during the IUE monitoring program from November 1 to 19, 1991 are presented. The optical observations reveal strong daily variability in both flux and linear polarization. Broadband UBVRI photometry shows that the slope of the optical continuum remained relatively constant even though the object brightened by nearly a magnitude. PKS 2155-304 was near its historical photometric maximum during the last two weeks of November. The degree of polarization varied between 2 and 8 percent, and fluctuations of 2-3 percent were observed in a day. Daily variations in the position angle of the polarization were observed to be as high as 25 percent, though the position angle was observed to lie between 105 and 140 deg throughout the monitoring program. Some of the implications that these optical data have on models of the source of the continuum emission in PKS 2155-304 are discussed.

Smith, Paul S.↗

The dusty, luminous broad-line radio galaxy 3C 109

In the present optical polarimetry and IR photometry for the broad line radio galaxy 3C 109, the absence of variability, in conjunction with a polarization in H-alpha that is identical to that of the adjacent continuum, suggests that the strong polarization of this galaxy is due to extinction by aligned dust grains. This is the process which gives rise to interstellar polarization within the Galaxy. The energy output of 3C 109, from the optical to 20 microns, exceeds by a factor of 2-4 that of the Seyfert 1 galaxy Markarian 231. These observations, together with recent polarimetry of other broad line radio galaxies, indicate that their broad line regions are more heavily reddened than those of either the Seyfert 1 galaxies or quasars. Evidence for a gradual decrease in dust content with increasing source luminosity is discussed.

Rudy, R. J.↗

Spin-carrier coupling induced ferromagnetism and giant resistivity peak in EuCd 2 P 2

EuCd 2 P 2 is notable for its unconventional transport: upon cooling the metallic resistivity changes slope and begins to increase, ultimately 100-fold, before returning to its metallic value. Surprisingly, this giant peak occurs at 18 K, well above the Néel temperature (T N ) of 11.5 K. Here, using a suite of sensitive probes of magnetism, including resonant x-ray scattering and magneto-optical polarimetry, we have discovered that ferromagnetic order onsets above T N in the temperature range of the resistivity peak. The observation of inverted hysteresis in this regime shows that ferromagnetism is promoted by coupling of localized spins and itinerant carriers. The resulting carrier localization is confirmed by optical conductivity measurements.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗