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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on PuP by Materials Project

PPu is Halite, Rock Salt structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Pu3+ is bonded to six equivalent P3- atoms to form a mixture of corner and edge-sharing PuP6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Pu–P bond lengths are 2.83 Å. P3- is bonded to six equivalent Pu3+ atoms to form a mixture of corner and edge-sharing PPu6 octahedra. The corner-sharing octahedral tilt angles are 0°.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on PuP3 by Materials Project

PuP3 crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Pu7+ is bonded in a 12-coordinate geometry to twelve equivalent P+2.33- atoms. There are six shorter (2.80 Å) and six longer (2.99 Å) Pu–P bond lengths. P+2.33- is bonded in a 6-coordinate geometry to four equivalent Pu7+ and two equivalent P+2.33- atoms. Both P–P bond lengths are 2.30 Å.

36 MATERIALS SCIENCE↗