Materials Data on OsCl4O by Materials Project
OsOCl4 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four OsOCl4 clusters. Os6+ is bonded in a 1-coordinate geometry to one O2- and four Cl1- atoms. The Os–O bond length is 1.68 Å. There are three shorter (2.27 Å) and one longer (2.28 Å) Os–Cl bond lengths. O2- is bonded in a single-bond geometry to one Os6+ atom. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Os6+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Os6+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one Os6+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Os6+ atom.
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